• Title/Summary/Keyword: 평형모델

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Kinetics and Equilibrium Study on β-glucosidase under High Hydrostatic Pressure (고압에서 β-glucosidase 반응속도론 및 평형에 관한 연구)

  • Han, Jin Young;Lee, Seung Ju
    • Food Engineering Progress
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    • v.15 no.3
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    • pp.214-220
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    • 2011
  • $\beta$-Glucosidase enzyme reaction under high hydrostatic pressure was investigated in terms of physical chemistry. A model substrate (p-nitrophenyl-${\beta}$-D-glucopyranoside(pNPG)) was used, and the pressure effects on the enzymatic hydrolysis (pNPG${\rightarrow}$pNP) at 25 MPa, 50 MPa, 75 MPa, and 100 MPa were analyzed. Two parts of the reaction such as kinetic and equilibrium stages were considered for mathematical modelling, and their physicochemical parameters such as forward and inverse reaction constants, equilibrium constant, volume change by pressure, etc. were mathematically modeled. The product concentration increased with pressure, and the two stages of reaction were observed. Prediction models were derived to numerically compute the product concentrations according to reaction time over kinetic to equilibrium stages under high pressure condition. Conclusively, the $\beta$-Glucosidase enzyme reaction could be activated by pressurization within 100 MPa, and the developed models were very successful in their prediction.

Development of Gas/Particle Transport Mechanism using Modal Dynamics Approach with Global Equilibrium Method (Modal Dynamics 방법과 광역적 평형 방법을 이용한 기체/입자간 물질이동모델 개발)

  • 정창훈;김용표;이규원
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.215-216
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    • 2000
  • 대기 중에 존재하는 입자의 생성 및 변화를 모델링 하는데 있어서 가장 중요한 요소는 응축/휘발 (condensation/evaporation)과 같은 기체/입자간의 상호 과정을 어떻게 모사 하느냐 하는 것이다. 일반적으로 지금까지의 연구는 입자와 가스상의 농도가 순간적으로 평형을 이룬다고 가정해 왔으나 실제 대기상의 입자는 비 평형(non-equilibrium)상태의 응축/휘발 과정을 따르는 것으로 알려져 왔다. (중략)

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A Practical Design Methodology Considering Maximum and Starting Characteristics of a Single-phase Line Start PM Motor Based on Magnetic Balance (자기적 평형에 기초한 단상 LSPM 전동기의 정동특성과 기동특성을 고려한 실용적인 설계방법)

  • Baek, Soo-Whang;Kim, Byung-Taek;Kwon, Byung-Il
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.840-841
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    • 2011
  • 본 논문은 평형운전조건 및 고정자 동손 최소화조건이 적용된 단상 LSPM 전동기를 기본모델로 하며 이를 기초로 기동특성 및 정동특성을 고려한 최적설계 방법을 제안한다. 기동특성 및 정동특성을 고려한 설계 변수로는 회전자 도체의 형상과 엔드링의 축방향 길이를 선정 하였으며 이를 통하여 평형운전조건과 고정자 동손최소화 조건을 만족하는 동시에 기동특성 및 정동특성을 고려한 최적모델을 설계하였다. 또한 최적설계 과정을 통하여 얻은 특성들을 유한요소해석을 통해 비교 및 분석하였으며 본 논문에서 제안하는 실용적인 최적설계 방법의 타당성을 검증한다.

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Experimental study of Auto Balancer Using Steel Ball (볼을 이용한 자동평형장치의 실험적 연구)

  • 김유신;양보석;전상범;이장우;김성진
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 1996.04a
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    • pp.53-59
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    • 1996
  • 오늘날 산업현장에서 사용되는 대부분의 기계와 가전 제품에는 회전기계가 중요한 역할을 담당하고 있고, 이러한 회전 요소에서 종종 진동이 발생하여 문제가 되고 있다. 이러한 진동이 발생시키는 원인 중에서도 회전체의 불평형(unbalance)이 대부분이다. 이러한 불평형 중에도 매 운전 사이클마다 불평형의 크기나 위치가 바뀌는 경우에는 평형잡이 기계로는 불평형을 수정할 수 없다. 이를 자동적으로 수정하는 장치로써 Thearle가 볼(steel ball)을 이용한 자동평형장치를 제안하였고, 정상는 2개의 볼을 내장한 1개 또는 2개의 원판을 설치하여 계의 기본적인 진동특성을 조사하였다. 그리고 볼과 저점성유체를 내장한 단일원판의 자려진동에 대한 안정성을 조사한 연구결과도 있다. 본 연구에서는 위의 이론들을 기초로 하여 1) 2개의 원판을 모델한 기본적인 진동거동, 2) 자동 평형장치로서 이용가능한 운전영역과 자려진동의 발생 영역 및 조건, 3) 계의 파라메터, 즉 각가속도, 원판내의 유체의 점성계수 및 볼의 갯수의 변화에 대한 자동평형장치의 성능 등을 실험적으로 조사하였다.

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The Effect of Solvent Density on the Ethyl Acetoaceate Tautomerism (에틸 아세토아세테이트 토토머리즘 평형 상수의 밀도 의존성)

  • Park, YoonKook
    • Applied Chemistry for Engineering
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    • v.17 no.3
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    • pp.291-295
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    • 2006
  • The keto-enol tautomeric equilibrium constant, K, of ethyl acetoacetate in compressed and supercritical carbon dioxide was determined by using FT-IR (Fourier transform infrared) spectroscopy at three different temperatures. In order to investigate the effect of solvent density, the $CO_{2}$ pressure was systematically changed at a constant temperature. As the $CO_{2}$ density is increased, the amount of keto tautomer is increased, causing the K value to decrease. The modified lattice fluid hydrogen bonding theory has been applied to investigate the effect of density on the K.

Absorption Characteristics of and a Prediction Model for Spray-Dried Protein-bound Polysaccharide Powders isolated from Agaricus blazei Murill (아가리쿠스버섯에서 분리한 단백다당류 분말의 흡습특성과 예측모델)

  • Hong, Joo-Heon;Youn, Kwang-Sup
    • Food Science and Preservation
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    • v.16 no.5
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    • pp.719-725
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    • 2009
  • We investigated the absorption characteristics of protein-bound polysaccharide powders of various molecular weights isolated from the mushroom Agaricus blazei Murill. The monolayer moisture content calculated using the GAB equation showed a higher level of significance than did the BET equation. The higher the water activity, the lower the isosteric heat of sorption. The fitness of the isotherm curve was shown to be in the order of the Khun, Oswin, Caurie and Henderson models. The prediction model equations for moisture content were established by use of ln(time), water activity, and temperature.

Adaptive Load Balancing based on Consistency (일관성에 기초한 적응 부하 평형)

  • Kim, Jun-Hyeong;O, Ha-Ryeong;Lee, Jae-Mun
    • The Transactions of the Korea Information Processing Society
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    • v.2 no.3
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    • pp.288-298
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    • 1995
  • Load balancing attempts to improve the performance of a distributed computing system by transferring some of the workload of a congested site to others. A load balancing scheme that supports both the source-initiated and the server- initiated load balancing is proposed in this paper. It can model both the m/m/1 queue(no load balancing) and the m/m/n queue(perfect load balancing) as the extreme State variables are replicated into every site, and copy consistency constraints are relaxed more weakly. We propose weak copy consistency constraints which correlate the outdated state information to that of the current state. We also derive sufficient conditions under which each scheduler can guarantee the load balancing without communication Using this model, the problem of load balancing is converted to that of maintaining the consistency of states and communication overhead becomes less than that of the bidding algorithm. The scheme is simulated by event tracing, compared to the two extreme cases and the bidding algorithm. The results show that the mean response time and the number of messages are reduced by 0-35% and 40-100% respectively, compared with the bidding algorithm. Finally the effects of some system parameters are described.

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Dynamic Interaction Modelling between Arctic Offshore Structures and Ice Floe (극지 해양 구조물과 얼음의 동적 모델화)

  • 황철성;김상준
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.1 no.1
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    • pp.87-92
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    • 1989
  • In this study, the nonlinear dynamic model of the systems which include the offshore structure, the surrounding sea water in terms of the added mass, the foundation in terms of frequency independent springs, dashpots, and the floating ice feature with its hydrodynamic added mass, are proposed for the problem of the large ice floes impact. Dynamic Analysis is performed on two site conditions, sand site and silt site, and on two seasons, winter and summer, for various ice floe velocities. As a result of study, Ice floes from energy balenced method is lower than that from dynamic modeling on sand site, and higher than the on silt site.

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Moisture Sorption Characteristics and a Prediction Model of Anchovy Powder with Particle Size (입자크기에 따른 분말멸치의 흡습특성 및 예측모델)

  • Youn, Kwang-Sup
    • Food Science and Preservation
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    • v.17 no.4
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    • pp.513-518
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    • 2010
  • This study was carried out to estimate the moisture sorption characteristics and prediction model of anchovy powders with different particle size as above 80 mesh, 80-60 mesh and 40-60 mesh. The equilibrium moisture content had higher values at lower storage temperatures, and higher water activity. The monolayer moisture content calculated using the GAB equation showed a higher level of significance than that of BET equation. The estimated monolayer moisture content was 0.024-0.052 g $H_2O/g$ dry solid. The absorption enthalpy was calculated with different particle size and various water activities. It showed that the absorption energy was decreased with increasing water activity but no difference was found on particle size increasement. The fitness of the isotherm curve was shown to be in the order of Khun, Halsey, Caurie and Oswin model. The prediction model equations for the moisture content were established by ln(time), water activity, and temperature, respectively. The model equation will be helpful for future work on drying and storage of anchovy powder.