• Proceedings of the KAIS Fall Conference
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• 2002.05a
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• pp.137-139
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• 2002

이온교환은 액체상 이온과 고체상 이온간의 화학반응이며 연수 및 탈염공정, 특정물질의 제거 및 회수, 토양을 통한 이온성 물질의 이동에서 널리 이용되고 있다. 이온교환수지는 이온교환시 원자가가 높을수록, 수화반경이 작을수록, 이온농도가 낮을수록 증가한다. 본 연구는 이온교환수지에 대한 평형실험을 선택도가 칼럼실험에 적용되는지 조사하였다. 이 실험치 결과에서 음이온 교환수지의 선택도 순서는 OH/sup -/ < F/sup -/ < HCO₃/sup -/ < Cl/sup -/ < Br/sup -/ ≤ No₃/sup -/ < So₄/sup 2-/ 이였으며, 음이온 칼럼 교환도 동일하였다. 또한 바탕 양이온의 가수가 높을수록 이온교환이 빠르게 진행됨을 알 수 있다.

• Journal of the Korean Chemical Society
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• v.50 no.3
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• pp.247-255
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• 2006

The purpose of this study was to investigate the correlation between concepts on chemical reaction rates and concepts on chemical equilibrium in high school students. The subjects of the investigation consisted of 120 third grade students attending high school in K city of Kyunggi province. For this study, questionnaire relevant to the subject of chemical reaction rates and chemical equilibrium was developed and the answers were analyzed. As a result of the study, a large percentage of high school students answered questions on reaction rates correctly, but only a small percentage of the students could give explanations. Many high school students answered questions on the rates of forward reactions correctly, but not the questions on the rates of reverse reactions. For the concepts on chemical equilibrium, many high school students gave correct answers when faced with equilibrium questions that only required the understanding of one side of the reaction. But the students could not answer the questions requiring understanding of both forward and reverse reactions as well. Overall, there was a little high correlation between concepts on chemical reaction rates and concepts on chemical equilibrium in high school students. Especially, high school students with little understanding of reverse reaction rates did not understand that chemical equilibrium is a dynamic equilibrium. Also, high school students with little understanding of the collision mechanism regarding chemical reaction rates did not understand the effect of concentration and catalyst factors on chemical equilibrium. And the correlation between concepts on chemical reaction rates and concepts on chemical equilibrium related to concentration and catalyst factors was low. In conclusion, the formation of scientific concepts on chemical reactions rates can decrease misconceptions on chemical equilibrium. Also the teaching-learning method limited to one side of a reaction can cause difficulty in forming the concepts on chemical dynamic equilibrium. Therefore, the development of a teaching-learning method which covers both the forward and reverse reactions can be effective in helping students form the concepts on chemical equilibrium.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.15 no.1
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• pp.36-40
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• 2010

Ballast water has been known as a major vector for global dispersal of toxic dinoflagellates and other microalgae. In this study, biodiversity in ships’ ballast water was examined using a dinoflagellate-oriented PCR primer set and species-specific real-time PCR. While motile dinoflagellates could be observe at very low cell densities by light microscopy,a wide range of dinoflagellate taxa including parasitic and phototrophic pico-dinoflagellates as well as harmful species to marine fish/shellfish was detected when techniques for cloning/sequencing of SSU rDNA of sample cells were used. Present result suggests that molecular methods including species-specific PCR primers may offer rapid and accurate detection of invasive species in ballast water.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.4
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• pp.2029-2035
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• 2014

In this study, we conducted the adsorption equilibrium and batch experiments of dissolved organic carbon (DOC) in the wastewater by granular activated carbon (GAC). The components of organic compound were Beef extract (1.8 mg/L), Peptone (2.7 mg/L), Humic acid (4.2 mg/L), Tannic acid (4.2 mg/L), Sodium lignin sulfonate (2.4 mg/L), Sodium lauryle sulfate (0.94 mg/L), Arabic gum powder (4.7 mg/L), Arabic acid (polysaccharide) (5.0 mg/L), $(NH_4)_2SO_4$ (7.1 mg/L), $K_2HPO_4$ (7.0 mg/L), $NH_4HCO_3$ (19.8 mg/L), $MgSO_4{\cdot}7H_2O$ (0.71 mg/L), The adsorption characteristics of DOC in synthetic wastewater was described using the mathematical model through a series of isotherm and batch experiments. It showed that there was linear adsorption region in the low DOC concentration (0~2.5 mg/L) and favorable adsorption region in high concentration (2.5~6 mg/L). The synthetic wastewater used was prepared using known quantities of organic and/or inorganic compounds. Adsorption modelling isotherms were predicted by the Freundlich, Langmuir, Sips and hybrid isotherm equations. Especially, hybrid isotherm of Linear and Sips equation was a good adsorption equilibrium in the region of the both the low concentration and high concentration. In applying carbon adsorption for treating water and wastewater, hybrid adsorption equation plus linear equation with Sips equation will be a good new adsorption equilibrium model. Linear driving force approximation (LDFA) kinetic equation with Hybrid (linear+Sips) adsorption isotherm model was successfully applied to predict the adsorption kinetics data in various GAC adsorbent amounts.

• Korean Journal of Food Science and Technology
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• v.24 no.4
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• pp.335-340
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• 1992

The amounts of salt diffused into radish after immersing in various concentrations of salt solution at different temperatures were measured and the changes of radish texture by the salt diffusion were estimated with the viscoelastic constants of a 3 element solid model determined by a stress relaxation test. The amount of salt diffused through radish was increased with increasing the salt concentration and soaking temperature. While the instantaneous stress, equilibrium elastic solid content and viscoelastic constants of radish were decreased as salt concentration and soaking temperature increased, the stress relaxed fast. Viscoelastic constants as well as the diffusivity were influenced by salt concentration more than by soaking temperature. The rheological equations for the predictable stress changes of radish after immersed in the salt solution at various conditions (temperature, salt concentration and impure salt) were suggested as a function of time.

• Applied Biological Chemistry
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• v.39 no.5
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• pp.398-402
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• 1996

This study was carried out to compare the fermentation rates of Dongchimi as affected by fermentation temperature and salt concentration of brining solution. The Dongchimi was prepared by fermentation of the radish in salt solutions of 2.0, 3.2 and 5.1% NaCl respectively with addition of garlic, green onion, ginger at $4^{\circ}C,\;10^{\circ}C,\;20^{\circ}C$. The fermentation was classified into 3 steps of initial, intermediate and final stages according to pH changes and the rates of fermentation and color change were calculated from intermediate stage. The time reached equilibrium in hardness of radish and salt concentration and their equilibrated values were also compared. Fermentation rate became more rapid as fermentation temperature and salt concentration increased. The rates of Hunter color change of Dongchimi liquid were increased as the temperature increased. The 'L' values decreased slowly, and 'a' and 'b' values increased rapidly to maximum at the intermediate stage. The time required to reach equilibrium was reduced for both salt concentration and hardness of radish as the fermentation temperature increased. The equilibrated values of salt concentration were increased while those of hardness of radish were decreased as the temperature and salt concentration increased. The data obtained can be used for prediction of some of the major characteristics of Dongchimi during fermentation.

• Proceedings of the Korean Nuclear Society Conference
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• 2004.10a
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• pp.99-100
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• 2004

AMBIDEXTER-NEC의 천이노심은 $^{Nat}Th$과 $^{Nat}U$의 주입만으로 전 출력의 Break-even 노심에 도달하기위한 중간 단계이다. 선행연구에서 수행한 전 출력노심인 평형노심의 핵종수밀도에 도달하기 위해서 평형노심에서의 기저물질, 잠재핵분열성물질, 핵분열물질의 수밀도를 각 SEU-기반, Pu-기반, ADS-기반에서 그대로 유지하여 초기노심을 구성하였다. 또 각 시나리오에 대해 최대첨두출력과 원자로의 안전성을 고려해 Excess Reactivity를 5mk 내에서 초기노심을 결정하였다. 각 노심은 주 핵분열성물질 $^{235}U$, $^{239}Pu$ 및 $^{233}U$의 핵반응단면적 특성에 따라 평균 전환율이 각각 0.95, 0.83 및 1 .21 로서 핵연료물질의 적절한 선택만으로도 전환로, 연소로 및 증식로로 설계할 수 있음을 보여준다. 이러한 $Th/^{233}U$, U/Pu 핵연료주기를 사용하는 AMBIDEXTER-NEC 용융염핵연료 원자로의 초기노심에서 시작한 천이노심은 평형노심에장전할 충분한 $^{233}U$ 양을 확보해야 하므로 천이노심의 목표는 평형노심 $^{233}U$의 요구량에 최소한의 기간에 가장 적은 외부주입을 통해 도달하는 것이다. 천이노심에서 임계가 유지되는 AMBIDEXTER-NEC 원자로시스템의 3군 핵종변환 코드인 HELIOS-SQUID-AMBIBURN 체제를 개발하였고 그림 1.에 나타내었다. 이 알고리즘은 각 초기노심 중원소의 미시단면적, 중원소를 제외한 원소들의 거시단면적, 임계도를 만족하는 중성자속 및 외부주입율을 계산하여 SQUID 및 AMBIBURN 입력자료를 제공한다. 또한 일정시간 중원소의 핵종농도, 외부주입율과 중성자속이 일정하다는 가정 하 에 반복수행 하고 SEU-기반과 Pu-기반의 경우에는 각각 핵변환을 거쳐 재순환되는 $^{233}U$ 및 $^{239}Pu$의 양을 바로 주입하는 최대재순환 경우와 평형노심 요구 장전량에 이를 때까지 시설 내 저장하는 최소재순환 경우로 상황을 모사하였다. 그림 2 는 각 시나리오별 초기노심에서부터 200FPD까지 단위 용융염 체적당 $^{233}U$의 수밀도 시간변화를 나타낸 것이다. 그림을 보면 50일 이후부터는 수밀도의 변화가 일정한 기울기를 보이고 있고 재처리공정에서 $^{233}Pa$를 분리하는 최소재순환의 경우에는 최대재순환보다 2-3%정도에 지나지않아 그림에서 나타내지않았다. SEU-기반 및 Pu-기반에서 $^{233}U$의 증가율이 각각 2.54E+13, 2.81E+13 #/cc/d 로 Pu 기반이 조금 더 큰 증가율을 나타내고 있지만 평형노심 농도 1.04E+20 #/cc/d 에 도달하기 위해서는 두 경우 모두 매우 긴 시간이 걸릴 것을 예상할 수 있다. 요컨대 250MWth AMBIDEXTER-NEC가 평형노심을 이루기 위해 필요로 하는 $^{233}U$을 생산하는데 제안한 SEU-기반, Pu-기반 시나리오는 천이노심주기기간이 전형적인 원자로 수명 3-40년 보다 매우 큰 것으로 나타났다. 따라서 장전될 $^{233}U$의 확보를 위한 최적옵션은 초기노심부터 ADS와 같은 외부생산시설로부터 전량을 공급 받아 운전하는 것이라 판단된다.

• Resources Recycling
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• v.24 no.3
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• pp.3-10
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• 2015

A study has been made on the recovery & separation of cobalt and copper from organic acid leaching solution by solvent extraction. The experimental parameters such as the equilibrium pH, concentration of extractant and phase ratio were observed. Copper was extracted using LIX 84 and Cobalt was extracted using cyanex 272 and versatic acid 10. Experimental results showed that extraction percent of copper was 99% at above eq. pH 2.0 and then more than 90% of cobalt were extracted by cyanex 272 in eq. pH 6.0 and versatic acid 10 in eq. pH 7.5. Stripping of copper and cobalt from the loaded organic phases can be accomplished by sulfuric acid as a stripping reagent and 120 ~ 150 g/L of $H_2SO_4$ was effective for the stripping of copper and cobalt respectively. Finially, the basic optimal process for recovery of copper and cobalt from the bio-leaching solution was proposed.

• Journal of the Korean Chemical Society
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• v.47 no.3
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• pp.283-291
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• 2003

The purpose of this research was to analyze and improve the experiment, observing the color change under compression on the equilibrium of $2NO_2\;{\rightleftarrow}\;N_2O_4$ system, described in high school and general chemistry textbooks. Chemistry textbooks described that the reddish brown color got lighter on the compression of $2NO_2\;{\rightleftarrow}\;N_2O_4$ system. This misinterpretation was due to no consideration of $NO_2$ concentration increase by the volume decrease. In order to propose a correct interpretation, the changes of color and temperature on compression were quantitatively measured and compared with theoretical studies. In addition, an improved experiment, excluding the effect of $NO_2$ concentration increase, was proposed to observe only the color change of the net equilibrium shift.

• Resources Recycling
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• v.17 no.3
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• pp.29-34
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• 2008

Solvent extraction behaviors of iron(III) from chloride solution at high ionic strength condition between Alamine336 and TBP were compared by using MaCabe-Thiele diagram. Extraction isotherms of iron by the two extractants were obtained by calculating the equilibrium concentrations of iron in both phases from the initial extraction conditions. In calculating the equilibrium concentration of iron, chemical equilibria in the aqueous phase and mass balance together with the solvent extraction reaction were considered. MaCabe-Thiele diagram of iron by 1M Alamine336 indicated that two extraction stages could lead to complete extraction of 0.5M iron from 3M HCl solution at an A/O ratio of 6/5. The extraction power of 1M Alamine336 was found to be the same as 2-3M TBP. MaCabe-Thiele diagram together with the physical properties of the two extractants indicated that Alamine336 is superior to TBP in extracting ferric iron from chloride solution.