• Title/Summary/Keyword: 폴리머 개질

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Properties of Polymer-Modified Pastes with Alumina Powder (알루미나 분말을 혼입한 폴리머 개질 페이스트의 성질)

  • Joo, Myung-Ki;Lee, Youn-Su;Yeon, Kyu-Seok
    • Journal of the Korea Concrete Institute
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    • v.19 no.5
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    • pp.539-547
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    • 2007
  • The effects of binder and alumina content on the setting time, drying shrinkage, strength, freezing and thawing resistance and water absorption of polymer-modified pastes with alumina powder were examined. As a result the setting time of the polymer-modified pastes with alumina powder tended to delay with increasing binder content. Irrespective of the type of polymer, the drying shrinkage of the polymer-modified pastes with alumina powder tended to decrease with increasing binder content and alumina powder content. Regardless of the type of polymer, the tensile and adhesion strengths of the polymer-modified pastes with alumina powder tended to increase with increasing binder content and alumina powder content. Irrespective of the type of polymer, the durability factors of the polymer-modified pastes with alumina powder tended to increase with increasing alumina content. Irrespective of the type of polymer, the water absorptions of the polymer-modified pastes with alumina powder tended to decrease with increasing binder content and alumina content.

Cost Analysis of Asphalt Pavements Reinforced with Glass Fiber and Polymer Modified Using Falling Weight Deflectometer (Falling Weight Deflectometer를 이용한 섬유보강 아스팔트 및 폴리머 개질 아스팔트 포장의 비용 효과 분석)

  • Kim, Boo-Il;Lee, Moon-Sup;Jeon, Sung-Il;Kim, Sang-Kyu
    • International Journal of Highway Engineering
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    • v.11 no.4
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    • pp.153-160
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    • 2009
  • Falling Weight Deflectometer (FWD) tests were performed to evaluate the structural capacity of glass fiber reinforced (GFR), polymer modified (PM), and unmodified asphalt pavement in Korea-LTPP (Long Term Pavement Performance) section. FWD tests showed that the tensile strains of GFR and PM asphalt pavements at the bottom of asphalt layer were 29% and 21% less than that of unmodified asphalt pavement. The structural capacity was then used as a performance criterion for calculating the cost effect of GFR and PM asphalt pavements. From the results, 5cm of asphalt layer thickness was reduced by applying GFR asphalt, and 3cm by applying PM asphalt. However, construction cost of PM and GFR asphalt pavement were increased due to the higher GFR and PM asphalt price. Life cycle cost analysis showed that the initial construction cost of GFR and PM asphalt pavement were higher but the management and user cost were less than those of unmodified asphalt pavement.

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Improving the Wettability of Polymeric Surfaces and Surface Modification of Ceramic by Ion Beam in Reactive gases Environments (반응성 가스 분위기하에서 이온빔을 이용한 폴리머 표면의 친수성 증대 및 세라믹표 면개질)

  • 손용배
    • Journal of the Microelectronics and Packaging Society
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    • v.3 no.1
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    • pp.11-24
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    • 1996
  • 부분압이 다른 여러 가지 반응성 가스분위기하에서 이른곤 이온을 이용하여 PC, PET PMMA 그리고 PTFE 폴리머 표면의 삼차 증류수에대한 진수성을 증대하였다. 폴리머 표면의 친수성의 변화는 여러 가지 반응성 가스 분위기하에서 아르곤 이온의 조사량을 1014 부터 1x1017cm2까지 변화하면서 조사하였다. 접촉감은 아르곤 이온이 조사되는 폴리머 표면 근처에 유입된 가스의 방응성(O2>N2>H2)에 따라 많이 감소하였다, 폴리머 표면에 형성된 친수성기는 XPS Cls, Ols, 그리고 Nls 스펙트럼을 분석하여 확인하였다. 표면 개질된 PC와 PTFE에 대한 Al 금속의 접착력 증대를 Scotch tape와 인장실험을 통하여 확인하였다. 접착 력 증가는 표면 에너지 중 polar force의 증가에 의한 것으로 입증되었다. 에너지를 가진 아 르곤 입자 폴리머 체인 그리고 반응성 가스 사이의 반응기구는 2단계 모델로 설명가능하였 는데 그 기구는 첫 번째 이온의 조사에 의한 불안정한 폴리머 체인의 형성과 두 번째 단계 로 이렇게 형성된 폴리머 체인과 반응성 가스들 사이의 화학반응으로 이루어진다. 질화아루 미늄의 표면을 산소분위기하에서 아르곤 빔을 조사하여 표면개질한후 AlON층이 새롭게 형 성된 것을 XPS를 이용하여 확인할수 있었다. 개질된 질화알루미늄과 구리금속 박막간의 접 착력을 scratch 실험을 통하여 조사하였다.

The Evaluation of Technology for Temperature Reduction of Mixing & Compaction for Polymer Modified Asphalt (폴리머 개질 아스팔트의 생산 및 시공 온도 저감기술 평가)

  • Jo, Shin-Haeng;Ryu, Ju-Yeol;Lee, Jin-Gu;Kim, Nak-Seok
    • 한국방재학회:학술대회논문집
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    • 2010.02a
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    • pp.46.2-46.2
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    • 2010
  • 아스팔트 포장의 공용성능 행장을 위해 널리 사용되고 있는 폴리머 개질 아스팔트(PMA)는 높은 생산온도와 다짐온도로 인해 생산 시 연료 소비가 많고 시공관리가 어려운 단점을 가지고 있다. 이에 중온형 아스팔트 기술을 접목하여 고온에서의 아스팔트 점도를 낮춤으로써 이와 같은 문제점을 해결하고자 하였다. 바인더의 전반적 공용성능 향상을 위해서 폴리머 (SBR)와 작업성 개선을 위해 Wax 및 기타 첨가제를 혼합하여 아스팔트 바인더를 제조하였으며, 실험결과 PG 82-22의 높은 공용등급의 바인더를 얻었으며, 생산 및 시공온도는 기존의 PMA 아스팔트와 달리 일반 스트레이트아스팔트와 비슷한 수준을 확보하였다. 이를 이용한 아스팔트 혼합물의 공용 성능 면에서도 PMA개질 아스팔트와 비슷한 수준을 나타내었다.

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Experimental Study on the Characteristics of Polymer-modified Lightweight Aggregate Concrete Using SBR Latex (SBR Latex를 이용한 폴리머 개질 경량콘크리트의 특성에 관한 실험적 연구)

  • Ahn, Nam-Shik;Won, Dong-Min;Park, Noh-Hyun;Kim, Hee-Cheul;Kim, Kwan-Soo
    • Journal of Korean Association for Spatial Structures
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    • v.9 no.4
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    • pp.61-72
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    • 2009
  • As a trend of construction has become high-rise and larger, it is necessary to reduce the self-weight of structures and buildings. One of the most effective methods to reduce the self-weight of structures and buildings is to use the lightweight aggregate concrete. To complement the strength of the lightweight aggregate concrete, polymer was added to concrete's mixing. In this study, experiments to make the moderate mixing proportion of polymer modified lightweight concrete were performed. Also the hardened concrete tests were performed to investigate the physical characteristics of the polymer-modified lightweight aggregate concrete. As a result, the flexural strength was increased by a small quantity of SBR Latex. Based on the test results the estimating equation was proposed through the regression analysis.

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Tensile Strength of Polymer-Modified Asphalt Concrete at Low-Temperature (폴리머 개질아스팔트 콘크리트의 저온 인장강도 특성)

  • Doh, Young-Soo;Kwon, Seung-Zoon;Kim, Kwang-Woo
    • International Journal of Highway Engineering
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    • v.4 no.3 s.13
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    • pp.35-42
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    • 2002
  • Many temperature-related problems are created in asphalt pavement due to the low temperature. In particular, loss of tensile strength due to low temperature is known to be responsible for thermal failure of pavements in cold regions under $-20^{\circ}C$. The objective of this study is to evaluate characteristics of resistance against low-temperature cracking of polymer asphalt concrete mixtures modified with LDPE and SBS. The test results showed that the mixtures had the maximum indirect tensile strength(ITS) at low temperature ranging from $-10^{\circ}C. It was proved through ITS test that the stress due to differential thermal contraction over the tensile strength did generate internal damage at the temperature below $-20^{\circ}C$. It was shown that the asphalt mixtures modified with polymer had better ITS than the normal asphalt mixture at the temperature below $-20^{\circ}C$. Thus the effect of modification was revealed as tensile strength improvement. From the results of this study, it was recommended that polymer-modified asphalt should be used in order to prevent low-temperature cracking in cold region.

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Strength Properties of Ultrarapid-Hardening Acrylic-Modified Concrete (아크릴 개질 초속경 폴리머 시멘트 콘크리트의 강도 특성)

  • Joo, Myung-Ki;Noh, Byung-Chul;Kim, Young-Sang;Choi, Kyu-Hyung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.945-948
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    • 2008
  • The effects of polymer-cement ratio on strength properties of ultrarapid-hardening acrylic-modified concretes. As a result, the flexural and tensile strengths of ultrarapid-hardening acrylic-modified concretes increase with increasing of polymer-cement ratio. In particular, the acrylic-modified concretes with a polymer-cement ratio of 20% provide approximately 1.5 times higher flexural and tensile strengths than unmodified concretes. Such high strength development is attributed to the high flexrul and tensile strengths of arcylic polymer and the improved bond between cement hydrates and aggregates because of the addition of acrylic polymer. However, the compressive strengths of ultrarapid-hardening acrylic-modified concretes decrease with increasing of polymer-cement ratio.

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Experimental Investigation of the Flexural Behavior of Polymer-modified Lightweight Aggregate Concrete One-Way Members (폴리머 개질 경량콘크리트 일방향 부재의 휨 거동에 관한 실험적 연구)

  • Byon, Eun-Hyuk;Kim, Min-Sook;Lee, Young-Hak;Kim, Hee-Cheul
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.23 no.5
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    • pp.551-557
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    • 2010
  • The purpose of this study is to estimate experimentally the flexural behavior, capacity and validity of existing regulation of net tensile strain in lightweight concrete beams and polymer modified lightweight concrete beams. One normal weight concrete beam and four lightweight concrete beams, three polymer modified lightweight concrete beams were constructed as same figure and attempted to evaluate the difference of strength and ductility in specimens of different net tensile strain in extreme tension steel. Test results are indicated in terms of load-deflection behavior and ductility index. As the value of net tensile strain increased, the flexural strength and stiffness of specimen decreased but ductility index increased in both of lightweight concrete beams and polymer modified lightweight concrete beams. It is considered that to achieve similar ductility index of normal weight concrete, net tensile strain in extreme tension steel should exceed 0.005 for lightweight concrete beam and polymer modified lightweight concrete beam.

Cycling Performances of Lithium-Ion Polymer Cells Assembled with Surface-Modified Separators Containing Aluminum Fluoride (불화 알루미늄을 포함하는 표면 개질된 분리막으로부터 제조되는 리튬이온폴리머전지의 싸이클 특성에 관한 연구)

  • Eo, Seung-Min;Kim, Dong-Won
    • Journal of the Korean Electrochemical Society
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    • v.11 no.2
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    • pp.125-129
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    • 2008
  • Rechargeable lithium-ion polymer batteries have been considered to be next-generation power sources for portable electronic devices and electric vehicles. In this work, we tried to improve the cycling performances of lithium-ion polymer cells by coating aluminum fluoride and acrylonitrile-methyl methacrylate copolymer to the polyethylene separator. It was found that the addition of aluminum fluoride to the surface-modified separator reduced the interfacial resistances and thus the cell exhibited a less capacity fading and better high rate performance. The cell showed an initial discharge capacity of 150 mAh/g and good capacity retention at 0.5 C rate.

Durability of concrete using sulfur-modified polymer (개질유황 폴리머를 사용한 콘크리트의 내구성 평가)

  • Hong, Chang Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.5
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    • pp.205-211
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    • 2015
  • Most of the sulfur is obtained from desulfurization of natural gas and crude oil. In Korea, more than 120 tons of sulfur are produced by refinery, and about 50 % of the produced sulfur is used as a raw material for the production of fertilizer and sulfuric acid. Modified sulfur is manufactured from excessive sulfur that could be used to improve concrete properties, and this study evaluated concrete strength and durability that contains modified sulfur. Flexural and compressive strengths of concrete with sulfur modified polymer were comparable to those of OPC concrete with mixing water at similar temperatures, while the strengths increased a little as mixing water temperature increased. It was also confirmed that the resistance to freeze-thaw damage was more dependent on entrained air characteristics obtained by a proper use of air entraining agent than on the use of sulfur modified polymer. When concrete was immersed in 5 % sulfuric acid, the rate of reduction in compressive strength of OPC concrete was less than 1/4 of the strength reduction of concrete with sulfur modified polymer. Also, the resistance of concrete with sulfur modified polymer to scaling due to the use of de-icing salt was evaluated as Class 1, while that of OPC concrete was evaluated as Class 4, as aggregates were exposed. Accordingly, it is believed that sulfur modified polymer could be effectively used for bridge deck concrete since sulfur modified polymer improves the durability of concrete.