• Journal of the Mineralogical Society of Korea
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• v.7 no.1
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• pp.49-61
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• 1994

As the groundwater flows along the fractures of crystalline rocks, it will be in contact with the fracture walls mostly coated by secondary minerals which are quite different form those of host rocks. The presence of fracture-filling minerals in crystalline rocks is important on the view point of radioactive waste disposal because of their great surface reactivity. The Surichi drill hole of 200 m in depth in the Yugu area composed mainly of Precambrian gneiss was selected to study the formation process of clay minerals on the fracture wall of gneiss, and their relation with present groundwater. The water-rock interaction in fractures resulted in the formation of gibbsite and clay minerals. They are formed by two different processes : (1) Incongruent dissolution of feldspar by groundwater diffused from a fracture path into rock matrix produced smectite and illite in situ, (2) on the wall of fracture, gibbsite, kaolinite, smectite and illite are formed by precipitation of dissolved species in groundwater. They show the paragenetic sequence such as gibbsite${\leftrightarrow}$kaolinite${\leftrightarrow}$smectite or illite. The paragenetic sequence of fracture-filling minerals was controlled by increase of pH of groundwater, decrease of fracture permeability by precipitation of fillings, and immobility of alkali or alkaline earths in groundwater. The groundwater from the Surichi borehole is a $Na-HCO_{3}$ type with pH range of 8.6-9.2. The sodium and bicarbonate in groundwater would be supplied by the dissolution of albite and calcite, respectively. The saturation index of groundwater and surface water calculated by WATEQ4F indicates that gibbsite and kaolinite are under precipitation to equilibrium state, and that smectite and illite are under equilibrium to redissolution environment. The stability relation of clay minerals in the $Na_{2}O-Al_{2}O_{3}-SiO_{2}-H_{2}O$ system shows that kaolinite is stable for all waters.

• Journal of Bio-Environment Control
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• v.24 no.3
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• pp.161-166
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• 2015

To determine the adequate levels of light intensity and $CO_2$ concentration for mango grown in greenhouses, quantitative measurements of photosynthetic rates at various leaf positions in the tree are required. The objective of this study was to develop two-variable leaf photosynthetic models of Irwin mango (Mangifera indica L. cv. Irwin) using light intensity and $CO_2$ concentration at different leaf positions. Leaf photosynthetic rates at different positions (top, middle, and bottom) were measured by a leaf photosynthesis analyzer at light intensities (0, 50, 100, 200, 300, 400, 600, and $800{\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$) with $CO_2$ concentrations (100, 400, 800, 1200, and $1600{\mu}mol{\cdot}mol^{-1}$). The two-variable model consisted of the two leaf photosynthetic models expressed as negative exponential functions for light intensity and $CO_2$ concentrations, respectively. The photosynthetic rates of top leaves were saturated at a light intensity of $400{\mu}mol{\cdot}^{-2}{\cdot}s^{-1}$, while those of middle and bottom leaves saturated at $200{\mu}mol{\cdot}^{-2}{\cdot}s^{-1}$. The leaf photosynthetic rates did not reach the saturation point at a $CO_2$ concentration of $1600imolmol^{-1}$. In validation of the model, the estimated photosynthetic rates at top and bottom leaves showed better agreements with the measured ones than the middle leaves. It is expected that the optimal conditions of light intensity and $CO_2$ concentration can be determined for maximizing photosynthetic rates of Irwin mango grown in greenhouses by using the two-variable model.

• The Journal of the Petrological Society of Korea
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• v.19 no.3
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• pp.167-180
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• 2010

The geochemical studies on the plutonic rocks of the Geochang, the central part of the Ryongnam massif, were carried out in order to constrain the petrogenesis and the paleotectonic environment. The objects of this study are dioritic rocks, biotite granite and hornblende granite. The modal compositions indicate that the dioritic rocks are quartz diorite, quartz monzodiorite, tonalite, biotite granites are granodiorite, granite and hornblende granites are granite, quartz monzonite, quartz syenite. These rocks belong to the calc-alkaline series. Especially, trace elements such as Sr, Nb, Sr, Ti are depleted, suggesting that these rocks are produced in the subduction zone related to calc-alkaline series. Also, the studied granitic rocks correspond to peraluminous and I-type. Chondrite-normalized REE patterns show that LREE are enriched much more than HREE, and have weak Eu(-) anomaly. It is similar to pattern of Jurassic granitoids in the South Korea. Total REE value of the biotite granite and hornblende granite ranges 76.21~137.05 ppm and 73.84~483.21 ppm, respectively, also $(La/Lu)_{CN}$ value ranges 9.61~36.47 and 7.17~21.85. It is suggest that studied rocks suppor their emplacement at active continental margin. Also, these rocks are derived from magma generated by partial melting of lower continental crust materials.

• Journal of Soil and Groundwater Environment
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• v.7 no.3
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• pp.115-132
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• 2002

To distinguish the anthropogenic inputs from the chemical weathering with water-rock interaction on the chemical compositons of groundwater in Kwangju city, four different water groups were established based on the landuse type, lithology and topology. The sample from greenbelt area belongs to Group Ⅰ, whereas those from green buffer zone, urban area and industrial area belong to Group II, Group Ⅲ and Group Ⅳ, respectively. The geology of this city mainly consists of biotite granite and granitic gneiss. The concentration of main cations is subject to the behavior of feldspars, micas and carbonate minerals. Cl$\^$-/ and NO$_3$$\^$-/ are supplied by anthropogenic inputs such as domestic sewage whose concentration of these anions is highest in the Group Ⅲ samples. With the Piper diagram, the groundwaters of Group Ⅲ are mainly plotted in CaSO$_4$-CaCl$_2$ type, whereas those of other groups are plotted in Ca(HCO$_3$)$_2$ type, The calculation for the activities of ions and saturation indices of some minerals shows that most of the minerals are undersaturated and plotted in the area of equlibrium with kaolinite. Three factors were extracted from the factor analysis for chemical data. Factor 1 controlled by HCO$_3$$\^$-/, Ca$\^$2-/, SO$_4$$\^$2-/, Mg$\^$2+/ and Na$\^$+/, explains the dissolution of carbonate minerals. mica and plagioclase. Factor 2, controlled by Cl$\^$-/ and NO$_3$$\^$-/, explains the influence of artificial pollution. Factor 3, controlled by Mn, Fe and Zn is subject to the industrial waste water, but the evidence is not clear. Factor 1 is dominant in the Group I and II, indicating that those samples are subjected to natural chemical weathering, The higher scores of factor 2 in the Group Ⅲ samples indicate the potential artificial pollution.

• Journal of the Mineralogical Society of Korea
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• v.22 no.2
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• pp.139-151
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• 2009

Mineralogical characteristics of secondary precipitate formed at some mineral water springs in Gyeongbuk Province, Korea were studied in relation to water chemistry. The chemical water types of mineral water springs are mostly classified as $Ca-HCO_3$ type, but $Na(Ca)-HCO_3$ and $Ca-SO_4$ types are also recognized. Ca, Fe, and $HCO_3\;^-$ are the most abundant components in the water. The pH values of most springs lie in 5.76${\sim}$6.81, except Hwangsu spring having pH 2.8. Saturation indices show that all springs are supersaturated with respect to iron minerals and oxyhydroxides such as hematite and goethite. The result of particle size analysis shows that the precipitate is composed of the composite with various sizes, indicating the presence of iron minerals susceptible to a phase transition at varying water chemistry or the mixtures consisting of various mineral species. The particle size of the reddish precipitate is larger than that of the yellow brown precipitate. Based on XRD and SEM analyses, the precipitate is mostly composed of ferrihydrite (two-line type), goethite, schwertmannite, and calcite, with lesser silicates and manganese minerals. The most abundant mineral fanned at springs is ferrihydrite whose crystals are $0.1{\sim}2\;{\mu}m$ with an average of $0.5\;{\mu}m$ in size, characterized by a spherical form. It should be interestingly noted that schwertmannite forms at Hwangsu spring whose pH is very low. At Shinchon spring, Gallionella ferruginea, one of the iron bacteria, is commonly found as an indicator of the important microbial activity ascribed to the formation of iron minerals because very fine iron oxides with a spherical form are closely distributed on surfaces of the bacteria. A genetic relationship between the water chemistry and the formation of the secondary precipitate from mineral water springs was discussed.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.27 no.4
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• pp.246-257
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• 2015

The progressive degradation paths of structures have quantitatively been tracked by using stochastic processes, such as Wiener process, gamma process and compound Poisson process, in order to consider both the sampling uncertainty due to the usual lack of damage data and the temporal uncertainty associated with the deterioration evolution. Several important features of stochastic processes which should carefully be considered in application of the stochastic processes to practical problems have been figured out through assessing cumulative damage and lifetime distribution as a function of time. Especially, the Wiener process and the gamma process have straightforwardly been applied to armors of rubble-mound breakwaters by the aid of a sample path method based on Melby's formula which can estimate cumulative damage levels of armors over time. The sample path method have been developed to calibrate the related-parameters required in the stochastic modelling of armors of rubble-mound breakwaters. From the analyses, it is found that cumulative damage levels of armors have surely been saturated with time. Also, the exponent of power law in time, that plays a significant role in predicting the cumulative damage levels over time, can easily be determined, which makes the stochastic models possible to track the cumulative damage levels of armors of rubble-mound breakwaters over time. Finally, failure probabilities with respect to various critical limits have been analyzed throughout its anticipated service life.

• The Journal of Engineering Geology
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• v.30 no.3
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• pp.289-302
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• 2020

To determine the shallow subsurface structure and sliding surface of land creeping in 2016 at Hadong-gun, Gyeongsangnam-do, geophysical surveys (electric resistivity, and refraction seismic methods, borehole televiewer) and slope stability analysis were conducted. The subsurface structure delineated with borehole lithologies and seismic velocity structures provided the information that the sediment layer on the top of the slope was rather as thick as 20 m and the underlying weathered rock (anorthosite) was thinner than 1 m. Based on the tension cracks observed during the geological mapping, televiewer scanning was performed at the borehole BH-2 and detected the intensive fracture zones at the ground-water level, associated with the slip weak zones mapped in dipole-dipole electrical resistivity section. Downslope sliding and slightly upward pushing at the apex of high resistive bedrock explains the curved slip plane of the land creeping. Such a convex structure might play a role of natural toe abutment for preventing the downward development of slip weak zones. In slope stability analysis, the safety factors of the slip weak zone are calculated with varying the groundwater levels for dry and rainy seasons and the downslope is founded to be unstable with safety factor of 0.89 due to fully saturated material in rainy season.

• Journal of the Korean Society for Marine Environment & Energy
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• v.6 no.4
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• pp.24-36
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• 2003

In this study, we estimated the seasonal fluctuations of water quality and effect of small tide embankment in coastal water around the Muan Peninsula, which is located in the northern part of Mokpo city, and layer farming ground is spread around there. Some physical and chemical factors were analyzed to characterize water quality from Jan. to Oct. in 1994. The results were as follows: Dissolved oxygen was slightly under saturation in the almost areas of July, and in some bottom layer at ebb tide of October. Distribution of COD showed high values that over 2㎎/L in October and flood tide of April by the discharge of freshwater and resuspension of benthic sediment, which exceeded water quality criteria II. Maximum values of dissolved inorganic nitrogen ware appeared in surface layer during the flood tide of October, while minimum of that showed in surface layer in April. Concentration of dissolved inorganic phosphorus was higher at July than the others, which ranged from 0.24 to 2.08㎍-at/L. Mostly mean values of N/P ratio were lower than 16, it mean that nitrogen is more limiting nutrient than phosphorus for the growth of phytoplankton. The values of eutrophication index were in the range of 0.07~0.81. However, very high values due to increase of COD were estimated near the tide embankment and southern part in relation to tidal current in October. Water quality around tide embankment was suddenly changed worse within a short period after opening the water gate during the rainfall.

• Journal of the Korean Society for Marine Environment & Energy
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• v.19 no.4
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• pp.274-285
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• 2016

In order to elucidate the spatiotemporal variations of marine environmental parameters, we collected seawater samples in the middle east coast of Korea in 2013-2014. A high temperature and low salinity were distinctively observed in the summer and a low temperature and high salinity pattern in the winter. The temperature of the bottom water was in the range of $2^{\circ}C$ to $7^{\circ}C$, with the temperature being relatively high in the winter, while the salinity was measured to be around 34, with no large differences across the seasons. The dissolved oxygen concentrations were in the range of $7mg\;L^{-1}$ to $12mg\;L^{-1}$, and it was relatively high in May compared to other seasons. The seawater temperature and dissolved oxygen concentration at the surface layer showed a significant negative correlation in the autumn and winter seasons, based on which it is seemed that water temperature is the main factor controlling the amount of dissolved oxygen in the autumn and winter seasons. The dissolved inorganic nitrogen (DIN) and silicate (DSi) increased 11- and 7-fold, respectively, in the winter compared to the summer. The DIN to DIP (dissolved inorganic phosphorus) ratio for the surface seawater was approximately 16, but it was relatively low in the spring season. On the other hand, the DIN to DIP ratio was relatively high in the summer. Based on this, it is seemed that nitrogen and phosphorus were the growth-limiting nutrients for phytoplankton in the spring and summer, respectively. Water quality was I (excellent) ~III (medium) level at the most stations except for some stations (level IV) during the autumn season, having low dissolved oxygen saturations.

• Journal of the Korean Geotechnical Society
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• v.33 no.3
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• pp.49-62
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• 2017

In order to understand response of geo-structures to the freezing-thawing process in the ground, it is necessary to consider phase change of the pore water of the ground and also to understand soil interaction with structures. In this study, numerical analysis was carried out for freezing and thawing effect on the modular road system. Neumann's theoretical equation for freezing-thawing processes in porous media can be used to estimate frozen depth and heaving from basic soil properties and ground and surface temperature, but its application is limited to the case for the sediment with fully saturated condition and zero unfrozen water content. Numerical analysis of the modular road system was performed on various soil types and different ground water table as the varying freezing index. The amount of heaving in the silty soil was much larger than those in granite weathered soil or sandy soil, and lowering groundwater level reduced ground heaving induced by freezing. Numerical analysis for temperature history of the ground surface predicted residual heaving near the surface by the freeze-thaw process in silty soil. It ought to reduce stiffness and bearing capacity of the ground so that it will impair stability and serviceability of new road system. However, the amount of residual heaving was insignificant for the road system installed in weathered soil granite and sandy soil. Since modular road system is a pavement structure mounted on the supporting substructure unlike the prevalent road pavement system, strict criteria should be applied for uniform and differential settlement of the pavement system.