• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2003.04a
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• pp.35-35
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• 2003

)를 금속와이어에 인가하면 저항발열에 의해 와이어가 미세한 입자나 금속증기상태로 폭발하는 현상을 이용한 것으로 기상합성법에 속한다고 할 수 있다. 선폭법은 다른 제조법에 비해 공정이 간단하여 생산비용이 저렴하며, 원재료의 조성을 갖는 분말의 합성과 금속간화합물, 융점차이가 나는 재료의 합금화 등이 가능하다. 인가에너지의 크기와 폭발 시 분위기를 제어함으로써 분말의 평균크기와 분포 제어 또한 가능하다. 본 연구는 러시아의 우수한 기초기술을 바탕으로 Pb-Sn계 합금은 전기폭발법으로 극미세분말을 제조하였으며, 분말의 형상, 상 화학조성의 변화를 조사하였다. 본 실험에 사용된 Sn-Pb계(All-Union State Standard 1499-70, 0.53mm)합금와이어는 자동시스템(1-0.6Hz)에 의해 챔버안으로 공급되었다. 이 때 임계폭발 와이어 길이는 50-80nm으로 실험을 행하였다. 챔버 압력은 1.4~2.0atm으로 유지하였다. 제조된 분말의 특성은 XRD, XRPES, SEM등을 이용하여 분말의 형상과 상, 화학조성, 표면분석을 행하였으며 DSC, TGA, BET분석을 통하여 온도변화에 따른 금속분말의 열량변화, 질량변화, 비표면적을 측정하였다. 제조된 Sn-Pb계 분말은 모두 평균 입도 117nm~220nm의 구형형상이었다. 이때 합금분말의 조성은 51.17~63.21 at%Sn, 35.47~46.37 at%Pb로 나타났다. 와이어에 인가되는 비에너지(W/Wc)가 감소된에 EK라 표면층의 Pb함량이 증가함을 보였다. 이는 와이어 내부 저항의 감소로 인한 공정시간의 지연과 Sn, Pb의 확산계수 차이에 의한 것으로 사료된다. 열분석 결과, Sn~Pb계 화합물의 융점은 167~$169^{\circ}C$로 관찰되었으며, $10^{\circ}C$/min로 $920^{\circ}C$까지 승은 하였을 때 17.1~18 wt%의 질량증가를 보였다.TEX>계 나노복합분말이 얻어짐을 알 수 있었다. 이 때 X션 회절피크의 line broadening으로부터 복합분말의 Fe 명균 결정립 크기는 24nm로 초미세 결정럽의 분말합금이었다. 포화자화값은 볼밀처리에 따라 점점 증가하여 MA 30시간에는 20.3emu/g로 포화됨을 알 수 있었다. 또한 보자력 Hc는 MA초기단계에 350e로 매우 낮으나 30시간 후에는 Hc값이 2600e로 매우 큰 값을 나타내었다. 이것은 환원반응결과 초기에 생성된 Fe의 결정립이 비교적 크고 결정결함이 적으나 볼밀처리를 30시간까지 행하면 Fe 결정렵의 미세화 빛 strain 증가로 magnetic hardening이 일어나기 때문인 것으로 사료된다.길이가 50, 30cm인 압출재를 제조하였다. 열간압출한 후의 미세조직을 광학현미경으로 압출방향에 평행한 방향과 수직방향으로 관찰하였고, 열간 압출재 이방성을 검토하기 위하여 X선 회절분석을 실실하여 결정방위를 확인하였다. 전기 비저항 및 Seebeck 계수 측정을 위하여 각각 2$\times$2$\times$10$mm^3$ 그리고 5$\times$5$\times$10TEX>$mm^3$ 크기의 시편을 준비하였다.준비하였다.전류를 구성하는 주요 입자의 에너지 영역(75~l13keV)에서 가장 높은(0.80) 상관계수를 기록했다. 넷째, 회복기 중에 일어나는 입자들의 유입은 자기폭풍의 지속시간을 연장시키는 경향을 보이며 큰 자기폭풍일수록 현저했다. 주상에서 관측된 이러한 특성은 서브스톰 확장기 활동이 자기폭풍의 발달과 밀접한 관계가 있음을 시사한다.se that were all low in two aspects, named "the Nonsignificant group". And the issues were high risk perception in general setting and lo

• Tunnel and Underground Space
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• v.17 no.6
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• pp.464-474
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• 2007

An enhancement in the performance and safety of a high-level waste repository requires a validation of its engineered barrier. An engineering-scale test (named "KENTEX") has been conducted to investigate the thermal-hydro-mechanical behaviors in the engineered barrier of the Korean reference disposal system The validation test started on May 31, 2005 and is still under operation. The experimental data obtained allowed a preliminary and qualitative interpretation of the thermal-hydro-mechanical behaviors in the bentonite blocks. The temperature was higher as it became closer to the heater, while it became lower as it was farther away from the heater. The water content had a higher value in the part close to the hydration surface than that in the heater part. The relative humidity data suggested that a hydration of the bentonite blocks might occur by different drying-wetting processes, depending on their position. The total pressure was continuously increased by the evolution of the saturation front in the bentonite blocks and thereby the swelling pressure. Near the heater region, there was also a significant contribution of the thermal expansion of bentonite and the vapor pressure in the pores of the bentonite blocks.

• The Journal of Engineering Research
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• v.3 no.1
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• pp.223-233
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• 1998

The kinetic and mechanism of the hydrothermal reaction between lime and quartz used solid state reaction equations have been investigated. Hydrothermal reaction on the starting materials was carried out in an autoclave that quartz mixed with calcium hydroxide in CaO/$SiO_2$ ratio of 0.8-1.0 for 0.5-8 hour at saturated steam pressure of $180-200^{\circ}C$. The rate of reaction was given from the ratio of uncombined lime and quartz content to the total lime and quartz content. The rate of reaction was obtained the results by the Jander's equation $[1-(1-\alpha)^{1/3}]^N=Kt$. The reaction of lime is controlled mainly by the dissolution such as N=1, and the reaction of quartz is controlled mostly by the diffusion such as $N\risingdotseq2$. The rate of hydrothermal reaction in the calcium silicate hydrates system is suggested to be determined generally by the mass transfer through the product laver formed around the reactant particles. The rate equation for whole hydrothermal reaction is shown that it is converted into the rate determining step by the diffusion from the boundary reaction such as approximately $N=1-2$.

• Journal of the Korean Geotechnical Society
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• v.19 no.4
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• pp.55-64
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• 2003

Desiccation of a soil is basically the removal of water by evaporation, which is controlled by evaporativity and evaporability. Surface evaporation improves the trafficability which is essential for the access of construction equipment in the area reclaimed with soft clay. The existing traditional methods for evaluating evaporation can not account for the deformation of reclaimed soft soils during evaporation. Therefore, a theoretical model for predicting the rate of evaporation from the surface of a deformable material is proposed. The model is based on a system of equations for coupled heat and mass transfer in unsaturated soils. The modified pressure plate extractor test and glass desiccator test were carried out to obtain the soil-water characteristic curve for a deformable soil. The column drying test was conducted to investigate one dimensional water flow, heat flow and evaporation in the surface. A finite difference program was developed to solve the coupled nonlinear partial differential equations, which permit the study of water, vapor and heat flows in the deformable soil. Comparison between measured and simulated values shows a reasonably good matching between the two.

• Journal of the Korean Institute of Gas
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• v.12 no.3
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• pp.43-49
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• 2008

The evaporation heat transfer coefficient and pressure drop of R-22 and R-407C in horizontal copper tubes were investigated experimentally. The main components of therefrigerant loop are a receiver, a compressor, a mass flow meter, a condenser and a double pipe type evaporator (test section). The test section consists of a smooth copper tube of 4.3 mm and 6.4 mm inner diameter. The refrigerant mass fluxes were varied from 100 to $300[kg/m^2s]$ and the saturation temperature of evaporator were 5 [$^{\circ}C$]. The evaporation heat transfer coefficients of R-22 and R-407C rise with the increase in mass flux and vapor quality. The evaporation heat transfer coefficient of R-22 for inner diameter tube of 4.3 mm and 6.4 mm is about $7.3{\sim}47.1%$ and $5.68{\sim}46.6%$ higher than that of R-407C, respectively.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.11a
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• pp.342-342
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• 2007

원자층 증착(Atomic Layer Deposition: ALD) 방법은 반응물질들을 펄스형태로 챔버에 공급하여 기판 표면에 반응물질의 표면 포화반응에 의한 화학적 흡착과 탈착을 이용한 박막증착기술이다. ALD법은 박막의 조성 정밀제어가 쉽고, 파티클 발생이 없으며, 대면적의 박막 증착시 균일성이 우수하고, 박막 두께의 정밀 조절이 용이한 장점이 있다. 원자층 증착 공정에서 짧은 시간 안에 소스를 충분히 공급하기 위한 방법으로는 소스 온도를 증가시켜 전구체의 증기압을 높여 반응기로의 유입량을 증가시키는 방법, 전구체의 공급시간을 늘리는 방법 등을 들 수 있다. 그러나 전구체 온도를 상승시키는 경우, 공정 조건의 변화가 요구되며 전구체의 변질에 의하여 형성된 막이 의도하는 막 특성을 만족시키지 못하게 되는 문제점이 발생될 우려가 있다. 그리고 전구체를 충분히 공급하기 위하여 전구체의 공급시간을 늘이는 방법을 사용하면, 원하는 두께의 막을 형성하기 위하여 소요되는 공정시간이 증가된다. 이를 해결하기 위해 수송가스를 이용한 버블러 형태의 전구체 공급 장치를 사용하지만 이 또한 전구체의 수명을 단축시키는 단점을 가지고 있다. 본 논문에서는 위의 문제점을 극복할 수 있는 새로운 개념의 수송가스 도움 전구체 공급 장치를 소개한다. 본 연구에서 사용된 수송가스 도움 전구체 공급 장치를 가지는 ALD 장비는 Lucida-D200 (NCD Technology사)이며 기판으로는 8인치 실리콘 웨이퍼를 사용하였으며 (TEMA)Zr을 사용하여 ZrO2 박막을 성장하였다. 수송가스 도움 전구체 공급 장치를 사용한 경우, 그렇지 않은 경우 보다 $30^{\circ}C$ 이상 전구체 온도를 낮출 수 있으며, 또한 증착 속도를 약 2배정도 증가시킬 수 있었다. 이들 박막들은 XRD, XPS, AFM 등을 이용하여 결정구조, 결합에너지, 표면 거칠기 등의 특성을 관찰하였다. 그리고 C-V, I-V 측정을 이용해 정전용량, 유전율, 누설전류 등의 전기적 특성을 평가하였다.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.8 no.2
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• pp.121-131
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• 2003

We have found that the east coast of Korea has had few sea fogs on January, February, November and December for the past 20 years by the analysis of monthly fog frequency and duration time. These phenomena appear to relate to the topographical characteristics of which the Taebaek Mountains descends toward the east to bar the radiation fog. On the other hand, the cause of occurring the spring and summer fog which has 90% of the whole frequency is divided into three cases. The first is the steam fog caused by the advection of the northeast cold air current on the East Sea due to the extension of Okhotsk High. The second is the advection fog caused by cooling and saturation of warm airmass advected on cold sea surface. And the last is the frontal fog caused by the supply of enough vapor due to the movement of low-pressure system and the advection of cold air behind a cold front. While, we simulate the sea fog for the period of the case studies by implementing fog prediction system(DUT-METRI) that makes it possible to forecast the fog in the vertical section of neighborhood of the East Sea and to predict the sea surface wind, relative humidity, ceiling height, visibility etc. Finally we verified this result by satellite image.

• Journal of the Korean Institute of Gas
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• v.22 no.3
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• pp.38-44
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• 2018

Ammonia is used primarily as a refrigerant in refrigeration facility and SCR of a plant, and is frequently involved in leakage accidents. This study was conducted by selecting ammonia, a material with a wide influence range when evaluated, as a material with higher vapor pressure and lighter than air. In this study, the influence ranges were computed using KORA(Korea Off-site Risk Assessment supporting tool) with four different environmental factors : ground roughness, sealing, operating temperature, pressure, and leakage hole size. As a result, the difference in the influence range of ground roughness is approximately 4.62 times, while the ammonia storage tank shows a difference in the reduction rate of 0.64 when sealed. The extent of impact increased with increasing leakage depending on storage temperature and pressure, and when storing higher than the saturation vapor pressure, the impact range showed an average growth rate of 3.45 % per 0.1 Mpa($45^{\circ}C$). The influence ranges based on the size of the leakage holes is shown to be proportional to the area of the leakage zone.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.9
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• pp.150-155
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• 2019

Cavitation refers to a phenomenon in which empty spaces occur in a fluid due to changes in pressure and a velocity. When a liquid moves at a high speed, the pressure drops below the vapor pressure, and vapor bubbles are generated in the liquid. This study used CFD to analyze the flow of fluid machinery used in marine and offshore plants. The goals are to ensure the validity of the analysis method for marine propellers in an open water test, to increase the forward ratio, and to use FLUENT to understand the flow pattern due to cavitation. A three-dimensional analysis was performed and compared with experimental data from MOERI. The efficiency was highest at advance ratios of 0.7 - 0.8. Thrust was generated due to the difference between the pressure surface and the suction surface, and it was estimated that bubbles would be generated in the vicinity of the back side surface rather than the face side of the propeller, resulting in more cavitation. The cavitation decreased sharply as the advance ratio increased. The thrust and torque coefficients were comparable to those of the MOERI experimental data except at the advance ratio of 1, which showed a difference of less than 5%. Therefore, it was confirmed that CFD can evaluate an open water propeller test.

• Journal of Food Hygiene and Safety
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• v.29 no.3
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• pp.234-240
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• 2014

Fluxapyroxad is classified as carboxamide fungicide that inhibits succinate dehydrogenase in complex II of mitochondrial respiratory chain, which results in inhibition of mycelial growth within the fungus target species. This study was carried out to assure the safety of fluxapyroxad residues in agricultural products by developing an official analytical method. A new, reliable analytical method was developed and validated using High Performance liquid Chromatograph-UV/visible detector (HPLC-UVD) for the determination of fluxapyroxad residues. The fluxapyroxad residues in samples were extracted with acetonitrile, partitioned with dichloromethane, and then purified with silica solid phase extraction (SPE) cartridge. Correlation coefficient($R^2$) of fluxapyroxad standard solution was 0.9999. The method was validated using apple, pear, peanut, pepper, hulled rice, potato, and soybean spiked with fluxapyroxad at 0.05 and 0.5 mg/kg. Average recoveries were 80.6~114.0% with relative standard deviation less than 10%, and limit of detection (LOD) and limit of quantification (LOQ) were 0.01 and 0.05 mg/kg, respectively. All validation parameters were followed with Codex guideline (CAC/GL 40). LC-MS (Liquid Chromatograph-Mass Spectrometer) was also applied to confirm the analytical method. Base on these results, this method was found to be appropriate fluxapyroxad residue determination and can be used as the official method of analysis.