• Title/Summary/Keyword: 폐액

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Adsorption Removal of Sr by Barium Impregnated 4A Zeolite (BaA) From High Radioactive Seawater Waste (Barium이 함침된 4A 제올라이트 (BaA)에 의한 고방사성해수폐액에서 Sr의 흡착 제거)

  • Lee, Eil-Hee;Lee, Keun-Young;Kim, Kwang-Wook;Kim, Ik-Soo;Chung, Dong-Yong;Moon, Jei-Kwon;Choi, Jong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.2
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    • pp.101-112
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    • 2016
  • This study investigated the removal of Sr, which was one of the high radioactive nuclides, by adsorption with Barium (Ba) impregnated 4A zeolite (BaA) from high-radioactive seawater waste (HSW). Adsorption of Sr by BaA (BaA-Sr), in the impregnated Ba concentration of above 20.2wt%, was decreased by increasing the impregnated Ba concentration, and the impregnated Ba concentration was suitable at 20.2wt%. The BaA-Sr adsorption was added to the co-precipitation of Sr with $BaSO_4$ precipitation in the adsorption of Sr by 4A (4A-Sr) within BaA. Thus, it was possible to remove Sr more than 99% at m/V (adsorbent weight/solution volume)=5 g/L for BaA and m/V >20 g/L for 4A, respectively, in the Sr concentration of less than 0.2 mg/L (actual concentration level of Sr in HSW). It shows that BaA-Sr adsorption is better than 4A-Sr adsorption in for the removal capacity of Sr per unit gram of adsorbent, and the reduction of the secondary solid waste generation (spent adsorbent etc.). Also, BaA-Sr adsorption was more excellent removal capacity of Sr in the seawater waste than distilled water. Therefore, it seems to be effective for the direct removal of Sr from HSW. On the other hand, the adsorption of Cs by BaA (BaA-Cs) was mainly performed by 4A within BaA. Accordingly, it seems to be little effect of impregnated Ba into BaA. Meanwhile, BaA-Sr adsorption kinetics could be expressed the pseudo-second order rate equation. By increasing the initial Sr concentrations and the ratios of V/m, the adsorption rate constants ($k_2$) were decreased, but the equilibrium adsorption capacities ($q_e$) were increasing. However, with increasing the temperature of solution, $k_2$ was conversely increased, and $q_e$ was decreased. The activation energy of BaA-Sr adsorption was 38 kJ/mol. Thus, the chemical adsorption seems to be dominant rather than physical adsorption, although it is not a chemisorption with strong bonding form.

주정증류 폐액을 이용한 Actinobacillus sp. EL-9로부터 Poly-$\beta$-Hydroxybutyrate의 생산 및 폐약의 처리

  • 손홍주;이상준
    • Microbiology and Biotechnology Letters
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    • v.24 no.3
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    • pp.352-356
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    • 1996
  • Alcoholic distillery wastes are utilized as dual purposes to produce PHB in lower production cost and to reduce the amount of waste to be treated. In this study, various attempts were made to increase PHB production under various conditions by Actinobacillus sp. EL-9 in a shaker culture. The addition of glucose, NH$_{4}$NO$_{3}$ to alcoholic distillery wastes slightly promoted cell mass and PHB production. Enzyme hydrolysis of alcoholic distillery wastes increased the production of PHB than that of untreated waste and acid hydrolysis treatment. The PHB weight in alcoholic distillery wastes was 1.91 g/l. Fermentation process of PHB production reduced the amount of COD value up to 54%, which reduced organic loading rate and capacity of activated sludge system.

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Preparation of Concrete Admixtures from Pine Bark Wasts(III) -Improvement of Strength Properties on Cement Mortar Using ASAQ Cooking Spent Liquor with Surfactants- (폐 소나무 수피로부터 콘크리트 혼화제의 제조(III) -ASAQ 증해폐액에 계면활성제 첨가에 의한 시멘트 모르터의 강도 특성 개선-)

  • 박성천;문성필;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04b
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    • pp.751-754
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    • 1998
  • The study was carried out the efficiency of spent liquor(BSL) obtained from alkaline sulfite-anthraquinone cooking of pine bark added various surfactants. By adding surfactant to alkaline, weak alkaline, nertralized BSL, the dispersing ability of cement was remarkably improved. It was shown that the rate of water-reducing was 20~22%. The most superior efficiency surfactant was MTG. When BSL, MBSL and ABSL were added to MTG, the improvement of early and later strength was clear and also exhibited the superior properties of strength compared to PLAIN. Therefore, is a possibility that BSL will be used instead of melamine-base admixtures.

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Preparation of Concrete Admixtures from Pine Bark Wasts(II) -Conversion of Spent Liquor Obtained from Alkaline Sulfite- Anthraquinone(ASAQ) Cooking of Pine Bark Waste to Normal and Accelerating Concrete Admixtures- (폐 소나무 수피로부터 콘크리트 혼화제의 제조(II) - 소나무 수피 ASAQ증해 폐액의 표준형 및 촉진형 콘크리트 혼화제로의 전환 -)

  • 박성천;문성필;문소현;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04b
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    • pp.747-750
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    • 1998
  • The application of spent liquor(BSL) obtained from alkaline sulfite-anthraquinone cooking of pine bark to cement mortar significantly improved the water-reducing ability and decreased the rate of cement hardening. However, the compressive and flexural strength of BSL addition to cement mortar were lower than that of PLAIN. The application of 0.2% antifoamer to BSL slightly decreased water-reducing ability, but remarkably improved the compressive and flexural strength of cement mortar. On the other hand, BSL decreased the rate of hardening of cement, which exhibited the protperties of the lignosulfonated based retarding water-reducing type. but the setting time of cement could be controlled by addition of Na2CO3 could be used to convert BSL to normal or accelerating concrete admixtures.

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Waste Heat Recovery by Heat Pipe Heat Exchanger in Spray Dryer (분무건조장치에서의 히트파이프식 열교환기의 폐열회수)

  • 박기호;이기우;박준택;이계중;임상근
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2000.11a
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    • pp.193-198
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    • 2000
  • 분무건조장치는 Solution, Slurry, Emulsion, Colloidal Suspension 등의 액상원료를 미립화하여 표면적을 증가시켜 수열면적을 크게 하여 열풍과 직접 접촉함으로써 순간적으로 건조를 행하여 액상원료로부터 바로 분립상의 제품을 얻는 건조법이다. 분유를 비롯하여 Instant 식품류, 합성세제, 염료, 안료, Ceramic, 공해 폐액의 처리에 이르기까지 폭넓게 이용되고 있다. 분무건조기는 통기, 회전, 기류 건조기 등 다른 건조기에 비하여 고도의 설계 및 제작 기술을 요하며, 설계에 있어서 일부 이론적인 취급이 행해지고 있는 것은 사실이나 아직은 경험에 의존하고 있는 현실이다. 국내에서 제작되고 있는 분무건조기의 열효율은 25-33%로 선진국의 35-48%에 비해 매우 낮다. 국내에서 사용되고 있는 분무건조기의 92%는 덴마크, 일본 등에서 수입된 것이다.(중략)

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Collecting method of silk sericin from degumming solution and characteristics of recovered sericin (정련폐액에서 실크 세리신의 회수방법 및 회수세리신의 특성)

  • 김영대;권해용;우순옥
    • Journal of Sericultural and Entomological Science
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    • v.43 no.1
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    • pp.37-40
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    • 2001
  • This study was carried out to investigate the optimum condition for silk sericin collection from degumming solution using some aluminium salts with various treatment conditions and examine the thermal properties of silk sericin collected from degumming solution. Silk sericin was precipitated by treatment of aluminium metal compound from degumming solution. The best optimum collecting conditions of silk sericin from degumming solution are the concentration of 2 $m\ell$/l of polyaluminium chloride (PAC), pH range of 5~7 and room temperature. The reduction of water pollution was evaluated by decreasing the chemical oxygen demand (COD) and nitrate ion (NO$_3$ ̄). Thermal stability of silk sericin collected from degumming solution was a little lower than that of hot water.

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Burning Up of the Sludge occurred during Activated Sludge Treatment of Washing Wastewater and by-product Waste in Cuttlefish Processing Manufacture (활성오니법에 의한 오징어 가공공장 폐액처리중에 발생하는 슬러지의 소각재처리)

  • 조순영;서재수
    • Journal of Environmental Science International
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    • v.4 no.2
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    • pp.195-220
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    • 1995
  • A lot of sludges occur during an activated sludge treatment process of the washing wastewater and by-product waste in the cuttlefish processing manufacture. The sludges give also out a bad smell, and their amicable reclamation is very difficult because of the limited area of the filling-up. To reduce the heavy weight and large volume of the sludges, they was burning up. After the burning up at 350t for 2hrs the weight(volume) of the sludges were reduced to 5% level of the initial value. In contents of the bad heavy metals for human after the burning up, cadmium and lead metal were slightly detected, while mercury and the bad others not detected.

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Chemical Compositions and Biological Feeding Values of Spirutina platensis Grown at Swine-Waste Effluent (돈분폐액 배양 Spirulina platensis의 화학적 조성 및 생물학적 사료가치)

  • 오상집;정연종;이준엽;이현용
    • Korean Journal of Poultry Science
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    • v.22 no.3
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    • pp.155-160
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    • 1995
  • To evaluate the nutritive values of outdoor mass cultivated Spirulina platensis both chemical analysis and bioassay were carried out using adult cockerels. Blue-green algae, Spirulina platensis contained about 71g /l00g DM of crude protein with balanced amino acid profiles although methionine is liable to he limiting to animals. Compared to fish meal, calcium content and calcium : phosphorus ratio of the Spirulina were not suitable in terms of animal requirements. Reasonable amount of y-linolenic acid(C18: 3 $\omega$6) in Spirulina platensis draws a clinical attention due to its historically recognized pharmacotheraputic functions. Metabolizable energy contents of Spirulina were 3.67 and 3.11 mcal /kg DM for TMEn and AMFn, respectively, which therefore, can he a reliable energy source for poultry. True amino acid availabilities of essential amino acids of Spirulina platensis were higher than 90% for poultry, which is better than comparative ingredient like fish meal. Overall data from both chemical analysis and bioassay demonstrated that the Spirulina platensis could he a favorable protein feedstuffs for poultry.

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Studies on the Treatment of Photographic Wastewater by Electrowinning and Electrorefining of Silver (은의 전해채취 및 전해정련을 통한 사진폐액의 처리에 관한 연구)

  • Chung, Won-Ju;Kim, Dong-Su;Lee, Hwa-Young
    • Journal of Korean Society on Water Environment
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    • v.22 no.4
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    • pp.658-665
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    • 2006
  • The removal characteristics of silver ion from waste photographic solution have been investigated by recovering silver electrochemically. Cyclic voltammetry for synthetic and actual wastewater which containing silver ion was investigated to understand its electrochemical behavior. For both synthetic and actual wastewater, the recovery of silver according to the electrowinning time was observed to be increased as the applied potential was raised. In addition, the applicable potential for the electrowinning of silver was found to be lower for synthetic wastewater compared with actual wastewater. As the temperature was increased, more silver was recovered for both wastewater, which indicated the electrowinning reaction was endothermic. The electrowinned silver was refined electrochemically to increase its purity and the variation of the purity of silver was examined according to the electrorefining potential.

The study of chemical treatment of pulp mill bleaching waste liquor using sea water (해수를 이용한 펄프공장 폐액의 화학적 처리에 관한 연구)

  • 정병곤;이헌모;윤종호
    • Journal of environmental and Sanitary engineering
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    • v.12 no.1
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    • pp.39-48
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    • 1997
  • The study was conducted to know the possibility that the removal efficiency of organic and suspended solids(SS) could be increased by suppling of sea water and the optimum amount of sea water to be supplied treat bleaching waste water by lime coagulation settlement at pulp mill process. When the lime dosage was increased, the removal efficiency of COD and SS in the waste water was increased based on the removal efficiency of COD and SS. The lime dosage and removal efficiency was increased proportionally with the lime concentration of 4,000 mg/l, but the increase of removal efficiency was presented slightly above the 4,000mg/l. It was evaluated that the removal efficiencies of COD and SS could be increased and the requirement of lime dosage could be decreased by the sea water supplement. The removal efficiency of SS was most increased when the sea water supplement was 10% or more in the waste water. The removal efficiencies of COD was the best at 4% sea water excepting the dilution efficiency by sea water supplement.

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