• Fire Science and Engineering
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• v.27 no.1
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• pp.39-45
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• 2013

This study analyzes the explosion hazard of dry cleaning solvent recovery machine in laundry shop in two aspects, i.e. combustible and ignition source, and determines the explosive conditions of this machine by conducting mockup explosion tests repeatedly, varying conditions and using real dry cleaning solvent recovery machines. As to combustibles, two kinds of combustibles used widely in Korea have been selected and tested. The flash points, LEL's, and saturation vapor pressures of those combustibles have been measured, and their explosion specific curves have been drawn, based on the results of the measurements, so that the explosion risks of those materials may be determined, depending on the temperatures. Potential voltages generated from materials for laundry and foreign materials of metals have been assumed to be the ignition sources in this application, and their potential voltages have been measured, depending on temperature, humidity, and antistatic agent, by using real materials for laundry and a potential voltage measuring device. Tests have been conducted, varying the quantities, concentrations, and operating temperatures of materials for laundry. As a result, explosions have not been generated with potential voltages of materials for laundry, but explosions have been observed when applying artificial spark energy of 2.0 mJ.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.14 no.3
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• pp.655-668
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• 1994

Conventional deodorization filters using soil and compost reach the capacity limitation of deodorization in short period, because its removal mechanism primarily depends on adsorption. Therefore, in this study the experiment was performed on the removal of ammonia which is a strong inorganic malodor, frequently emitted from night soil treatment plants and sewage treatment plants, by seeding activated sludges on the bio-peat containing higher organic contents, water conservation capacity, permeability and lower pressure drop. As a result, in raw peat filter natural ammonia outlet was observed in consequence of pH increase resulted from ammonia ionizing in liquid phase. Ammonia removal mechanism primarily depended on the adsorption onto the anion colloidal substances in peat. In peat bio-filter, theoretical ammonium salts ratio was higher than that of raw peat, resulted from slight pH increase by microorganism activity, however, the experimetal value of ammonia-nitrogen accumulated in bio-peat was lower than that of raw peat because of nitrification by nitrifying bacteria. In the initial reaction period, adsorption was predominant in the ammonia removal mechanism, but nitrification was conspicuous after the middle period. Mass balance of nitrogen was established using experimental data of input $NH_3$ loading, output $NH_3$ loading, $NH_4{^+}$-N, $NO_x$-N, and Org-N. The critical time of unsteady state, which is the maximum activating point of microorganism in bio-filter, was determined using experimental data, and the ammonia adsorption curve was computed using regression analysis. On the basis of the results obtained by above analysis, the delay days for the saturation of adsoption capacity in peat bio-filter was calculated.

• Korean Chemical Engineering Research
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• v.47 no.6
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• pp.727-733
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• 2009

Effects of $Ca(OH)_2$ concentration(0.16~0.64 wt%), total volumetric flow rate(3~6 L/min) and $CO_2$ volume fraction(0.3~0.6) on morphology of the precipitated $CaCO_3$ and the mean particle size of the precipitated $CaCO_3$ were investigated in the slurry bubble column reactor. Experiments were carried out in acrylic reactor($0.11m-ID{\times}1.0m-high$) with a internal tube($0.04m-ID{\times}1.0m-high$). The calibration curve on the mass ratio of $CaCO_3$ to $Ca(OH)_2$ was obtained by FT-IR for the conversion of $Ca(OH)_2$ with the reaction time. The reaction rate of $Ca(OH)_2$ increased with increasing the volumetric flow rate of $CO_2$. From SEM images, the crystal size of $CaCO_3$ increased with increasing the reaction rate in the saturated concentration of $Ca(OH)_2$ (0.16 wt%). In addition, the crystal size of precipitated $CaCO_3$ decreased with increasing the concentration of $Ca(OH)_2$, but the mean particle size of precipitated $CaCO_3$ increased with increasing the concentration of $Ca(OH)_2$.

• Resources Recycling
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• v.12 no.6
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• pp.13-18
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• 2003

The initial NiCuZn synthetic ferrite were acquired from thermally decomposing the metal nitrates Fe($NO_3$)$_3$ㆍ$9H_2$O, Zn($NO_3$)$_2$ㆍ$6H_2$O, Ni($NO_3$3)$_2$ㆍ $6H_2$O and Cu(NO$_3$)$_2$ㆍ $3H_2$O at 1$50^{\circ}C$ for 24 hours and was calcined at $500^{\circ}C$. Each of those was pulverized for 3 and 9 hours in a steel ball mill and was sintered between $700^{\circ}C$ and $1,000^{\circ}C$ for 1 hour, and then their microstructures and magnetic properties were examined. We could make the initial specimens chemically bonded in liquid at the temperature as low as $150 ^{\circ}C$, by using the melting points less than $ 200^{\circ}C$ of the metal nitrates instead of the mechanical ball milling, then narrowed a distance between the particles into a molecular level, and thus lowed sintering temperature by at least $200 ^{\circ}C$ to $300^{\circ}C$ Their initial permeability was 50 to 490 and their saturation magnetic induction density and coercive force 2,400G and 0.3 Oe to 1.2 Oe each, which were similar to those of NiCuZn ferrite synthesized in the conventional process.

• Journal of the Korean Magnetics Society
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• v.13 no.2
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• pp.64-69
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• 2003

Ba-ferrite thin films were prepared on Si substrate with ${\alpha}$-Fe$_2$O$_3$ underlayer by a pulsed laser deposition system and characterized by X-ray, SEM, Mossbauer spectroscopy and VSM. The appropriate conditions of pulsation in ${\alpha}$-Fe$_2$O$_3$ and Ba-ferrite were the oxygen pressure of 0.1 Torr at a substrate temperature of 400$^{\circ}C$. Ba-ferrite crystals had the forms of ellipsoidal or needle and the grains shaped the more lumps with increasing the film thickness. Mossbauer spectroscopy assured that the direction of atomic spin in Fe ion was not random but had the tendency of arrangement normal to the substrate. The coercive force and squareness of hysteresis were larger in normal than in plane to the substrate but, the magnetic saturation moment was contrary to them. The spin arrangement was strongly affected by ${\alpha}$-Fe$_2$O$_3$ underlayer and the high coercive force and squareness were influenced by this. The crystal structure was conformed to be a Magntoplumbite symmetry with the hexagonal unit cell and the lattice constant of a increased with increasing film thickness, while c decreased

• Journal of the Korean Magnetics Society
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• v.21 no.3
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• pp.88-92
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• 2011

We grew $Zn_{0.4}Fe_{2.6}O_4$ thin films using Pulsed Laser Deposition and studied their crystal structure and magnetical characteristics as a function of growth temperature ($T_g$). For the film with $T_g=300^{\circ}C$, X-ray reflections from ${\alpha}-Fe_2O_3$ and ZnO were observed. However, when $T_g$ was increased from 300 to $500^{\circ}C$, crystal structure of inverse spinel was stabilized with the crystal orientation of $Zn_{0.4}Fe_{2.6}O_4(111)/Al_2O_3(0001)$ without any detection of ${\alpha}-Fe_2O_3$ and ZnO phases. The surface morphology shows flattening behavior with increasing $T_g$ from 300 to $500^{\circ}C$. These observations indicate that Zn is substituted into tetrahedron A-site of the inverse-spinel $Fe_3O_4$. M-H curves exhibit clear ferromagnetism for the sample with $T_g=500^{\circ}C$ whereas no ferromagnetism is observed for the film with $T_g=300^{\circ}C$.

• Journal of the Korean Magnetics Society
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• v.17 no.2
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• pp.60-64
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• 2007

Ba-Ferrite single crystals were prepared and characterized by X-ray, SEM and Mossbauer spectroscopy. The single crystal layers was cut in the c-axis and radiated to the surface by ${\gamma}-rays$ for Mossbauer spectroscopy. We found out that the spin states in Fe atoms were parallel to the ${\gamma}-rays$ direction. The temperature dependence of the hyperfine field is almost similar to that of powder samples. The crystal structure is a Magnetoplumbite without any other phases and the lattice parameters are found out with $a_0=5.892{\AA},\;b_0=5.892{\AA},\;c_0=23.198{\AA}$. $M\"{o}ssbauer$ spectrum in single crystal have 5 sets off absorption lines in each Fe site when the ${\gamma}-rays$ have the same radiation direction with the c-axis in the crystal, which mean that the whole crystal bulk formed only one crystal and same spin direction. The hysteresis curve shows the saturation moment and coercive force of 70.71 emu/g and 320 Oe respectively.

• Journal of Radiation Protection and Research
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• v.23 no.4
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• pp.237-242
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• 1998

The goal of this work was to optimize the liquid scintillation counting techniques for the determination of C-14 in environmental samples such as biological and air samples. Carbon-14 activities in most environmental samples were measured with direct $CO_2$ absorption method. The highest figure of merit was found through the variation of Carbosorb $E^{TM}$ and Permatluor $V^{TM}$ ratio, in the measurement windows. The best condition was 1:1 volume ratio. Average 2.35 g of $CO_2$ was reproducibly absorbed in the 20 ml mixture within 40 min. The counting efficiency determined by repeated analysis of NIST oxalic acid standard and the background count rate were measured to be $58.8{\pm}1.4%$ and $1.88{\pm}0.06\;cpm$, respectively in case of saturated solution. The correction curves of counting efficiency for partially saturated solutions and for saturated solutions with quenching were prepared, respectively. The overall uncertainty of the sample specific activity for near background levels was estimated to be about 7 % for 4 hours counting at 95 % confidence level. The long-term stability of samples has been checked for all the counting techniques over a two week periods, and no apparent change in counting efficiency and background level was found at that time.

• Korean journal of applied entomology
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• v.39 no.4
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• pp.251-258
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• 2000

These studies were conducted to investigate the prey consumption and suppression of cotton aphid and green peach aphid by Chrysopa pallens Ramber as a predator. The 3$^{rd}$ instar of C. pallets fed on 29.8, 77.9, 133.6, and 155.7 individuals of apterous Aphis goussypii Glover a day at 17,22, 27, and 32$^{\circ}C$, respectively. A preovipositing female fed on 73.1 individuals, ovipositing female on 86.6 individuals, and adult male on 69.7 individuals of apterous Myzus persicae (Sulzer) a day at the 27$^{\circ}C$. The functional response curve of the larvae and adults of C. pallens to the densities of A. gossypii indicated Helling’s Type II: the consumption of prey by the C. pallens increased with the prey density but the consumption rate decreased. The attack rate of 3rd instar of C. pallens was the highest among the 2nd instar, 3$^{rd}$ instar, adult male and adult female, and handling time was the shortest. The critical ratio of the predator vs. the prey to effectively suppress the population of A. gossypii by releasing C. pallets eggs was 1 : 4 on red pepper and egg plant, and 1 : 3 on cucumber. Release of second larval stave of C. pallens at the ratio of 1 : 30 of the predator vs. the prey controlled satisfactorily A. gossypii on red pepper, and 1 : 20 on cucumber and tomato. The three-times introduction of the eggs of C. pallens was as effective as four applications of insecticides from mid-June to late September.r.

• Journal of Korea Soil Environment Society
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• v.2 no.2
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• pp.25-33
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• 1997

To investigate the effects of cow manure compost(CMC) on soil and water environment as non-point source, the elution patterns of anions were determined in muti-layered soil columns which were consisted of one top and one bottom in combination. The top soil columns were uniformly packed with Ap horizon soils amended with air-dried CMC at different ratios(0, 2, 4, 6%, wt/wt), the bottom ones were packed with of B horizon soils of 15, 30, and 45cm in length. After saturating the each soil column, the leachate were collected from the bottom of the column while the double-ionized water was applied from the surface of the column by constant head method. From the hydraulic conductivity and anion eluted were measured in the leachate. Each saturated hydraulic conductivities for top and the bottom soils were 3$\times$$10^{-4}$sec and 1.6$\times$$10^{-3}$cm/sec. Most of water soluble chloride and sulfate, having non-specific adsorption characteristics onto the soil particles, were eluted within 1 PV, showing that there was no apparent retardation of anion movement with increasing CMC contents in the top soils. The effect of soil depths on anion movement were similar to the results of CMC contents. Sulfate of having both of non-specific and specific adsorption characteristics was also recovered in the effluent within 1 PV, while the elution curves were slightly skewed to the right showing that the CMC affected the movement of sulfate. Phosphate of specific adsorption characteristics was hardly eluted within 5 PV.