• Analytical Science and Technology
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• v.27 no.2
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• pp.108-113
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• 2014

The harmful materials as volatile organic compounds (VOCS) that is easy for gas to be changed from liquid on ambient temperature, those should be controlled by Korea Chemicals Management Association. The VOCs samples should be collected directly in place so that those could be analyzed. Generally but it couldn't avoid to have the risk of analyst. Moreover, if there is the place limited to entrance, it is impossible to collect directly and measure. Owing to such problem, it tried to be solved by open path FT-IR spectrometer that could be studied on the combustion gases within long path and VOCs samples were tried to measure to large volume by remote and real time. Firstly, it was to investigate optimized measured length between the system and benzene sample of VOCs. As result, The optimized measured length was confirmed with 15 meter length and the qualitative analysis could be measured on seven VOC samples. The calibration curve as quantitative analysis of benzene samples could be worked. On the basis of the result, the system as remote monitor could show to have potentiality.

• Economic and Environmental Geology
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• v.47 no.6
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• pp.625-633
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• 2014

The Aquistore project is the world's first commercial capture, transportation, utilization and storage project of post-combustion $CO_2$ from a coal-fired thermo electric power plant, and the proposed storage is a saline aquifer at a depth of about 3,500 m. Deep saline aquifer, compared to hydrocarbon reservoir, provides the great volumetric potential for storage of $CO_2$ anywhere in the world, therefore the research results from the project may be exported globally to other sites. Geological $CO_2$ storage characterization for saline aquifer instead of hydrocarbon reservoir needs to estimate the geophysical properties of subsurface geology. This study calculated the geophysical property of water-saturated formation by applying amplitude variation analysis developed from oil and gas exploration. We correlated horizon tops at the well logs to seismic traveltime of 1,815 and 1,857 ms as Winnipeg and Deadwood formations. Gradient analysis from seismic traces showed correlation coefficient of 45 - 81 % on amplitude variation with respect to incident angle. Crossplot of intercept and gradient shows the inverse proportional trend which represents typical water saturated sediments. Product attribute of intercept and gradient described the base of wet sediment. Poisson's ratio change attribute increased at the top of target area satisfying with wet sediment and decreased at the top of basement in a dry rock bed.

• Korean Journal of Food Science and Technology
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• v.23 no.4
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• pp.420-427
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• 1991

The structure of fresh, salted and heated petiole tissue from Chinese cabbage was examined with optical microscope, and the pectin of the tissues was fractionated by successive extraction. The pectin in Chinese cabbage consisted mainly of high methoxyl pectin(pA) and low methoxyl pectin(pB). The pA content was converted to pB markedly by salting and heating at $60{\sim}70^{\circ}C$ for 30 min while heating the cabbage above 80 decreased pB content. The firmness of heated tissue was highly correlated with pB content(r=0.996). Cytorrhysis test showed that pore size of the tissue became smaller by salting and heating at temperature below $80^{\circ}C$.

• Tunnel and Underground Space
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• v.26 no.4
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• pp.293-303
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• 2016

Underground $CO_2$ storage technology is one of the most effective methods to reduce atmospheric $CO_2$. In this study, $CO_2$ storage condition was simulated in the laboratory. Sandstone and shale specimens were saturated in 1M NaCl and were reacted at $45^{\circ}C$, 10 atm for 4 weeks. The physical and microstructural properties of rock specimens were measured. Variations on physical properties of shale specimens were bigger than those of sandstone specimens, such as volume, density, elastic wave velocity, Poisson's ratio and Young's modulus. Microstructure were analyzed using X-ray computed tomography. Total number of pores were decreased, and average volume, average area and average equivalent diameter of each pore were changed after $CO_2$ reaction. Swelling and leakage of clay mineral caused by $CO_2$-mineral reaction were the reason of changes. The results of this study can be applied to predict the physical and microstructural changes in underground $CO_2$ storage condition.

• Tunnel and Underground Space
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• v.26 no.3
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• pp.181-191
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• 2016

In geological storage of $CO_2$, the behavior of $CO_2$ is influenced by pore network of rock. In this study, the drilling cores from Pohang Basin were analyzed quantitatively using three-dimensional images acquired by X-ray micro computed tomography. The porosities of sandstone specimens around 740 m-depth (T1), 780 m-depth (T2) and 810 m-depth (T3) which were target strata were 25.22%, 23.97%, 6.28%, respectively. Equivalent diameter, volume, area, local thickness of pores inside the sandstone specimens were analyzed. As a result, the microstructural properties of T1 and T2 specimens were more suitable for geological storage of $CO_2$ than those of T3 specimens. The result of the study can be used as input data of the site for decision of injection condition, flow simulation and so on.

• Journal of the Korean GEO-environmental Society
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• v.24 no.6
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• pp.5-11
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• 2023

The engineering industry heavily relies on fossil fuels such as coal and petroleum to generate energy through combustion. However, this process emits carbon dioxide into the atmosphere, leading to global warming. To mitigate this issue, researchers have explored various methods to reduce carbon dioxide emissions, one of which is carbon dioxide underground storage technology. This innovative technology involves capturing carbon dioxide from industrial plants and injecting it into the saturated ground layer beneath the earth's surface, storing it securely underground. Despite its potential benefits, carbon dioxide underground storage efficiency needs improvement to optimize storage in a limited space. To address this challenge, our research team has focused on improving storage efficiency by utilizing surfactants. Furthermore, we evaluated how different carbon dioxide states, including gaseous, liquid, and supercritical, impact storage efficiency based on their respective pressures and temperatures within the underground reservoir. Our findings indicate that using surfactants and optimizing the injection rate can effectively enhance storage efficiency across all carbon dioxide states. This research will pave the way for more efficient carbon dioxide underground storage, contributing to mitigating the environmental impact of fossil fuels on the planet.

• Journal of Navigation and Port Research
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• v.47 no.3
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• pp.134-146
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• 2023

The issue of 'carbon reduction' can be said to be one of the most important issues worldwide. For efficient carbon reduction, it is necessary to consider ways to increase absorption and reduce emissions. Accordingly, much attention has been paid to increasing carbon absorption using blue carbon biomass. Blue carbon biomass refers to an ecosystem related to blue carbon, which has a higher carbon absorption rate than inland ecosystems and a longer collection period. It is very efficient in reducing carbon. Therefore, in this study, a current status survey was conducted on domestic and foreign policies, studies, and plans related to the preservation of blue carbon biomass habitats. Basic research was conducted to prepare plans for future preservation of blue carbon biomass habitats suitable for the domestic environment.

• Applied Chemistry for Engineering
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• v.35 no.2
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• pp.134-139
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• 2024

In the steam reforming of methane reactions, the effect of adding noble metals Ru and Pd to a Ni-based catalyst as promoters was analyzed in terms of catalytic activity and hydrogen production. The synthesized catalysts were coated on the surface of a honeycomb-structured metal monolith to perform steam methane reforming reactions. The catalysts were characterized by XRD, TPR, and SEM, and after the reforming reaction, the gas composition was analyzed by GC to measure methane conversion, hydrogen yield, and CO selectivity. The addition of 0.5 wt% Ru improved the reduction properties of the Ni catalyst and exhibited enhanced catalytic activity with a methane conversion of 99.91%. In addition, reaction characteristics were analyzed according to various process conditions. Methane conversion of over 90% and hydrogen yield of more than 3.3 were achieved at a reaction temperature of 800 ℃, a gas hourly space velocity (GHSV) of less than 10000 h^-1, and a ratio of H₂O to CH₄ (S/C) higher than 3.

• Journal of the Korean Society for Marine Environment & Energy
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• v.18 no.2
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• pp.94-101
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• 2015

To mitigate the greenhouse gas emission, many carbon capture and storage projects are underway all over the world. In Korea, many studies focus on the storage of $CO_2$ in the offshore sediment. Assurance of safety is one of the most important issues in the geological storage of $CO_2$. Especially, the assessment of possibility of leakage and amount of leaked $CO_2$ is very crucial to analyze the safety of marine geological storage of $CO_2$. In this study, the leakage of injected $CO_2$ through fault was numerically studied. TOUGH2-MP ECO2N was used to simulate the subsurface behavior of injected $CO_2$. The storage site was 150 m thick saline aquifer located 825 m under the continental shelf. It was assumed that $CO_2$ leak was happened through the fault located 1,000 m away from the injection well. The injected $CO_2$ could migrate through the aquifer by both pressure difference driven by injection and buoyancy force. The enough pressure differences made it possible the $CO_2$ to migrate to the bottom of the fault. The $CO_2$ could be leaked to seabed through the fault due to the buoyancy force. Prior to leakage of the injected $CO_2$, the formation water leaked to seabed. When $CO_2$ reached the seabed, leakage of formation water stopped but the same amount of sea water starts to flow into the underground as the amount of leaked $CO_2$. To analyze the effect of injection rate on the leakage behavior, the injection rate of $CO_2$ was varied as 0.5, 0.75, and $1MtCO_2/year$. The starting times of leakage at 1, 0.75 and $0.5MtCO_2/year$ injection rates are 11.3, 15.6 and 23.2 years after the injection, respectively. The leakage of $CO_2$ to the seabed continued for a period time after the end of $CO_2$ injection. The ratios of total leaked $CO_2$ to total injected $CO_2$ at 1, 0.75 and $0.5MtCO_2/year$ injection rates are 19.5%, 11.5% and 2.8%, respectively.

• Korean Journal of Remote Sensing
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• v.28 no.4
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• pp.449-458
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• 2012

Using the MODerate resolution Imaging Spectro-radiometer (MODIS) retrieved aerosol optical thickness (AOT) along with ground measurements of PM2.5 mass concentration, we assessed local air quality over Dukjuk and Jeju island and estimated possibility of satellite derived PM2.5 during nine intensive observation periods in 15 October 2005 - 24 October 2007. Averaged PM2.5 mass concentrations showed relatively variable as $25.61{\pm}22.92{\mu}g/m^3$ at Dukjuk and $17.33{\pm}10.79{\mu}g/m^3$ at Jeju. The maximum values of $188.89{\mu}g/m^3$ (Dukjuk) and $50.46{\mu}g/m^3$ (Jeju) were recorded during Asian dust storm day. Similarly, the maximum values of MODIS AOT were found as 3.73 (Gosan) and 1.14 (Jeju). Averaged MODIS AOTs at Dukjuk ($0.79{\pm}0.81$) were larger than that at Jeju ($0.42{\pm}0.24$). An empirical relationship between MODIS AOT and PM2.5 mass was obtained and results show that there was a good correlation between satellite and ground based values with a linear correlation coefficient of 0.85 at Dukjuk. The result clearly demonstrates that satellite derived AOT is a good surrogate for monitoring PM air quality over study area. However, meteorological and other ancillary datasets are necessary to further apply satellite data for air quality research.