• Title/Summary/Keyword: 팔라듐(II)

Search Result 30, Processing Time 0.026 seconds

Preparation and Characteristics of Pt/GDE Loaded with Pd Promoter for PEMFC (Pd 조촉매가 도입된 PEMFC용 Pt/GDE 제조 및 특성)

  • LEE, HONGKI;LEE, WOOKUM
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.27 no.3
    • /
    • pp.264-269
    • /
    • 2016
  • A simple dry chemical approach was developed in order to load palladium (Pd) as a promoter on Pt/gas diffusion electrode (GDE) for polymer electrolyte membrane fuel cell (PEMFC). Palladium(II) bis (acetylacetonate), $Pd(acac)_2$ was sublimed, penetrated into Pt/GDE and then reduced to Pd nanoparticles simultaneously without any reducing agent and any solvent in a glass reactor of $N_2$ atmosphere at $180^{\circ}C$ for 3, 5 and 15 min. Pd distribution was analyzed by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS), and I-V curve was estimated by using a unit cell with $5{\times}5cm^2$ active area.

The Extraction of Palladium by Polyurethane Foam impregnated with ${\beta}$-Diphenylglyoxime (${\beta}$-디페닐글리옥심으로 침윤시킨 폴리우레탄 포움에 의한 팔라듐의 추출)

  • Sam Woo Kang;Seung Seok Lee
    • Journal of the Korean Chemical Society
    • /
    • v.27 no.4
    • /
    • pp.268-272
    • /
    • 1983
  • Polyurethane foam impregnated with ${\beta}$-diphenylglyoxime has been applied to the extraction of palladium(II) from platinum(IV) and nickel(II) in aqueous solution. Palladium(II) is quantitatively extracted from $0.01{sim}0.05M$ HCl. On the other hand, platinum(Ⅳ) was slightly extracted and nickel(II) was not found to be extraction in the same experimental condition. Based on the results obtained, the selective separation, removal and recovery of Pd(II) from Pt(IV) or Ni(II) was possible by batch or elution method.

  • PDF

Molecular Orbital Interpretation on Antitumor Activity of trans-Palladium(Ⅱ) Complexes by Geometrical Structure of Ligands (Ⅰ) (리간드의 기하학적 구조에 의한 trans-팔라듐(Ⅱ) 착물의 항암활성에 관한 분자궤도함수론적 해석 (Ⅰ))

  • Song, Young Dae;Park, Byung Kak
    • Journal of the Korean Chemical Society
    • /
    • v.39 no.4
    • /
    • pp.244-251
    • /
    • 1995
  • The palladium(II) complexes(where, [Pd(L)2X2], L=isoxazole(isox), 3,5-dimethylisoxazole(3,5-diMeisox), 3-methyl, 5-phenylisoxazole(3-Me, 5-Phisox), and 4-amino, 3,5-dimethylisoxazole(4-ADI); X=Cl, Br] with isoxazole and its derivatives are investigated on antitumor activity by EHMO calculation. It is found that the net charge of the two halogen atoms in trans-isomers are greater than those in cis-ones, indicating that ionic character of Pd-X bond in trans-isomers is greater than that of cis-ones, and so dissociation of Cl- ion is easier than that of Br- ion in aqueous solution in body. Furthermore, it is found that the ${\sigma}MO$ energy of Pd(dx2-y2)-X(px) bond $(E{\sigma}(Pd-X))$ is higher than that of Pd(dx2-y2)-N(px) bond $(E{\sigma}(Pd-N))$ without exception, about all the complexes, and also the $E{\sigma}(Pd-X)$ of trans-isomers is higher than that of cis-isomers. From the above facts, the degree of dissociation in Pd-X bond would be related to antitumor activity. In fact, the linear equation of correlation coefficient 0.96 is fairly established between ${\Delta}E{\sigma}(N-X)(E\sigma(Pd-N)-E{\sigma}(Pd-X))$ and inhibitory activity coefficient, logIA.

  • PDF

Electronic Structure and Electrochemistry of Complexes Trans-bis(tri-phenyl phosphine) Palladium(II) and Nickel(II) with Ligands $(CH_3COO-,\;Cl-\;and\;CO)$ (리간드 $(CH_3COO-,\;Cl-,\;CO)$와 트란스-비스(트리페닐포스핀) 팔라듐(II) 과 니켈(II) 착물들에 대한 전자적구조와 전기화학적 연구)

  • Choe Chil Nam;Jung Oh Jin;Kim Se Bong
    • Journal of the Korean Chemical Society
    • /
    • v.36 no.1
    • /
    • pp.44-50
    • /
    • 1992
  • The ability to account for magnetic and spectra properties of complexes was investigated for the splitting of the degenerate d-orbitals and with nonaqueous solution by UV/vis-spectrophotometric method. The correlation of the magnetitude of 10Dq obtained from the spectra, the pairing energy, and the spin state of the complexes. The electrochemical behavior of complexes were investigated by the use of cyclic voltammetry in aprotic media. These reduction peak of $[(C_6H_5)3_P]_2Pd(II)(CH_3COO)_2$ and $[(C_6H_5)_3Pd]_2Pd(II)Cl_2$ were irreversible one-electron processes at peak $E_{pc1} = -1.32 V,\;E_{pc2} = -1.56 V$ and $E_{pc1} = -1.74 V,\;E_{pc2} = -1.88 V$ of these complexes vs. Ag/AgCl, but nickel complexes were not to be reducible.

  • PDF

Metal Complexes of Ambidentate Ligand (VI). Palladium(II) Complexes of Isonitrosoethylacetoacetate Imines (Ambidentate 리간드의 금속착물 (제 6 보). Isonitrosoethylacetoacetate Imine 리간드의 팔라듐 (II) 착물)

  • Jun Young-Sook;Lee Man-Ho;Kim In-Whan;Kim Soo-Han
    • Journal of the Korean Chemical Society
    • /
    • v.35 no.4
    • /
    • pp.368-373
    • /
    • 1991
  • Palladium(II) complexes of the type Pd(IEAA-NR)$_2$ (R = H, CH$_3$, C$_2$H$_5$, n-C$_3$H$_7$, n-C$_4$H$_9$, or CH$_2$C$_6$H$_5$), where IEAA-NR represents N-alkyl derivative of isonitrosoethylacetoacetate (H-IEAA) imine, have been prepared. And the structure of the complexes have been studied by elemental analyses, electronic, infrared, $^1$H and $^{13}$C-NMR spectra. It is proposed that both of IEAA-NR ligands coordinate to metal through nitrogens of imine and isonitroso groups to form 5-membered chelate rings in the complexes.

  • PDF

Mechanical Property of Nafion Membrane Incorporated with Pd Nanocatalyst and the Performance of PEMFC (Pd 나노 촉매가 도입된 나피온 막의 기계적 강도 및 고분자 전해질막 연료전지 (PEMFC) 성능)

  • LEE, WOOKUM;LEE, HONGKI
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.27 no.3
    • /
    • pp.270-275
    • /
    • 2016
  • A simple solid state incorporation method was employed in order to incorporate Pd nanocatalyst into a Nafion film for polymer electrolyte membrane fuel cell (PEMFC) via the reduction of palladium (II) bis (acetylacetonate), $Pd(acac)_2$. It was sublimed, penetrated into Nafion film and then reduced to Pd nanoparticles simultaneously in a glass reactor of N2 atmosphere at $180^{\circ}C$ for 1, 3 and 5 min. This reaction was took place without any reducing agent and any solvent. The morphology of the Pd nanoparticles was observed by transmission electron microscopy (TEM), and Pd distribution was analyzed by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). And 23% modification of tensile strength of Pd/Nafion composite film was measured by universal testing machine and I-V curve was estimated by using a unit cell with $5{\times}5cm^2$ active area.

Performance Evaluations of Direct Formic Acid Fuel Cell (DFAFC) using PdCu Catalysts Synthesized by Control in Amount of Ethylene Glycol (에틸렌글리콜 양 조절에 의해 제조된 팔라듐구리 촉매를 이용한 개미산연료전지 성능평가)

  • YANG, JONGWON;KIM, LAEHYUN;KWON, YONGCHAI
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.27 no.3
    • /
    • pp.283-289
    • /
    • 2016
  • In this study, electrochemical characterizations of PdCu/C catalysts that are synthesized by modified polyol method are investigated. Most of all, amount of ethylene glycol (EG) that is used as main component for catalyst synthesis is mainly modulated to optimize synthetic condition of the PdCu/C catalyst, For evaluations about catalytic activity and performance of direct formic acid fuel cell (DFAFC), half cell and full cell tests are implemented. As a result, when amount of EG is 4M, catalytic activities of the PdCu/C catalyst such as peak current of formic acid oxidation and active surface area are best, while maximum power density of DFAFC using the optimized PdCu/C catalyst is better than that using commercial Pd/C (30 wt%) by 6%. Based on that, PdCu/C catalyst synthesized by modified polyol method plays a critical role in improving (i) catalytic activity for formic acid oxidation and (ii) DFAFC performance by employing as anodic catalyst.

Phase Equilibria of the System Pd-Sb-Te and Its Geological Implications (팔라듐-안티몬-테루르 계(系)의 상평형(相平衡)과 지질학적(地質學的) 의의(意義))

  • Kim, Won-Sa;Chao, George Y.
    • Economic and Environmental Geology
    • /
    • v.26 no.3
    • /
    • pp.327-335
    • /
    • 1993
  • Phase relations in the system Pd-Sb-Te were investigated at $1000^{\circ}$, $800^{\circ}$, and $600^{\circ}C$, using the sealed-capsule technique; the quenched products were studied by reflected light microscopy, X-ray diffraction, and electron microprobe analysis. At $1000^{\circ}C$, the solid phases Pd, $Pd_{20}Sb_7$, $Pd_8Sb_3$, $Pd_{31}Sb_{12}$, and $Pd_5Sb_2$ are stable with a liquid phase that occupies most of the isothermal diagram. Additional solid phases at $800^{\circ}C$ are $Pd_5Sb_3$, PdSb, $Pd_8Te_3$, $Pd_7Te_3$, and a continuous $Pd_{20}Te_7-Pd_{20}Sb_7$ solid solution becomes stable. At $600^{\circ}$, $PdSb_2$, $Pd_{17}Te_4$, $Pd_9Te_4$, PdTe, $PdTe_2$, $Sb_2Te_3$, and Sb and continuous PdSb-PdTe and $PdTe-PdTe_2$ solid solutions are stable. All the solid phases exhibit solid solution, mainly by substitution between Sb and Te to an extent that varies with temperature of formation. The maximum substitution (at.%) of Te for Sb in the Pd-Sb phases is: 44.3 in $Pd_8Sb_3$, 52.0 in $Pd_{31}Sb_{12}$, 46.2 in $Pd_5Sb_2$ at $800^{\circ}C$; 15.3 in $Pd_5Sb_3$, 68.3 in $PdSb_2$ at $600^{\circ}C$. The maximum substitution (at.%) of Sb for Te in the Pd-Te phases is 34.5 in $Pd_5Sb_3$ at $800^{\circ}C$, and 41.6 in $Pd_7Te_3$, 5.2 in $Pd_{17}T_4$, 12.4 in $Pd_9Te_4$, and 19.1 in $PdTe_2$ at $600^{\circ}C$. Physical properties and X-ray data of the synthetic $Pd_9Te_4$, PdTe, $PdTe_2$, $Pd_8Sb_3$, PdSb, and $Sb_2Te_3$ correspond very well with those of telluropalladinite, kotulskite, merenskyite, mertieite II, sudburyite, and tellurantimony, respectively. Because X-ray powder diffraction data consistently reveal a 310 peak ($2.035{\AA}$), the $PdSb_2$ phase is most probably of cubic structure with space group $P2_13$. The X-ray powder pattern of a phase with PdSbTe composition, synthesized at $600^{\circ}C$, compares well with that of testibipalladite. Therefore, testibiopalladite may be a member of the $PdSb_2-Pd(Sb_{0.32}Te_{0.68})$ solid solution series which is cubic and $P2_13$ in symmetry. Thus the ideal fonnula for testibiopalladite, presently PdSbTe, must be revised to PdTe(Sb, Te). Borovskite($pd_3SbTe_4$) has not been found in the synthetic system in the temperature range $1000^{\circ}-600^{\circ}C$.

  • PDF

Synthesis and Characterization of Hybrid Nanocomposites of Pd Nanoparticles Containing POSS(Pd-POSS) and Poly(acrylic acid) via Ionic Interactions (실세스키옥세인을 포함한 팔라듐 나노입자와 폴리아크릴산과의 이온결합에 의한 나노복합체 제조 및 특성평가)

  • Jeon, Jong-Hwan;Lim, Jung-Hyurk;Chujo, Yoshiki;Kim, Kyung-Min
    • Polymer(Korea)
    • /
    • v.33 no.6
    • /
    • pp.615-619
    • /
    • 2009
  • Pd-POSS nanoparticles were produced from the reaction of palladium (II) acetate and octa(3-aminopropyl)octasilsesquioxane octahydrochloride (POSS-${NH_3}^+$) in methanol at room temperature. Pd-POSS nanoparticles with a mean diameter of 60-80 nm were the highly ordered spherical aggregates. In contrast, Pd nanoparticles with a size of 4.0 nm were obtained when POSS-${NH_3}^+$ was not introduced. Pd-POSS/PAA nanocomposites of Pd-POSS nanoparticles and poly(acrylic acid) (PAA) were fabricated by utilizing ionic interactions between positively charged Pd-POSS nanoparticles and negatively charged carboxylate groups of PAA. PAA was used as a cross-linker for the preparation of hybrid nanocomposites with the controlled organized structures of Pd-POSS nanoparticles. That is, the self-organization of Pd-POSS nanoparticles was formed into the shape of continuous lines by using PAA as a cross-linker. The composition, structure, surface morphology, and thermal stability of the Pd-POSS/PAA nanocomposites were studied by FE-SEM, AFM, TEM, FT-IR, and TGA.

Development of the Efficient Synthetic Route for Itraconazole Antifungal Agent (이트라코나졸 항진균제의 효과적인 합성법 개발)

  • Baek, Du-Jong
    • Applied Chemistry for Engineering
    • /
    • v.17 no.6
    • /
    • pp.633-637
    • /
    • 2006
  • In this study, the efficient large-scale synthetic route for itraconazole, triazole antifungal agent, was developed. The original synthetic route for medicinal chemistry reported by Janssen Pharmaceutica was linear (14 linear steps) starting from 2,4-dichloroacetophenone with the total yield of 1.4%, and potential hazardous materials such as methanesulfonyl chloride ($CH_{3}SO_{2}Cl$), hydrogen gas, and sodium hydride (NaH) were used. Furthermore, the expensive 1-acetyl-4-(4-hydroxyphenyl)piperazine and palladium were used in this medicinal chemistry route, thus the manufacturing cost would be practically high. In order to improve the commercial route, we developed the process of 12 step convergent synthesis combining two intermediates which are roughly halves of itraconazole with the total yield of 12.0%, and hazardous materials and expensive reagents were excluded in this process, thus the manufacturing cost could be cut down to a great extent.