• Journal of the Korea Organic Resources Recycling Association
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• v.4 no.2
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• pp.55-62
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• 1996

The purpose of this study is the evaluation of adsorption capacity of casts for heavy metals comparing with the activated carbon. The casts was obtained from vermicomposting of the mixed organic sludges which were generated from the treatment facilities for leather wastewater and cattle wastewater. The physico-chemical characteristics of cast was investigated. Also, the batch adsorption experiments of cast and activated carbon for heavy metals were carried out, and the results were analyzed by Freundlich isotherm. The buffering capacity to the acidic wastewater was founded in the cast, and the cation exchange capacity of cast impling adsorption capacity for soluble substances was evaluated as about 55me/100g. Those were implied that the cast have a large potential as a good adsorbent for soluble pollutants in wastewater. From the results of batch experiments, the removal efficiencies of tested various heavy metals including Pb, Cu, Cd, and Cr were very high value as 89-98% for the activated car-bon, and 80~95% for the casts except for Zn. The adsorption equilibriums for the two materials were achieved within 90 minutes. The order of preferable metals in the adsorption was found to be Pb>Cu>Cd>Cr>Zn on the cast and to be Pb>Cd>Cu>Cr>Zn on the activated carbon, respectively. From the above results, it might be con-cluded that cast is effectively available as a good adsorbent to treating the heavy metal bearing wastewater.

• Journal of the Korea Organic Resources Recycling Association
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• v.20 no.1
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• pp.61-70
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• 2012

Feasibility of co-digestion was investigated by a series of anaerobic batch experiments using sewage sludge, swine waste, and food waste leachate as substrates. The organic solid wastes were collected from M city, where the daily productions of sewage sludge, swine waste, and food waste leachate were 178 ton/d, 150 ton/d, and 8 ton/d, respectively. Both swine waste and food waste leachate showed superior methane yields, methane productivities, and organic pollutant removal efficiencies compared to sewage sludge. Co-digestion of the total amounts of organic solid wastes would enhance methane production by 5.60 times $(530\;m^{3}\;CH_{4}/d\;{\rightarrow}\;2,968\;m^{3}\;CH_{4}/d)$. However, it also increase the amount of digestate by 1.88 times with 3.79 to 4.92 times higher pollutants (chemical oxygen demands total nitrogen, and total phosphorus) loading rates. Co-digestion of organic solid wastes is a valid strategy to enhance the performance of an anaerobic sludge digester and the energy independence of a wastewater treatment plant. Anyhow,the increment of digestate with higher pollutant loading would need a careful counterplan in the operation of the main stream of the treatment plant.

• Microbiology and Biotechnology Letters
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• v.34 no.3
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• pp.257-264
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• 2006

An aerobic submerged membrane bioreactor (MBR) treating ammonium wastewater was studied in respect of nitrification characteristics and distribution of nitrification bacteria over a period of 350 days. MBR was fed with ammonium concentration of 500-1000 mg $NH_4-N/L$ at a nitrogen load of $1-2kg\;N/m^3{\cdot}d$. Overall ammonium oxidation rate increased with dissolved oxygen (DO) concentration, temperature, and sludge retention time (SRT). Under a higher concentration of free ammonia ($NH_3-N$) due to the decrease of ammonium oxidation rate, the nitrite ratio ($NO_2-N/NO_x-N$) in the effluent increased. The sudden collapse of nitrification efficiency accompanied by sludge foaming and the increase of sludge volume index (SVI) was observed unexpectedly during the operation. At the later stage of operation, additional carbon source was fed to the MBR and resulted in twice higher value of SVI and the decrease of ammonium oxidation rate. In fluorescence in situ hybridization (FISH) analysis, genus Nitrosomonas which is specifically hybridized with probe NSM156 was initially the dominant ammonia oxidizing bacteria and the amount of Nitrosospira gradually increased. Nitrospira was the dominant nitrite oxidizing bacteria during whole operational period. Significant amount of Nitrobacter was also detected which might due to the high concentration of nitrite maintained in the reactor.

• Journal of Korea Soil Environment Society
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• v.3 no.2
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• pp.89-99
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• 1998

Sorption of the aqueous cyanide onto steel mill sludge and steel mill slag, both of which are the by-products from the converter furnace, was studied. In the study, the influence of temperature, activation energy, concentration and pH on sorption of cyanide was investigated. Three different temperature($25^{\circ}C$ > $37^{\circ}C$> $50^{\circ}C$) was chosen to represent that of landfill leachate. Initial concentration was 1 mg/$\ell$ 5 mg/$\ell$, 10 mg/$\ell$, and 20 mg/$\ell$. In addition, pH was set to three different level, that is, 3, 7, and 11 respectively. As the result of batch mode experiment for cyanide adsorption, the removal rate was found to be proportional to the initial concentration of cyanide. The order of removal rate was 20 mg/$\ell$> 10 mg/$\ell$> 5 mg/$\ell$> 1 mg/$\ell$. Similarly the influence of pH was proportional because of the change in solubility of cyanide. The order of removal rate was pH 11 > pH 7 > pH 3. As the temperature increased, so did the removal rate. The reaction was endothermic and the value of activation energy(Ea) was 127.93 J/mole and 59.44 J/mole respectively at 1 mg/ιand 20 mg/ιof initial concentration. From the experiment, it can be postulated that the capability of steel mill by-products to attenuate aqueous cyanide is enough to be used as substitute for clay liner of landfill site in the aspect of pollutant removal.

• Journal of Veterinary Clinics
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• v.28 no.2
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• pp.219-224
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• 2011

The health status of three groups of Hanwoo steers (n=157) aged 2-3 years, raised at three different altitudes (600 m, n=50; 200-400 m, n=58; plane land, n=49) and environment with more or less similar management have been evaluated through hematological, biochemical and globulin examinations in order to determine the optimum environment suitable for raising cattle while at the same time minimizing the risk of disease. Five mL of blood samples from each animal were collected by jugular veinipuncture and 2 mL was transferred to a tube containing EDTA for complete blood count (CBC) and 3 mL in lithium heparin for chemistry screening (CS) and immunoassay. Among the CBC parameters a significantly higher white blood cell count (tWBC), total red blood cell count (tRBC), hemoglobin (Hb) and packed cell volume (PCV) were noticed in the high altitude groups, whereas those were lower in the plane land group. In the CS parameters higher levels of aspartate aminotransferase (AST), creatinine, lactate dehydrogenase (LDH) and total bilirubin (TBL) were found in the plane land group, whereas those were lower in the high altitude groups. The total protein (significantly) and globulins were higher in the 600 m group. The results of this study revealed that the overall health status of the Hanwoo cattle based on the hemato-biochemical indices was superior in the highest altitude and inferior in the plane land group but all the parameters were within the reference range in all the groups. Therefore, for recommendation of a suitable environment at an appropriate altitude for raising cattle there need to be further studied along with the hemato-biochemical parameters; considering, breeding, feeding, management, marketing, waste disposal and other factors.

• Journal of Korean Society on Water Environment
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• v.20 no.6
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• pp.603-609
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• 2004

The objective of this study was to determine the optimal operation conditions in an anoxic oxic process to eliminate both organic and nitrogen matters in swine wastewater. For the purpose of this, the removal efficiency was evaluated with various HRTs and internal recycling ratio. During the whole 580 days of experiment, HRTs had been gradually decreased in an order of 20, 14, 12 and l0days, and the internal recycle ratio was kept at 20Q. So as to determine the effect of the internal recycle ratio on the nitrogen removal, the internal recycle ratio had been gradually increased from 20Q to 50Q while HRT was maintained at 12days. As a result, it was shown that the removal efficiency of organic matter was above 95% regardless of changing of HRTs. The average influent concentration of TCODcr and SCODcr were 24,854 mg/L and 18,920 mg/L, respectively. Average removal efficiency of TKN was shown to be nearly 98% when HRT was kept at 12days; however, the $NH_4{^+}-N$ concentration of effluent was shown to be increased when the loading rate of $NH_4{^+}-N$ was increased to $0.602 kgNH_4{^+}-N/m^3$-day by means of decreasing HRT to 10days. It was concluded that nitrogen loading rates should be more considered rather than organic loading rates in case of determining an optimal HRT. When gradually increasing the internal recycle ratio from 20Q to 50Q, the removal efficiency of organic matters and TKN were 96% and 98%, respectively so that no significant changes in removal efficiency was detected. However, when the internal recycle ratio was kept at 50Q, it was revealed that the $NO_3-N$ concentration of effluent seemed to drop and the average $NO_3-N$ concentration of effluent was around 52 mg/L.

• Journal of Korean Society on Water Environment
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• v.26 no.1
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• pp.1-9
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• 2010

Technology-Based Effluent Limitations (TBELs) is a permit limits for a pollutant that is based on the capability of a treatment technology to reduce the pollutant to a certain concentration. Widely practiced for regulations of industrial wastewater in US, TBELs has been accepted as an effective means that can achieve balanced goals between complete elimination of pollutants discharge and economic feasibility for industries. The review of TBELs application in US and the applicability of TBELs to the domestic industry categories was given in three papers. In the first paper, the development and practices of TBELs in US were reviewed including case studies. The developments of TBELs in US in the four major categories, the metal products & machinery, the petroleum refining, the porcelain enameling and the meat & poultry products were reviewed. The applicability of TBELs to the domestic industrial categories was also assessed. In the second paper, the pollution loads analysis for domestic industrial wastewater was conducted based on risk assessment indicator using Toxic Weighting Factors (TWFs). This is an essential part to determine the priority of TBELs application for the domestic industrial categories. In the last paper, the application of TBELs to the domestic industries was demonstrated through a case-study for the pulp/paper/paperboard category. Direct application of TBELs of US into the Korean regulation system may not be desirable because the specific goals and the environment for the regulations for the two countries may not be identical. For example, unlike US, Korea does not adopt the individual permit system for pollution sources. However, among the unproductive and exhaustive controversies over the uniform regulations regardless of the industrial categories in Korea, the introduction of the principles of TBELs are inevitable and more extensive study for applications of TBELs optimized for Korean regulation system will be necessary.

• Proceedings of the Korea Water Resources Association Conference
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• 2007.05a
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• pp.981-986
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• 2007

현재 인천연안에는 홍수방지와 원활한 하천수 방류를 목적으로 많은 유수지가 설치되어 있다. 그러나 이들 유수지는 유역으로부터 유입된 오염물질의 축척으로 수질이 심각한 상태에 있으며 대부분의 유수지 수질이 5등급을 초과하는 등 악취에 의한 민원도 증가하고 있는 실정이다. 특히 이러한 유수지를 통해 저류되었던 유량이 해안으로 방류되면서 인천연안의 해양수질에 악영향을 미치게 되어 해양수질 개선에 큰 장애물이 되고 있는 것이 사실이다. 이러한 상황에서 최근 인천의 승기천, 장수천, 굴포천을 포함한 5대 하천복원사업이 활발히 진행되고 있는데, 특히 승기천의 경우 승기천 본류에 대한 하천복원사업이 성공적으로 마무리되기 위해서는 승기천 최하류에 위치하고 있는 남동유수지와 연계된 하천복원이 이루어져야 할 것이다. 그러나 현재 진행되고 있는 승기천 복원사업은 남동유수지와는 별도로 진행되고 있어 승기천의 성공적인 복원을 위해서는 남동유수지가 당면하고 있는 수질개선 문제, 퇴적된 저니의 준설 문제, 향후 남동유수지의 운영 개선방안 등에 대한 구체적인 해결방안이 필수적으로 마련되어야 한다. 과거 남동유수지의 수질을 개선하기 위하여 1996년과 1997년에 열대성 식물인 부레옥잠을 유수지에 식재하여 남동유수지의 자연정화를 유도하려는 시도가 있었으나, 예산의 과다소요와 동절기 정화능력 상실 및 부레옥잠 사멸시 2차 오염 초래의 문제 등으로 인하여 사업을 중단하였고 같은 해 유수지 퇴적물의 준설을 통한 수질개선도 시도하였으나, 퇴적물 성분 중에 함유된 중금속으로 인해 준설토의 처리문제가 해결되지 못해 사업이 유보되어 남동유수지는 현재까지 특별한 환경개선 방안이나 운영방안 없이 유지되고 있는 실정으로 남동유수지가 현재와 같은 상황으로 유지된다면 승기천 복원사업 종료 이후에도 남동유수지는 생활환경을 저해하는 지배적인 요인으로 남게 될 것이다. 본 연구에서는 현재 진행중인 승기천 오염하천 정화사업이 종료되는 시점을 기준으로 남동유수지에 대해 승기천과 연계한 유수지의 환경개선 방법을 제안하였다. 준설을 통해 유수지의 근본적인 오염원을 제거하고 남동유수지 유입부에 인공습지와 수처리설비를 설치하여 유수지의 수질을 개선하고 개선된 수질이 3급수로 유지하도록 하였으며, 설치된 인공습지에는 철새도래지를 조성하여 유수지 유입수인 철새가 날아드는 하천인 승기천의 테마와 연계하도록 하였다. 인공습지 주변으로 식생호안을 설치하고 유수지 주변에는 산책로를 설치하여 지역주민들의 친환경 수변공간으로 활용하도록 하였다. 1유수지와 연결된 2유수지는 BTL사업을 통해 주변공단으로부터의 오폐수를 원천적으로 차단하도록 하였으며 2유수지를 매립하여 지하는 강우시 유출수 저류가 가능한 화물차주차장으로 활용하고 지상은 녹지공간으로 조성하여 공단근로자 및 지역주민을 위한 휴식공간으로 활용될 수 있도록 제안하였다. 본 연구는 남동유수지 환경 개선 사업 실행을 위한 정책 연구로 연구결과를 인천시가 적극 수용하기로 결정함에 따라 인천시의 환경 현안 문제인 남동유수지의 수질개선을 통해 시민의 휴식 및 여가선용 공간으로 활용하기 위한 사업의 기초자료로 활용되며 이미 설계검토가 시작되었다. 본 연구결과는 유수지 및 저수지의 환경개선 사업의 선두적인 성공사례로 국내 타 지역의 유사한 사업에 있어 벤치마킹을 할 수 있는 훌륭한 사례가 될 것이다.

• Analytical Science and Technology
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• v.17 no.3
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• pp.263-270
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• 2004

A method is described for the analysis of short-chain alkylphenol ethoxylates (APEOs), 4-octylphenol-di-ethoxylate (OP2EO) and 4-nonylphenol-di-ethoxylate (NP2EO), in drinking water or wastewater using reversed phase high-performance liquid chromatography with electrospray ionization mass spectrometry. The solvent system was water and methanol containing $10{\mu}M$ trifluoroacetic acid as an ionization solvent. We acidified 1 L of water samples to less than pH 2 with concentrated $H_2SO_4$ and loaded onto Sep-Pak $C_{18}$, and eluted with acetone. The calibration of OP2EO and NP2EO was performed for the concentration range from 20 to 500 ng/L and the correlation coefficients were 0.999 and 0.990, respectively. The limits of detection were 20 ng/L (OP2EO) and 50 ng/L (NP2EO) at a signal-to-noise ratio of 3. Accuracy and precision of this analytical method were 85.8 ~ 122.1% and 8.2 ~ 18.8%, respectively. The proposed method allowed a sensitive and rapid detection of OP2EO and NP2EO and it could be applied for monitoring of APEOs from environmental samples.

• Journal of Life Science
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• v.15 no.3 s.70
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• pp.337-343
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• 2005

Tapioca alcoholic distillery waste was utilized as dual purposes to produce citric acid and to reduce the amount of waste to be treated. Primarily an attempt was made to optimize the process conditions by Aspergillus niger in shake bath. The effects of pH, temperature, nitrogen and phosphorus sources on citric acid production were investigated. Maximum concentration of citric acid was made at temperature of $30^{\circ}C$ and pH of 4.3, while maximum cell dry weight was obtained at $35^{\circ}C$. The addition of methanol or ethanol to culture medium promoted citric acid production remarkably, but the addition of $NH_4NO_3,\;KH_2PO_4$ and Manganese as mineral source decreased the acid production.