• Journal of the Korea Concrete Institute
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• v.19 no.4
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• pp.457-465
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• 2007

In this paper, polymer-modified repair materials using polymer dispersions with six repair methods are prepared with various polymer-cement ratios, and tested for compressive and flexural strengths through each curing condition such as dry cure, water cure, and freezing and thawing cyclic action. And, the adhesive interface between the polymer-modified mortar and mortar substrate is observed by a scanning electron microscope. From the test results, the compressive and flexural strengths of cement mortar repaired by polymer-modified mortar are improved with a rise in the polymer-cement ratio regardless of the type of polymer and curing conditions. Such an improvement in the strengths of polymer-modified repair materials to ordinary cement mortar is explained by the high adhesion of polymer-modified mortar. Strength reduction of polymer-modified repair materials after freezing and thawing cyclic actions is recognized, but it is lower than that of unmodified mortar. Especially, cement mortar repaired by polymer-modified mortar with a St/BA emulsion has good strength properties compared with those of SBR latex and PA emulsion. Accordingly, it is judged that polymer-modified mortars with a St/BA emulsion are possible to use as repair materials to ordinary cement mortar and concrete.

• Journal of the Korea Concrete Institute
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• v.14 no.2
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• pp.190-198
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• 2002

In this research the physical properties of polymer modified mortar containing pulverized FRP(Fiber-Reinforced Plastics) wastes fine powder as a part of fine aggregate were investigated. Styrene-butadiene rubber(SBR) latex, polyacrylic ester(PAE) emulsion and ethylene-vinyl acetate(EVA) emulsion were used as Polymer modifier. Polymer modified mortars containing FRP wastes fine powder were prepared with various FRP wastes fine powder replacement(5∼30 wt％) for fine aggregate and polymer-cement ratios(5∼20 wt％). The water-cement ratio, water absorption rates and hot water immersion test, compressive and flexural strengths of polymer modified mortars were tested and the results compared to those of ordinary portland cement mortar. As the results, compressive and flexural strengths of polymer modified mortar containing FRP wastes fine powder depend on the contents of FRP wastes fine powder, type and additional amounts of polymer modifier. Some of them showed higher compressive and flexural strengths than those of ordinary portland cement mortar. Especially, SBR-modified mortar showed the highest strengths properties among three types of polymer modifier. Also water absorption rates, compressive and flexural strengths of SBR-modified mortar were more superior than those of PAE or EVA-modified mortar. The optimum mix proportions of SBR-modified mortar was 20 wt％ of polymer-cement ratio and 20 wt％ of FRP wastes fine powder replacement. Otherwise heat cured polymer modified mortar accelerated the improvement of early compressive and flexural strengths.

• Polymer(Korea)
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• v.33 no.4
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• pp.342-346
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• 2009

The effects of the monomer ratios on the typical properties of polymer modified mortars that contain styrene and butyl acrylate latexes was investigated. Basic data was also obtained that is necessary for the development of appropriate latexes for cement modifiers. Polymer modified mortars that contain styrene and butyl acrylate latexes polymerized with various monomer ratios were prepared for different polymer-cement ratios. They were then tested to obtain the particle size of the polymer latexes, air contents, water-cement ratios, flexural and compressive strengths, water absorption, and chloride-ion penetration. From the test results, the polymer modified mortars that have styrene and butyl acrylate latexes (with the mix proportions of synthesis having monomer ratios of between 40:60 to 60:40 for the appropriate mix proportions) could be recommended for practical applications. The basic properties of the polymer modified mortars were more affected by the polymer-cement ratio than by the monomer ratio, and were improved over unmodified mortar.

• Applied Chemistry for Engineering
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• v.8 no.6
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• pp.979-984
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• 1997

Test specimens of polymer-cement concrete composites were prepared using styrene-butadiene rubber(SBR) latex, ethylenevinyl acetate(EVA) and polyacrylic ester(PAE) emulsions as polymer dispersions in cement modified system at constant slump($10{\pm}0.5cm$), then compressive and flexural strengths water absorption, pore size distribution, and microstructures were investigated. Compressive and flexural strengths of these composites were remarkably improved with an increase of polymer-cement ratio. These composites had a desirable pore size distribution against frost damage due to a small capillary pore volume. Continuous polymer film was able to form in higher than 15% of polymer cement ratio.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2013.10a
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• pp.247-249
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• 2013

열화한 철근콘크리트 구조물에 대하여 성능회복을 위하여 전기화학적 방식, 단면복구공법, 균열보수공법, 표면마감공법 등이 상용되고 있다. 본 연구에서는 단면복구공법의 적용과 성능예측을 위한 해석 모델의 입력값으로 사용될 보강철근과 단면복구재의 부착특성을 평가하기 위하여 철근인발실험을 실시하였다. 폴리머시멘트몰탈이 사용되었으며 부착요소의 강성과 강도를 구하여 비선형 해석을 실시하여 상당한 정확도의 예측값을 도출하였다.

• Journal of the Korea Concrete Institute
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• v.13 no.4
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• pp.406-413
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• 2001

Up to this day, reinforced spun concrete pipes have been widely used as drain pipes. However, many reinforced spun concrete pipes are exposed to the deteriorated environment such as freezing-thawing damage and chemical attack by the growth of a sulfur-oxidizing bacterium isolated from corroded concrete. The purpose of this study is to evaluate the effects of lining by polymer-modified mortar using polymer dispersions as cement modifier on the development in durability of reinforced spun concrete pipe. The polymer-modified mortars were prepared with various polymer types and polymer-cement ratios, and tested for compressive and flexural strengths, acid, freezing-thawing, and heat resistances. And then, the reinforced spun concrete pipe product lined by polymer-modified mortars was tested for adhesion in tension and surface conditions according to curing temperatures in the field. From the test results, it is apparent that the polymer-modified mortars have good mechanical properties and durability as a lining material. In practice, all polymers can be used as lining the materials for reinforced spun concrete pipe, and types of polymer, and polymer-cement ratio and curing conditions are controlled for a good lining product.

• Journal of the Korea Concrete Institute
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• v.27 no.6
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• pp.633-640
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• 2015

Polymer cement slurry (PCS) is made from organic polymer dispersion and cement has good adhesion to steel, waterproofness and acid resistance due to being of polymer films formed in cement slurry. The purpose of this study is to evaluate the bond strength of coated rebar by polymer cement slurry made of EVA and ultra high-early strength cement. The test pieces are prepared with EVA polymer dispersion and ultra high-early strength cement having four types of polymer-cement ratios, four types of coating thicknesses and four curing ages, and tested for the bond strength test. From the test results, in general, bond strength of PCS-coated rebar is better than that of uncoated rebar and epoxy-coated rebar. It is also high bond strength at curing ages of 7-day, and coating thicknesses of $75{\mu}m$ and $100{\mu}m$. The maximum bond strength of PCS-coated rebar with ultra high-early strength cement and EVA at polymer-cement ratio of 80%, and coating thickness of $100{\mu}m$ is about 1.32 and 1.38 times respectively, the strength of uncoated rebar and epoxy-coated rebar. It is apparent that the curing age, coating thickness, type of polymer and cement are very important factors to improve the bond strength of PCS-coated rebar to cement concrete. We can have basic information that PCS-coated rebar with polymer-cement ratio of 80% or 100% and coating thickness of $100{\mu}m$ at curing age of 1-day can replace epoxy-coated rebar.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.9 no.2
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• pp.81-86
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• 2011

Polymer-modified cement is the composite material made by partially replacing and strengthening the cement hydrate binders of conventional mortar with polymeric modifiers such as polymer latexes and redispersible polymeric modifiers. It is known that the addition of polymer to cement mortar leads to improved quality, which would be expected to have a high chemical resistance. Therefore, the purpose of this study is to identify the improved chemical resistance, such as low permeability and low ion diffusivity, of the polymer-modified cement as a solidification agent for the radwaste. First, polymer-modified cement specimens by latex modification were prepared according to the polymer content from 0% to 30% to select the optimized polymer content. At those specimens, the water-to-cement (W/C) ratio was maintained to 33% and 50% respectively. After the much curing time, the structural integrity of specimens was evaluated through the compressive strength test and the porosity evaluation by the water immersion method. From the results, 10% of the polymer content at 33% of the W/C ratio was shown to have the most improved quality. Finally, the leaching test referredfrom ANS 16.1 for the specimens having the most improved quality was conducted. Dedicated specimens for the leaching test were then mixed with radioisotopes of $^{60}Co$ and $^{137}Cs$ at the specimen preparation.

• Magazine of the Korea Concrete Institute
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• v.8 no.5
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• pp.145-154
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• 1996

Polymer-modified mortars have an excellent water proofness and water retentivity. Therefore, the study on the moisture diffusion behavior- is very important. The purpose of' this study is to investigate the effects of relative humidity and moisture content in mortars on the moisture diffusion, and the relationship between the shrinkage and moisture diffusion coefficient of polymer-modified mortars cured at $20{\circ}C$ 50% R.H and 80% R.H. The pore size distribution of the polymer-modified mortars was also measured. From the test results, the relative humidity and moisture content in mortars influenced on the moisture diffusion of polymer-modified mortars. The shrinkage and moisture diffusion coefficient of polymer-modified mortars cured at $20{\circ}C$ 50% R.H. was bigger than that cured at $20{\circ}C$ 80% R.H.. and decreased with increasing polymer-cement ratio regardless of polymer type.

• Journal of the Korea institute for structural maintenance and inspection
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• v.27 no.5
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• pp.97-104
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• 2023

The aim of this study was to produce polymer cement composites (PCCs) composed of polymer dispersion and cement as crack repair materials for RC structures, and to investigate their fundamental properties. The test mixtures for the study were based on EVA and SAE polymer dispersions, and the water-cement ratio was determined while varying the polymer-cement ratio(P/C) in four different levels (20%, 60%, 80%, and 100%) to achieve the desired viscosity of PCCs considering their fillability as crack repair materials. Additionally, silica fume was incorporated into P/C 80% and 100% specimens to enhance their stiffness. The basic properties of PCCs as crack repair materials, such as viscosity, flowability, fillability, tensile strength, elongation, and modulus of elasticity, were examined. The results showed that P/C depending on the type of polymer significantly affected the viscosity and flowability, and appropriate w/c ratios were needed to achieve the desired viscosity for the mixture design with consideration of fillability as crack repair materials for RC structures. All designed mixtures in this study exhibited excellent fillability. The tensile strength and elongation of PCCs satisfied the KS regulation for cement- polymer modified waterproofing coatings. The incorporation of silica fume improved the tensile strength and modulus of elasticity of PCCs. Depending on the type of polymer, mixtures using SAE showed better fundamental properties as crack repair materials for RC structures compared to those using EVA. In conclusion, SAE-based P/C 80% or 100% with the addition of up to 30% silica fume can be recommended as suitable mixtures for crack repair of RC structures.