• Title/Summary/Keyword: 폴리아크릴

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Effects of Polyacrylamide and Biopolymer on Soil Erosion and Crop Productivity in Sloping Uplands: A Field Experiment (고랭지 밭 토양유실 방지를 위한 폴리머 소재(폴리아크릴아마이드 및 바이오폴리머)의 현장적용성 평가: 작물재배실험)

  • Choi, Yong-Beom;Choi, Bong-Su;Kim, Se-Won;Lee, Sang-Soo;Ok, Yong-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.11
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    • pp.1024-1029
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    • 2010
  • Use of polymeric soil amendments is an emerging way to reduce soil erosion, and improve crop productivity and soil quality. Objective of this study was to evaluate the effects of anionic polyacrylamide (PAM) and synthetic biopolymer on soil erosion, crop growth and soil quality. The aqueous solutions of PAM and biopolymer at 40 kg/ha were applied to loamy soil plots (3 m width by 18 m long) having a 20% slope during radish (Raphanus sativus) cultivation. Results showed that PAM and biopolymer treatments increased aggregate stability up to 11% compared to the untreated control. Treatments of PAM and biopolymer also increased leaf length of radish but there was no significant difference in crop yield. Soil loss was decreased by up to 41% using the polymeric soil amendments; however, no difference in runoff was found, compared to the untreated control. Soil loss was logarithmically increased against an increase in rainfall intensity ($R^2=0.85$). Our findings suggest that proper use of polymeric soil amendments would be beneficial to maintain soil quality and reduce soil erosion in sloping uplands.

A study on the Manufacture and Application of UV-Cured Anti-stain Coating Compounds for PVC Tile (PVC 바닥상재용 광경화형 내오염 코팅액의 제조 및 응용에 관한 연구)

  • Yoon, Hyun-Jung;Ha, Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.5
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    • pp.1741-1746
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    • 2010
  • This study is on development of UV-cured anti-stain coating compounds which have more improved anti-stain function to prevent a surface of PVC tile from stain. To make an anti-stain coating composition, water soluble antistatic agent made from ammonium(IV) salt, antistatic agents for acrylic and polyurethane were used. Their contents varied from 5 to 20wt% against quantities of resin in coating composition. After coating PVC tiles using bar-coating method that can adjust a thickness, we estimated surface properties of coated layer such as anti-stain, electric resistance, adhesive power, thickness of coating, and so on. Results showed that a coating composition added 15wt% of water soluble antistatic agent and coated with No.12 bar-coater had the optimum surface property in electric resistance($3.24{\times}10^9{\Omega}/cm^2$), anti-stain(ink Test, Dust Test) and adhesive power. We could also find electric resistance and anti-stain effect were improved as antistatic agent content increased. However, excessive addition of antistatic agents(over 20wt%) caused the migration.

Feeding efficiencies and growth rates of tiger worms(Eisenia fetida Savigny) when they were fed with differently pretreated sewage sludges (하수슬러지의 전처리 방법에 따른 줄지렁이(Eisenia fetida savigny)의 섭식효율 및 생장)

  • Park, Kwang-ll;Bae, Yoon-Hwan
    • Journal of the Korea Organic Resources Recycling Association
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    • v.11 no.4
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    • pp.66-78
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    • 2003
  • The effects of several factors such as heavy metals, living microorganims, high molecular conglomerator in sewage sludge were analysed. And the effects of the sewage sludges which were mixed with other organic waste such as paper mill sludge or night soil sludge upon the feeding rate and biomass of earthworm population were also estimated. The earthworm populations could not survive when newly produced sewage sludges were fed without any pretreatment. The contents of heavy metals were under the levels that could inhibit earthworm's growth. The living microorganisms and the high molecular conglomerator in the sewage sludge had no relations with ecotoxicological effects of sewage sludge upon the earthworm population. Sewage sludge which had been mixed with paper mill sludge and aged for more than 21 days showed no ecotoxicological effects on tiger worm(Eisenia fetida) population. And the feeding rate of earthworm population and the turnover rate of earthworm biomass were higher in those sewage sludges than in the sewage sludges pretreated by other ways.

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Synthesis of modified polyacrylamides and their applications for the retention system of papermaking (변성 폴리아크릴 아미드의 합성 및 제지공정의 보류시스템에 응용)

  • Son, Dong-Jin;Yoon, Ji-Hyun;Choi, Eun-Jeong;Kim, Bong-Yong
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2009.04a
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    • pp.23-28
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    • 2009
  • The purpose of this study was to improve not only wet-end performances but also paper characteristics by the modification of various factors like molecular design and ionic characteristics of polyacrylamides First of all physical characteristics were observed after modify molecular design of the cationic polyacrylamides to linear, branched and cross-linked. In addition it was found analysis method to confirm branch degree of cationic polyacrylamides to combine ionic titration characteristics and spectroscopic behavior, After application of these structure modified polyacrylamides to the multiple retention systems with inorganic microparticles, it was found adjusting of branch degree of polyacrylamides was very important to optimize wet-end improvement. Second, After polymerization of amphoteric polyacrylamide to have both of cationic and anionic functional group in the polymer, we observed not only physical characteristics but also wet-end improvement to apply recycled pulp and found that the improvement of solution stability to prevent hydrolysis and increase of ash retention dramatically to compare traditional cationic polyacrylamide retention aid, Finally, After polymerization of anionic polyacrylamide, we observed not only wet-end improvement but also paper characteristics to apply preflocculation of PCC and it was found the improvements of flocculation efficiency, retention, ash retention, optical properties of the paper and bursting strength to compare traditional preflocculant of cationic polyacrylamide.

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Liquid Film Thickness Measurement by An Ultrasonic Pulse Echo Method (초음파 Pulse-echo 방법에 의한 액체막 두께 측정)

  • Jong Ryul Park;Jong-Ryul Park;Se Kyung Lee
    • Nuclear Engineering and Technology
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    • v.17 no.1
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    • pp.25-33
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    • 1985
  • The main purpose of this work is to investigate the effects of the wall thickness, the ultrasonic frequency, and the acoustic impedance of wall material on the liquid-film thickness measurement by an ultrasonic pulse echo method. A series of liquid-film thickness measurements in a horizontal air-water stratified system was performed employing a plate-type and a tube-type test sections. Measurements were repeated changing (1) the wall thickness of the test section and (2) the transducer frequency. Also, in an effort to improve the accuracy of the measurement and to exam me the effect of acoustic impedance of wall material on the measurement by an ultrasonic technique, two different stand-off rods, one made of stainless steel and the other polyacrylate, were used in the liquid-film thickness measurement. These experimental results are discussed and compared with the actual film thicknesses.

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Derivation of the Effective Energy Calculation Formula of the X-ray Beam Generated by the CT Simulator (CT 모의치료장치에서 발생된 X-선 빔의 유효에너지 계산식 유도)

  • Kim, Jong-Eon;Lee, Sang-Hun
    • Journal of the Korean Society of Radiology
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    • v.15 no.6
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    • pp.869-875
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    • 2021
  • The purpose of this study is to derive a formula for calculating the effective energy of an X-ray beam generated by a CT simulator. Under 90, 120, and 140 kVp X-ray beams, the CT number calibration insert part of the AAPM CT performance phantom was scanned 5 times with a CT simulator. The CT numbers of polyethylene, polystyrene, water, nylon, polycarbonate, and acrylic were measured for each CT slice image. The average value of CT number measured under a single tube voltage and the linear attenuation coefficients corresponding to each photon energy calculated from the data of the National Institute of Standards and Technology were linearly fitted. Among the obtained correlation coefficients, the photon energy having the maximum value was determined as the effective energy. In this way, the effective energy of the X-ray beam generated at each tube voltage was determined. By linearly fitting the determined effective energies(y) and tube voltages(x), y=0.33026x+30.80263 as an effective energy calculation formula was induced.

Laboratory Evaluation of Polysulfide Epoxy Overlay Material for Bridge Deck (교면포장용 폴리설파이드 에폭시재료의 실내물성 평가)

  • Kim, Jun-Hyung;Suh, Young-Chan
    • International Journal of Highway Engineering
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    • v.13 no.2
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    • pp.159-166
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    • 2011
  • This research was performed to evaluate physical properties of polysulfide epoxy overlay material for bridge deck as part of a review for possibility of domestic application of polymer concrete for bridge deck pavement. In order to evaluate strength characteristics, compressive strength, flexural strength and bond strength were tested, and, for durability characteristics, chloride ion penetration resistance and freeze/thaw resistance were tested along with ultraviolet rays impact evaluation. The tests showed that the results met the criteria suggested by the American Concrete Institute in terms of compressive strength, flexural strength and bond strength. However, in terms of the strengths measured at various test temperatures, it was found that the epoxy material was highly dependent on temperature, and, therefore, this should be considered at the time of domestic application of the epoxy material later. Deflection characteristics was checked through flexural strength test and it was found that bridge deck pavement using the epoxy material was excellent compared to bridge deck pavement using asphalt. Furthermore, the results of chloride ion penetration resistance test and freeze/thaw resistance test were also excellent. In the evaluation of ultraviolet rays impact on epoxy slurry mixture, reduction of strain was noticed with increased strength, but the deflection characteristics after exposure to ultraviolet rays was better than the existing acryl polymer concrete. Therefore, it is concluded from the research that the polysulfide epoxy overlay material has the physical properties that are appropriate to pavement of bridge deck.

Permeation Behavior of Olefin/Nitrogen Gases through Siloxane based Polymeric Membranes (실록산계 고분자 막을 통한 올레핀/질소 기체 투과 거동)

  • 이수복;신효진;최승학;김정훈;박인준;노재성;강득주
    • Membrane Journal
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    • v.13 no.4
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    • pp.246-256
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    • 2003
  • For the olefin recovery from polyolefin off-gas, the permeation behaviors of olefins and nitrogen were investigated through three kinds of PDMS membranes - cross-linked PDMS membranes, a polysiloxaneimide membrane, and oligo-PDMS modified PDMS membranes. Their pure gas permeabilities were measured as a function of operation temperature(-20 to $50^{\circ}C$) and pressure(1 to 25 atm) with ethylene($C_2\;H_4$), propylene($C_3\;H_6$), butylene($C_4\;H_8$), and nitrogen($N_2$) gases. The permeabilities of olefins and nitrogen highly depended upon the nature of PDMS membranes. Among these membranes, cross-linked PDMS membranes showed stable and high olefin/nitrogen selectivities over a wide operation pressure range and further study in various test conditions. Their permeability of olefin and nitrogen were governed by the condensation temperature(solubility selectivity) and plasticization, not the order of the size(diffusivity selectivity) of gases, which matched well with the general permeation behavior of rubbery polymeric membranes for condensable and non-condensable gases. With increasing feed pressure or decreasing feed temperature, the permeabilities of more condensible olefins increase highly, presumably due to high solubility and plasticization, but that of non-condensible nitrogen decreases slightly and thus, the selectivities of olefin/nitrogen increase highly.

The Characteristics of Poly(acrylamide)-SiOx Nanoparticles Prepared by Graft-polymerizaton (그라프트 중합에 의해 만들어진 폴리아크릴아마이드-실리카 나노 입자의 특성)

  • Min, Jun Ho;Min, Seong Kee
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.34-39
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    • 2010
  • Methacryloxypropyltrimethoxysilane (MPTMS) was used for the surface modification of silica nanoparticles in the toluene dispersion system for 8 h (MPSN). Then, methacryloxypropyl-modified silica nanoparticles were successfully prepared by solutioun polymerization in the ethanol solution at $60^{\circ}C$ for 14 h with adding AIBN initiator. The modification of ultra-fine particles (SiOx-PAA nanospheres) was investigated via EA, XPS, FTIR, TGA, SEM and TEM. The mean diameter of the bare silica nanoparticles, MPSN and SiOx-PAA monodisperse nanoparticles was about 25, 30 and 35 nm, respectively.

Synthesis and Solution Properties of Fluorinated Amphiphilic Polyacrylamide (불화계 양친매성 폴리아크릴아마이드의 합성과 용액거동)

  • Zhao, Fangyuan;Du, Kai;Yi, Zhuo;Du, Chao;Fang, Zhao;Mao, Bingquan
    • Polymer(Korea)
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    • v.39 no.3
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    • pp.403-411
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    • 2015
  • A series of hydrophobically associating fluorinated amphiphilic polyacrylamide copolymers with remarkably high heat resistance and salt tolerance were synthesized by free radical micellar copolymerization, using acrylamide (AM) and sodium 2-acrylamido-tetradecane sulfonate ($AMC_{14}S$) as amphiphilic monomers, and 2-(perfluorooctyl) ethyl acrylate (PFHEA) as hydrophobic monomer. The structure of the terpolymer was characterized by FTIR, $^1H$ NMR and $^{19}F$ NMR. The solution properties of the terpolymers were investigated in details, and the results showed that the terpolymer solution had strong intermolecular hydrophobic association as the concentration exceeded the critical association concentration 1.5 g/L. The terpolymer solution possessed high surface activity, viscoelasticity, excellent heat resistance, salt tolerance and shearing resistance. The viscosity retention rate of copolymer solution was as high as 59.9% under the condition of fresh wastewater, $85^{\circ}C$ and a 60-days aging test.