• Applied Chemistry for Engineering
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• v.9 no.7
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• pp.1090-1097
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• 1998

Lidocaine compounds have widely been used as local anesthetics. Regarding the molecular mechanism for anesthesia by lidocaine, it is proposed that lidocaine molecules penetrate to the hydrophobic region of cell membrane and expand the membrane volume, producing a change in protein conformation that blocks sodium permeability or lidocaine molecules directly adsorb into lidocaine receptor in the protein channel without expanding the cell membrane. But these proposals have never been proven experimentally. In this study, the expansion of cell membrane by lidocaine compounds was investigated by employing lipid monolayer at the air/water interface as the mimetic system of cell membrane. It was found that oil-soluble lidocaine contracted the area/molecule of lipid in the monolayer of phosphatidyl choline, sphingomyelin, DS-PL95E and lipoid, but expanded the monolayer of phosphatidyl ethanolamine only in a certain range of mixing ratios. On the contrary, water-soluble lidocaine-HCl salt expanded the monolayers of all lipids used in this study.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.1
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• pp.75-83
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• 2014

In order to prevent brittle failure of concrete, steel fiber reinforcement is effective composite material. However ductility of steel fiber reinforced concrete may be limited due to shrinkage caused by large content of cement binder. Chemical prestressing for steel fiber reinforcement in cement matrix can be induced through expansive admixture and this can increase reinforcing effect of steel fiber. In this study, mechanical performances in concrete with CSA (Calcium sulfoaluminate) expansive admixture and steel fiber reinforcement are evaluated. For this work, steel fiber reinforcement of 1 and 2% of volume ratio and CSA expansive admixture of 10% weight ratio of cement are added in concrete. Mechanical and fracture properties are evaluated in concrete with steel fiber reinforcement and CSA expansive admixture. CSA concrete with steel fiber reinforcement shows increase in tensile strength, initial cracking load, and ductility performance like enlarged fracture energy after cracking. With appropriate using expansive admixture and optimum ratio of steel fiber reinforcement, their interactive action can effectively improve brittle behavior in concrete.

• Journal of the Korean Geotechnical Society
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• v.38 no.12
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• pp.7-17
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• 2022

The ratios of water and controlled low-strength materials (CLSM) were selected as 1:0.4, 1:0.6, 1:0.8, 1:1.0, and 1:1.2 to minimize the construction and long-term decrease in uniaxial compressive strength due to dry shrinkage through the combination of water, CLSM, and expansion agent. Approximately 2% and 5% of the expansion agent were added for each blending condition. As a result, it was found that the compressive strength decreased and the expandability increased as the specific gravity of the water increased. In addition, it was confirmed that the compressive strength increased rapidly up to 15 days of age compared to the CLSM used in the field. However, the compressive strength decreased compared to the 15 days of the age as of the 28 days of the age. It showed engineering characteristics similar to CLSM generally used in the field. Therefore, the water and the CLSM were mixed at a ratio of 1:0.8, and the field test was performed by adding 5% of an expansion agent. As a result, 28 days after age, the cavity waveform was observed using the handy GPR exploration system, and it was found that cavity waveform was relaxed or disappeared.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.3
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• pp.452-459
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• 2017

In recent years, to reduce self-weight of structural elements, the use of SCP (Steel Concrete Plate) instead of prestressed concrete is increasing. Because SCP has a complicated sectional shape and includes a large number of studs, the use of high-fluidity concrete is required. Therefore, in this study, to prevent the restrained shrinkage behavior by the stud, the effects of using an expansive agent (EA) and shrinkage reducing agent (SRA) were investigated, and the optimal mixture proportions to maximize the filling capacity were determined based on the fine aggregate ratio. The test results indicated that the combined use of EA and SRA exhibited the smallest shrinkage. The ratio of the crushed sand and washed sea sand was determined to be 5:5, and the proper fine aggregate ratio was found to be 55.6%, because when the ratio was too high, a decrease in strength and an increase in shrinkage strain were expected. The high-fluidity concrete effectively filled the large-sized SCP module.

• Journal of the Korea Institute of Building Construction
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• v.15 no.4
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• pp.359-365
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• 2015

Floor mortar experiences dry shrinkage by temperature and humidity difference of internal matrix with material type. Also, since floor mortar is influenced by environmental conditions during placing and curing period, cracks are likely to be occurred. In this study, it was evaluated the hardening and dry shrinkage properties of non-sintered binder based floor mortar utilizing alpha-hemihydrate gypsum which has expansibility in order to prevent crack of the floor mortar. It was applied to the construction site, and examined the effects of external environmental conditions on shrinkage deformation and cracking. Different types of slag accelerated initial and final setting in comparison with cement mortar and its compressive strength was satisfied standard compressive strength for floor mortar. Also shrinkage deformation behavior after the initial expansion exhibited a similar tendency with the cement mortar. From the field application result, no crack was found from slag mortar, and it is determined that the slag mortar has better dimensional stability than cement mortar caused by external environment conditions.

• Journal of the Korean Ceramic Society
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• v.38 no.2
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• pp.193-198
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• 2001

유한요소법을 이용하여 STS VOD 래들에서 내장 내화물의 재질 및 back filler의 시공 위치에 따른 열응력을 수행하였다. 불소성 내화물의 경우 높은 열전도율에 의해 가동면과 배면(back face)간의 온도구배가 소성품에 비해 감소하였으며 탄성계수도 낮아 발생되는 열응력이 2~4배 낮았다. Back filler는 dolomite 내화물의 열간 팽창을 흡수하기 위해 시공하는 것으로, 상대적으로 낮은 열전도율을 가지고 있기 때문에 back filler의 내부와 외부에 급격한 온도구배가 발생된다. 결과적으로 래들의 내부는 고온을 유지하여 내화물이 팽창이 되고, 외부는 온도가 낮아지므로 수축되어 열응력이 증가하였다.

• Journal of the Korean Geosynthetics Society
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• v.19 no.4
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• pp.21-32
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• 2020

As the global large-scale infrastructure construction market expands, the construction of civil engineering structures in extreme environments such as cold or hot regions is being planned or constructed. Accordingly, the construction of the pile foundation is essential to secure the bearing capacity of the upper structure, but there is a concern about loss of stability and function of the pile foundation due to the possibility of ground deformation in extreme cold and hot regions. Therefore, in this study, a new type of pile foundation is developed to respond with the deformation of the ground, and the ground deformation that can occur in extreme cold and hot region is largely divided into heaving and settlement. The new type of pile foundation is a form in which a cylinder capable of shrinkage and expansion is inserted inside the steel pipe pile, and the effect of the cylinder during the heaving and settlement process was analyzed numerically. As a result of the numerical analysis, the ground heaving caused excessive tensile stress of the pile, and the expansion condition of the cylinder shared the tensile stress acting on the pile and reduced the axial stress acting on the pile. Ground settlement increased the compressive stress of the pile due to the occurrence of negative skin friction. The cylinder must be positioned below the neutral point and behave in shrinkage for optimum efficiency. However, the amount and location of shrinkage and expansion of cylinder must comply with the allowable displacement range of the upper structure. It is judged that the design needs to be considered.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.10a
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• pp.386-391
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• 1998

Recently, high performance concrete developed has a good quality at fresh and hardened state, but high binder contents results in spending much money on manufacturing and many cracks by drying and autogenous shrinkage. Therefore, in this paper, not only prevention of cracks caused by drying and autogenous shrinkage, but improvement of quality and accmplishment of economy by applying F.A(fly ash), S.F(silica fume) and CSA(calcium sulfa aluminate) expansive additives as an inorganic admixtures in W/B 35% are discussed. According to the experimental results, when 5% of CSA Expansive additives and 15:5 (F.A:S.F)are replaced at unit cement content, high performance concrete with both good compensation of drying and autogenous shrinkage at hardened state is accomplished.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.61-64
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• 2006

Comparing with traditional high performance concrete, ultra high performance concrete (UHPC) has the property of high-tenacity. However, drying shrinkage and autogenous shrinkage can be arisen as the major defect to UHPC. In this study, therefore, it was tested to reduce drying shrinkage and autogeneous shrinkage by adding expanding admixture (EA) and shrinkage reducing agent (SRA). As a result, for a case drying shrinkage, the shrinkage was decreased by 94% when EA was exchanged, and it was decreased by 64% when SRA was added. For the case of autogenous shrinkage, the mortar was expanded at early age and the shrinkage was decreased by 87% when EA was exchanged, and the shrinkage was decreased by 70% when SRA was added.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.14 no.5
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• pp.1091-1096
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• 1994

Since horizontal movements due to shrinkage and thermal gradients in concrete pavements involve no actual load, the stresses induced will be those due to closing of the pavement joints and subbase friction. Consequently, complete derivations of stiffness matrix and equivalent nodal loads due to planar effects on the concrete pavements was throughly undertaken using the finite rectangular elements with two degrees of freedom at each node. The numerical example shows that the tensile stress induced in a pavement due to concrete shrinkage might be negligible except at very long slab and very high coefficient of frictions. However the stresses in conjunction with principal traffic loads might cause cracking problems.