• Title/Summary/Keyword: 파라핀계

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Combustion Characteristics of the Paraffin-Based Hybrid Rocket Fuel (파라핀계 하이브리드 로켓 연료의 연소 특성)

  • Kim, Soo-Jong;Cho, Jung-Tae;Kim, Gi-Hun;Kim, Hak-Chul;Woo, Kyong-Jin;Lee, Jung-Pyo;Moon, Hee-Jang;Sung, Hong-Gye;Kim, Jin-Kon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.225-228
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    • 2009
  • Combustion characteristics of the paraffin-based hybrid rocket fuel were compared with HDPE fuel. Regression rate of the pure paraffin wax was increased 12.1 times, but characteristic velocity was lower than HDPE. In case of paraffin fuel with 10%wt LDPE, regression rate was lower than pure paraffin wax, but regression rate compare with HDPE was increased 3.5 times and characteristic velocity was increased. According to these results, it was confirmed that blending of polymeric fuel improves combustion efficiency.

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Removal of Paraffin Wax from Ceramic Injection Mold Using Supercritical Carbon Dioxide (세라믹 사출성형체로부터 초임계이산화탄소를 이용한 파라핀왁스의 제거)

  • Kim, Dong-Hyun;Hong, Seung-Tae;Yoo, Ki-Pung;Lim, Jong-Sung
    • Clean Technology
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    • v.14 no.1
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    • pp.1-6
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    • 2008
  • Removal of paraffin wax from a ceramic injection mold using supercritical $CO_2$ has been studied. The paraffin wax is used as a binder in the ceramic injection molding process. The effects of pressure, temperature and flow rate of supercritical $CO_2$ on the removal of the paraffin wax were investigated. The removal rates were measured with various flow rates of $CO_2$ in the range of 328.15 - 348.15 K and 15 - 30 MPa. The removal rate of paraffin wax increased as the pressure increased. In the effect of temperature, the paraffin wax was effectively removed over 329.15K (melting point of paraffin wax), however, the efffct of temperature was not significant when the temperature was further increased. The increase of $CO_2$ flow rate also affected the removal of paraffin wax. However, the effect of flow rate was not observed when the flow rate reached a certain value. Propane was used as a co solvent in order to remove the paraffin wax effectively. When the propane was added to the $CO_2$, the removal efficiency was improved. The paraffin wax was completely removed from the ceramic injection mold without any change in their shape and the structure.

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Study on Combustion Characteristics of Diesel Fuel and Low Quality Oil Droplet with Additive Oxygenate and Paraffin (함산소계 및 파라핀계 혼합 경유 및 저질유 액적의 연소특성에 관한 연구)

  • Kim Bong-Seock;Ogawa Hideyuki
    • Journal of Advanced Marine Engineering and Technology
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    • v.30 no.5
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    • pp.552-561
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    • 2006
  • The single droplet combustion characteristics of diesel fuel and low quality oil with additive oxygenate and paraffin under high ambient temperature and atmospheric pressure were investigated in the study. The results of the study may are concluded as follows: In the combustion of diesel fuel and low quality oil droplet with additive of oxygenate and paraffin. the dimensionless droplet size of $(D/Do)^2$ was linearly decreased with time. A fuel droplet with low boiling temperature additives and in high boiling temperature base fuel evaporates and burns faster than usual base fuel. Especially. these trends were remarkably obtained by decreasing boiling point and increasing blending contents of additives in case of oxygenated agents rather than n-paraffin agents. This rapid burning may result from so-called 'micro-explosion' and its burning intensity varies with the types of additives. The results above may suggest that rapid evaporation of oxygenate additive in the middle stage of combustion can contribute much to combustion improvement of blended fuels.

A Study on the Combustion Characteristics of Diesel Fuel Droplet with Additive Oxygenate and Paraffin (함산소 및 파라핀계 혼합 디젤유 액적의 연소특성에 관한 연구)

  • Kim, Bong-Seock;Miyamoto, Noboru
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.2
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    • pp.49-56
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    • 2006
  • The single droplet combustion characteristics of multicomponent fuel such as diesel-oxygenate and diesel-paraffin blends under high ambient temperature and atmospheric pressure were investigated in the study. The results of the study may be concluded as follows : In the combustion of diesel fuel droplet with additive of oxygenate and paraffin, the dimensionless droplet size of $(D/D_o)^2$ was linearly decreased with time. A fuel droplet with low boiling temperature additives and in high boiling temperature diesel fuel evaporates and burns faster than usual diesel fuel. This rapid burning may result from so-called "micro-explosion" and its burning intensity varies with the types of additives. The results above may suggest that rapid evaporation of oxygenate additive in the middle stage of combustion can contribute much to combustion improvement of blended fuels. When compared to ordinary diesel fuel, neat oxygenate and paraffin fuels show blue flame during entire combustion which prove smokeless combustion.

Isomer Formation in the Chlorination of Highmolecular Paraffinic Hydrocarbons by Various Halogenating Agents (여러 종류의 할로겐 화합물과 고분자량 파라핀계 탄화수소의 염소화에서 생기는 이성질화에 관한 연구)

  • Li-Hoan Kung
    • Journal of the Korean Chemical Society
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    • v.32 no.4
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    • pp.390-405
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    • 1988
  • The chlorination of $C_7H_16,\;C_8H_18,\;C_10H_22,\;and\;(Me_2CH)_2$ with N-Chlorosuccinimide, tert-BuOCl, $CCl_3SO_2Cl,\;CCl_4,\;CCl_3SCl,\; PCl_5,\;and\;Cl_2\;in\;C_6H_6\;or\;CS_2$ which both form loose complexes with $Cl_2$ atoms yielded mixtures of isomeric monochloroalkanes which were analyzed quantitatively. An isomer ratio differing from that known for the substitution of paraffinic hydrocarbons was observed. The isomer distribution observed is the result of the combined effects of the differing C-H dissociation energies of the different types of H atoms of the alkane and of the free energy of the attacking radical with polar effects of the attacking radical as well as of the hydrocarbon.

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Reaction characteristics of hydrocarbon fuels under various operation conditions of hydro-upgrading process for vegetable oil-based bio-jet fuel production (식물성 오일 기반 바이오항공유 제조공정에서 수소첨가 업그레이딩을 위한 운전조건에 따른 탄화수소화합물의 특성)

  • Kwak, Yeonsu;Jang, Jung Hee;Kim, Sungtak;Ahn, Minhwei;Lee, Eun-Sil;Han, Gi Bo;Jeong, Byung Hun;Han, Jeong Sik;Jeon, Cheol-Hwan
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.731-743
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    • 2018
  • In bio-jet fuel production, selecting operating conditions of hydro-upgrading is of great importance to make iso-Paraffin rich hydrocarbons with carbon distribution including jet fuel range. Herein, iso-Paraffin rich biofuel including jet fuel range hydrocarbons ($C_8-C_{16}$) is produced from simultaneous cracking and isomerization using n-Paraffin rich hydrocarbon derived from hydrotreated vegetable oil over 0.5 wt..% Pt/Zeolite catalyst. We report and analyze the yields and compositions in the produced hydrocarbons affected by various operating conditions, such as reaction temperature, reaction pressure, molar ratio of reactants, and weight hourly space velocity. Aforementioned operating conditions not only can help interpret the reaction dynamics of hydro-upgrading, but also further produce bio jet-fuel after distillation.

A Study of Droplet Combustion Characteristics with Mulicomponent Fuel (다조성 연료 액적의 연소특성에 관한 연구)

  • 김봉석
    • Journal of Energy Engineering
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    • v.10 no.2
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    • pp.153-160
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    • 2001
  • 본 연구에서는 고온 분위기 온도 및 대기압 하에서 액적의 급속가열과 연소가 가능한 고온 연소로 장치와 고속도 비디오 카메라를 이용하여 다조성 단일 액적 연소에 대해 고찰하였다. 그 결과 저비점 성분을 혼합한 경유의 액적은 기본적으로 입경의 2승 법칙에 의해서 감소되었으며, 그 과정에서 입경이 일시적으로 급속히 감소하는 현상이 보여짐과 더불어 연소기간도 단축되었다. 즉, 저비점 성분을 혼합한 경유의 액적은 미세폭발 현상에 의해 기존 디젤 연료에 비해 더 빨리 증발되고 연소가 되었다. 또한, 순수 파라핀계 및 함산소계 연료의 화염은 전체 연소기간동안 기존 경유의 화염에 비해 푸른색을 띠고 있어, 매연이 없는 연소를 입증해 주었다.

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The Preparation of Non-Silicone Oil Based Adhesion Promoted Silicone Sealant (비실리콘 오일을 BASE로 한 접착력 강화 실리콘 실란트의 제조 개발)

  • Han, Gil-Soo;Jeong, Kyoung-Han;Chun, Yong-Jin
    • Proceedings of the KAIS Fall Conference
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    • 2008.05a
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    • pp.309-312
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    • 2008
  • We have prepared the silicone sealant using non silicone oil without silicone oil for solvent and using adhesion promotor against various substrate. We are replaced the silicone oil by the mineral oil and the normal adhesion promotor by mixed adhesion promotor at the multi purpose silicone sealant.

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Preparation process of functional particles: III. Preparation of composite particles by rapid expansion of supercritical fluid solutions and release behavior (기능성 미분말의 제조공정에 관한 연구 : III. 초임계 분출법에 의한 복합분체의 합성과 용출특성)

  • ;;;Eiichi Abe
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.1
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    • pp.55-59
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    • 1999
  • The Rapid Expansion of Supercritical fluid Solutions (RESS) process was applied to particles coating. Microcapsules prepared by spray drying were used as the core particles, and two kinds of paraffin were used as the coating materials. Supercritical $CO_{2}$ solutions of paraffin were expanded through the short nozzle into the bed that was fluidized by air. Extraction temperature and pressure were varied at $50~120^{\circ}C$, $150~200\;kg/\textrm{cm}^2$, respectively. The thickness of theoritical coating layer ws measured, and precipitate coating layer on surface was analyzed by using SEM, FT-IR. The release behaviors of $Mg^{2+}$ ions were inspected by atomic absorbance spectrophtometer.

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