• Title/Summary/Keyword: 폴리머 박막

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Characterization of superhydrophilic thin films fabricated by a layer-bylayer self-assembly method (교호흡착법에 의해 제조된 초친수 박막 특성)

  • Kim, Jin-Ho;Hwang, Jong-Hee;Lim, Tae-Young;Jang, Jang-Hoon;Kim, Sae-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.4
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    • pp.168-172
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    • 2010
  • Superhydrophilic thin film consisted of positively charged poly (allylamine hydrochloride) (PAH) and negatively charged poly (acrylic acid) (PAA) was fabricated by a layer-by-layer (LBL) self-assembly. Glutaraldehyde (GA) was used in order to increase an adhesion hardness by amine-aldehyde reaction. The surface morphology, thickness, transmittance, water contact angle and adhesion hardness of PAH/PAA thin film with or without GA were measured. The adhesion hardness of PAH/PAA thin film with GA deposition increased over 2 times although the film thickness of PAH/GA/PAA decreased than that of PAH/PAA thin film. The increase of adhesion hardness by amine-aldehyde reaction between PAH and GA was measured by fourier transform infrared (FT-IR) spectroscopy. Fabricated PAH/PAA and PAH/GA/PAA thin films showed water contact angel under $5^{\circ}$ and high transmittance over 91.3% at 550 nm.

Fabrication of TiO2/polyelectrolyte thin film for a methyl mercaptan gas sensor (메칠멜캅탄 가스센서용 TiO2/전해질폴리머 박막 제조)

  • Kim, Jin-Ho;Hwang, Jong-Hee;Lee, Mi-Jai;Kim, Sei-Ki;Lim, Tae-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.5
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    • pp.221-226
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    • 2010
  • Quartz crystal microbalance (QCM) gas sensor to detect methyl mercaptan ($CH_3SH$) gas was fabricated by depositing $TiO_2$ nanoparticles and polyelectrolyte on the electrode of QCM. The $TiO_2$/poly(sodium 4-styrenesulfonate) (PSS) thin film fabricated by a layer-by-layer self-assembly (LBL-SA) method showed a high surface area and increased the sensitivity of gas sensor. When the QCM sensors coated with triethanolamine (TEA) or ($TiO_2$/PSS) were exposed to methyl mercaptan gas (1.0 ppm), the frequency shifts of QCM with TEA casting film and $TiO_2$/PSS thin film were ca. 9 Hz and ca. 24 Hz, respectively. As the bilayer number of ($TiO_2$/PSS) increased, the frequency shift of QCM sensor with ($TiO_2$/PSS) thin film was gradually increased. In addition, the frequency shift of QCM sensor was gradually increased as the concentration of methyl mercaptan gas increased from 0.5 ppm to 2.0 ppm. In this study, the surface morphology and sensor property of QCM sensor coated with ($TiO_2$/PSS) thin film were measured.

Design of Variable Optical Attenuators Incorporating Large Core Polymer Waveguides (대형 코어 폴리머 광도파로를 이용한 가변 광감쇠기 설계)

  • Cho, Su-Hong;Oh, Min-Choel
    • Korean Journal of Optics and Photonics
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    • v.16 no.3
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    • pp.254-260
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    • 2005
  • By incorporating large core polymer waveguides, which have been developed for increased alignment tolerance in passive fiber attachment, highly efficient variable optical attenuators are proposed. In order to find optimum device structures, 3-dimensional beam propagation method (BPM) simulations are performed. Heat distribution over the polymer film is calculated to find the 3-dimensional index profile data for the BPM simulation. Due to the small index contrast between the core and cladding materials in the large core waveguide, heat-induced radiation occurs for small heating power. While the ordinary VOA needs the temperature to change over $150^{\circ}C$ for 20 dB attenuation, the large core VOA requires only $70^{\circ}C$. In addition to the merit of passive fiber attachment, the proposed VOA has enhanced attenuation efficiency for the lower temperature change.

Surface Modification of Gold Electrode Using Nafion Polymer and Its Application as an Impedance Sensor for Measuring Osmotic Pressure (나피온 폴리머를 이용한 금 전극의 표면 개질 및 이의 삼투압 측정용 임피던스 센서 응용)

  • Min Sik, Kil;Min Jae, Kim;Jo Hee, Yoon;Jinwu, Jang;Kyoung G., Lee;Bong Gill, Choi
    • Applied Chemistry for Engineering
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    • v.34 no.1
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    • pp.9-14
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    • 2023
  • In this work, we developed a Nafion polymer-coated impedance sensor with two gold electrode configurations to measure the ion concentration in solution samples. The gold electrodes were fabricated through the sputtering process, followed by surface modification using Nafion polymer. The resulting sensors enable the prevention of the polarization phenomenon on the electrode surface, resulting in stable measurement of electrochemical signals. Spectroscopy and scanning electron microscopy measurements revealed that the thin film of Nafion was coated uniformly onto the surface of the gold electrode. The Nafion-coated sensor exhibited more stable impedance signals than the conventional gold electrode. It showed a highly reliable calibration curve (R2 = 0.983) of the impedance sensor using a standard sodium chloride solution. In addition, a comparison experiment between the impedance sensor and a commercial conductivity sensor was performed to measure the ion concentration of artificial tears, showing similar results for the two sensors.

Flexural Reinforcement of RC Structures with composite fiber rods inserted in high strength special purposed polymer mortar for various deteriorated conditions. (박막형 고강도 폴리머 및 열화원인별 적용 몰탈내에 섬유로드를 삽입하는 RC 구조물의 보강공법 연구)

  • 정원용;이상근;박홍진
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10a
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    • pp.828-835
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    • 2000
  • In recent years, RC structures need reinforcement due to physical and chemical deterioration, reduction of serviceability and structural capacity. For reinforcement of RC structures, steel plate attachment, area increase and composite fiber sheet attachment methods are used, but there are some problems like weight increase, workability, quality control and fire resistance capacity. This study presents the effectiveness of flexural reinforcement of RC beams using composite rods that are inserted in high strength special purposed polymer mortar.

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Light diffraction in anisotronic surface relief phase grating (비등방 표면 부조 격자에서의 빛의 회절)

  • 장혜정;강보영;최현희;박병주;우정원
    • Proceedings of the Optical Society of Korea Conference
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    • 2003.07a
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    • pp.166-167
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    • 2003
  • 아조벤젠 그룹의 trans-cis-trans photo isomerization 특성에 의한 광배향 (photoinduced orientation) 성질을 이용하여 아조벤젠이 함유된 폴리머박막에 표면 부조 격자 (surface relief grating)를 만드는 것은 널리 알려져 있다. 특히 최근 들어, 비선형 물질의 주기적인 배열 구조를 만들기 위해서 surface relief grating을 corona poling 하는 방법들이 연구되어 지고 있다. poling된 surface relief grating은 poling 방향으로의 azo분자의 극질서가 유도되기 때문에, $C_{{\infty}v}$점대칭을 가지는 비등방 회절 격자(anisotropic grating)가 되며 2차 비선형 특성 중의 하나인 선형 전기 광학 효과를 나타낼 수 있다. (중략)

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Micro Patterning Using Near-Field Coupled Nano Probe Laser Photo Patterning Of Chloromethylated Polyimide Thin Film (클로로메틸 폴리이미드(CMPI) 박막과 근접장 나노 프로브 레이저 패터닝을 이용한 미세 형상 가공 기술)

  • 최무진;장원석;김재구;조성학;황경현
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.369-372
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    • 2004
  • Photo-induced surface alignment is charming as a non-contact photo-patternable alignment technology which can be used in the next generation of displays, such as large area, multi-domain. For decades, many polymer film have been investigated and developed to be used in the photo alignment. Among these photoreactive materials, recently developed polyimide, Chloromethylated Polyimide(CMPI) now became the focus of interests in this area because of its high photosensitivity and superior thermal stability. In this report, we present micro patterning method to form the nanoscale structure by Mask-Less laser patterning using this CMPI film and NSOM probe.

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Fiber optic circular polarizing mirror using polymer cholesteric liquid crystal and it's application in the mode-locked fiber laser (콜레스테릭 액정 폴리머 박막을 이용한 광섬유 원편광 거울 제작 및 이를 이용한 모드 록킹 된 광섬유 레이저)

  • 장도일;김경헌;김인선;김성태
    • Korean Journal of Optics and Photonics
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    • v.11 no.2
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    • pp.91-96
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    • 2000
  • We propose a novel in-line fiber optic circular polarizing mirror utilizing cholesteric lIquid crystal (CLC) polymer [11m for the fiber laser applications. Ions matrix representation of this device has been derived and venfied experimentally. In a Fabry-Perot cavity configuration, a CLC fiber optic rmrror has been used to achieve longitudinal mode suppression as well as to obtain passively mode~locked laser operations with 630 fs laser pulses via nonlinear polarization evoluhon.oluhon.

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