• Title/Summary/Keyword: 폐기물 가스화

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The Removal of NOx by Mediated Electrochemical Oxidation Using Ag(II) As a Mediator (Ag(II)를 매개체로 사용하는 전기화학적 매개산화에 의한 NOx 제거)

  • Lee, Min-Woo;Park, So-Jin;Lee, Kune-Woo;Choi, Wang-Kyu
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.9 no.3
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    • pp.121-129
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    • 2011
  • The effects of the applied current density, the $AgNO_3$ concentration, the scrubbing liquid flow rate and the NO-air mixed gas flow rate on the NO removal efficiency were investigated by using $Ag^{2+}$ mediated electrochemical oxidation (MEO). Results showed that the NO removal efficiency increased with increasing the applied current density. The effect of the $AgNO_3$ concentration on the NO removal efficiency was negligibly small in the concentration of $AgNO_3$ above 0.1 M. When the scrubbing liquid flow rate increased, the NO removal efficiency was gradually increased. On the other hands, the NO removal efficiency decreased with increasing the NO-air mixed gas flow rate. As a result of the treatment of NO-air mixed gas by using the MEO process with the optimum operating condition and the chemical absorption process using 3 M $HNO_3$ solution as a scrubbing liquid, the removal efficiency of NO and $NO_x$ was achieved as 95% and 63%, respectively.

Factors Affecting the Minimum Detectable Activity of Radioactive Noble Gases (방사성 노블가스 측정을 위한 최소검출방사능 산출의 조절인자)

  • Park, Ji-young;Ko, Young Gun;Kim, Hyuncheol;Lim, Jong-Myoung;Lee, Wanno
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.3
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    • pp.301-308
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    • 2018
  • Anthropogenic radioactive noble gases formed by nuclear fission are significant indicators used to monitor the nuclear activity of neighboring countries. In particular, radioactive xenon, owing to its abundant generation and short half-life, can be used to detect nuclear testing, and radioactive krypton has been used as a tracer to monitor the reprocessing of nuclear fuels. Released radioactive noble gases are in the atmosphere at infinitesimal amounts due to their dilution in the air and their short half-life decay. Therefore, to obtain reliable and significant data when performing measurement of noble gases in the atmosphere, the minimum detectable activity (MDA) for noble gases should be defined as low as possible. In this study, the MDA values for radioactive xenon and krypton were theoretically obtained based on the BfS-IAR system by collecting both noble gases simultaneously. In addition, various MDA methods, confidence level and analysis conditions were suggested to reduce and optimize MDA with an assessment of the factors affecting MDA. The current investigation indicated that maximizing the pretreatment efficiency and performance maintenance of the counter were the most important aspects for Xe. In the case of Kr, since sample activities are much higher than those of Xe, it is possible to change the target MDA or to simplification of the analysis system.

Analysis of Environmental Impacts for the Biochar Production and Soil Application (폐목재를 이용한 바이오차 생산 및 토양적용의 환경평가)

  • Kim, Mihyung;Kim, Geonha
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.7
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    • pp.461-468
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    • 2014
  • Biochar is a carbon rich solid produced by the pyrolysis of biomass such as energy crops, forestry residues, and wood wastes. Biochar returned to soil is to mitigate climate change and the feedstock of wood wastes reduces fossil fuel consumption as well as disposal costs. This study was practiced to evaluate a biochar system by gasification in terms of global warming regarding the soil application of the produced biochar. Life cycle assessment methodology was used to analyze the environmental impacts of the system, and the functional unit was 1 tonne of wood wastes. The result shows that the biochar system by using wood wastes as feedstock produces 4.048E-01 $kgCO_2-eq$ from the pre-treatment process as chipping and drying, 4.579E-01 $kgCO_2-eq$ from the pyrolysis process, and 9.070E-02 $kgCO_2-eq$ from the spreading to agricultural land, therefore total 9.534E-01 $kgCO_2-eq$ are generated. About 252 kg of $CO_2$ is still stored in the produced biochar in soil after carbon offsetting of the system. Therefore, the net carbon of the system is -251 kg of $CO_2-eq$.

Evaluation of Landfilling Method of Organic Sludge from Mix of Pre-treated Organic Sludge and Municipal Solid Waste (전처리된 유기성오니와 생활폐기물 혼합에 따른 유기성오니 매립방법 평가)

  • Ko, Jae-Young;Phae, Chae-Gun;Do, In-Hwan;Park, Joon-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.3
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    • pp.278-285
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    • 2008
  • This research was performed to evaluate the landfilling method of organic sludge from mix of pre-treated organic sludge (OS) and municipal solid waste(MSW). Organic sludges were dried, composted, and solidified as pre-treatment and the OS and MSW were mixed in ratios of 2 to 8 and 4 to 6. Approximately 1,800$\sim$2,500 L of landfill gas(LFG) was generated in the lysimeter with solidified-OS, which was higher than 1,150$\sim$1,650 L of the dried- and composted- ones. Maximum H$_2$S concentration was found in the following order : Composted-20(80 ppmv) > Composted-40(55 ppmv) > Dried-20(30 ppmv) > Dried-40 $\fallingdotseq$ Solidified-20 $\fallingdotseq$ Solidified-40 (20 ppmv). BOD$_5$ at initial leachate generation period was 38,000 mg/L for Composted-40, 28,000 mg/L for Dried-40, 26,000 mg/L for Dried-20, 21,000 mg/L for Composted-20 and Solidified-40, and Solidified-20 for 17,000 mg/L. In the final period of experiment, BOD$_5$ was low as 300$\sim$500 mg/L in the lysimeter with solidified-OS and MSW and showed 2,000$\sim$3,500 mg/L in dried- and composted- ones. As the results, landfilling by mix of solidified-OS and MSW was evaluated as the most appropriate method for biodegradable organics. Direct landfilling of OS is permitted for landfill site with CDM facility. Therefore, mixed landfilling of solidified-OS and MSW should be considered for much more LFG generation as methane.

Methane Production Using Peel-type Fruit Wastes and Sewage Sludge in Batch Anaerobic Digestion Process (껍질 형태의 과일폐기물과 하수슬러지를 이용한 회분식 혐기 소화공정에서 메탄 생산)

  • Jeong, Tae-Young;Lee, Jong Hak;Chung, Hyung-Keun;Cha, Hyung Joon;Choi, Suk Soon
    • Applied Chemistry for Engineering
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    • v.20 no.5
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    • pp.542-546
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    • 2009
  • Methane production using the mixed organic wastes of peel-type fruit wastes from apple or orange and sewage sludge was investigated in the batch anaerobic degradation process. When apple or orange peels with sewage sludge were used as mixed substrates, higher methane production was achieved under the condition of 3 : 7 (fruit peel : sewage sludge) mixing ratio. However, above the 3 : 7 mixing ratio, the pH of mixture was decreased from 8.0 to 4.5~4.7 due to organic acid production from the fruit wastes. Subsequently, methane production was low. The results in this study could be effectively applied to the methane gas production system as a bioenergy in the mixed batch anaerobic digestion process using the peel-type fruit wastes and sewage sludge.

Effect of Waste Activated Sludge Mixing Ratio on the Biogas Production in Bioelectrochemical Anaerobic Digestion (생물전기화학혐기소화조를 이용한 바이오가스생산에서 폐활성슬러지 혼합비의 영향)

  • Chung, Jae-Woo;Lee, Myoung-Eun;Seo, Sun-Chul;Ahn, Yongtae
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.4
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    • pp.53-61
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    • 2018
  • Anaerobic digestion (AD) is one of the most widely used process that can convert the organic fraction of waste activated sludge (WAS) into biogas. However, most researched actual methane yields of anaerobic digester (AD) on lab scale is lower than theoretical ones. Bioelectrochemical, anaerobic digester was used to increase methane yield from waste activated sludge. The influence of anaerobic digestion sludge and raw sludge mixing ratio (3:7, 5:5) on methane yield and organic matter removal efficiency were explored. As a result, when the mixing ratio of bioelectrochemical anaerobic sludge was 5:5 compared with 3:7, the highest methane yields were 294.2 mL $CH_4/L$ (0.63 times increase) and 52.5% (7.5% increase), the bioelectrochemical anaerobic digester(5:5) was more stable in the pH, t otal alkalinity and VFAs, respectively. These results showed that the increase in the mixing ratio of anaerobic digestion sludge was found to be effective for maintaining the stable performance of bioelectrochemical anaerobic digester.

A Study on the Characteristics of Combustion and Manufacturing Process on Refuse-derived Fuel by Mixing Different Ratios with Organic and Combustible Wastes (유기성폐기물 고체연료화를 위한 연소 및 제조과정의 특성연구)

  • Ha, Sang-An
    • Journal of the Korea Organic Resources Recycling Association
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    • v.17 no.1
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    • pp.27-38
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    • 2009
  • To investigate the feasibility of refuse derived fuels (RDFs) combined of sewage sludge and combustible wastes such as substitutive fuels instead of a stone coal, several different RDFs made with different mixtures of sewage sludge and combustible wastes were analyzed by various experiments. The combustion characteristics for the RDFs were investigated by analyzing fuel gases, and heating values were also measured by a bomb calorimeter. The fundamental properties such as moisture contents, ratios of combustible materials, amounts of ashes, heavy metals, ratios of each chemical elements and heating values were analyzed in accordance with mixing ratios of wt(%) for researching the characteristics of the RDFs. $RDF_{k-1}$ was made of mixing materials which were dried sewage sludge, food wastes and combustible wastes. $RDF_{k-2}$ was made of mixing materials which were peat-moss, tar and sewage sludge. Combustion experiments were carried out at the optimal conditions which were m=2 under air-fuel condition and $850^{\circ}C$. The retention times in the combustor were set at 5, 10 and 15minutes. 50 g of RDFs was put in the combustor for each experiments. The ranges for heating values of $RDF_{k-1}$ with different mixing ratios were from 6,900 kcal/kg to 8120 kcal/kg. The ranges for heating values of $RDF_{k-2}$ with different mixing ratios were from 4,014 kcal/kg to 8,050 kcal/kg. As a result of this study, the heating values, moisture contents, components of chemical elements and mixing ratios of the materials in RDFs had big effects on the efficiency of the combustion. In $RDF_{k-1}$, the higher amounts of combustible wastes in the mixtures, the higher heating values, concentrations of $C_xH_y$ and amounts of ashes were produced. In $RDF_{k-2}$, the higher tar amounts in the mixtures caused the higher heating values, amounts of ashes, concentrations of CO gas and CxHy.

Importance-Performance Analysis of the Livestock Organic Wastes Recycling Policy (축산 유기성 폐기물 자원화 정책의 중요도-만족도 분석)

  • Kim, Won-Tae;Suh, Dae-Seok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.12
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    • pp.523-531
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    • 2018
  • The purpose of this paper is to derive priorities and implications for the organic resource conservation policy in the livestock sector. We conducted a survey on the importance-performance of the organic waste resource reclamation of livestock sector using a 5-point Likert scale. The importance average for the resource recycling of livestock organic waste was 3.63 and the average of performance was 3.04. As a result of the IPA on livestock manure recycling measures, it is necessary to improve feed quality, establish a local recycling system, increase demand for compost and liquid, enhance customer linkages, and develop cost reduction technologies. It requires intensive support for promoting the spread of odor reduction technologies and integrated management of biomass. It is necessary to introduce mid- and long-term measures such as the revival of feed in tariff, promote by-product feeding, establish solid fuel process management standards, create hygiene safety standards, develop eco-beads and promotion of feed conversion. It is required to strengthen support for the development of odor reduction technologies and prepare consultative organizations among related departments, develop eco-friendly solid fuel technology, and support policies for renewable energy certification.

알루미늄선박의 건조 단위공정별 작업표준에 대한 고찰

  • Gang, Byeong-Jae
    • Journal of Korea Ship Safrty Technology Authority
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    • v.20
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    • pp.18-28
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    • 2005
  • 연안소형어선에 주로 사용하는 FRP선질은 가볍고 강도는 우수하나 인화성이 높아서 기관실 화재사고 등 위험에 노출되어 있고 선박 제작 과정에서 인체에 해로운 유해성분이 발생할 뿐만 아니라, 폐선의 경우 산업폐기물로써 환경오염에 큰 영향을 미치고 있다. 그런 반면에, 알루미늄합금 어선은 FRP 어선의 단점을 보완할수 있는 재료로써, 고강도 경량화의 효과를 낼 수 있고, RFP어선보다 인화성이 낮아서 열에 강하고 내구성이 높고 강선보다 해수의 부식방지에 뛰어나므로 알룸늄어선의 개발이 요구되고 있다. 이번 호에서는 알루미늄선박 건조시 각각의 단위공정에 대한 작업방법, 작업순서 및 주의사항 등 표준에 대해 코리아타코마조선공법(주)의 알루미늄선박 작업지침과 KSB 0897(불황가스 및 아크용접 작업표준)를 일부 발췌하여 기술하고자 한다.

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Characteristics of the PCDD/DFs Emissions in the Flue Gases of Full Scale Incinerators (다양한 소각시설 배출가스 중 다이옥신류의 배출특성)

  • 최진수;문영훈;김민관;오정은;김병훈;장윤석
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.330-331
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    • 2000
  • 환경오염 유기물질 중 다이옥신류는 높은 화학적 안정성과 생화학적 잔류성으로 인해 1970년대 이후 외국에서는 가장 중요한 환경물질의 하나로 취급되면서 다양한 연구가 이루어지고 있다. 이러한 다이옥신은 여러 가지 경로를 통해 생성되는데 이 중에서도 연소과정, 특히 폐기물 소각로에서 생성되는 것이 주 배출원으로 알려져 있다. 국내에서 1997년도 1차로 실시한 전국의 소각시설 다이옥신 배출 실태조사 이후 정부에서는 신설 도시쓰레기 소각장에 대해서는 0.1 ng-TEQ/Nm$^3$의 배출기준을 설정하고 정기적인 다이옥신 측정을 의무적으로 실시할 것을 법규화한 바 있다. (중략)

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