• Title/Summary/Keyword: 포름알데히드 흡착

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Adsorption Properties of Indoor Air Pollutants in Blast Furnace Slag Matrix with Active Alumina Gel (활성 알루미나 겔을 혼입한 고로슬래그 경화체의 실내오염물질 흡착 특성)

  • Park, Chae-Wool;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.11a
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    • pp.29-30
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    • 2019
  • The indoor air quality of modern people who work indoors more than 80 percent a day has also become a very important factor in their lives. But most indoor air quality is highly polluted due to energy conservation and lack of ventilation. This can lead to pneumonia, asthma and even lung cancer, which can be fatal to children, the elderly and the elderly. Indoor pollutants are caused by boards, wallpaper, paint, etc. used in interior By producing indoor finishing materials using active alumina gel, which is used as dehumidifier, indoor pollutants will be reduced and the possibility of developing respiratory diseases and lung cancer will be reduced.

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Pproperties of formaldehyde and CO2 adsorption type matrix using TiO2 photocatalysis (광촉매를 활용한 흡착형 경화체의 포름알데히드 및 CO2 특성)

  • Lee, Won-Gyu;Pyeon, Su-Jeong;Kyoung, In-Soo;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.153-154
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    • 2018
  • As the air pollution progresses, the pollution degree of the indoor air quality is increased, and when the pollution degree of the indoor air quality is increased, it causes respiratory diseases and skin diseases. In addition, volatile organic compounds are released from the materials used for architectural interior decoration, and volatile organic compounds are the main cause of polluting indoor air quality. In order to improve indoor air quality, we tried to secure indoor air quality pollution by using photocatalyst which has the function of decomposing harmful substances. photocatalyst is a material that promotes chemical reaction by absorbing light. The photocatalyst used in the experiment was TiO2, In this study, an adsorption type hardener for reducing volatile organic compounds was prepared by photocatalytic reaction. the formaldehyde and CO2 concentrations of the cured products were analyzed according to the TiO2 content.

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Adsorption Characteristics of Commercial Wood Charcoal in Korea (I) (국내 시판용 목탄의 흡착 특성(I))

  • Lee, Dong-Young;Kim, Byung-Ro
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.1
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    • pp.27-35
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    • 2010
  • To evaluate the basic characteristics and adsorption properties of commercial wood charcoal, we investigated the proximate analysis, porosimetry analysis, methylene blue adsorption, removal ratios of formaldehyde, and removal ratio of ethylene gas. Fixed carbon contents of traditional black and white charcoal, and mechanical charcoal were 51.8~76.6%, 72.9~84.6%, and 48.5~80.3%, respectively. Refining degrees of the most traditional black charcoal were 9, and those of white charcoal and mechanical charcoals were zero. Specific surface area of traditional black charcoal was 0.1~13.7 $m^2/g$, which was quite lower than that of white charcoal (53.2~372.6 $m^2/g$) and mechanical charcoals (224.3~464.6 $m^2/g$). Also, amounts of methylene blue adsorption were quite lower in black charcoal (0.53~1.97 mg/g) compared with white charcoal (2.68~7.68 mg/g) and mechanical charcoal (11.63~26.10 mg/g). Removal ratios of formaldehyde of the black charcoal were 11.4~26.7%, which is quite similar to white charcoal (17.9~34.9%) and mechanical charcoal (5.5~25.8%). Removal ratios of ethylene gas for traditional black charcoal, traditional white charcoal, and mechanical charcoal were 2.2~43.5%, 21.7~39.1%, 21.7~39.1%, respectively. There was no significant difference in the removal ratios of formaldehyde and ethylene gas among traditional black charcoal, traditional white charcoal, and mechanical charcoal.

Treatment of Phenolic Resin Wasterwater by Candida tropicalis PW-51 (Candida tropicalis PW-51을 이용한 페놀수지 폐수의 처리)

  • 김성빈;김희식;오희목;윤병대;김치경
    • Korean Journal of Microbiology
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    • v.35 no.3
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    • pp.237-241
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    • 1999
  • Phenolic resin wastewater contained 41,000 mglI phenol, 2,800 mg/l fonualdehyde and various chlorinated phenolic compounds. Candida tropicalis PW-51 isolated [rom the natural enVlfooment was able to degrade 1,000 mg/l phenol in the presence of 100 mglI formaldehyde, but it took much time to degrade phenol with the increase of formaldehyde in phenolic resin wastewater. %en the phenolic resin wastewater was diluted to 1/40, the initial concentration of phenolic compounds (phenols) was 882 mglI and degraded to 81 mglI by C tfVpicalis PW-51 in batch culture. In a continuous biological treatment, the phenolic resin wastewater was diluted to 40 (745 mglI), 20 (1,356 mglI), or 10 (2,875 mglI) times. The removal efficiency of phenols in 1/40- and lI20-diluted phenolic resin wastewater was about 92%, but the phenols in 1!1O-diluted wastewater were not degraded. The remained phenols in wastewater were absorbed by a mixture of activated carbon and rice bran (1:1, v:v) in the process of absorption which was connected to the biological treatment. The total removal efficiency of phenols in 1!40~ and l/20-diluted phenolic resin wastewater was 99.9%.

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Effect of Overlaid White Charcoal Board on the Ethylene Gas Adsorption and Preservation Life of Strawberry (오버레이 백탄보드의 에칠렌가스 흡착과 딸기 보관성 효과)

  • Lee, Hwa-Hyoung;Cho, Youn-Mean;Park, Han-Sang
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.5
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    • pp.86-92
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    • 2004
  • This research was carried out to examine the ethylene gas adsorption and preservation life of white charcoal boards for packaging. Two types of white charcoal board were made of #40-60 charcoal particles and mixed charcoal particles with PVA and MDI resin by wet process. For not only beauty effect but also avoiding stain from touching, white charcoal boards were overlaid with two kinds of overlay material, thin printed paper and non woven fabric. A charcoal board adsorbed ethylene gas much more than the paper and even white charcoal itself. There was no difference between two board types, between overlay treatments, and between overlay materials. Gray mold growth of strawberry arised after 2 days in a paper box and after 4 days in a white charcoal board. Preservation life of white charcoal board box was approximately twice more than that. of a paper box. There was no difference in the ability of keeping freshness between two board types, between overlay treatments, and between overlay materials.

Aldehydes formation in the treatment of humic acid by Ozone/GAC hybrid process (오존/활성탄 혼합공정에 의한 부식산 처리에 따른 알데히드류의 생성특성)

  • Choi, Eun-Hye;Kim, Kei-Woul;Rhee, Dong Seok
    • Analytical Science and Technology
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    • v.18 no.6
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    • pp.535-541
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    • 2005
  • The formation of aldehydes as by-product was investigated in the treatment of humic acid by Ozone/GAC hybrid process. Ozone/GAC hybrid process was operated under varying initial pH (pH 3~pH 11) and temperature ($0^{\circ}C$, $20^{\circ}C$, $40^{\circ}C$) at an ozone dose of 0.08 g $O_3/g$ DOC and GAC amount of 16.5 v/v%. The results were compared with those of GAC adsorption and ozone alone process. The formed aldehydes were derivatized by PFBOA method and quantified by GC/PDECD. Formaldehyde and glyoxal were identified as the substantial aldehydes in the treatment of humic acid by ozone/GAC hybrid process. Quantities of formaldehyde and glyoxal formed in ozone/GAC hybrid process were less than one in ozone alone process. In ozone/GAC hybrid process, formaldehyde was produced with a considerable concentration of 400 ppb at pH 11 and pH 7 at the beginning of the treatment, and then the concentration was decreased with time. And, the concentrations of formaldehyde and glyoxal were increased with an increase of temperature. They were respectively 520 ppb and 120 ppb at the beginning of the treatment at $40^{\circ}C$.

Preparation and Characterization of Multilayer Microcapsules using Biocompatible Polymers (생체적합성 고분자를 사용한 다층 조립 구조 캡슐의 제조와 특성)

  • Jeon, Woohong;Kim, Gwang Yeon;Kim, Gue-Hyun;Ha, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.178-184
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    • 2010
  • The aim of this work is the fabrication of polyelectrolyte microcapsules composed of biocompatible polymers such as chitosan, heparin and alginate, to encapsulate the fluorescein isothiocyanate(FITC)-albumin, and to investigate the protein release behavior therefrom. Polyelectrolyte capsules with 4-layer structures could be prepared with biocompatible materials by oppositely charged adsorption using melamin-foramide as a template. Transmission electron microscope(TEM), scanning electron microscope(SEM) and optical microscope confirmed hollow capsule structures. Protein release before and after encapsulation was monitored with a UV-Vis spectrometer. Microcapsules have different behaviors depending on the kind of polyelectrolyte polymers, chitosan-heparin capsules or chitosan-alginate capsules. In conclusion, the polyelectrolyte multilayer shells can be switched between an open and closed state by means of tuning the pH value.

An Analysis on the Properties of Concrete Used as the Mixture Material with Carbon Black (카본블랙을 혼화재료로 사용한 콘크리트의 특성 분석)

  • Ryu, Hyun-Gi;Kwon, Yong-Ju
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.2
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    • pp.59-66
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    • 2010
  • The purpose of this study is to determine the possibilities of blending carbon black, which is known for its permeability as well as its strong heat and fire resistance, into concrete, in a manner that reinforces its strengths mentioned above. Experiments show that in non-solidified, fresh-mixed concrete, the addition of carbon black effectively reduced slump level and air content due to its absorptiveness and minute particle size. It also showed good results in terms of coagulation time, penetration resistance and bleeding level. In solid concrete, it showed better strength than plain concrete. Due to the pozzolanic reaction, its strength became more pronounced over time. At approximately 850 degrees Celsius, the heat and fire resistance level increased in parallel to the level of chemical substitution (by carbon black). Drying shrinkage level appeared to be optimal, and environmental assessment test results related to CO, CO2 and formaldehyde also scored better than plain concrete. In summary, with the appropriate use of AE water-reducing agents, carbon black can prove to be a strong candidate as an ingredient for industry-grade concrete.

Manufacture and Performance Evaluation of Medium-density Fiberboard Made with Coffee Bean Residue-Wood Fiber (커피박과 목섬유를 이용한 중밀도섬유판의 제조 및 성능 평가)

  • Yang, In;Lee, Kwang-Hyung;Oh, Sei-Chang
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.4
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    • pp.293-301
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    • 2013
  • This study discusses the feasibility of coffee bean residue as a raw material of medium-density fiberboard (MDF). In this relation, the effect of coffee bean residue known as an absorbent material on the physical and mechanical properties of MDF manufactured at its different addition level. Coffee bean residue which is a by-product of coffee mill and large amount of waste left over after processing for instant coffee was added at the level of 3, 6, and 9% on dry basis and urea formaldehyde resin was used as the adhesive. The MDF made with mixture of wood fiber and coffee bean residue was tested for physical and mechanical properties as well as formaldehyde emission. The bending strength and internal bonding strength of the MDF made with mixture of wood fiber-coffee bean residue were higher than that of the KS standard in randomized mat structure type, but not in layered mat structure type. Also, the physical properties of MDF made with mixture of wood fiber-coffee bean residue showed a considerable improvement in thickness swelling over the commercial MDF. More importantly, the formaldehyde emission rate of MDF made with mixture of wood fiber-coffee bean residue met the KS standard and was close to that of commercial MDF. These results showed the feasibility of coffee bean residue as a raw material for the production of environmentally-friendly MDF. Additional works on adhesive-coffee bean compatibility, improvement of moisture absorption effect and reduction the formaldehyde emission rate by carbonization of coffee bean residue may be required.

Synthesis of AlPO4-type Mesoporous Materials Using Alum Sludge (Alum 슬러지를 이용한 AlPO4-계 다공성 물질의 합성)

  • Kang, Kwang Cheol;Kim, Young Ho;Kim, Jin-man;Lee, Choul Ho;Rhee, Seog Woo
    • Applied Chemistry for Engineering
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    • v.22 no.2
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    • pp.173-177
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    • 2011
  • In this study, the formation of $AlPO_4$-type porous materials from alum sludge was investigated. The materials were synthesized by the reaction of aluminum hydroxide and phosphoric acid with an organic template. Cationic surfactant, natural humic acid, and amino acids were used for the organic template. The residual organic templates were removed by calcination at $600^{\circ}C$ in the air. Powder X-ray diffraction patterns showed the charicteristic patterns of the $AlPO_4$-type porous materials. The morphology of the material was examined using a scanning electron microscopy. The coordination environment of $Al^{3+}$ ion was investigated by $^{27}Al$ MAS NMR technique. Both tetrahedrally and octahedrally coordinated$Al^{3+}$ ions were found in the as-synthesized samples while all $Al^{3+}$ ions were tetrahedrally coordinated in the calcined products. The development of mesopore in the solid material was confirmed by the measurement of BET specific surface area. Finally, they were used for removal of toxic formaldehyde from the air and the formaldehyde molecules were adsorbed on the surface of pores. In conclusion, $AlPO_4$-type porous materials from alum sludge might be applicable in the removal of toxic volatile organic compounds from the air.