• Title/Summary/Keyword: 평형위치

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Screening test of commercial catalysts for direct synthesis of Dimethyl ether from syngas produced using coal and waste (석탄 및 폐기물로부터 생산된 합성가스로부터 Dimethyl ether의 직접합성을 위한 상용촉매 스크린테스트)

  • Kim, Eun-Jin;Han, Gi-Bo;Park, No-Kuk;Ryu, Si-Ok;Lee, Tae-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.11a
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    • pp.689-692
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    • 2005
  • 2020년까지 전 세계 수송에너지의 수요가 현재의 2배까지 증가할 것으로 예상되면서 석유 자원의 안정적 공급이 어려워지기 이전에 이를 대체할 수 있는 에너지원 개발이 시급하다. 이러한 노력의 일환으로 최근 들어 대두되고 있는 가스화용융 기술은 석탄 폐기물 등으로부터 합성가스를 생산하는 고청정 고효율 기술이다. 여기에서 생산되는 합성가스는 천연가스를 대체하여 전기 및 화학원료를 생산하기 위한 원료로 이용 가능하다. 폐기물로부터 가스화용융기술을 통하여 생산되는 합성가스로부터 DME(dimethyl ether)를 생산할 수 있다. 가스화용융기술로부터 생산되는 합성가스는 자체의 일산화탄소와 수소의 조성비가 DME를 합성하는데 적당하다고 알려져 있다. DME는 에너지원의 다원화와 대기오염 물질의 저감, 지구온난화 대응 등과 아울러 제 4세대 수송 연료로 부각되고 있다. DME를 합성하는 방법은 합성가스로부터 메탄올의 합성 단계를 거친 후 DME를 합성하는 간접법과 단일단계의 반응에서 합성가스로부터 직접적으로 DME를 합성하는 직접법이 있다. 현재는 화학 평형적 측면 경제적 측면에서 이점을 가지고 있는 직접법에 관한 연구가 활발히 이루어지고 있다. DME 직접합성법에서는 메탄올 합성 촉매와 메탄올 탈수촉매의 물리적 혼합에 의한 혼성촉매가 주로 이용되고 있는 것으로 알려져 있다 본 연구에서는 일산화탄소와 수소로 이루어진 합성 가스로부터 직접 DME를 생산할 수 있는 직접 합성 공정에 적용 가능한 고효율 촉매 기술을 개발하기 위해 상용촉매의 스크린 테스트를 수행하였다. 상용촉매로는 sud-chemi사에서 메탄을 합성 촉매와 탈수촉매를 각각 구입하였으며, 이들 촉매를 원하는 조성비로 물리적으로 혼합한 다음 반응온도 ($250-290^{\circ}C$) 압력 (30-50 atm), $H_2$/CO 몰비 (0.5-2.0) 등의 다양한 반응조건 하에서 스크린 테스트를 수행하였다.대장조영영상을 얻을 수 있어 대장암의 위치에 관한 정보를 삼차원적으로 제공하므로 대장암의 성상을 정확히 알 수 있는데 도움을 주었다.요인은 없는 것으로 사료된다. 이 중 2예의 CT에서 선상 혹은망상형의 음영을 보였다. 결론: 유방암 환자의 방사선 치료 후 CT 소견은 방사선 치료의 방법에 따라 폐첨부 혹은 폐의전면 흉막하 부위에 선상 혹은 망상형의 음영으로서 방사선 폐렴 혹은 섬유화 소견이다. CT는 단순 흉부 촬영보다 이상 소견의 발견이 쉽다.이러한 소견은 후에 합병될 수 있는 다른 폐질환의 감별 진단에 도움이 될 것으로 보인다.moembolization via the radial artery approach were involved in this study. All underwent Allen’s test to check ulnar arterial patency. In all cases, we used the radial approach hepatic artery (RHA) catheter designed by ourselves, evaluating t\ulcorner selec\ulcorneron ability of the hepatic artery using an RHA cathter, the number of punctures, the procedure time, and compression time at the puncture site as well as complications occurring during and after the procedure. Results: Except for three in which puncture failure, brachial artery variation or hepatic artery variation occurred, all procedures were successful. The mean number of punctures was 3.5, and the

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Occurrence and Genesis of Amphiboles in Hornblende Gabbro in Guwoonri, Hwacheon and in Otanri, Chuncheon (화천 구운리와 춘천 오탄리 일대에 분포하는 각섬석 반려암체내에 존재하는 각섬석류의 산출양상 및 생성작용)

  • Kim, Guan-Young;Park, Young-Rok
    • The Journal of the Petrological Society of Korea
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    • v.18 no.2
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    • pp.79-91
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    • 2009
  • Jurassic hornblende gabbo intrusives are distributed in Otanri, Chuncheon, and in Guwoonri, Hwacheon located in the northern part of Gyeonggi Massif. The intrusives composed mainly of amphiboles and plagioclase can be divided into two distinct rocks depending on the shape of amphiboles: (i) subspherical amphibole gabbro which has subspherical amphibole phenocryst as a major mafic phase(Sag); (ii) prismatic amphibole gabbro which has prismatic amphiboles as a principal mafic mineral(Pag). Subspherical amphiboles in Sag have higher Cr content and higher Mg($Mg+Fe^{2+}$) ratio relative to the prismatic amphiboles in Pag. This is indicative of conversion of pyroxene into amphibole with pyroxene pseudomorph. Oxygen isotopic results of plagioclase and amphibole separated from the hornblende gabbro suggest that theses minerals have experienced oxygen isotopic exchange with relatively heavy-$^{18}O$fluid for a long period, and magmatic fluid has been involved in the formation of subspherical amphiboles. Amphiboles in hornblende gabbro are composed of distinct species of pargasite, magnesiohornblende, actinolite, which formed at different stages.

Behavior of Reinforced Concrete Slabs Connected with Hinge Joints of Remodelling Buildings (리모델링 건물의 활절점에 의하여 연결된 철근콘크리트 바닥판의 거동 평가)

  • Sim Kyu-Kwan;Kim Sang-Sik;Lee Jung-Yoon;Choi kwang-Ho;Im Juhyeuk
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.761-768
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    • 2005
  • Lately outmoded and functionally obsolete buildings constructed in 1960s and 1970s are often remodelled and restored. Even though there are not serious structural defects in the existing buildings, many old buildings have been reconstructed to improve residence quality or to extend residence area of the buildings. The experimental or theoretical research on plane expansion of RC apartments is quite scare. In this research, 12 specimens and 19 RC slabs connected by hinged joints were tested. The new slab was connected to the existing slab by hinge joints injecting dowel bars between two slabs. Main parameters of the slabs are types of the dowel bars (D13 and D19), spacing of the dowel bars (150mm, 300mm, and 450mm), and the locations of the steel bars in the existing slabs. The test results indicated that the shear strength of the RC test slabs having various types of dowel bars was about twice that calculated by the ACI 318-02 code. All slabs failed in concrete spatting and the dowel steel bars did not reach their yield strengths.

Development of advanced technology shoes combined conical top foundation mechanism (팽이기초 메카니즘을 융합한 신개념 신발 개발 연구)

  • Kim, Yeon-Deok;Lee, Ji-Hyun;Kim, Sang-Hwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.3
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    • pp.724-731
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    • 2016
  • This paper presents the interdisciplinary study of a combined mechanism on the interactions between ground and foot using bioengineering and geotechnical engineering. A new mechanism of advanced technology shoes, which can be made safe with a comfortable gait on both soft and hard ground, were developed combining the mechanism of conical top foundation. The experimental tests were carried out to verify the developed shoes. The prototype shoes and test grounds were designed and produced to perform the tests. The general existing shoes and advanced technology shoes were used to measure the pressures re-acting the sole during the tests by a special measurement system. The results clearly showed that the pressures acting on the sole of advanced technology shoes were distributed uniformly compared with that of the existing shoes, and were in good agreement with theoretical approach of the new mechanism. Therefore, the advanced technology shoes could allow a safe gait ergonomically by a new mechanism on any ground type. The load transfer could occur by the interaction between ground and shoes. In addition, these results are expected to be useful for the development of an interdisciplinary study of a new mechanism in the future.

Analysis on the Ventilation Performance of Single-span Tomato Greenhouse with Roof Windows (천창을 설치한 토마토 재배 단동 온실의 환기성능 분석)

  • Nam, Sang-Woon;Kim, Young-Shik;Both, Arend-Jan
    • Journal of Bio-Environment Control
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    • v.20 no.2
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    • pp.78-82
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    • 2011
  • Ventilation rates, inside and outside weather data were measured in a arch-shape single-span plastic greenhouse growing tomatoes. On the roof of the experimental greenhouse, round windows which have a diameter of 0.6 m were installed at intervals of 8m. It showed that the number of air changes in this greenhouse were average 0.17 volumes per minute and in the range of 0.02 to 0.32 volumes per minute. These air changes are insufficient to meet the recommended ventilation rate for commercial greenhouses, and it is estimated that interval of 6 m is appropriate for spring or fall season. For summer season, it is necessary to narrow the space or to enlarge the open area of roof windows. Using the heat balance model, the evapotranspiration coefficients of greenhouse tomatoes were estimated from experimental ventilation data, overall heat transfer and solar radiation. It showed that the evapotranspiration coefficients were average 0.62 and in the 0.39 to 0.85 range. We suggest applying 0.6 as the evapotranspiration coefficient in design of ventilation for the single-span tomato greenhouses.

Study on Material Characteristics and Firing Temperature of Jar Coffins from Oryang-dong Kiln Site and Jeongchon Tomb, Naju, Korea (나주 오량동 유적 및 정촌 고분 출토 옹관의 재료적 특성 및 소성온도 연구)

  • Kim, Su Kyoung;Jin, Hong Ju;Jang, Sungyoon
    • Journal of Conservation Science
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    • v.34 no.3
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    • pp.179-193
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    • 2018
  • This study is aimed to investigate the provenance of raw materials and firing temperature of jar coffins excavated from the Oryang-dong kiln site and Jeonchon tomb site, Naju, Korea. Most of jar coffin samples shows same range of magnetic susceptibility and have gray color, while 404 and 405 of Jeongchon site are reddish yellow. In some samples fired at high temperature, the water absorption at the mouth rim and body part of same jar coffin were 3.50% and 7.56% respectively. It means that heat transfer and equilibrium in the kiln was not properly continued and the heat energy transferred to the mouth rim and the body part was different. In the petrographic analysis, As a tempering materials, biotite, weathered quartz and feldspar were added in the jar coffins of Oryang-dong site, and biotite, polycrystalline quartz and feldspar in it of Jeongchon site. Tempering materials were found more in the body than in the mouth rim of same jar coffin of Oryang-dong site. It seemed that some samples were fired at over 1,000 to $1,100^{\circ}C$, which showed vitrified texture in the scanning electron images and the rest of samples were fired at below $900^{\circ}C$. Due to similarity of chemical compositions, it is estimated that jar coffins of Jeongchon tomb were produced and supplied from Oryang-dong kiln site. However, the slight difference of some trace elements distribution of samples is attributed to the selection of clay depending on the location.

Neutral zone approach and external impression for rehabilitation of macroglossia: a case report (거대설을 가진 환자에서 중립대 개념과 연마면 인상을 이용한 총의치 수복 증례)

  • Kang, Hyeon;Seo, Nu-Ri;Park, Sang-Won;Yun, Kwi-Dug;Park, Chan;Lim, Hyun-Pil
    • Journal of Dental Rehabilitation and Applied Science
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    • v.34 no.3
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    • pp.218-224
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    • 2018
  • Macroglossia is an obstacle in regard to general prosthodontic restoration. Not only is it difficult to obtain support and stability from dentures manufactured from normal protocol, obtaining efficacy from basic mastication is also difficult. In such cases, realizing harmony between the occlusion and surrounding muscle structures may be important with regard to manufacture of stable full dentures, and it is necessary to form the appropriate polished surface for this case. The neutral zone is defined as the potential area resulting from the neuromuscular function that results in equilibrium between the outward force exerted by the tongue and the inward force exerted by the lips and cheeks. The artificial teeth of the full denture lies in this area, and if the polished zone follows the anatomic form of the dynamic muscles, the movement of the muscles simply acts as an element of stabilizing the dentures improving the esthetics through facial support.

Gas hydrate stability field in the southwestern Ulleung Basin, East Sea (동해 울릉분지 남서부 해역에서의 가스 하이드레이트 안정영역)

  • Ryu Byong Jae;Don Sun woo;Chang Sung Hyong;Oh Jin yong
    • The Korean Journal of Petroleum Geology
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    • v.7 no.1_2 s.8
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    • pp.1-6
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    • 1999
  • Natural gas hydrate, a solid compound of natural gas (mainly methane) and water in the low temperature and high pressure, is widely distributed in permafrost region and deep sea sediments. Gas hydrate stability field (GHSF), which corresponds to the conditions of a stable existence of solid gas hydrate without dissociation, depends on temperature, pressure, and composition of gas and interstitial water. Gas hydrate-saturated sediment are easily recognized by the bottom simulating reflector (BSR), a strong-amplitude sea bottom-mimic reflector in seismic profiles. It is known that BSR is associated with the basal boundary of the GHSF, The purpose of this study is to define the GHSF and its occurrence in the southwestern part of Ulleung Basin, East Sea. The hydrothermal gradient is measured using the expandable bathythermograph (XBT) and the geothermal gradient data are utilized from previous drilling results for the adjacent area. By the laboratory work using methane and NaCl $3.0 wt{\%}$ solution, it is shown that the equilibrium pressures of the gas hydrate reach to 2,920.2 kPa at 274.15 K and to 18,090 kPa at 289.95 K for the study area. Consequently, it is interpreted that the lower boundary of the GHSF is about 210 m beneath 400-m-deep sea bottom and about 480 m beneath 1,100-m-deep sea bottom. The resultant boundary is well matched with the depth of the BSR obtained from the seismic data analysis for the study area.

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Analysis of Deformation and Stability of Slope at the Wiri Region of Local Road 999 Nearby Andong, Gyeongsangbukdo in Korea. (999번 지방도로 경상북도 안동시 위리 지역의 사면 변형 및 안정성 분석)

  • 장현식;장보안
    • The Journal of Engineering Geology
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    • v.10 no.1
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    • pp.1-12
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    • 2000
  • Heaving of road and subsidence of slope took place at the Wiri region of the local highway 999 in Gyeongsangbukdo, Korea after heavy rain in the next year of construction. Although the state government had performed remedial treatments by reducing the angle and the height of the slope, deformation had never stopped. Therefore, we have preformed the analysis of deformation and stabilityof the slope. Study area consists of the Cretaceous shale, siltstone and sandstone and two faults are found. The major deformation occurred by sliding of rock mass along faults after heavy rain because not only thepore pressure at the fault plane and the unit weight of sliding mass increased, but did the shearstrength of saturated fault clay become very low. The decrease in shear strength of saturated fault clayis the major factor among the reasons for deformation. Numerical simulations using limit equilibriummodel, finite difference model and finite element model were performed for eight cross sections.Although safety factors are above 1.7 during the dry season, they become below 1.0 when groundwaterlevel raises to surface. The maximum displacement is about 15-3Ocm. However, safety factors increasedto above 2.4 and the maximum displacement is below 2.08cm after remedial treatment, Indicating thatthe slope becomes stable.

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Numerical investigation of space effects of serial spur dikes on flow and bed changes by using Nays2D (수치모형을 이용한 수제 간격에 따른 흐름 및 하도변화 연구)

  • Lee, Kyung Su;Jang, Chang-Lae
    • Journal of Korea Water Resources Association
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    • v.49 no.3
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    • pp.241-252
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    • 2016
  • In this study, the characteristics of flow and bed changes with variation of space and length of serial spur dikes were investigated with 2 dimensional numerical simulation. Upstream spur dike was affected by flow and made a role as a single spur dike. As time increased, local scouring was developed around outside of spur dike, and migrated upstream. The aggradation of the bed at the back of spur-dike was made at the initial stage of experiment and numerical modelling. However, the aggradation of the bed was increased in the downstream area. The scour whole around a spur dike upstream was not deep as the Dimensionless spur-dike interval (b) of the dike increased. The depth of scour hole was nearly constant at the dynamic equilibrium state. The dimensionless scour depth ($y_s/H$) increased with L/b. The spur dike downstream had the characteristics of single spur dike as the L/b was larger than 10. However, the spur dike downstream was affected by the dike upstream as the L/b was less than 4, and the bed of the upstream in the spur dike was aggradated and the effects of the serial spur dikes on the bed decreased.