• Title/Summary/Keyword: 파울링 물질

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A Study of Efficacy of Physical Water Treatment Devices for Mineral Fouling Mitigation Using Artificial Hard Water (인공 경수를 이용한 미네랄 파울링 저감에 물리적 수처리 기기들의 효과에 관한 연구)

  • Pak, Bock Choon;Kim, Sun Do;Baek, Byung Joon;Lee, Dong Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.11 s.242
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    • pp.1229-1238
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    • 2005
  • The objective of the present study was to investigate the efficacy of physical water treatment (PWT) technologies using different catalytic materials and an electronic anti-fouling device in the mitigation of mineral fouling in a once-through flow system with mini-channel heat exchanger. Effects of flow velocity and water hardness on the effectiveness of PWT technologies were experimentally studied. The artificial water hardness varied from 5.0 to 10 mo1/m$^{3}$ as CaCO$_{3}$. For 10 mo1/m$^{3}$ solution, fouling resistance reduced by 13-40$\%$ depending on flow velocity and types of PWT devices. On the other hand, fouling resistance reduced by 21-29$\%$ depending on the PWT devices for 5 mo11m3 solutions. The PWT device using alloy of Cu and Zn as catalyst (CM2) was slightly more effective than the others. SEM photographs of scale produced from the 10 mol/m$^{3}$ solution at 1.0 m/s indicated that calcium carbonate scales without PWT devices were needle-shaped aragonite, which is sticky, dense and difficult to remove. Scales with the PWT devices showed a cluster of spherical or elliptic shape crystals. Both the heat transfer test results and SEM photographs strongly support the efficacy of PWT technologies using catalytic materials and an electronic anti-fouling device in the mitigation of mineral fouling.

Membrane Permeation Characteristics and Fouling Control through the Coating of Poly(vinyl alcohol) on PVDF Membrane Surface (PVDF막 표면에 폴리비닐알코올 코팅을 통한 분리막의 투과특성 및 막오염 제어)

  • Jang, Hanna;Kim, In-Chul;Lee, Yongtaek
    • Membrane Journal
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    • v.24 no.4
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    • pp.276-284
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    • 2014
  • In this study, a hydrophobic polyvinylidene fluoride (PVDF) membrane was modified by coating neutral hydrophilic poly(vinyl alcohol). The flux of pure water was measured and then fouling test was conducted with bovin serum albumin (BSA) as model protein foulant. As a result, the experiments showed that pure water flux was decreased but anti-fouling property was significantly enhanced. Pure water flux with increasing molecular weights of the polymer was decreased and fouling resistance was enhanced. Also, Pure water flux with increasing solution concentration was decreased and fouling resistance was enhanced. It is probably due to the increase in hydrophilicity and decrease in roughness of the membrane surface, as revealed by contact angle and AFM analysis.

The Study on Optimum Operation Conditions of Ceramic MF Membrane Process in Y Water Treatment Plant (Y 정수장 세라믹막 여과공정 최적 운영인자 평가)

  • You, Sang-Jun;Ahn, Hyo-Won;Park, Sung-Han;Lim, Jae-Lim;Hong, Sung-Chul;Yi, Pyong-In
    • Membrane Journal
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    • v.24 no.3
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    • pp.201-212
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    • 2014
  • This study was performed to discover the optimum operation conditions for the advanced water treatment using the ceramic membrane, introduced the first in the nation at the Y water treatment plant (WTP). The result of investigation to find the optimum operation conditions which can continue preserving the filtration performance as well as satisfying both the economics and the water quality is as follows. In the ordinary water quality condition of the Y WTP, the optimum filtration time(the backwash period), which can minimize the production of backwash waste and preserve the membrane performance was examined to be 4.0 hours on basis of institution capacity ($16,000m^3/day$). Examining the recovery rate of TMP from the chemical cleaning (CIP) discovered that the inorganic contaminants, which cause membrane fouling, such as iron, manganese, aluminum, were removed through the acidic cleaning using citric acid, whereas the membrane recovery rate was found to be low. But, on the other hand, the TMP was recovered to the initial value from the alkali cleaning using the NaOCl. Therefore, the main contaminant causing the fouling was determined to be hydrophilic organic compound( biopolymer). The membrane recovery rate is highly influenced by the temperature of the cleaning chemical. That is, the rate increased with increasing temperature.

The Effect of Cooling Efficiency on Fouling by EGR Cooler Internal Shape (EGR Cooler 내부 형상에 따른 Fouling이 냉각 성능에 미치는 영향)

  • Nam, Youn-Woo;Oh, Kwang-Chul;Lee, Chun-Hwan;Lee, Chun-Beom;Lee, Won-Nam
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.1
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    • pp.101-108
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    • 2011
  • Understanding the exhaust gas recirculation (EGR) cooler fouling in diesel engine is important factor in the durability characteristic of a EGR system. We develope a test rig and PM feeder using carbon black to examine the effect of fouling on EGR cooler devices those were consisted of flat and shell & tube type. The EGR cooler fouling process is a complex interaction involving heat exchanger shape, boundary condition, constitutes, chemistry and operating mode. As the soot deposited to EGR cooler, these formed a thin deposit layer that was less heat exchange than the fresh status of tube enclosing the exhaust gas, resulting in lower heat exchange effectiveness in both type coolers. But these deposits caused different results in pressure drop, it is increased in flat type, but decreased in Shell & tube type of EGR cooler. A cause was estimated from a change of the flow structure and a decrease of contact area as the EGR cooler fouling.

Micro-Filtration Performance of Metal Membrane md Fouling Reduction by Intermittent Ozonation (금속 막의 정밀 여과 특성 및 간헐적 오존 처리에 의한 막 오염 저감)

  • 김종오;정종태
    • Membrane Journal
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    • v.14 no.1
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    • pp.66-74
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    • 2004
  • Total resistance of membrane in a micro-filtration system using a metal membrane was mainly attributed to the permeate resistance of cake layer($R_c$), which was formed by deposited particles from the physico-chemical interactions of solids on membrane surface. Intermittent back ozonation was highly effective than the air backwashing for fouling reduction. As far the operational effect, under same ozone injection, the increase of gas flow-rate was more favorable than the increase of injection time far the recovery of permeation flux. As the filtration time was longer, the effect of flux recovery by intermittent back-ozonation decreased. Therefore, it is preferable to operate membrane cleaning before the foulant is consolidated on membrane surface.

Effects of Alkali Metals and Chlorine on Corrosion of Super Heater Tube in Biomass Circulating Fluidized Bed Boiler (순환유동층보일러의 과열기 튜브 부식에 알칼리 금속과 염소가 미치는 영향)

  • Back, Seung-Ki;Yoo, Heung-Min;Jang, Ha-Na;Joung, Hyun-Tae;Seo, Yong-Chil
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.29-34
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    • 2017
  • This study provides the identification of corrosion cause substances in super heater tube from a commercial scale circulating fluidized bed boiler. Electricity is produced by the combustion of biomass mainly wood waste. The biomass, super heater tube, super heater tube ash, and boiler ash were collected and components associated with corrosion were analyzed. A large amount of oxygen-containing material was found due to oxidation. The chlorine content was analyzed as 6.1% and 4.3% in super heater tube ash and boiler ash respectively which were approximately 20 and 14 times higher than those of designed values. Also, alkaline metal contents (K, Na, Ca) were very high in ash samples collected from super heater tube and boiler. The tendency of slagging and fouling was predicted based on X-Ray Fluorescence (XRF) results. Basicity that can lead to slagging was estimated as 3.62 and 2.72 in super heater tube and boiler ash, respectively. Slagging would occur with ash content when considering the designed value as 0.35.

A Study on Optimization of Manufacture Conditions for Water Treatment Membrane by Using Electrospinning Method (전기방사법을 이용한 수처리용 막 제조 조건 최적화 연구)

  • Lee, Sang Hyun;Choi, Sung Yeol;Chang, Soon Woong;Kim, Sung Su
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.8
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    • pp.456-461
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    • 2017
  • In this study, nano fibers with various physical properties were materialized by using a variety of polymers [PAN (Polyacrylonitrile), PU (Polyuretane), PSU (Polysulfone)] which are raw materials of dope solution manufactured for electrospinning and solvents [NMP (N-methyl-2 pyrrolidone), DMF (Dimethylformamide)] and evaluated characteristics of their flux and SS (Suspended Solids) separation and then ascertained application of manufactured fibers as separation membrane for water treatment. In this study, analysis of surface of manufactured material was carried out through SEM analysis to ascertain the cause of flux and SS separation performance by checking diameter, uniformity and straightness of fiber. If additive is used in manufacturing nano fiber water treatment separation membrane, it is expected to solve problems such as membrane fouling and mechanical strength and to be used as basic factor for manufacturing separation membrane with catalyst function added.

Scale Thickness Measurement of Steam Generator Tubing Using Eddy Current Signal of Bobbin Coil (보빈코일 와전류신호를 이용한 증기발생기 세관 스케일 두께 측정)

  • Kim, Chang-Soo;Um, Ki-Soo;Kim, Jae-Dong
    • Journal of the Korean Society for Nondestructive Testing
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    • v.32 no.5
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    • pp.545-550
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    • 2012
  • Steam generator is one of the major components of nuclear power plant and steam generator tubes are the pressure boundary between primary and secondary side, which makes them critical for nuclear safety. As the operating time of nuclear power plant increases, not only damage mechanisms but also scaled deposits on steam generator tubes are known to be problematic causing tube support flow hole blockage and heat fouling. The ability to assess the extent and location of scaled deposits on tubes became essential for management and maintenance of steam generator and eddy current bobbin data can be utilized to measure thickness of scale on tubes. In this paper, tube reference standards with various thickness of scaled deposit has been set up to provide information about the overall deposit condition of steam generator tubes, providing essential tool for steam generator management and maintenance to predict and prevent future damages. Also, methodology to automatically measure scale thickness on tubes has been developed and applied to field data to estimate overall scale amount.

Effects of F/M ratio on the EPS production and fouling at MBR (MBR에서 F/M비가 EPS 생성 및 fouling에 미치는 영향)

  • Kim, Yun-Ji;Choi, Yun-Jeong;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.3
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    • pp.197-204
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    • 2021
  • In MBR, extracellular polymeric substance (EPS) is known as an important factor of fouling; soluble EPS (sEPS) affects internal contamination of membrane, and bound EPS (bEPS) affects the formation of the cake layer. The production of EPS changes according to the composition of influent, which affects fouling characteristics. Therefore, in this study, the effects of the F/M ratio on the sEPS concentration, bEPS content, and fouling were evaluated. The effects of F/M ratio on the amount and composition of EPS were confirmed by setting conditions that were very low or higher than the general F/M ratio of MBR, and the fouling occurrence characteristics were evaluated by filtration resistance distribution. As a result, it was found that the sEPS increased significantly with the increase of the F/M ratio. When the substrate was depleted, bEPS content decreased because bEPS was hydrolyzed into BAP and seemed to be used as a substrate. In contrast, when the substrate is sufficient, UAP (utilization-associated products) was rapidly generated in proportion with the consumption of the substrate. UAP has a relatively higher Protein/Carbohydrate ratio (P/C ratio) than BAP, and this means, it has a higher adhesive force to the membrane surface. As a result, UAP seems like causing fouling rather than BAP (biomass-associated products). Therefore, Rf (Resistance of internal contamination) increased rapidly with the increase of UAP, and Rc (Resistance of cake layer) increased with the accumulation of bEPS in proportion, and as a result, the fouling interval was shortened. According to this study, a high F/M ratio leads to an increment in UAP generation and accumulation of bEPS, and by these UAP and bEPS, membrane fouling is promoted.

A study on possibility of using CST as a fouling evaluation index at MBR (MBR에서 fouling 평가지표로서 CST의 활용 가능성에 대한 연구)

  • Kim, Yun-Ji;Choi, Yun-Jeong;Sim, Tae-Suk;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.6
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    • pp.379-387
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    • 2021
  • In general, trans-membrane pressure (TMP), flux, filtration resistance are used as indicators to evaluate the degree of fouling in MBR. However, they have limitations in determining the level of EPS generation, which is known as an important factor of fouling. Therefore, a new evaluation method is required to monitor the amount of EPS generation. In this study, the applicability of capillary suction time (CST), which is used to measure the dewaterability of sludge, was evaluated as an indirect fouling evaluation index. Statistical analysis was performed to evaluate the effect of EPS on CST, and to determine whether EPS has high similarity with representative fouling evaluation indicators and CST, and quantitatively compared them. As a result, the correlation coefficient between CST and bEPS was 0.7988, which was higher than the correlation coefficient between filtration resistance and bEPS. Since bEPS is a major factor inducing fouling by affecting the formation of the cake layer, it was evaluated that CST, which has a high correlation with bEPS, is suitable to represent EPS. In addition, it was evaluated that the correlation coefficient between filtration resistance and CST was high as 0.7187, which could be used as a fouling evaluation index.