• Resources Recycling
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• v.16 no.6
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• pp.34-38
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• 2007

For recycling of tantalum from obsolete condenser, physical separations and chlorination of tantalum scraps with $Cl_2$ and $CCl_4$ were investigated. The recovery ratio of tantalum from obsolete condenser was 98% by using a multidisciplinary process of crushing by stamp mill, wet gravity separation by the shaking table, and air classification. In the chlorination reaction of non-oxidized Ta anode with $Cl_2$, the highest weight loss ratio is at least 60%, while in the chlorination reaction of Ta anode with $CCl_4$, the reaction rate for the oxidized Ta anode is faster than that of the non-oxidized Ta anode.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2003.10a
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• pp.56-60
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• 2003

폐 적층세라믹콘덴서(MLCC)로부터 Ni을 회수하기 위하여 침출실험을 수행하였다. 침출용매로 $HNO_3,\;HCl\;H_2SO_4$을 사용하여 시간의 변화, 반응온도의 변화, 시료 입도와 광액농도의 변화가 Ni의 침출율에 미치는 영향과 최적 침출 조건을 조사하였다. 그 결과 HCl, $H_2SO_4$을 침출용매로 사용했을 때 Ni 침출의 최적 조건은 산농도 5M, 반응온도 $90^{\circ}C$나타났으며, $HNO_3$을 침출용매로 사용했을 때 최적 침출 조건 산농도 1M, 반응온도 $70^{\circ}C$에서 광액농도 500ml당 20g일때 Ni 침출율이 98%로 최대였다.

• Resources Recycling
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• v.14 no.5 s.67
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• pp.32-39
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• 2005

Leaching behavior of nickel contained in waste Multi-Layer Ceramic Capacitor (MLCC) was investigated using a batch reactor. The effects of acid type, acid concentration, leaching temperature, particle size, and reaction time on the extraction of nickel metal from waste MLCC were examined. As a result, 97% of nickel contained in waste MLCC was leached out in 30 min at the temperature of $90^{\circ}C$ under the condition of $HNO_3$ concentration 1N, solid/liquid ratio 5 g/L and particle size $-300/+180{\mu}m$. It was also found that a Jander equation was useful to fit well the leaching rate data. The rate of nickel leaching is controlled by pore diffusion in $BaTiO_3$ layer and has an activation energy of 37.6 kJ/mol (9.0 kcal/mol).

• Resources Recycling
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• v.12 no.3
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• pp.3-12
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• 2003

Physical separation containing grinding, sieving, dry magnetic separation and air classification were carried out in order to recover Ta anode from waste Ta condenser. Roll crusher wat used for the liberation of resin and metals in closed circuit system. The liberation between Ta anode and resin was easily achieved, whereat some of metals did not liberated from the Ta anode when the waste condenser was crushed below 8 mesh. When the crushed sample were divided into 8/10 mesh, 10/18 mesh and -18 mesh, metals was mainly remained in 8/10 mesh in contrast to Ta anode was in +18 mesh. It was shown that resin was more easily crushed rather than metals from the result of that resin content was 71.5％ in -18 mesh. The liberation efficiency was different with the input size of the crushed sample and average efficiency was 62.3% due to the locked Ta anode particles. The results of air classification test for the crushed samples showed that optimal air flow are 39㎥/h, 32㎥/h, 20㎥/h. respectively. When the sample were separated with optimal condition, 94.45％ Ta anode containing 97.47 wt.％ Ta anode, 0.93 wt.％ resin. 1.61 wt.％ metal was recovered with 49.39 wt.％ yield.

• Environmental Analysis Health and Toxicology
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• v.4 no.1_2
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• pp.11-17
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• 1989

A quantitative analytical method of highly concentrated PCB is established in the research. With the quantitative analytical method PCB of insulating oil was examined. The following conclusions are derived from this research. 1. The recovery ratio was 95.7% with the quantitative analytical method, which indicates it can be used for the analysis of PCB. 2. PCB concentration of insulation oil in waste condenser was found to be 21.2% thru 13.85% , which was highly concentrated. 3. PCB insulation oil in waste condenser was same as PCB-42.