• Title/Summary/Keyword: 파울링 물질

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Effect of Operating Conditions on the Fouling of UF Membrane in Treatment of Dissolved Organic Matter (UF를 이용한 용존성 유기물질 제거시 운전조건이 파울링에 미치는 영향)

  • Kwon, Eun-Mi;Yu, Myong-Jin
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.7
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    • pp.1183-1191
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    • 2000
  • Operating conditions for reduction of membrane fouling in treatment of dissolved organic matter by UF membrane process were investigated by pilot-scale plant using various operating conditions. As inlet pressure increased, increament of transmembrane pressure and flux decline were faster. The reason was due to the increase in adsorption of dissolved organic matter and the development of cake layer compression on the membrane surface. When efficient pressure (the difference of pressure between backwash and transmembrane pressures) was high, small amount of pollutant was retained on the membrane surface. When backwash was frequently conducted, low concentration of pollutant was maintained in recycling water. Therefore, backwash could be efficiently conducted with high efficient pressure and high frequency. Fouling rate was correlated with backwash and inlet pressures, recovery rate and cumulative permeated volume. Among the operating parameters backwash pressure was most closely related to fouling rate and inlet pressure was next to backwash pressure. It seems that the fouling was strongly related to pressure which leads to the cake layer compression and adsorption of dissolved organic matter.

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Identification of Fouling Phenomena and Establishment for Optimized Removal Process of Alginic Acid Sodium Salt Through Capacitive Deionization (CDI 공정에서 Alginic Acid Sodium Salt의 파울링 현상 확인 및 제거 조건 확립)

  • Lee, Jin Yeon;Rhim, Ji Won
    • Membrane Journal
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    • v.30 no.5
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    • pp.342-349
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    • 2020
  • In this study, we suggest conditions to reduce fouling in capacitive deionization (CDI) caused by alginic acid sodium salt, one of the most common fouling-causing substances in natural water and wastewater management. First, NaCl is used as feed material, which is selected as the control of the experiment. As expected, fouling phenomena is not observed from NaCl. On the other hand, when alginic acid sodium salt is added to the inlet, the fouling phenomena can be observed. In order to minimize the fouling phenomena, the feed concentration of alginic acid sodium salt, applied potential during desorption process, and duration of applied potential to our CDI cell are controlled. With 7 mg/L of feed stream concentration, CDI performed using 1.2 V for 1 min during adsorption followed by desorption with -2 V for 1 min exhibited the highest alginic acid salt removal efficiency reaching 50.07%.

Confirmation of The Fouling Phenomena in CDI Process and The Establishment of Its Removal Process Conditions (CDI 전극 내 파울링 현상 확인 및 제거공정 조건의 확립)

  • Kim, Tae Yeong;Rhim, Ji Won
    • Membrane Journal
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    • v.29 no.5
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    • pp.276-283
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    • 2019
  • In this study, The experiments of the confirmation of the fouling phenomena in CDI process and the establishment of its removal process conditions were carried out. The foulant concentrations of humic acid sodium salt (HA) added to the feed solution were 5, 10, 15 mg/L, respectively. The occurrence of fouling under the certain adsorption/desorption conditions could be confirmed with an increase in adsorption and desorption concentration curve over time. Both the voltage and time in adsorption and desorption processes were changed to eliminate the fouled pollutants. Typically, the fouling removal condition was found at the adsorption condition 1.2 V/5 min and the desorption condition -3 V/2 min, respectively.

Studies on the Fouling Reduction by Coating of Cationic Exchange Polymer onto Reverse Osmosis Membrane Surfaces (역삼투막 표면의 양이온 교환 고분자 코팅에 의한 파울링 감소 연구)

  • Park, Chan Jong;Kim, Sung Pyo;Cheong, Seong Ihl;Rhim, Ji Won
    • Polymer(Korea)
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    • v.36 no.6
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    • pp.810-815
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    • 2012
  • The cation exchange polymer, poly(styrene sulfonic acid) (PSSA), was coated onto polyamide (PA) thin film composite reverse osmosis (RO) membranes. Then these membranes were investigated for the model foulants, bovine serum albumin (BSA), humic acid (HA), and sodium alginate (SA) to check whether there are some improvement. The contact angle of PSSA coated PA RO membrane showed $58^{\circ}$ from $78^{\circ}$, the value of PA RO membrane, which confirmed successful hydrophilization. As the operating pressure increased (2, 4, 8 atm for BSA, HA and SA 100 ppm in feed solution), the fouling phenomena was worse for both none- and PSSA-coated membranes. The fouling increased in the order of BSA>SA>HA due to the interactions between sulfonic acid in PSSA and functional groups of foulants. On the other hand more significant fouling reduction was observed in the order of HA>SA>BSA. The photographs of scanning electron microscopy showed the same trend. As a result, there was the improvement of fouling phenomena for the PSSA coated RO membranes, distinctly in the case of HA.

Understanding Alginate Fouling in Submerged Microfiltration Membrane System for Seawater Pretreatment (해수전처리를 위한 침지식 정밀여과 멤브레인 시스템에서 Alginate 파울링의 이해)

  • Jang, Hoseok;Kwon, Deaeun;Kim, Jeonghwan
    • Membrane Journal
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    • v.26 no.1
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    • pp.55-61
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    • 2016
  • Organic fouling observed in submerged membrane filtration as a pretreatment for seawater desalination increases energy consumption for membrane operation because of requiring frequent chemical cleaning and membrane replacement. In membrane pretreatment for seawater facing with algae blooms, membrane fouling was observed in submerged microfiltration using sodium alginate model compound which is one of the main components of extracellular polymeric substances. Without aeration, aglinate fouling increased with its concentration while aeration reduced the alginate fouling effectively regardless of its concentration tested. In the absence of aeration, alingate fouling tended to be decreased with increasing calcium concentration. However, this effectiveness was reduced by increasing sodium chloride concentration. At high concentration of sodium chloride and calcium similar to the seawater conditions, aeration reduced initial fouling. However, as time progressed, the effect of increased airflow rate on fouling reduction was not significant, implying that optimum airflow rate to control alginate fouling in submerged microfiltration can exist.

Studies on the Fouling Reduction through the Coating of Poly (vinyl alcohol) on Polyamide Reverse Osmosis Membrane Surfaces (역삼투막 표면에 폴리비닐알코올 코팅을 통한 파울링 현상 감소연구)

  • Kim, Il Hyoung;Ji, Eun Hee;Rhim, Ji Won;Cheong, Seong Ihl
    • Membrane Journal
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    • v.22 no.4
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    • pp.272-279
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    • 2012
  • The neutral polymer, poly (vinyl alcohol) (PVA), was coated onto polyamide (PA) thin film composite reverse osmosis (RO) membranes. And then these membranes were investigated for the model foulants, bovine serum albumin (BSA), humic acid (HA), and sodium alginate (SA) whether there are aome improvement. As the operating pressure increased with 2, 4, 8 atm for BSA, HA and SA 100 ppm in feed solution, the fouling phenomena was worse for both none and PSSA coated membranes. The fouling occurred in the sequence of BSA > HA > SA due to the interactions between PVA snd functional groups of foulants, and on the other hand the fouling reduction was observed in the order of HA > BSA > SA. The observation of scanning electron microscopy photographs showed the same trend. As a result, there should be the improvement of fouling phenomena for the PVA coated RO membranes and the case of HA was shown distinct.

A Study on the Entrance Region Fouling of Sludge Incinerator Air-preheater at IronWorks (제철슬러지 소각로의 공기예열기 입구의 파울링특성 연구)

  • 박상일;김정근
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2003.05a
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    • pp.557-562
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    • 2003
  • 산업체 소각로의 고온 배가스에는 소각물질의 특성에 따라 다양한 성분의 오염물질이 함유되어 있다. 고온 소각배가스의 후처리를 위하여 배가스냉각용 열교환기가 사용되고 있다. 그러나, 소각로 열교환기의 입구와 전열면에 파울링 현상이 발생하여 열교환기의 전열성능이 감소하고 또한 심한 경우, 유로면적이 줄어들어 통풍저항이 증대된다.(중략)

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Study on the Fouling Reduction of the RO Membrane by the Coating with an Anionic Polymer (역삼투막 표면에 음이온 고분자 코팅을 통한 파울링 현상 감소연구)

  • Cho, Eun Hye;Cheong, Seong Ihl;Rhim, Ji Won
    • Membrane Journal
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    • v.22 no.6
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    • pp.481-488
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    • 2012
  • The anionic exchange polymer, poly(vinyl amine)(PVAm), was coated onto polyamide (PA) reverse osmosis (RO) membranes by using 'salting-out' method. The effects of the fouling phenomena for these PVAm coated membranes were investigated using the model foulants, bovine serum albumin (BSA), humic acid (HA), and sodium alginate (SA). The surface coating and the fouling phenomena were observed by the scanning electron microscopy. And the flux was measured for each 100 ppm of above foulant aqueous solution at the operating pressure, 2, 4, 8 bar. The PVAm-coated PA membranes showed somewhat fouling improvements and the fouling reduction was shown in the order of HA > SA > BSA, particularly HA case was distinct.

Characteristics of the Air-side Particulate Fouling Materials in Finned-Tube Heat Exchangers of Air Conditioners (공기조화기용 열교환기의 공기측 파울링 입자 분석 연구)

  • 안영철;신희수;황유진;이창건;이재근;이현욱;안승표;윤덕현;하삼철
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.7
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    • pp.611-617
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    • 2003
  • The air-side particulate fouling in the heat exchangers of HVAC applications degrades the performance of cooling capacity, pressure drop across a heat exchanger, and indoor air quality. Indoor and outdoor air contaminants foul heat exchangers. The purpose of this study is to investigate the characteristics of the air-side particulate fouling materials in finned-tube heat exchangers of air conditioners. Air conditioners being used in the field such as inns, restaurants, and offices are collected in chronological order in use. Typical fouling materials on the heat exchangers include fibers and dusts ranged from 6.6 to 20.9 ${\mu}{\textrm}{m}$ in mass median diameter.

A Study on Fouling Characteristics and Applicability of Fouling Reducer in Submerged MBR Process (침지형 MBR공정에서 파울링 특성과 파울링 완화제의 적용성에 관한 연구)

  • Park, Jun Won;Park, Hong June;Kim, Min Ho;Oh, Yong Keol;Park, Chul Hwi
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.5
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    • pp.371-380
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    • 2013
  • Though MBR process has many advantages, the greatest risk factors in operating MBR process are occurrence of membrane fouling and decrease of flux. It is very difficult to find exact mechanism due to complex influence by many effects, although there have been recently many studies of membrane fouling. The purposes of this study are firstly evaluating bioreactor of lab-scale and micro-filtration hollow fiber membrane, secondly investigating correlation between foulants affecting membrane performance and membrane fouling, and lastly evaluating various parameters affecting fouling and applicability of membrane fouling reducer. This study found that TMP was increasing rapidly and showed 0.32 bar and the average of flux was 88 LMH. EPS concentration tends not to change much above MLSS concentration (6,000 mg/L). However, EPS concentration variation is wide below MLSS concentration (6,000 mg/L). Also, from results of membrane surface condition and element analysis using SEM/EDX, carbon and fluorine were founded to be the highest percentage in membrane because of characteristics of membrane material. In operating continuously, inorganic fouling was generated by increase of these inorganic substances such as $Al^{3+}$ and $Mg^{2+}$. Lastly, the best filtration performance was obtained for 0.03 mg MFR/mg MLSS by results of particle size, zeta potential, $SCOD_{cr}$, EPS and MLSS concentration.