• Polymer(Korea)
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• v.32 no.3
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• pp.251-255
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• 2008

This study suggested antistatic material which can increase anti-static properties and mechanical strength by mixing polystyrene for conveying electronic stuffs with metal salt and ester compound as a anti-static agent. We studied about mechanical, thermal and electrical characteristics by changing the contents of MAH of poly(styrene-co-maleic anhydride), compatibilizer. As the result of measuring residue space charge of the blends of HIPS(75)/TPU(25)/poly(styrene-co-maleic anhydride)(MAH weight ratio : 25, 32, 43.5 wt%), we could find small residue charge in the blend which MAH(25 wt%) was added and it showed the highest values in tensile strength. Additionally we found out the material to which compatibilizer was added kept better anti-static properties than one to which compatibilizer was not added. In the event we could confirm that the adding of PS-co-MAH enables two polymers were mixed well when HIPS/TPU was blended and anti-static agent made easier dissipative in the blend.

• Polymer(Korea)
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• v.37 no.4
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• pp.526-532
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• 2013

The effect of CNT dispersion method on rheological and electrical properties of polystyrene/carbon nanotube (PS/CNT) nanocomposites via latex technology was compared. The nanocomposites were prepared through freeze-drying the dispersed suspension comprised of CNTs and PS particles. In this study, physical dispersion method, either sodium dodecylsulfate (SDS) addition or polyvinyl pyrrolidone (PVP) wrapping, was employed to prevent the deterioration of intrinsic properties of CNT caused by chemical modification. The physical method applied to latex technology was very effective in CNT dispersion. With SDS addition, the enhancement of rheological properties was low compared to PVP wrapping because the properties of matrix were deteriorated due to the incorporation of low molecular weight SDS. The electrical percolation threshold of PS/SDS-stabilized CNT and PS/PVP-wrapped CNT nanocomposites was 0.23 and 0.90 wt%, respectively. The enhancement of electrical conductivity was low in the case of PVP wrapping because the non-conducting PVPs wrapped around CNT restricted the electrical connection between CNTs.

• Polymer(Korea)
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• v.31 no.2
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• pp.98-104
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• 2007

The expansion behavior of polystyrene (PS) chains with various molecular weights has been investigated above Flory $\Theta$temperature by viscometry after dissolving in the three different mixed solvents systems such as benzene/n-heptane, 1,4-dioxane/isopropanol, and 1,4-dioxane/n-heptane. Two different regimes are observed as increasing temperature: one regime is for the expansion of chain and the other is for the contraction. For the higher molecular weight sample of PS, the higher peak temperature showing its maximum expansion is obtained. Within a certain system of Ps/mixed solvents, the $\tau/\tau_c$ parameter shows universality for the variation of molecular weight. But while each system of Ps/mixed solvents has shown its own different slope, the universality breaks down in the overall system of mixed solvents. However after introducing a new empirical $b^{2/3}\tau/\tau_c$ parameter, all data points of three different systems have dropt on one master curve and the universality of chain expansion has recovered again. Here $\tau$ and $\tau_c$ are defined as $(T-\Theta)/\Theta$ and $(\Theta-T_c)/T_c$, respectively and $T_c$ is the critical solution temperature, and b of Schultz-Flory equation is corresponding to the effective slope in the plot of $1/T_c$ against $1/M_w^{1/2}$.

• Polymer(Korea)
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• v.33 no.2
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• pp.158-163
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• 2009

In this study, we synthesized a series of dendritic polystyrene-b-linear poly (t-butyl acrylate) copolymers with well-defined molecular architectures. The hydroxyl group located at the focal point of the second generation dendron bearing polystyrene ($M_n$ = 1000 g/mol) peripheries was converted into amine group via the following stepwise reactions: 1) tosylatoin, 2) azidation, and 3) reduction. On the other hand, the linear poly (t-butyl acrylate)s were prepared by an atom transfer radical polymerization (ATRP) of t-butyl acrylate where benzyl 2-bromopropanoate and Cu(I)Br/PMDETA were used as initiator and catalyst, respectively. To convert the end group of prepared poly (t-butyl acrylate) s into carboxylic acid, a debenzylation was performed using Pd/C catalyst under $H_2$ atmosphere. In the final step, dendritic-linear block copolymers were obtained through a simple amide coupling reaction mediated by 4-(dimethylamino) pyridine(DMAP) and N,N'-diisopropylcarbodiimide(DIPC). The resulting diblock copolymers were shown to have well-defined molecular weights and narrow molecular weight distributions as supported by $^1H$-NMR spectroscopy and gel permeation chromatography(GPC).

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2001.10a
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• pp.190-194
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• 2001

The integration of rapid prototyping and tooling has the potential for the rapid net shape manufacturing of three-dimensional parts with geometrical complexity. In this study, a new rapid prototyping process, transfer type of Variable Lamination Manufacturing (VLM-ST), was proposed to manufacture net shape of 3-D prototypes. In order to examine the efficiency and applicability of the proposed process, various 3-D parts, such as a world-cup logo, and extruded cross and a knob shape, were fabricated on the apparatus. In addition, the new rapid tooling process, which is a triple reverse process, was proposed to manufacture of 3-D functional part using VLM-ST prototypes and the plastic part of the knob shape was produced by the new rapid tooling process.

• Journal of the Korean Society for Precision Engineering
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• v.22 no.4
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• pp.194-202
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• 2005

The objective of this paper is to develop a multi-functional hotwire cutting system (MHC) using EPS-foam block or plate as the working material. Because the MHC apparatus employs a four-axis synchronized hotwire cutter with the structure of two XY movable heads and a turntable, it allows the easy fabrication of various 3D shapes, such as (1) an axisymmetric shape or a sweeping cross-sectioned pillar shape using the hot-strip in the form of sweeping surface and EPS foam block on the turntable, (2) a polyhedral complex shape using the hotwire and EPS foam block on the turntable, and (3) a ruled surface approximated freeform shape using the hotwire and EPS foam plate. In order to examine the applicability of the developed MHC apparatus, an axisymmetric shape, a polyhedral shape and a large-sized freeform shape were fabricated on the apparatus.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2002.05a
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• pp.947-951
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• 2002

During the hotwire cutting of EPS foam sheet, the dimensional accuracy and part quality of the cut par are highly dependent upon the thermal field in the EPS. The thermal field is determined by operating parameters such as heat input, cutting speed and cutting angle. The objective of this study is to investigate into the influence of cutting angle on the kerfwidth and part quality of the cut part in hotwire cutting of EPS foam using the experiments and the numerical analysis in the case of a single sloped cutting. In order to estimate an accurate temperature field, the transient thermal analysis using a moving coordinate system and the sloped heat flux model is carried out. From the results of the experiments and the analysis, it has been found that the effect of cutting angle on the kerfwidth and the melted area at the edge are 0.1 mm and 0.11 m$m^2$ respectively. The results of the experiments show that the surface roughness is not appreciably influenced by the cutting angle.

• Journal of the Korean Society for Precision Engineering
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• v.18 no.8
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• pp.64-70
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• 2001

In all the Rapid Prototyping (RP) techniques, the computer-aided design (CAD) model of a three-dimensional part is sliced into horizontal layers of uniform, but not necessarily constant, thickness in the building direction. Each cross- sectional layer is successively deposited and, at the same time, bonded onto the previous layer. The stacked layers form a physical part of the model. The objective of this study is to develop a software for automatic generation of unit shape part(USP) for a new RP process, Variable Lamination Manufacturing using the linear hotwire cutting technique and expandable polystyrene foam sheet as part material(VLM-S). In order to examine the applicability of the developed software to VLM-S, USPs of general three-dimensional shapes, such as an auto-shift lever knob and a pyramid shape were generated.

• Journal of the Korean Society for Precision Engineering
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• v.27 no.11
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• pp.72-77
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• 2010

The fatigue characteristic of a material or a structure is derived from fatigue tests of standard specimens. However, many test results of standard specimens are very different from those of real structures. One reason for this difference is the constraint effects according to the geometrical difference. Therefore, to calculate more accurate fatigue life, the constraint effect must be considered by comparing test results of standard specimens with those of real structures. In this study, a blade of an air-conditioner was evaluated by both the test and the analysis. The results showed that a standard specimen is conservative, compared with a structure specimen. And fatigue life of an air-conditioner's blade was predicted from those.

• Journal of the Korean Society for Marine Environment & Energy
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• v.5 no.2
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• pp.35-40
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• 2002

By the introduction of cleaning and drying processes, thermal extrusion system for the volume reduction of used polystyrene buoys was developed. It was tested in the costal area for the determination of operational reliability. By the removal of oyster shells and cleaning of salt, waste polystyrene buoys was changed to the raw material of plastics. The lower cost of one-tenth compared with that of the outer request treatment is promising the practical use of waste buoys' volume reduction system.