• Title/Summary/Keyword: 폴리머 필름

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Fabrication and Straining Model of a CNT/EAP Composite Film (카본나노튜브/도전성폴리머(CNT/EAP) 복합재 필름의 제조 및 특성분석)

  • Zhang, Shuai;Kim, Cheol
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.117-120
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    • 2005
  • The relationship between strain and applied potential was derived for composite actuators consisting single-wall carbon nanotubes (SWNTs) and conductive polymers (CPs). During deriving the relationship, an electrochemical ionic approach is utilized to formulate the electromechanical actuation of the composite film actuator. The results show that the well-aligned SWNTs composite actuator can give good actuation responses and high actuating forces available. The actuation is found to be affected by both SWNTs and CPs components and the actuation of SWNTs component has two kinds of influences on that of the CPs component: reinforcement at the positive voltage and abatement at the negative voltage. CNT/EAP was fabricated successfully using the chemical polymerization method.

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Advances in Photopolymer for the Next Generation Holographic Applications (차세대 홀로그래픽 응용을 위한 포토폴리머의 발전)

  • Kim, Hee-Youn;Park, Sang-Hyun;Jung, Suk-Ju;Choi, Bong-Keun;Seo, Dong-Sun;Hong, Sang-Jeen
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.344-345
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    • 2005
  • 본 논문에서는 홀로그래피용 감광물질로서, 앞으로 가장 발전가능성이 있다고 기대되는 photopolymer에 대해서 언급하고자 한다. 홀로그램은 물체에서 방출되는 빛의 파면에 대한 정보를 기록하는 필름을 말하며 이러한 홀로그램을 이용한 기술을 홀로그래피라고 한다. 먼저 홀로그램 및 홀로그래피의 개념과 원리에 대해 서술하고 현재 사용되고 있는 홀로그래피용 감광물질인 silver-halide나 dichromatic gelatin 등에 대해 소개한다. 이와 비교하여 photopolymer가 가지는 특성과 장점을 기술하고 photopolymer를 기반으로 한 holography의 발전에 따른 차세대 holographic applications에 대해 알아본다.

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Synthesized silicon oxide thin film by low pressure chemical vapor deposition(LPCVD) (저진공 화학기상증착법을 이용한 산화실리콘 박막 제작)

  • Lee, Gyeong-Hwang;Kim, Sang-Won;Park, Jong-Won;Park, Yeong-Hui;Heo, Gyu-Yong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2008.11a
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    • pp.59-60
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    • 2008
  • 산화실리콘 박막은 생체적합성, 폴리머 필름의 gas barrier, 저유전율, 환경차단 보호막 등 다양한 특성을 갖고 있어 연구개발이 활발하게 이루어지고 있다. 본 연구는 저진공 화학기상증착법 (LPCVD)를 이용하여 산화실리콘 박막을 제작하였다. 실리콘 박막을 위한 전구체는 환경 친화적이며 상온에서 비교적 높은 증발점을 갖는 hexamethyldisiloxane (HMDSO)을 이용하였으며, 이때 기판은 실리콘을 이용하였다. LPCVD의 공정변수는 전구체 공급량(진공도)과 RF power를 중심으로하여 Taguchi 실험계획법에 따라 박막을 제작하였다. 또한, 실험계획법에 의해 최적 전구체 공급량과 RF power를 결정하고 산소분압의 변화에 따른 산화실리콘 박막을 제작하였다. 산화실리콘 박막은 표면특성 및 화학적 결합상태를 수접촉각, SEM, AFM, FTIR 등을 이용하여 관찰하고 분석하였다.

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Energy Generating Self-cooling Greenhouse (열-전기 병합 에너지 생산 겸 자체 냉각 온실)

  • Kleinwachter, Jurgen;Chung, Mo;Kim, Jong-Sung
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.584-587
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    • 2006
  • An energy generating greenhouse based on fluoropolymer envelope and fresnel lens is proposed. The outstanding properties of the fluoropolymer films make them very suitable for large scale solar applications. Extremely high optical transmission over the whole solar spectrum, combined with mechanical strength, and durability allows us to design a highly optimized greenhouses for both plant growing and energy generation. Systems such as photovoltaic triple junction cells are especially attractive since they have up to 35% efficiency with much less cell material when the sun beam is focused with concentrators such as fresnel lenses. Cooling such devices will enhance the efficiency and provide useful thermal energy that could be further utilized for various applications depending on the local demands. This article introduces the basic ideas and principles of the energy generating greenhouses as a first step towards the actual deployment of such systems under Korean environment.

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Fabrication of Vertically Oriented ZnO Micro-crystals array embedded in Polymeric matrix for Flexible Device (수열합성을 이용한 ZnO 마이크로 구조의 성장 및 전사)

  • Yang, Dong Won;Lee, Won Woo;Park, Won IL
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.4
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    • pp.31-37
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    • 2017
  • Recently, there has been substantial interest in flexible and wearable devices whose properties and performances are close to conventional devices on hard substrates. Despite the advancement on flexible devices with organic semiconductors or carbon nanotube films, their performances are limited by the carrier scattering at the molecular to molecular or nanotube-to-nanotube junctions. Here in this study, we demonstrate on the vertical semiconductor crystal array embedded in flexible polymer matrix. Such structures can relieve the strain effectively, thereby accommodating large flexural deformation. To achieve such structure, we first established a low-temperature solution-phase synthesis of single crystalline 3D architectures consisting of epitaxially grown ZnO constituent crystals by position and growth direction controlled growth strategy. The ZnO vertical crystal array was integrated into a piece of polydimethylsiloxane (PDMS) substrate, which was then mechanically detached from the hard substrate to achieve the freestanding ZnO-polymer composite. In addition, the characteristics of transferred ZnO were confirmed by additional structural and photoluminescent measurements. The ZnO vertical crystal array embedded in PDMS was further employed as pressure sensor that exhibited an active response to the external pressure, by piezoelectric effect of ZnO crystal.

A Study on Crystallization of Thermoplastic Aromatic Polymer (열가소성 방향족 폴리머의 결정화 특성에 대한 연구)

  • Park, Dong-Cheol;Park, Chang-Wook;Shin, Do-Hoon;Kim, Yun-Hae
    • Composites Research
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    • v.31 no.2
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    • pp.63-68
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    • 2018
  • Thermoplastic composite has been limitedly used in high performance aerospace industry due to relatively low mechanical properties even though it has various advantages. But, thermoplastic aromatic polymer composite has recently been researched and utilized much. In this study, PEEK and PPS neat resin film as representative thermoplastic aromatic polymer were processed through continuous heating, cooling and reheating cycle. Property change such as glass transition temperature and melting temperature were identified and crystallinity variation by different cooling rate were evaluated. In the first (heating) run, polymer specimens were kept for 5 minutes at higher temperature than melting point to remove previous thermal history, and crystallization reaction was controlled by adjusting cooling rate to 2, 5, 10, 20 and $40^{\circ}C/minute$ in the second (cooling) run. In the third (heating) run, specimen crystallinity were verified by measuring the melting enthalpy. The initial specimens containing high portion of amorphous structure exhibited cold crystallization and clear glass transition in the first run whereas they did not show in the third run due to the increase of crystalline structure portion. As cooling rate decreases through the second cooling run, the crystallinity of the specimen increased. PEEK polymer had 21.9~39.3% crystallinity depending on cooling rate change whereas PPS polymer showed 29.1~31.2%.

Strengths of Rapidly Hardening SBR Cement Mortars as Building Construction Materials According to Admixture Types and Curing Conditions (혼화재 종류 및 양생조건에 따른 속경성 SBR 시멘트 모르타르의 강도)

  • Jo, Young-Kug;Jeong, Seon-Ho;Jang, Duk-Bae
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.6
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    • pp.587-596
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    • 2011
  • Ultra rapid-hardening cement is widely used for latex-modified mortar and concrete as repair and finishing material during urgent work. The purpose of this study is to evaluate the improvements in strength made to SBR cement mortars by the adding of various admixtures and by the use of different curing methods. SBR cement mortar was prepared with various polymer-cement ratios, curing conditions and admixture contents, and tested for flow, flexural and compressive strengths. From the test results, it was determined that the flow of SBR cement mortar increased with an increase in the polymer-cement ratio, and the water reducing ratio also increased. The strength of cement mortar is improved by using SBR emulsion, and is strengthened by adding metakaoline. The strength of SBR cement mortar cured in standard conditions was increased with an increase in the polymer-cement ratio, and attained the maximum strengths at polymer-cement ratios of 15 % and 10 %, respectively. The maximum strengths of SBR cement mortar are about 1.8 and 1.3 times the strengths of plain mortar, respectively. In this study, it is confirmed that the polymer-cement ratio and curing method are important factors for improving the strengths of rapid-hardening SBR cement mortar.

Investigation of Physical Properties and Self Healing of Hardener-Free Epoxy-Modified Mortars with GGBFS (고로슬래그미분말을 혼입한 경화제 무첨가 에폭시수지 모르타르의 물리적 성질 및 자기치유 검토)

  • Jo, Young-Kug;Kim, Wan-Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.1
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    • pp.80-87
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    • 2020
  • The purpose of this study is to investigate the physical properties and self-healing effects of hardener-free epoxy-modified mortars(EMMs) using ground granulated blast furnace slag(GGBFS). The EMMs with GGBFS were prepared with various polymer-binder ratios and GGBFS contents, and tested for strengths, adhesion in tension, water permeation and self-healing effects. The conclusions obtained from the test results are summarized as follows. The compressive strength of the EMMs with GGBFS is reduced with increasing polymer-binder ratios because of reduction of the degree of hardening in the EMMs, and is somewhat inferior to that of unmodified mortars. In the flexural and tensile strengths, the flexural strength of the EMMs is almost constant with increasing polymer-binder ratios. However, the tensile strength of the EMMs is gradually increased with increasing polymer-binder ratios. Regardless of the GGBFS contents, the adhesion in tension of the EMMs increases sharply with increasing polymer-binder ratios. The water permeation of the EMMs is remarkably reduced with increasing polymer-binder ratios and GGBFS contents. The self-healing effect of the hardener-free EMMs with GGBFS is improved with increasing water immersion period at a GGBFS content of 20%.

Study on the Effects of BaTiO$_3$ Particle Size on Dielectric Constant and Leakage Current of Epoxy/BaTiO$_3$ Composite Films for Embedded Capacitors (BaTiO$_3$ 분말의 입자 크기가 내장형 커패시턴용 에폭시/BaTiO$_3$복합체 필름의 유전상수와 누설전류에 미치는 영향에 관한 연구)

  • 조성동;이주연;백경욱
    • Journal of the Microelectronics and Packaging Society
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    • v.9 no.2
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    • pp.11-17
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    • 2002
  • Polymer/ceramic composite is of great interest as a dielectric material for embedded capacitors. This paper is concerned in the effects of $BaTiO_3$ particle size on epoxy/$BaTiO_3$ composite films for embedded capacitors. 6 different size powders smaller than 1 $\mu\textrm{m}$ in diameter and bisphenol-A type epoxy were used for this experiment. Dielectric constant of the epoxy/$BaTiO_3$ composite capacitors increases as the powder size increases at the same powder loading, which is due to the increase of tetragonality of the powders as particle size increases. And leakage current of the capacitors also increases dramatically as the powder size increases. It was explained that this is due to the decrease of the number of $BaTiO_3$epoxy/$BaTiO_3$ potential barriers per unit length and, moreover, the enhancement of potential barrier lowering effects caused by increase of potential drop per one barrier. As a result, there is tradeoff between high dielectric constant and low leakage current in the epoxy/$BaTiO_3$ composite capacitors. So it is important to select proper size $BaTiO_3$ powders in accordance with needs.

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Molecular Orientation of Evaporated Pentacene Film on Polyimide Alignment Layer (폴리이미드 배향막에 증착된 Pentacene 분자의 배향 연구)

  • Kim Beom-Kyung;Kim Do-Hoi;Chung Jae-Sun;Kim Young-Ju;Seo In-Seon;Kwon Soon-Ki;Song Ki-Gook
    • Polymer(Korea)
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    • v.30 no.4
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    • pp.362-366
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    • 2006
  • It was found by polarized FTIR spectroscopic studies that pentacene molecules are arranged with their molecular axes perpendicular to the substrate surface when pentacene films are deposited on a polyimide alignment layer. The ring plane in a pentacene molecule is arranged parallel to the rubbing direction of the polyimide alignment film while no specific arrangement of vertically deposited pentacene molecules was found for the film without rubbing. The pentacene band at $1296cm^{-1}$ which has a transition dipole moment parallel to the ring plane is much stronger in a polarized IR spectrum of parallel to the rubbing direction, whereas the band at $908cm^{-1}$ whose transition dipole align normal to the ring plane shows much stronger intensity in a spectrum of perpendicular to the rubbing direction. These findings indicate that orientation of polyimide chains affects the arrangement of pentacene molecules when they are deposited on a polyimide alignment film.