• Title/Summary/Keyword: 포졸란반응

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The Physical-Chemical and Pozzolanic Characteristics for the Recycling of Incinerated Pulp and Sewage Sludge Ashes (제지 및 하수슬러지 소각재의 재활용을 위한 물리화학적 특성 및 포졸란 반응특성)

  • Ju, So-Young;Yeon, Ik-Jun;Kim, Kwang-Yul
    • Journal of the Korean GEO-environmental Society
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    • v.4 no.4
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    • pp.35-43
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    • 2003
  • In this study, the physical and chemical characteristics of incinerated pulp and sewage sludge ashes for recycling and reuse were examined. Then we studied the application to the cement admixture by pozzolanic reaction. The particle size of incinerated pulp and sewage sludge ashes was distributed around $10{\sim}100{\mu}$, and the contents of $SiO_2$ and $Al_2O_3$ were 45.8~51.0%, respectively. Compressive strengths of the solidified ashes were relatively higher, when the content of substituted incineration ashes was 10% and the porosity was also lower except for the case of sewage sludge ash. As results, it is shown that it may be possible to recycle incinerated pulp sludge ashes as cement admixtures.

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Pozzolanic reaction of classified fly ash (분급 플라이애쉬의 포졸란반응 특성)

  • Lee, Seung-Heun;Hwang, Hae-Jeong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.753-756
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    • 2006
  • This paper discussed pozzolanic reaction properties of classified fly ashes by using of electrostatic precipitator. Blaine values of fly ashes at hoppers are respectively about 3000(ordinary), 5000(fine) and 8000cm2/g(super-fine). The pozzolanic reactivity of fly ash at early stage and at later stage are respectively related to the related to the fineness and the glass content of fly ash. But the early hydration of cement was retarded by addition of super fine fly ashes. the adiabatic temperature rise of mortar containing fly ash is increased with the fineness of fly ashes.

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Pozzolanicity of Calcined Sewage Sludge with Calcination and Fineness Conditions (소성조건 및 분말도에 따른 소성하수슬러지(CSS)의 포졸란 특성)

  • So, Hyoung-Seok;So, Seung-Young;Khulgadai, Janchivdorj;Kang, Jae-Hong;Lee, Min-Hi
    • Journal of the Korea Concrete Institute
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    • v.27 no.1
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    • pp.65-73
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    • 2015
  • This study discussed the pozzolanic properties of calcined sewage sludge (CSS) according to calcination and fineness conditions. The chemical and mineralogical analysis of CSS according to calcination temperature and time were carried out and compared with that of the existing pozzolanic materials such as fly-ash, blast furnance slag and meta-kaolin. Various mortars were made by mixing those CSS and $Ca(OH)_2$ (1:1 wt. %), and their compressive strength and hydrates according to experimental factors such as fineness of CSS and curing age were also investigated in detail. The results show clearly the potentiality of calcined sewage sludge (CSS) as an admixture materials in concrete, but the CSS should be controlled by calcination temperature and time, and fineness etc. In this experimental condition, the calcination temperature of $800^{\circ}C$, calcination time of 2 hours and fineness of $5,000cm^2/g$ were optimum conditions in consideration of the mechanical properties and economic efficiency of CSS. The compressive strength of CSS mortars was higher than that of fly-ash mortars and blast furnace slag mortars, especially at the early ages. Then, the utilization of CSS in construction fields was greatly expected.

Effect of Meta Kaolin addition to Activation of waste concrete sludge

  • 황규홍;김재준;연상흠
    • Cement Symposium
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    • no.32
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    • pp.217-221
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    • 2005
  • The utilization of calcined clay, in the form of meta kaolin, as a pozzolanic for mortar and concrete has received considerable attention in recent years. so, the influence of waste concrete sludge and meta kaolin on cement concrete strength has been stud

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Pozzolanic Properties of Coal Bottom Ash (화력발전소 바닥재의 포졸란 특성)

  • Han, Gi-Chun;Cho, Hee-Chan;Kim, Kwan-Ho;Kim, Jung-Ah;Ahn, Ji-Whan
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2004.05a
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    • pp.155-158
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    • 2004
  • 본 연구에서는 공냉(空冷)된 화력발전소 바닥재의 입도분포, 화학조성, 광물상 등 기초 특성과 압축강도비에 의해 포졸란 반응성을 측정하였다. 바닥재의 주요 성분은 $SiO_2$, $Al_2O_3,\;Fe_2O_3$로 이들의 합계가 91.2wt.%였으며, 주요 광물상은 mullite, quartz, cristobalite, tridymite, hematie 등이었다. 입도별 화학조성 변동은 거의 없었으나, 입도가 커짐에 따라 $SiO_2$는 quartz에서 cristobalite로 존재하는 비율이 증가하였다. 분쇄된 바닥재(blame 비표면적 $7,540cm^2/g$)의 양생 28일에서의 활성도 지수는 101을 나타내었다.

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An Experimental Study on the Pozzolan Reaction of discarded Bentonite by the Cooling Method after Heat Treatment (소성가공한 폐 벤토나이트 분말의 냉각방법에 따른 포졸란 반응성에 관한 실험적 연구)

  • Kim, Hyo-Yeul;Kang, Byeung-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.2 no.3
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    • pp.139-146
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    • 2002
  • As the bentonite is main material to prevent from collapse of drilling hole at underground excavation works, it is increased using quantity on construction industry day by day. But, the discarded bentonite that is over using at underground excavation works is caused various environmental trouble as soil and water pollution est. This study aims to propose a foundamental report for pozzolan reaction of discarded Bentonite powder by heat-treatment and cooling as concrete mineral admixture. To find out pozzolan reaction ability of discarded Bentonite powder by indirect cooling & cooling using of water after heat-treatment, the experiments are excuted Phenolphtalein test, setting test, pH test and the analysis by X-ray diffractor. As a result of this study, discarded Bentonite powder can be utilized as concrete mineral admixture by heat-treatment and especially, pozzolan reaction ability of discarded Bentonite powder is superior to the situation of 50$0^{\circ}C$~$700^{\circ}C$, 60min.

The Degree of Hydration and Mechanical Properties of High Volume Fly Ash Cement (하이볼륨 플라이애시 시멘트의 수화도 및 역학적 특성)

  • Cha, Soo-Won;Choi, Young-Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.5
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    • pp.95-102
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    • 2022
  • Recently, there has been a growing interest in reducing greenhouse gases in all industrial fields. In the construction industry, studies have been conducted for the use of high-volume fly ash concrete to replace cement with fly ash. Quantitative measurements of cement hydration and fly ash reactivity enable a clear understanding of the strength development mechanism of high-volume fly ash concrete. It is very difficult to describe the reactivity in a simple way because the hydration and pozzolanic reactions of cement paste containing fly ash are very complex and the composition of the hydration product cannot be accurately determined. This study investigated the hydration and mechanical properties of high volume fly ash (HVFA) cement according to the substitution rate of fly ash (FA). The hydration degree of cement and the reactivity of FA were evaluated through the selective dissolution method and the non-evaporable water content of the paste according to age. In addition, compressive strength was measured using HVFA mortar specimens according to age. As a result of the experiment, as the substitution rate of fly ash increased, the hydration degree of cement increased, but the reactivity of FA decreased.

Studies on Carbonation of Concrete with Low-Calcium Fly Ash and Blast Furnace Slag (플라이 애쉬 및 고로수쇄(高爐水碎)슬래그를 혼화(混和)한 콘크리트의 중성화(中性化)에 관한 연구(研究))

  • Nagataki, Shigeyoshi;Kim, Eun Kyum;Ohga, Hiroyuki
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.229-240
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    • 1987
  • Carbonation of concrete is one type of a chemical process. The reaction mechanism is very complex for the case when low-calcium fly ash and blast furnace slag is added. When fly ash and blast furnace slag is used as an admixture in concrete, they improve compressive strength in the long term, permeability and chemical resistance of concrete by a pozzolanic reaction and latent hydraulic property. On the other hand, the pozzolanic reaction of fly ash and latent hydraulic property of the blast furance slag leads to a reduction of the alkalinity of the concrete. It has been pointed out that this will accelerate the carbonation of the concrete and the corrosion of reinforcement steel embedded in the concrete. In order to clarify the effect of fly ash and blast furance slag on the carbonation of concrete, an accelerated carbonation testing of concrete was carried out by varying the conditions of concrete and the initial curing period in water. The test results of accelerated carbonation were compared to the carbonation test results of concrete stored for 15 years in open air, but protected from rain. As a result, the equation for the rate of carbonation based on compressive strength of concrete was proposed.

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Effect of the Fineness of Fly Ash on the Compressive Strength (플라이애시 입도가 압축강도에 미치는 영향)

  • Cho, Young-Keun;Kim, Ho-Kyu;Kim, Young-Ahn
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.3
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    • pp.313-319
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    • 2017
  • In general, various factors such as grain size, chemical composition, amorphous amount, amorphous Si and Al content of fly ash affect the reaction with cement. In this study, we investigate the effect of fly ash particle characteristics on compressive strength. The standard sand was pulverized to a particle size similar to that of fly ash and the compressive strength was measured by blending with the cement as in fly. Using the measured compressive strength results, strength enhancement by cement hydration reaction and strength enhancement by particle filling effect were confirmed. Strength increment by pozzolanic reaction of fly ash was calculated by using the compressive strength results of mortar substituted with standard powder. As a result of comparison between compressive strengths and the particle characteristics of fly ash, the blaine showed a weak correlation with the compressive strength and the PI(Pozzolanic Index) showed good correlation with the 10% penetration diameter(D10) and the 50% Respectively. Therefore, it is expected that PI will be a good means to evaluate the fly ash characteristics together with the chemical characteristics of fly ash.