• Title/Summary/Keyword: 폴리머 시멘트 비

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A Study on the Application of Very Rapid Hardening Acrylic Polymer Modified Concrete for Bonded Concrete Overlay Method (접착식 콘크리트 덧씌우기 공법을 위한 초속경 아크릴계 폴리머 개질 콘크리트의 적용성 연구)

  • Lee, Seung-Woo;Kim, Young-Kyu;Lee, Poong-Hee
    • International Journal of Highway Engineering
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    • v.13 no.1
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    • pp.139-148
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    • 2011
  • Asphalt concrete overlay method is used by general maintenance and rehabilitation of construction for aged concrete pavement in Korea. However, in case of the AC overlay method to extend service life of the existing concrete pavements, various distresses of reflection crack, pothole and rutting are the typical problems of the asphalt overlay on existing concrete pavement since it has different physical characteristics between asphalt overlay and existing concrete pavement. To achieve this, application of concrete overlay method is required instead of AC overlay method. Concrete overlay method has advantages that can reduce maintenance cycle and costs since it has excellent bearing value for heavy vehicles and no rutting. However, technical problems of detour road construction, traffic control and other disadvantages happened by long curing time. Thus, in this study and experimental research were launched to evaluate the workability, durability and resistance against environmental loading of Very Rapid Hardening Acrylic Polymer Modified Concrete(VRH-APMC) for application of bonded concrete overlay method. Test results showed that the compressive and bond strength were exceed 21MPa and 1.4MPa of target strength after four hours for rapid traffic opening properties. And tests of resistance against environmental loading results showed that VRH-APMC secured excellent durability. Thus, it was known that VRH-APMC was suitable material for large scale bonded concrete overlay method, and it was possible to use maintenance and rehabilitation method which needs enough workability and rapid traffic opening.

Characteristics of Polyester Polymer Concretes Using Spherical Aggregates from Industrial By-Products (III) (Using an Atomizing Steel Slag as a Filler and Fine Aggregate) (산업부산물 구형골재를 사용한 폴리에스테르 폴리머 콘크리트의 특성(III) (아토마이징 제강슬래그를 충전재와 잔골재로 사용))

  • Hwang, Eui-Hwan;Kim, Jin-Man
    • Applied Chemistry for Engineering
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    • v.26 no.1
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    • pp.104-110
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    • 2015
  • It is known that polymer concretes are 8~10 times more expensive than ordinary Portland cement concretes; therefore, in the production of polymer concrete products, it is very important to reduce the amount of polymer binders used because this occupies the most of the production cost of polymer concretes. In order to develop a technology for the reduction of polymer binders, smooth and spherical aggregates were prepared by the atomizing technology using the oxidation process steel slag (electric arc furnace slag, EAFS) and the reduction process steel slag (ladle furnace slag, LFS) generated by steel industries. A reduction in the amount of polymer binders used was expected because of an improvement in the workability of polymer concretes as a result of the ball-bearing effect and maximum filling effect in case the polymer concrete was prepared using the smooth and spherical atomized steel slag instead of the calcium carbonate (filler) and river sand (fine aggregate) that were generally used in polymer concretes. To investigate physical properties of the polymer concrete, specimens of the polymer concrete were prepared with various proportions of polymer binder and replacement ratios of the atomized reduction process steel slag. The results showed that the compressive strengths of the specimens increased gradually along with the higher replacement ratios of the atomized steel slag, but the flexural strength showed a different maximum strength depending on the addition ratio of polymer binders. In the hot water resistance test, the compressive strength, flexural strength, bulk density, and average pore diameter decreased; but the total pore volume and porosity increased. It was found that the polymer concrete developed in this study was able to have a 19% reduction in the amount of polymer binders compared with that of the conventional product because of the remarkable improvement in the workability of polymer concretes using the spherical atomized oxidation steel slag and atomized reduction steel slag instead of the calcium carbonate and river sand.

Estimation of Air Void System and Permeability of Latex-Modified Concretes by Image Analysis Method (화상분석법을 이용한 라텍스개질 콘크리트의 공극 구조와 투수성의 상관성 분석)

  • Jeong Won-Kyong;Yun Kyong-Ku;Hong Seung-Ho
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.695-702
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    • 2005
  • It is known that latex-modified concretes were increased their durability and permeability by added latex. The purpose of this study was to analysis the air void systems in latex-modified concretes using a reasonable and objective image analysis method with main experimental variables such as water-cement ratios, latex contents(0%, 15%) and cement types(ordinary portland cement, high-early strength cement and very-early strength cement). The results are analyzed spacing factor, air volume after hardened, air distribution and structure. Also, air void systems and permeability of latex-modified concretes were compared with correlation. The results are as follows; The same w/c ratio LMC showed better air entraining effect than OPC with AE water reducer. The VES-LMC showed that the number of entrained air below $100{\mu}m$ increased more than four times. In the HES-LMC, micro entraining air having range from 50 to $500{\mu}m$ increased above 7 times without antifoamer. Though spacing factor was measured low, latex-modified concretes were showed that permeability was good. It is considered that air void system does not have an effect on the property of latex-modified concretes but latex film is more influenced in the their durability.

Properties of SPE-Based Cement Grout for Semi-Rigid Pavements (Sulfur Polymer Emulsion을 활용한 반강성 포장용 시멘트 주입재의 특성)

  • Lee, Byung-Jae;Lee, Jun;Hyun, Jung-Hwan;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.4
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    • pp.57-65
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    • 2013
  • The development of the oil refining industry has resulted in an annual 120 million tons of sulphur, which is a by-product of the desulphurization process. To exploit this abundance, the applications of sulphur must be expanded. as excellent durability of reuse of leftover sulphur which has high potential for utilization in construction materials, the study is actively in progress. Meanwhile, there has been active research on semi-rigid pavements that draw on the strengths and overcome the weaknesses of asphalt and concrete pavements. Acrylate is used to prevent cracking but involves a high cost, thus, an alternative material is required. As such, this study presents methods on the reuse of leftover sulphur and examines the engineering performance of grout containing sulfur polymer emulsion (SPE) for use in semi-rigid pavements. Our analysis shows that grout in which 30% of acrylate is replaced with SPE has superior properties in terms of time of flow and strength compared to regular grout. However, performance declined when more than 50% of acrylate was replaced by SPE, indicating that the optimum replacement level is 30%. Through SEM analysis, we found that grout with utra harding cement in this study at three hours had similar hydration properties to that of Type 1 Ordinary Portland Cement (OPC) at seven days, and maintained the properties regardless of grout containing SPE. OPC and grout with a replacement level of 30% displayed similar levels of chloride invasion resistance, whereas grout without SPE was far less resistant. Within the scope of this paper, the optimum replacement level of acrylate with SPE was found to be 30% in consideration of various properties such as time of flow, strength, and chloride invasion resistance.

Influence of Fine Aggregate Properties on Unhardened Geopolymer Concrete (잔골재 특성이 굳지 않은 지오폴리머 콘크리트에 미치는 영향)

  • Cho, Young-Hoon;An, Eung-Mo;Lee, Su-Jeong;Chon, Chul-Min;Kim, Dong-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.2
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    • pp.101-111
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    • 2016
  • It is possible that aggregates add on to geopolymer based fly ash to mix mortar and concrete like cement. This is necessary to evaluate mineral composition, particle shape, surface, size distribution, density and absorption ratio for fine aggregates due to few detailed research to examine influence of fine aggregates properties on unhardened geopolymer concrete. In this research, used two different fine aggregates, Jumunjin sand(having quartz, mica, feldspar, pyroxene in mineral composition, more than 96% of total size between -0.60 and +0.30mm, angular shape and rough surface) and ISO sand(having almost all quartz in mineral composition, more than 51% size between -1.40 and +0.60mm, simultaneously varied size distribution, spherical shape and smooth surface). After an experimental result of the varied ratio of Si/Al=1.0-4.1 geopolymer paste, mix proportion respectively applied Si/Al=1.5 having the highest compressive strength to mortar and Si/Al=3.5 having the highest consistency to concrete. Geopolymer mortar by mixing with Jumunjin and ISO sand in varied range of 20-50wt.% showed flow size increase between 69.5 and 112.0mm, between 70.5 and 126.0mm respectively. Geopolymer concrete at an addition of 77wt.% of total aggregates ratio showed that average compressive strength was 32MPa and the consistency was favorable to molding. Since ISO sand observing varied size distribution, spherical shape, smooth surface, low absorption ratio resulted in advantageous properties on consistency of geopolymer, geopolymer concrete can be suitable for using the fine aggregates similar to ISO sand.

Watertightness and Durability Properties of Ultra Rapid Hardening Grout using Bottom-ash (잔골재 대체재로서 바텀애쉬를 이용한 초속경 그라우트재의 수밀성 및 내구특성)

  • Lee, Gun-Cheol;Oh, Dong-Uk;Cho, Byoung-Young;Kim, Young-Geun;Cho, Chung-Ki
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.3
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    • pp.102-109
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    • 2011
  • In this study, in order to develop ultra rapid hardening mortar(URHM) for tunnel repairs using bottom ash of low recycle ratio and Admixture as Eco concept, watertightness and durability properties of URHM on temperature condition of construction field were performed. Test result, seepage quantity and water absorption coefficient regarding watertightness of URHM were as in the following : series II > series I. Seepage quantity for the standard condition were smaller than low temperatures. all specimens were satisfied below 20g as standards of seepage quantity on KS F 4042. Because of the decrease of unit cement content by to replacement of blast furnace slag, the neutrlization resistance for durability properties was reduced. The result of alkali resistance and acide resistance, compressive strengths for specimens soaked in calcium hydroxide solution of seriesI were lower than compressive strengths for specimens not soaked. On the other hand, the case of series II show that the deterioration of compressive strengths for specimens was not almost showed. Compressive strengths of specimens soaked were similar with specimens not soaked except series II-C in $5^{\circ}C$. Therefore, specimens using both blast furnace slag and bottom ash were good in alkali resistance and acide resistance.

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Synthesis of Surface Crosslinked Poly(sodium acrylate) for Delayed Absorption in Cement Solution (시멘트 수용액에서 흡수 지연을 위한 Crosslinked Poly(sodium acrylate)의 표면 가교)

  • Hwang, Ki-Seob;Jang, Seok-Soo;Jung, Yong-Wook;Lee, Seung-Han;Ha, Ki-Ryong
    • Polymer(Korea)
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    • v.35 no.4
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    • pp.363-369
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    • 2011
  • To study the effect of incorporation of a surface crosslinking layer on a crosslinked poly (sodium acrylate) (cPSA) absorbent with ethylene glycol dimethacrylate CEGDMA), we synthesized several surface crosslinked cPSAs with EGDMA by an inverse emulsion polymerization method to delay the absorption of excess water in concrete, Liquid paraffin was used as a continuous phase. cPSA was synthesized with acrylic acid (AA) neutralized with aqueous 8 M sodium hydroxide solution as a monomer, N,N-methylene bisacrylamide (MBA) as crosslinking agent and ammonium persulfate (APS) and sodium metabisulfite (SMBS) as a redox initiator system by inverse emulsion polymerization. FTIR spectroscopy was used to characterize $Ca^{2+}$ ion interaction with cPSA and cPSA-EGDMAs. The swelling ratios of synthesized absorbents were evaluated from the absorption in deionized water, cement saturated aqueous solution and aqueous solution of calcium hydroxide (pH 12). Equilibrium swelling times for cPSA and surface crosslinked cPSA with EGDMA were 2 and 3 hrs, respectively. We also observed an increase in setting time of the cement and an increase in the compressive strength of mortar by addition of the synthesized cPSA-EGDMA.

Evaluation of Compressive Strength and Freeze-thaw Resistance Properties of Concrete using Superabsorbent Polymer (고 흡수성 폴리머를 혼입한 콘크리트의 압축 강도 및 동결융해 저항성 평가)

  • Kim, Il-Sun;Choi, So-Yeong;Yang, Eun-Ik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.5
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    • pp.86-94
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    • 2020
  • When the Superabsorbent Polymer (SAP) is added into concrete, the slump decreases rapidly, deteriorating the workability, the internal curing effect can be obtained through the water absorption and discharge process, and the internal voids of the concrete are increased. In this study, the effects of internal curing and voids were evaluated by evaluating the compressive strength, freeze-thaw resistance, and chloride penetration resistance of SAP-adding concrete that secured workability using a water reducing agent. Also, the internal curing effect of SAP was evaluated by dividing the curing conditions of concrete into water curing and sealed curing. From the result, as the SAP adding ratio increased, the amount of water reducing agent increased, and as for the compressive strength, the SAP adding ratio of 1.5% showed the greatest compressive strength. In particular, in the case of sealed curing showed higher compressive strength than the water curing. It is considered that the compressive strength increased due to the reduction of the effective water-cement ratio and the internal curing effect. Adding 1.0~1.5% of SAP improved the freeze-thaw resistance similar to the case of adding the AE agent, and the addition of more than 1.0% of SAP improved the chloride penetration resistance. The optimal adding ratio of SAP is 1.5%, and the adding ratio of 2.0% or more adversely affects the compressive strength and freeze-thaw resistance.

Numerical study on contact behavior of TSL (Thin Spray-on Liner) (접촉 거동을 고려한 TSL(Thin Spray-on Liner)의 수치해석 연구)

  • Lee, Chulho;Chang, Soo-Ho;Lee, Kicheol;Kim, Dongwook
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.17 no.6
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    • pp.665-674
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    • 2015
  • A TSL (Thin Spray-on Liner) which consists of polymers has a higher initial strength, faster construction time and higher waterproofing performance than the conventional cementitious shotcrete. Main supporting mechanism of TSL is the adhesion and tensile strength which is distinct from the conventional shotcrete. Even though highly in demand due to its outstanding characteristics, TSL is not yet well-known support material. In this study, to evaluate contact behavior of TSL, numerical analysis was performed with comparing result from laboratory tests. From the analysis, cohesive behavior at the contact surface between TSL and rock can be evaluated by using combination of cohesive and the damage model. In addition, results show that the cohesive stiffness controled slope between force and displacement, the fracture energy controled level of force at the contact.

Study on Pre-treatment Method for Vitrification of Concentrated Wastes (농축폐기물 유리화를 위한 전처리 방안 연구)

  • Cho, Hyun-Je;Kim, Deuk-Man;Park, Jong-Kil
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.3
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    • pp.221-227
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    • 2010
  • The solidification methods for powder wastes dried at CWDS(Concentrate Waste Drying System) in PWR have been studied in a variety of ways both at home and abroad. The solidification for these wastes has been performed using stabilization agents such as cement, paraffin and polymer. The applicability studies to maximize the reduction ratio of wastes and operational effectiveness for wastes treatment have been carried out, recently. It is necessary to pretreat the powder wastes before feeding wastes to vitrification facility because the fines flying brings about clogging of feeding pipes and off-gas treatment system or workers' exposure to radiation during maintenance. This paper describes an effective method for treatment of powder wastes to improve safety and stability of vitrification facilities.