• Title/Summary/Keyword: 팽창계

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Study about glass-ceramic tube having low thermal expansion and IR transparency (내열충격성 및 적외선 투과 글라스세라믹 제조 및 특성 분석)

  • Byun, W.B.;Park, Y.B.;Kim, Y.H.
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1494-1496
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    • 2002
  • 내열 충격성 및 적외선 투과를 갖는 LAS($Li_2O-Al_2O_3-SiO_2$)계 글라스세라믹스를 제조하였다. 본 연구에서는 LAS계에 $TiO_2$를 핵형성제로, 점도를 감소시키기 위해 $P_2O_5$를 첨가하여 유리를 제조한 후, 글라스세라믹 결정상을 석출시켰다. 석출된 주 결정상은 ${\beta}$-eucryptite(SS)이었으며, 열팽창 계수가 거의 제로에 가까운 값을 얻었다. 또한 선택적인 스펙트럼의 흡수를 위한 color dopants에 대한 기초 자료 등이 조사되었다.

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A Study on Safety Engineering & System Optimization in the Closed Piping System (밀폐배관계에 있어서의 열팽창에 대한 안전설계 및 시스템 최적 설정에 관한 고찰)

  • Char, Soon-Chul;Hwang, Soon-Yong;Kang, Kyung-Sik
    • Journal of the Korea Safety Management & Science
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    • v.9 no.1
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    • pp.1-8
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    • 2007
  • To improve the practical application of the thermal expansion of closed long pipeline exposing to external heating sources such as solar energy, safety engineering and system optimization for relief valve in the closed piping system are suggested through theoretical approach, correlation in view of temperature and pressure increase caused by external solar energy in the closed piping system. The profile for thermal relief valve including relieving capacity, influx heat energy, sizing criteria, set pressure, selection against back pressure is also presented. It is noted that following topic on solar relief valve should be applied to engineering, installation and commissioning.

manufacture and Characterization of Glass Ceramics of P2O3-PbO-SiO2-Al2O3 System for Ic Substrate (P2O3-PbO-SiO2-Al2O3계 회로기판용 glass ceramics의 제조 및 특성평가)

  • 김용철
    • Journal of the Microelectronics and Packaging Society
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    • v.4 no.2
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    • pp.55-62
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    • 1997
  • P2O3-PbO-SiO2-Al2O3계 조성을 이용하여 저온에서 소결이 가증하며 열팽창계수와 유전율이 낮은 회로기판용 glass ceramics를 제조하고자 하였다. 155$0^{\circ}C$에서 2시간 동안 용 융하여 제조한 모유리의열팽창 거동을 확인하기 위하여 TMA로 열분석을 실시하였으며 이 유리를 분말화하여 80$0^{\circ}C$에서 열처리 하였다. 이때 cristobalite 형성억제제로 Ga2O3를 사용 하였으며 Ga2O3 첨가량에 따른 억제 영향을 XRD를 통행 확인하였다. Ga2O3를 첨가한 유리 분말로 pellet을 제조하여 열처리를 하였고 소결시편의 표면을 SEM을 통해 관찰하였다. 열 처리한 pellet에 silver paste를 screen printing하여 유전율을 측정하였으며 조성에 따른 유 전율의 변화를 확인하였다.

Dielectric and Piezoelectric Properties of the xPb$xPb(Al_{0.5}Nb_{0.5})O_3-(1-x)Pb(Zr_{0.52}Ti_{0.48})O_3$ System (1) ($xPb(Al_{0.5}Nb_{0.5})O_3-(1-x)Pb(Zr_{0.52}Ti_{0.48})O_3$계의 유전 및 압전특성 (1))

  • 이홍렬;윤석진;김현재;정형진
    • Electrical & Electronic Materials
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    • v.5 no.2
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    • pp.207-215
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    • 1992
  • 본 연구에서 xPb(A $l_{0.5}$N $b_{0.5}$) $O_{3}$-(1-x)Pb(Z $r_{0.52}$ $Ti_{o.48}$) $O_{3}$계의 조성변화에 따른 유전 및 압전특성에 관해 실험한 결과 다음과 같은 결론을 얻었다. PAN의 첨가량이 증가함에 따라 c축은 수축되고 a축은 팽창하여 tetragonality는 감소하였고 grain의 크기와 Curie온도 또한 PAN의 첨가량에 따라 감소하였으나 밀도와 유전상수는 PAN의 양이 5mol%까지 증가하다가 그 이상에서는 감소하는 경향을 보였다. PAN의 첨가량이 증가함에 따라 시편의 비저항은 증가하였고 Kp는 PAN의 양이 5mol%첨가시 60%로 최대치를 보였으나 Qm은 최소치를 나타내었다.다.

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A Study on Rheological Properties of Cement Paste using Expansive Additives by Kind & Replacement Ratio (팽창재 종류 및 치환율에 따른 시멘트 페이스트의 레올로지 특성)

  • Park, Chun-Young;Kang, Byeung-Hee
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.2
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    • pp.99-106
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    • 2008
  • To improve concrete tensile strength and bending strength, New plan that have more economical and simple manufacture process is groped. By an alternative plan, chemical pre-stressed concrete is presented. In this study, we analyzed the rheological properties of cement paste with the kind and replacement ratio of k-type CSA type expansive additives that is used mainly in domestic. and we suggested that the algorithm of a mixing plan in the chemical pre-stressed concrete and from this, we presented the basic report for the right mixing plan. From the results, Flow increased more or less according to use of expansive additives. This phenomenon was observed by increasing paste amount that shows as substitution for expansive additives that specific gravity is smaller than that of cement. As linear regression a result supposing paste that mix expansive additives by Bingham plastic fluid. The shear rate and shear stress expressed high interrelationship. therefore, flow analysis of quantitative was available. The plastic viscosity following to replacement ratio of expansive additives is no change almost, the yield value is decreased in proportion to the added amount of expansive additives. Through this experiment, we could evaluate rheological properties of cement paste using the expansive additives. Hereafter by an additional experiment, we must confirm stability assessment of material separation by using the aggregate with the kind and replacement ratio of expansive additives.

Development of heat resistant body using Sanchung Kaolin and Jangsu gobdol sludge (산청고령토와 장수곱돌 슬러지를 사용한 내열소지 개발)

  • Kim, Sanggon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.1
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    • pp.27-32
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    • 2020
  • The main cystal phases of traditional ceramics made of clay, quartz, and feldspar are mullite and cristobalite. Although mullite can provide strength to the ceramic body, it cannot be used for the heat resistant ceramics because the thermal expansion coefficient of it is relatively high as 5.3 × 10-6/℃. In this study, development of lightweight heat resistant ceramics was tried by producing cordierite phase, of which the thermal expansion coefficient is 2.6 × 10-6/℃, instead of forming mullite phase in the ceramic body by using Sanchung Kaolin and Jangsu gobdol sludge. It was concluded that ceramics having good heat resistant, bending strength, and refractoriness under load could be fabricated when 80 wt% of Sanchung Kaolin and 20 wt% of Jangsu gobdol sludge were used as raw materials. Also, the bulk specific gravity is 1.78, which is lighter than the existing Buncheong ware.

Effect of Mechanical Restraint due to Steel Microfibers on Alkali-Silica Reaction in Mortars (미세 강섬유의 구속력이 모르타르의 알칼리-실리카 반응에 미치는 영향)

  • Yi, Chong-Ku
    • Journal of the Korea Concrete Institute
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    • v.19 no.5
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    • pp.577-584
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    • 2007
  • The effect of steel microfibers (SMF) on alkali-silica reaction (ASR) was investigated using two types of reactive aggregates, crushed opal and a pyrex rod of constant diameter. Cracks are less visible in the SMF mortars compared with the unreinforced mortars. Due to crack growth resistance behavior in SMF mortar specimens, the strength loss is eliminated and the ASR products remained well confined within the ASR site. The expansion and the ASR products were characterized by microprobe analysis and inductively coupled plasma (ICP) spectroscopy. The confinement due to SMF resulted in a higher Na and Si ion concentration of the ASR liquid extracted from the reaction site. The higher concentration reduced the ASR rate and resulted in a lower reactivity of the reactive pyrex rods in SMF mortars.

Preparation of Surface-anionized Poly(vinyl alcohol-co-methacrylic acid) Hydrogel Beads (표면에 음이온이 도입된 폴리(비닐 알코올-co-메타아크릴산) 하이드로젤 입자의 제조)

  • 윤주표;박연흠;이세근;박기홍;이철주
    • Polymer(Korea)
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    • v.27 no.2
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    • pp.159-166
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    • 2003
  • For the purpose of obtaining surface-anionized poly(vinyl alcohol) (PVA) hydrogel beads, vinyl acetate(VAc) and methacrylic acid(MMA) were copolymerized by the suspension polymerization technique and followed by the saponification. It was confirmed by $^1$H-NMR that the copolymerized microspheres contained carboxylic acid groups in their surface. poly(VAc-co-MAA) microspheres were completely saponified in the heterogeneous system. The saponification reaction was laster than that of PVAc microspheres. We observed the swelling property of saponified PVA microspheres treated in the acidic solution and in the alkaline solution successively. Saponified microspheres shrank in acidic solution and swelled in alkaline solution respectively, which was reversible. from the result, saponified microspheres were highly water-absorbing hydrogel beads and were certified -COOH group at their surface by $^1$H-NMR and FT-IR.

Process Design and Cost Estimation of Carbon Dioxide Compression and Liquefaction for Transportation (이산화탄소 수송을 위한 압축 및 액화 공정 설계 및 비용 평가)

  • Yang, Seeyub;Lee, Ung;Lim, Youngsub;Jeong, Yeong Su;Kim, Jeongnam;Lee, Chiseob;Han, Chonghun
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.988-993
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    • 2012
  • Energy and cost analysis of the preprocessing for carbon capture and storage transportation such as supercritical compression and liquefaction is done using chemical simulation model. Direct compression to supercritical phase (process 1-1), liquefaction and pumping (process 1-2), carbon dioxide compression and expansion as a refrigerant itself (process 2), usage of other refrigerant with compression and expansion (process 3-1), with absorption chiller (process 3-2), cascade refrigeration (process 3-2) have been simulated and evaluated. The specific cost is about 4 to 7 $/ton.

Evaluation of Temperature-dependency of CTE of Materials for MEMS Using ESPI (ESPI를 이용한 MEMS용 소재의 열팽창 계수 온도 의존성 평가)

  • Kim, Dong-Won;Kim, Hong-Jae;Lee, Nak-Kyu;Choi, Tae-Hoon;Na, Kyoung-Hoan;Kwon, Dong-Il
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.1315-1320
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    • 2003
  • The thermal expansion coefficient, which causes the micro failure at the interfacial state of thin films is necessary to consider for proper designing MEMS. The effect of temperature on the coefficient of thermal expansion(CTE) of $SiO_2$ and $Si_3N_4$ film was investigated. Thermal strain induced by mismatch of CTE between substrate and thin film continuously measured with resolution-improved electronic speckle pattern interferometry(ESPI). The thermal stress induced by mismatch of CTE derivate through thermal strain. The thermal expansion coefficients of thin film were calculated with the general equation of CTE and thermal stress in thin films, and it confirmed that CTE of $SiO_2$changed from $0.25{\times}10^{-6}/^{\circ}C$ to $1.4{\times}10^{-6}/^{\circ}C$ with temperature increasing from 50 to $600^{\circ}C$

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