• Title/Summary/Keyword: 평형 온도

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Analysis of Rotatory Equilibrium Sense using Rotating Stimulator (회전 자극기를 이용한 회전평형 분석)

  • 기호성;김종윤;양길태;김동욱;송철규;김남균
    • Proceedings of the Korean Society for Emotion and Sensibility Conference
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    • 2000.11a
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    • pp.202-206
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    • 2000
  • 본 연구에서는 회전 자극기를 이용하여 성별에 따른 회전 평형감각 특성을 분석하였다. 피검자는 정상성인 남녀 각각 10명에 대해, 두부회전과 rotatory chair test(RCT)에 의한 회전자극 전과 후의 변화정도를 살펴보았고, COP, Flicker Test, 적외선 카메라를 이용한 체열 측정 등을 통해 전정자극 특성을 평가하였다. 그 결과 COP를 통한 신체동요도 측정 결과 회전자극 제시 후 두부회전의 경우 총 누적거리가 1.47배, RCT의 경우 1.78배까지 증가했고, 플리커 치는 여성(8.6%)이 남성(5%)보다 높게 나타났고, 여성이 남성보다 회전자극에 민감함을 알 수 있었다. 또한, 남녀 모두 회전 자극 후 눈 주위의 온도상승이 미소하게 일어남을 알 수 있었다.

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An Experimental Study on the Capability of Arresting the Spread of a Fire of Fireproof Fabric Equipped over Ceiling Board of Wooden Cultural Properties (목조문화재 개판 상부에 설치하는 방염천의 화재전파 차단기능에 대한 실험연구)

  • Kim, Hyunju;Roh, Sam-Kew;Kim, Dong Cheol;Ham, Eun-Gu
    • Journal of the Society of Disaster Information
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    • v.8 no.3
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    • pp.297-303
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    • 2012
  • This study examines the isolation-heat performance of fire proof fabric that is equipped over ceiling board in order to secure the capability of arresting the spread of a fire at roof 'Jucsim' structure of Wooden Cultural Properties. For this examination, I conduct experiments with the model and compare two construction methods of fire proof fabric, or flat-type, folding-type. The experiments show the following results. In case of installing the fire proof fabric in flat-type, when the temperature under the ceiling board is $750^{\circ}C$, the temperatures over the ceiling board is $50^{\circ}C$; the difference is $700^{\circ}C$. Compared with the case of removing fire proof fabric, the temperature over the ceiling board is lower by approximately $580^{\circ}C{\sim}600^{\circ}C$. Therefore it can be said that the construction of fire proof fabric enhances the isolation-heat performance. In case of installing the fire proof fabric in folding-type, when the temperature under the ceiling board is $600^{\circ}C$, the temperatures over the ceiling board is $65^{\circ}C$; the difference is approximately $530^{\circ}C$. Thus its isolation-heat performance is a little inferior to the flat-type equipment.

Studies on Polymerization of Metal Anion (III). The Temperature Effect on Polymolybdate Ions Equilibrium in 1 M $NaCIO_4$ Solution (Metal Anion Polymerization에 관한 연구 (제3보). The Temperature Effect on Polymolybdate Ions Equilibrium in 1 M $NaClO_4$Solution)

  • Sang Woon Ahn;Eui Suh Park
    • Journal of the Korean Chemical Society
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    • v.17 no.3
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    • pp.145-153
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    • 1973
  • The temperature effects on the equilibria between polymolybdatd anions in 1M sodium perchlorate solution has been investigated in the temperature range of 20~50$^{\circ}$C. The polymolybdate anions formed are heptamolybdate ($Mo_7O_{24}^{6-}$) ions and the protonized forms of heptamolybdate ions ($H_LMo_7O_{24}^{(6-L)-}$). The equilibrium constants for the formation of heptamolybdate ions calculated by Sillen's method are as follow;$8H^{+}+7MoO_4^{2-}=Mo_7O_{24}^{6-}+4H_2O$, $k_{7.8}=2.77{\times}10^{53}:20^{\circ}C= 9.29{\times}10^{51}:40^{\circ}C$,$k_{7.8}= 4.22{\times}10^{52}:30^{\circ}C = 9.29{\times}10^{51}:50^{\circ}C$ The enthalpy change for calculated for the above reaction is 31.51 kcal/mole. A method of calculation of the equilibrium constants for the formation of protonized heptamolybdate ions from heptamolybdate ions and hydrogen ions has been derived. The equilibrium constants calculated for the formation of protonized heptamolybdate ions are as follow; $ LH^++ Mo_7O_{24}^{-6} = H_LMo_7O_{24}^{(6-L)-} : L = 1\;or\;2$, $k_1 = 2.31{\times}10^4=2.53{\times}10^4=2.76{\times}10^4= 3.10{\times}10^4$, $k_2 = 6.19{\times}10^7\;20^{\circ}C = 7.80{\times}10^7\;30^{\circ}C = 1.22{\times}10^8\;40^{\circ}C = 2.03{\times}10^8\;50^{\circ}C$The enthalpy change for the following step reactions are as follow;$H^{+}+Mo_7O_{24}^{6-}= HMo_7O_{24}^{5-}\;{\Delta}H^{\circ}=1.90 kcal/mole$, $2H^{+}+Mo_7O_{24}^{6-}=H_2Mo_7O_{24}^{4-}\;{\Delta}H^{\circ}=7.50kcal/mole$

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Oxygen Isotopic Ratios for Ultramafic Xenoliths from the Korean Peninsula (한반도 초염기성 포획암의 산소동위원소 비율)

  • Lee, Jeong-A;Kim, Kyuhan;Lee, Jong-Ik;Choo, Mikyung
    • Journal of the Korean earth science society
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    • v.34 no.1
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    • pp.28-40
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    • 2013
  • This study examined the geochemical characteristics, equilibrium temperature and pressure conditions, and oxygen isotopic ratios of mantle xenoliths from the various geological sites of the Korean peninsula. The results are as follows: (1) The ultramafic xenoliths from the Korean peninsula mainly consist of typical high magnesium olivine (MgO : 49.12-50.95 wt.%, Mg value: 90.1-92.2), corresponding to worldwide Cenozoic ultramafic xenoliths in chemical compositions. (2) The pressure-temperature conditions of ultramafic xenoliths in the Korean peninsula are from 854 to $1016^{\circ}C$ and 4.6 to 24.4 kbar. (3) The oxygen isotopic ratios (${\delta}^{18}O$) for olivines in ultramafic xenoliths range from 5.06‰ to 5.51‰, which are relatively uniform oxygen isotopic values and overlapped by the values of N-MORB and upper mantle peridotite (${\delta}^{18}O$: $5.2{\pm}0.2$‰). However, olivines of the ultramafic xenoliths from the Baegdusan and Chejudo have a relatively wide ${\delta}^{18}O$ values ranging from 5.07 to 5.51‰ and 5.07 to 5.45‰, respectively. Based on the results, this study suggests that the high ${\delta}^{18}O$ signature of the Baegdusan xenoliths give a hint that ~5% of the oxygen in typical EM2 sources originally derived from recycled sediments.

Adsorption Equilibrium, Kinetics and Thermodynamic Parameters Studies of Bismarck Brown R Dye Adsorption on Granular Activated Carbon (입상 활성탄에 대한 비스마르크 브라운 R 염료의 흡착평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.327-332
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    • 2013
  • Batch experiments were carried out for adsorption equilibrium, kinetics and thermodynamic parameters of the brilliant brown R onto granular activated carbon. The operating variables studied were the initial dye concentration, contact time and temperature. Experimental equilibrium adsorption data were fitted to Langmuir and Freundlich adsorption isotherm by linear regression method. The equilibrium process was well described by Freundlich isotherm model and from the determined separation factor (1/n), granular activated carbon could be employed as an effective treatment for the removal of bismarck brown R. From kinetic experiments, the adsorption processes were found to confirm the pseudo second order model with a good correlation and the adsorption rate constant ($k_2$) increased with increasing adsorption temperature. Thermodynamic parameters like the activation energy, change of Gibbs free energy, enthalpy, and entropy were also calculated to predict the nature of adsorption in the temperature range of 298~318 K. The activation energy was determined as 8.73 kJ/mol for 100 mg/L. It was found that the adsorption of bismarck brown R on the granular activated carbon was physical process. The negative Gibbs free energy change (${\Delta}G$ = -2.59~-4.92 kJ/mol) and the positive enthalpy change (${\Delta}H$ = +26.34 kJ/mol) are indicative of the spontaneous and endothermic nature of the adsorption process.

Study on the Resistance for Atmospheric Corrosion of Conventional Epoxy Resins applied to the Restoration of Iron Relics (철기 유물 복원에 사용되는 에폭시 수지 내후성 연구)

  • Lee, Sang-Jin;Kwon, Jeong-Soon;Nam, Byeong-Jik;Ahn, Byung-Chan
    • Journal of Conservation Science
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    • v.21
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    • pp.41-48
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    • 2007
  • The resistance for atmospheric corrosion of the conventional 5 epoxy resins (Araldite rapid, Araldite AW 106, Araldite SV 427, Devcon, and CDK), those were used to restoration of the iron relics, were investigated in this study. Temperature, UV light, and water were chosen for the factors of the atmospheric corrosion. The drastic voluminous changes of the epoxy resins were found at the temperature range between $40^{\circ}C$ and $70^{\circ}C$ After UV exposure, the colors of the epoxy resins were severely changed. In case of the indoor exposure the chroma value(${\Delta}E$) of the resins were less than 2, which showed a little changes of the colors. The result of the water contact angle test was Araldite rapid>AW 106>Devcon>SV 427>CDK. Although the contact angles of the resins were reduced by UV exposure, SV 427 was stable comparatively.

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Temperature Distribution and It's Contribution to Self-equilibrium Thermal Stress in Bridge (교량 단면 내 온도분포에 따른 자체평형 열응력 해석)

  • Kwak, Hyo-Gyoung;Kwon, Se-Hyung;Ha, Sang-Hee
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.24 no.5
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    • pp.531-542
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    • 2011
  • The time-dependent temperature distribution across the section in bridges is determined on the basis of the three-dimensional finite element analyses and numerical time integration in this study. The material properties which change with time and thermal stress of concrete are taken into account to effectively trace the early-age structural responses. Since the temperature distribution is nonlinear and depends upon many material constants such as the thermal conductivity, specific heat, hydration heat of concrete, heat transfer coefficients and solar radiation, three representative influencing factors of the construction season, wind velocity and bridge pavement are considered at the parametric studies. The validity of the introduced numerical model is established by comparing the analytical predictions with results from previous analytical studies. On the basis of parametric studies for four different bridge sections, it is found that the creep deformation in concrete bridges must be considered to reach more reasonable design results and the temperature distribution proposed in the Korean bridge design specification need to be improved.

Browning and Sorption Characteristics of Dried Garlic Flakes with Relative Humidity and Storage Temperature (상대습도와 저장온도에 따른 건조마늘 플레이크의 갈변 및 흡습특성)

  • Kim, Hyun-Ku;Jo, Kil-Suk;Kang, Tong-Sam;Shin, Hyo-Sun
    • Korean Journal of Food Science and Technology
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    • v.19 no.2
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    • pp.176-180
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    • 1987
  • The sorption characteristics of dried garlic flakes stored at various relative humidity and storage temperature were studied. At low relative humidity below RH 51%, the sorption equilibrium was easily attained, whereas at higher relative humidity above RH 67%, the flakes were browned by higher equilibrium moisture content. The flakes were browned at relative humidity above 67% at $20^{\circ}C$ and $35^{\circ}C$, above 84% at $5^{\circ}C$, respectively. The moisture contents of monolayer value for the flakes were ranging from 5.80% to 6.20% (DB) with varying temperatures. And the necessity of moisture-proof packaging material suggested for the long term storage of the flakes because the lower moisture content and storage temperature, the higher driving force of wetting. Regression equation for browning rate prediction with relative humidity and storage temperature of the flakes was determined.

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Promotion and Inhibition Phenomenon of Natural Gas Hydrates (촉진 및 저해 현상에 의한 천연가스 하이드레이트의 상평형)

  • Lee, Seungmin;Park, Sungmin;Lee, Youngjun;Kang, Boram;Seo, Yongwon
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.217.1-217.1
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    • 2010
  • 본 연구에서는 실제 천연가스 구성성분인 메탄 (90%)+에탄 (7%)+프로판 (3%) 혼합기체를 사용하여 심해저 퇴적부에 존재하는 천연가스 하이드레이트 개발과 가스 하이드레이트 형성법을 이용한 천연가스 수송 및 저장법 개발을 위한 열역학적 특성을 살펴보았다. 천연가스 하이드레이트 개발 연구에서는 심해저 퇴적층의 영향을 살펴보기 위해 기공의 직경이 6.0, 15.0, 30.0, 100.0 nm인 다공성 실리카 젤을 사용하여 기공 직경에 따른 3상(하이드레이트 (H)-물 (LW)-기상 (V)) 평형을 측정하였다. 천연가스 하이드레이트 수송/저장법 연구에서는 천연가스 하이드레이트 형성 압력을 낮추어 줄 수 있는 열역학적 촉진제인 TBAB(농도: 5, 10, 40, 60 wt%)와 THF(농도: 1, 5.56, 10 mol%)를 첨가하여 각각의 농도에 따른 혼합 가스 하이드레이트의 3상 평형을 측정하였다. 그 결과 다공성 매질인 실리카 젤의 경우 기공 직경의 크기가 작아질수록 벌크상태의 하이드레이트에 비해 평형 온도는 낮아지고, 평형 압력은 높아져 저해효과가 커짐을 알 수 있었고, 열역학적 촉진제를 첨가했을 경우 TBAB의 농도가 40 wt%, THF의 농도가 5.56 mol%일 경우 촉진 정도가 가장 크게 나타났으며, 그 이상의 농도일 경우 가스 하이드레이트 형성 반응에 참여하지 않은 TBAB와 THF에 의해 오히려 촉진 정도가 감소하는 것을 알 수 있었다. 또한 $^{13}C$ NMR 분석을 통해 혼합 가스 하이드레이트의 격자 형성과 기체 포집에 따른 구조적인 변화에 대해서도 살펴보았다.

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Calculations of Equilibrium Species and Solution Combustion Process for Spray Combustion Synthesis (SCS) (분사연소합성(SCS)을 위한 평형종 계산과 용액연소공정)

  • ;;;;Gary L. Messing
    • Journal of the Korean Ceramic Society
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    • v.38 no.6
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    • pp.545-550
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    • 2001
  • 본 연구에서는 분사연소합성(SCS)을 위한 기초단계로서 용액연소합성에 대한 거동을 살펴보고자 알루미나 합성을 모델로 하였으며 이를 위해 전구체에 대한 열분해거동, 그리고 각 온도에서의 평형종 분압 계산 및 합성과정을 조사하였다. 각각의 열중량 분석(TGA) 결과 산화제와 환원제(연료)의 열분해 이력이 서로 다르게 나타났으며, 열역학 응용 프로그램인 ChemSag에 의한 평형종 분압의 계산에서 연소속도를 저하시킬 수 있는 $CO_2$와 수증기 가스 분압이 상당부분 존재하였다. 산화제/환원제 혼합물의 열분석(DTA/TG) 결과 산화제와 환원제의 열분해 거동의 차이, 그리고 매우 작은 시료의 양으로 인해 263$^{\circ}C$에서 발열피크가 매우 작게 나타났다. 열분석 시료에 비해 발열 에너지를 높이기 위해 산화제와 환원제 혼합 전구체를 비이커에서 증기압을 조절하며 가열시켜 본 결과 27$0^{\circ}C$에서 $\alpha$-Al$_2$O$_3$생성물을 얻을 수 있었다. 따라서 분사연소합성 반응을 통해 세라믹 원료를 합성하기 위해서는 연소과정 중 열분해 거동과 평형종의 분압을 고려하여야 한다.

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