• Title/Summary/Keyword: 폐액

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How to Remove Radioactive Ions in Radioactive Waste (방사성 폐수 내 방사성 이온 제거방법)

  • Shin, Do Hyoung;Rhim, Ji Won;Park, Sung Kyun;Seo, Chang Hee;Park, Hun Hwee
    • Membrane Journal
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    • v.25 no.6
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    • pp.478-487
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    • 2015
  • This review article indicated accident examples in the past and discussed dangerousness according to these examples. In addition, the ways to remove radioactive ions in radioactive waste, they were divided broadly and enumerated experimental case. These were many results of the experiment and patents used various ways complexly, but domestic technology prowess lower than foreign technology prowess. Even in case of accidents that could happen afterwards, it is essential for growth and competitiveness of domestic technology. Through this article, it considered today's technology for removing radioactive ions and was trying to find out about the possibility of development.

Lignin Reactions During Alkali and Sulfate Pulping (알칼리 및 설페이트 펄프화중(化中)의 리그린반응(反應))

  • Yoon, Byung-Ho
    • Journal of the Korean Wood Science and Technology
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    • v.10 no.4
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    • pp.67-75
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    • 1982
  • 모텔리그닌의 펄프화(化) 처리(處理) 및 폐액(廢液)리그닌의 반응생성물(反應生成物)로부터 알칼리 및 설페이트 펄프화중(化中)에 일어나는 반응양식(反應樣式)을 조사(調査)한 것이다. 알칼리의 처리결과(處理結果)는 친핵시약(親核試藥)에 의해 페놀레이트 이온이 생성(生成), 퀴논메타이드 중간체(中間體)를 걸쳐 $C_6-C_3$ 단위(單位)의 ${\alpha}$위(位) aryl은 탈리(脫離)하여, 리그닌은 저분자화(低分子化)가 시작되고, 저분자생성물(低分子生成物)은 축합반응(縮合反應)에 의해 극(極)히 일부(一部)는 고분자화(高分子化)된다. 저분자화(低分子化)된 리그닌은 산화(酸化)에 의해 퀴노이드 착색구조(着色構造)를 형성(形成)한다. 페놀성의 일부(一部) 및 비(非)페놀성리그닌은 oxirane와 thiirane의 중간체(中間體)를 거쳐 $C_6-C_3$ 단위(單位)의 ${\beta}$위(位)의 arylether가 탈리(脫離)된다. 그러나, hydrosulfide 이온은 hydroxide 이용 보다 강(强한)한 친핵종(親核種)이므로 thiirane의 중간체(中間體) 생성(生成)이 용량(容量)하여 개열(開裂)이 더욱 촉진(促進)된다. 저분자(低分子)리그닌의 고분자축합(高分子縮合)은 벤젠핵(核)의 2.6 위(位)보다 5위(位)에 축합(縮合)이 많이 일어 난다.

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Determination of the Trace Elements in $UO_2$ Powder by ICP-AES Directyl Coupled with Extraction Chromatography (추출크로마토그래피와 유도결합플라스마 원자방출분광법을 이용한 이산화우라늄분말 중 미량금속불순물 분석)

  • Choi, Kwang-Soon;Lee, Chang-Heon;Pyo, Hyung-Yeal;Han, Sun-Ho;Suh, Moo-Yul;Eom, Tae-Yoon;Lee, Gae-Ho
    • Journal of the Korean Chemical Society
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    • v.37 no.9
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    • pp.813-819
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    • 1993
  • An ICP-AES system directly connected with a separation column was used in order to determine the trace elements in $UO_2$ powder promptly and reduce the volume of the waste solution. The outlet of a separation column, which was filled with Teflon powder ($330\;{\mu}m$) coated with tri-n-butyl phosphate (TBP) as extractant, was directly connected with sample injection tube of ICP-AES. Eleven elements including molybdenum in $UO_2$ powder were separated and determined simultaneously. Recoveries of these elements were $91{\sim}110%$ and these results were agreed with those of solvent extraction methods. This method was applicable to quality control in manufacturing nuclear fuel.

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Development of Paste Fertilizer for Rice -I. Manufacture of Paste Fertilizer (측조시비기용(側條施肥機用) 호상비료(糊狀肥料) 개발(開發)에 관(關)한 연구(硏究) -I. 제조시험(製造試驗))

  • Shin, Jae-Sung;Seong, Ki-Seog;Park, Yeong-Dae;Kim, Bok-Jin
    • Korean Journal of Soil Science and Fertilizer
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    • v.19 no.4
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    • pp.297-300
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    • 1986
  • A trial paste fertilizer for rice was manufactured by a developed process using major raw materials of waste liquid from glutamic acid fermentation, urea, phosphoric acid, diammomium phosphate and potassium chloride with potassium hydroxide for pH adjust and both glycerin and $HB_4O$ for enhancing and maintaining dispersion of paste. The ratios of N, $P_2O_5$ and $K_2O$ for trial products of paste fertilizer were 10:15:13 for Japonica var., and 12.5:15:13 for Indica var., and it was 6.0 in pH and 1.45g/cc in specific gravity.

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Development of Organic Compound Fertilizer Based on Treated Human Waste (분뇨잔사(糞尿殘渣)를 이용(利用)한 유기종합비료(有機綜合肥料) 개발(開發))

  • Shin, Jae-Sung;Seong, Ki-Seog;Lim, Dong-Kyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.17 no.1
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    • pp.55-59
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    • 1984
  • An organic compound fertilizer was manufactured using wet oxidation human waste as principal source of phosphorus and organic matter. The waste was treated with sulfuric and glutamic acids to increase the available and water-soluble $P_2O_5$ contents. The treatment of 0.1 N sulfuric acid with 24 hours curing was best way in recovering the maximum percentage of $P_2O_5$ originally in the waste. The particle size distribution of trial product varied considerably in the amount of glutamic acid used for granulation. The number of relatively large fertilizer particles was increased as the amount of glutamic acid was increased. The granule crushing strength was generally high in large granules in which 12.5 weight percent of glutamic acid were used for granulation. The trial product showed high moisture absorption due to its porous structure and chemical makeup.

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조류를 이용한 유기성 폐수 처리 시스템과 물벼룩 성장 조건

  • Jo, Jae-Hun;Kim, Jun-Hwi;Lee, Jeong-Seop;Yun, Seong-Myeong;Kim, Si-Uk
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.568-571
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    • 2001
  • Food wastewater eluted from the three-stage methane fermentation system developed in this lab showed high concentrations of TCOD, BOD, T-N and T-P. Because the effluent of biological filter chamber (BFC) still had high concentration of nitrogen and organic material, the effluent was treated with algal periphyton system using algae. The removal rates of COD, T-N and T-P wer 96, 98 and 91%, respectively, in this system. The grown algae could digested byy waterfleas using the ecological food chain system. Food wastewater is better than algal culture medium for growth of waterflea, Moima Macrocopa. During 12days, the individual of waterflea increased to 180 in the food wastewater containing a T-N concentration of 150 mg/ ${\ell}$.

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Determination of $^{241}$Am and $^{241}$Cm in Radwaste Samples (방사성폐기물 시료 중 $\^{241}$Am과 $\^{244}$Cm의 정량)

  • Joe Kih Soo;Kim Tae Hyun;Jeon Young Shin;Jee Kwsng Yong;Kim Won Ho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.1
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    • pp.1-7
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    • 2005
  • Anion exchange chromatography and HDEHP extraction chromatography using DTPA-lactic acid as an eluent were applied in series for the separation of $^{241}$Am and $^{244}$Cm in radwaste samples. The separated elements were determined by electrodeposition at the sodium hydrogen sulfate-sodium sulfate buffer solution followed by alpha-spectrometry. The recovery yields of $^{241}$Am and $^{244}$Cm were 85.2$\pm$$15.3\%$, respectively, from the synthetic solution of spent nuclear fuel sample. The amounts of 241Am and 2440m determined in radwaste sample solutions of condensate bottoms were at the range of 1.5-1.9 Bq/g and -1.7 Bq/g, respectively.

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Increase of the Treatment Efficiency of a Pharmaceutical Wastewater and a Paperboard Wastewater by the addition of Bacteria (세균첨가에 의한 제약폐수 및 판지폐수의 처리효율의 향상)

  • 이형춘
    • KSBB Journal
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    • v.15 no.4
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    • pp.370-374
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    • 2000
  • Some bacterial strains isolated from activated sludges and media and type cultures were cultivated in a pharmaceutical wastewater and a paperboard wastewater and added during batch treatment of those wastewaters in order for these strains to increase the treatment efficiency. Bacillus sp(PC-3) isolated from the charcoal media of the pharmaceutical wastewater plant grew remarkably over there strains in that wastewater and the viable cell count after 24hr cultivation was $1.1{\times}10^6m/L$. Bacillus subtills KCTC 1028 a type strain grew best in the paperboard wastewater and the viable cell count after 24hr cultivation was $1.1{\times}10^7m/L$. Addition of PC-3 in a batch treatment of the pharmaceutical wastewater increased COD removal by 18% after 8 day. And addition of Bacillus subtills KCTC 1028 in a batch treatment of the paperboard wastewater increased COD removal by 14% only after 24hy Bacillus subtills DCTC 1028 was though to be able to be produced economically using alcohol distillery wastewaters from starch material.

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Solidify Properties of Radioactive Waste using Paraffin Wax (파라핀 왁스를 이용한 방사성 폐기물의 고화 특성)

  • Lee, Han Chul;Chang, Yoon Ho
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.391-396
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    • 2006
  • When radioactive wastewater was solidified treatment by cement, the drying rate of cement and the volume reduction ratio was decreased because of boric acid component in the wastewater. In order to supplement the demerit, effects of paraffin wax investigated in this study. Paraffin wax has a hydrophobic properties and a low affinity with inorganic materials. When the radioactive wastewater was tested by a small of wax, the compressive strength of solidified waste are decreased Therefore boric acid in radioactive wastewater are first treated by alkali salt and coated by the stearic acid. During the solidification step, The amount of paraffin wax addition get the result that the compressive strength of solidification with cement was the same as that with paraffin wax. The leaching properties of radioactive waste solidified was the same CFL (cumulative fraction leached), PR (penetration rate), effective diffusivity if paraffin wax content in solidified waste was 20% or 25%.

Evaluation of External Carbon Source on the 2 Stage Denitrification Process by Simulation of GPS-X (GPS-X 시뮬레이션을 이용한 2단탈질 공정에서 외부탄소원 적용성 평가)

  • Chung, Chang-Wha;Shim, Yu-Seop;Kim, Tae-Hyung;Park, Chul-Hwi
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.1
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    • pp.37-48
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    • 2004
  • The purpose of this study was to evaluate adaptability of external carbon source using GPS-X program in pilot plant composed with 2-stage denitrification process. The result from analysis of pilot plant operation and GPS-X simulation showed that effluent concentration could be simulated similarly by modifying operation conditions, such as DO concentration, C/N ratio and other calibrated parameter. In order to satisfy the standard of the effluent water quality on T-N of 20mg/L, it required approximately 3.1 of C/N ratio and 50% of nitrogen removal efficiency when influent T-N is 36.9mg/L. To maintain the stable water quality of the receiving water, the effluent T-N concentration should be less than 10-15mg/L and the appropriate C/N ratio to remove nitrogen was 4.27-6.82. The analysis of sensitivity to kinetic coefficient and reaction constant showed that $Y_H$ and ${\mu}_{mAUT}$ were most sensitive to nitrate and ammonia nitrogen, relatively and sensitivity coefficient of their were 1.32, 1.98. It was concluded that as $Y_H$ decreased and ${\mu}_{mAUT}$ increased, the reaction rates of denitrification and nitrification increased and the removal efficiencies of $NO_3{^-}-N$ and $NH_4{^+}-N$ improved.