• Proceedings of the Korean Fiber Society Conference
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• 1994.10a
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• pp.141-141
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• 1994

• Polymer(Korea)
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• v.35 no.2
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• pp.176-182
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• 2011

Liquid crystalline aromatic polyesters (LCPs) are representative examples of thermotropic liquid crystalline polymers, whose structure-property relationships have been the subject of many researches. In this study, we synthesized organo-soluble liquid crystalline aromatic polyesters, and their composites with acetylene-terminated thermoset resins were prepared and characterized. Soluble LCPs were synthesized by employing 6-hydroxy-2-naphthoic acid, terephthalic acid, isophthalic acid, and 4-aminophenol as monomers via condensation polymerization based on transesterfication and transamidation. Acetylene-terminated thermoset resins were synthesized by the reaction of 4-ethynylaniline with terephthaloyl dichloride, isophthaloyl dichloride or 4,4'-biphenyldicarbonyl dichloride. We prepared the soluble LCP/thermoset composites by solution blending followed by thermal treatment. The thermal stability, thermal expansion coefficient, and dielectric properties of the composite were studied.

• Journal of Adhesion and Interface
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• v.5 no.1
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• pp.29-35
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• 2004

We have prepared polyster/nanQhybridized polyimide films in the range of 1~9 wt% of organophilic synthetic layered silicate (STN). Firstly, poly(amic acid)/STN nanocomposite solutions were prepared via solution blending method in DMAc or THF/MeOH solution, and then cast on the polyester film followed by imidization reaction, thermal and chemical method repestively. XRD and TEM experiment showed that the STN was fully exfoliated through the polyimide matrix. Surface morphologies of nanohybridized polyimide films were characterized by AFM and thermal, mechanical properties were also confirmed by TGA, DMA and UTM each. And also, the water vapor permeabilities highly depended on the content of STN. The sample from chemical imidization route and THF/MeOH solvent system showed better water vapor barrier properties than thermal one and DMAc system.

• Proceedings of the Korean Fiber Society Conference
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• 1998.04a
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• pp.350-353
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• 1998

최근 폴리에스테르(PET) 섬유는 각각의 분야에서 다양한 용도로 그에 적당한 섬도를 가진 것이 사용되며, 특히 극세섬도 PET 섬유의 제조시 폴리머의 개질, 방사, 연사, 제직, 염색가공 등 각각의 분야의 기술을 복합함에 따라 신감성, 고부가가치를 부여하는 신합섬이 등장하여 최근 수년간 차별화 상품으로서 이용되어 왔다.(중략)

• Journal of the Korea Organic Resources Recycling Association
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• v.13 no.3
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• pp.97-104
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• 2005

In this study, the change of water content, pH, and combustion weight on the decomposition of poly ester vinyl and high density poly ethylene were examined. The poly ester vinyl was degraded by microorganism in food wastes for 30 days, while high density poly ethylene vinyl was not degraded. Also, the poly ester vinyl was rapidly degraded after the 10 days of operation and its weight was decreased. In the combustion reaction between $300^{\circ}C$ and $600^{\circ}C$, complete combustion was performed. Due to the degradation of poly ester vinyl by microorganism in food waste, the pH was increased from 4.26 to 7.6. During of 60 days operation, poly ester vinyl was degraded over 90%.

• Polymer(Korea)
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• v.29 no.6
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• pp.575-580
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• 2005

The hydroxy terminated aliphatic hyperbranched polyesters having different generations were synthesized by using melt polycondensation procedure. Then, the terminal groups of hyperbranched polyesters were modified by using acryloyl chloride and characterized by $\^{1}H$-NMR and GPC techniques. As a result of the modification of terminal groups for hyperbranched polyesters, the phase of the polymers were changed from sticky solid to high viscous liquid indicating that the glass transition temperatures of modified hyperbranched polyesters were lower than the original one. The thermal stabilities of hydroxy terminated hyperbranched polyesters were higher than those of terminal group-modified polymers.

• Korean Chemical Engineering Research
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• v.48 no.5
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• pp.638-642
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• 2010

In order to develope anti - static polyester resin which may be employed to dangerous circumstance with high organic vapor content, the effect of anti - static agents on the surface resistance and tensile strength of polyester resin were studied. Three organic anti - static agents and a conductive carbon black were adapted and used separately and together. The effects of anti - static agents, their contents, and synergic effect of anti - static agents were experimentally examined. Surface resistance and tensile strength of the polyester resin were decreased with the content of anti - static agents, and polyester resin with low surface resistance and relatively high tensile strength could be prepared by synergic effect of organic anti - static agent and carbon black.

• Journal of the Korean Chemical Society
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• v.26 no.3
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• pp.188-193
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• 1982

Four new thermotropic copolyesters were prepared and their liquid crystal properties were investigated by differential scanning calorimetry and on a hot-stage of a polarizing microscope. Three copolyesters had same mesogenic unit, triad aromatic ester structure, interconnected through a random combination of either odd-even, or odd-odd, or even-even number of methylene groups in the polymethylene flexible spacers. Another random copolyester consisted of mesogenic units of 1 : 1 mixture of central methyl-and bromohydroquinone moieties with two flanking p-oxybenzoate units connected by decamethylene spacer. All of the polyesters formed nematic liquid crystal phase upon melting. The transitions for melting and nematic ${\to}$ isotropic transformations could be reversibly observed by DSC as well as by microscopic study. The thermodynamic properties for their liquid crystal ${\to}$ isotropic phase transitions were discussed in relation to their chemical structures.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.11a
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• pp.59-59
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• 2011

초극세 섬유는 종래의 섬유와 비교해서 매우 가늘고 큰 표면적을 지니므로 섬유고분자 고유의 성질 이외에 활성이 높은 섬유표면이 가지는 특수한 성질의 기여가 매우 커지게 되므로 흡착특성이나 접착특성 등 특수한 성질의 기여가 매우 커지게 된다. 초극세 섬유를 제조하는 방법은 통상적으로 멜트블로운법, 플래쉬법, 전기방사법 그리고 해도형 복합방사법의 4가지로 분류된다. 그중 해도형 복합방사법은 가장 안정적인 방법으로 PET기준으로 0.01데니어 급까지 상용화가 되어 있다. 해도형 복합섬유의 개발에 있어서 중요한 것 중에 하나가 해성분 폴리머의 용출기술이다. 초극세화를 목적으로 해성분인 변성폴리에스테르를 제거시키기 위해서 실시되는 알칼리(NaOH)에 의한 감량공정은 그 처리조건에 따라서 초극세사로 잔존해야하는 도성분의 정규 폴리에스테르까지 손상시킬 수 있기 때문에 균일한 용출조건의 확립은 매우 중요하다. 그러나 초극세화가 진행될수록 알칼 리가 섬유 내부까지 균일하게 침투하기가 어려우며 감량된 도성분도 비표면적이 증가하기 때문에, 해성분의 균일한 용출 및 감량을 위한 안정적인 조건을 선정하기가 어렵다. 본 연구에서는 코오롱FM에서 새롭게 개발한 800nm급 해도형 초극세사 제품의 감량특성에 대하여 고찰함으로써 제품화에 필요한 요소 기술의 기초를 마련하고자 한다. 유기산을 이용한 전처리가 해도형 초극세 폴리에스테르 섬유의 해성분 감량 특성에 미치는 영향에 대하여 조사하고, 알칼리 감량시 NaOH의 농도, 처리시간 및 처리온도별 감량특성에 대하여 고찰하였다.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2011.11a
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• pp.50-50
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• 2011

국내 섬유산업은 해외로부터의 저가 섬유제품이 대량으로 유입되는 속에서도 수출의 상당한 부분을 차지하며, 꾸준히 양에서 질로의 전환을 도모해 왔으며, 특히 최근에는 섬유 전반에 걸쳐 고부가 가치화를 지향하고 있다. 이러한 소비자의 요구에 부응하여 섬유소재에도 다양한 신개념과 이를 충족시킬 수 있는 기술이 요구되고 있으며, 그 가운데 하나의 영역을 구축해 나가고 있는 분야가 면 리플가공과 같은 표면 형태 가공이며, 최근 들어 폴리에스테르 입체(3D)가공제의 개발 및 가공 방법도 이런 흐름에 부응하여 업계에서 절실한 개발을 요구하고 있는 분야이다. 기존의 폴리에스테르 및 합성섬유의 입체 가공에 적용된 화학제품보다 성능은 우수하면서, 가공 공정이나 완성된 섬유제품에 전혀 잔존하지 않아 인체친화적(기존의 제품들은 인체에 유해한 재료이면서 가공 후 잔존함)이며, 환경적인 측면에서도 친환경을 유지하면서 새로운 폴리에스테르섬유, 좀 더 폭넓게는 열가소성인 모든 합성섬유의 입체가공이 가능한 약품의 개발 및 이를 이용한 가공방법의 개발은 매우 중요한 의의를 가지게 된다. 본 연구에서는 폴리에스테르의 3D입체 디보싱을 부여하는 합성바인더가 물에 의한 용해도를 확인하기 위하여 용액의 PH에 따른 용해성 시험을 진행하였으며, 합성한 발포제의 양에 따른 3D입체형성 정도를 이미지로 형상화 하였다.