• Applied Chemistry for Engineering
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• v.33 no.3
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• pp.309-314
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• 2022

Carbon dots (CDs) are few nanometer-sized carbon-based nanoparticles and emerging candidate materials in various fields such as biosensors and bioimaging due to their excellent optical properties and high biocompatibility. However, most CDs, emitting blue light, have limited their application in biomedical fields due to the low penetration of short-wavelength lights into the biological system. Therefore, there has been enormous need to develop long-wavelength emitting CDs. In this study, red-emitting CDs were successfully synthesized through the hydrothermal reaction of p-phenylenediamine with hydrochloric acid. In addition, the effect of the amount of hydrochloric acid on the formation of carbon dots, resulting in the variation of the chemical structures of CDs, were investigated, which was confirmed with the intensive structural analyses using infrared and X-ray photoelectron spectroscopy. It was found that the chemical structure of CDs governed their optical properties and quantum yield. Therefore, this study provides an insight into the role of acid in forming red-emitting CDs as the optimal probe for biomedical application.

• Journal of Korean Tunnelling and Underground Space Association
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• v.24 no.1
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• pp.57-78
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• 2022

The disc cutter and cutterbit, which are the most important factors to increase the excavation efficiency of TBM, are key factors in the design and construction of the cutter head. The arrangement, spacing, number, size, and material of disc cutters suitable for the ground conditions determine the success or failure of TBM construction. The disc cutter, which is a representative consumable part in TBM construction, can cause enormous disruption to the construction cost as well as the construction cost unless accurate prediction of wear and replacement cycle is accompanied. Therefore, in this study, the method of calculating the replacement cycle of the disc cutter calculated at the time of design for the slurry shield TBM field, and the depth of wear and replacement location of the disc cutter that occurred during actual construction were compared by analyzing the field data. For a quantitative comparison, weathered soil/weathered rock, soft rock, and hard rock were classified according to the ground in the section showing constant excavation data, and the trajectory of circle was different depending on the location of the disc cutter, so it was compared and analyzed.

• Journal of Korean Tunnelling and Underground Space Association
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• v.24 no.1
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• pp.95-108
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• 2022

The increase in the use time of tunnel users due to the lengthening of the road tunnel may increase the evacuation time in case of fire, resulting in a large number of casualties. In order to reduce the casualties caused by fire, the "Road Tunnel Design Manual, Part 6 Tunnel" and "Road Tunnel Disaster Prevention Facility Installation and Management Guidelines" stipulate that ventilation facilities should be installed along with the extension of the tunnel. The ventilation system design factor considers the wind speed of the external natural wind to be at least 2.5 m/s, and it is applied upward according to the characteristics of the tunnel. As a result of analyzing the five-minute average wind speed data in the Daegwallyeong region for the past 6 years, it was analyzed that 15.8% of the windy days were winds of 10 m/s or more, and the maximum was 20 m/s. Therefore, in this study, when a fire occurs in a tunnel, the pattern of natural wind flowing into the tunnel and the backlayering distance of the tunnel fire smoke according to the maximum wind speed were analyzed. As a result, it was analyzed that a backflow of up to 490 m occurs when a gust of 20 m/s blows.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.4
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• pp.219-226
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• 2021

We examined component analysis and lead isotope ratio analysis to find out the relationship between the excavation and the production site of 25 bronze weapons from prehistoric ages. All 25 bronze weapons are ternary alloys of copper-tin-lead and lead is artificially added. The lead isotope ratios of 25 bronze weapons show that bronze are made by raw materials in the southern regions of the Korean Peninsula, including northern China. The raw materials of narrow-shaped bronze dagger are supplied in zone 1-3 and northern China. In addition, provenance of lead for bronze halberd and pearhead are the rest of the region except for zone 1 and zone 4. Silver are enriched in most samples and zinc and cobalt are deficient. Arsenic and antimony detected only specific samples and can be used as critical parameter for provenance study. Lead isotopes and trace elements of archaeological bronzes will provide conservation scientist with useful tool to study the provenance of raw materials

• The Journal of the Korea Contents Association
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• v.22 no.9
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• pp.19-28
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• 2022

This study aimed at public officials who are most strongly demanded to tear up the corruption and diagnosed what they really think about 'the corruption'. So, a qualitative research method called 'subjectivity study' or 'Q methodology' was used to typing on the perception of corruption. In other words, 30 Q-samples related to corruption and P-samples composed of 30 public officials were investigated to derive the analysis results. As a result of the analysis, three types of perceptions of corruption were defined. That is, showed a high distribution of civil servants such as 'educational administration' and 'teacher', and and showed a high distribution of 'general administrative positions' civil servants. Also, among the respondents of , it was found that the distribution of 'high' was higher for the level of corruption in our society, and the distribution of 'medium' for and was found in the case of the respondents with high factor weight. The overall explanatory power was high at 62.11%, and based on the series of results, a hypothesis could be found that 'the perception of corruption differs according to the characteristics of the work of public officials'. By the results, the commonly recognized terms for 'corruption' were 'politician/politician' and 'solicitation'. Therefore, based on a series of results, this study is expected to be the 'Priming' for finding ways to move toward a more transparent society by diagnosing and reflecting on the thoughts of corruption in our society once again.

• Tunnel and Underground Space
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• v.32 no.6
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• pp.435-450
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• 2022

In step-by-step site selection for geological disposal of high-level radioactive waste, parameters necessary for site selection will be acquired through deep drilling surveys from the basic survey stage. Unlike site investigations of rock mass structures such as tunnels and underground oil storage facilities, those related to the geological disposal of high-level radioactive waste are not only conducted in relatively deep depths, but also require a high level of quality control. In this report, based on the 750 m depth drilling experience conducted to acquire the parameters necessary for deep geological disposal, the methodology for deep drilling and the geology, geophysics, geochemistry, hydrogeology and rock mechanics obtained before, during, and after deep drilling are discussed. The procedures for multidisciplinary geoscientific investigations were briefly described. Regarding in-situ stress, one of the key evaluation parameter in the field of rock engineering, foreign and domestic cases related to the geological disposal of high-level radioactive waste were presented, and variations with depth were presented, and matters to be considered or agonized in acquiring evaluation parameters were mentioned.

• Journal of the Korean GEO-environmental Society
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• v.22 no.12
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• pp.33-40
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• 2021

The deterioration of underground facilities, disturbance of the ground due to underground development activities, and changes in ground water can cause ground subsidence accidents in the urban areas. The investigation on the geotechnical and hydraulic factors affecting the ground subsidence accident is very significant to predict the ground subsidence risk in advance. In this study, an analysis DB was constructed through 3D ground modeling to utilize the currently operating geotechnical survey information DB and ground water behavior information for risk prediction. Additionally, using these results, the relationship between the actual ground subsidence occurrence history and ground conditions and ground water level changes was confirmed. Furthermore, the methodology used to visualize the risk of ground subsidence was presented by reconstructing the engineering characteristics of the soil presented according to the Unified Soil Classification System (USCS) in the existing geotechnical survey information into the internal erosion sensitivity of the soil, Based on the result, it was confirmed that the ground in the area where the ground subsidence occurred consists of more than 40% of sand (SM, SC, SP, SW) vulnerable to internal erosion. In addition, the effect of the occurrence frequency of ground subsidence due to the change in ground water level is also confirmed.

• Journal of Korean Society of Disaster and Security
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• v.15 no.3
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• pp.101-113
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• 2022

This study is planned with the aim of developing a systematic construction process based on the scientific and engineering theory of the water-sealing grouting construction applied to the tunnel excavation process during the construction of the downtown underground traffic network, so that the construction quality of the relatively backward domestic tunnel water-sealing grouting construction is improved and continuously maintained no matter who constructs it. The main contents of the improved tunnel water-sealing grouting can be largely examined in the classification of tunnel water-sealing grouting application and the definition of grouting materials, the correlation analysis of groundwater pressure conditions with groundwater inflow, the study of the characteristic factors of bedrock, and the element technologies and injection management techniques required for grouting construction. Looking at the trends in global research, research in the field of theoretical-based science and engineering grouting is actively progressing in Nordic countries (Sweden, Finland, Norway, etc.), Japan, Germany, and the United States. Therefore, in this study, the algorithm is established through theoretical analysis of the elements of tunnel water-sealing grouting construction techniques to provide an integrated solution including a construction process that can effectively construct tunnel water-sealing grouting construction.

• The Journal of Engineering Geology
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• v.33 no.1
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• pp.39-49
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• 2023

Soil contaminants measured and managed in Korea include those of geologic origin such as arsenic, cadmium, copper, lead, zinc, nickel, mercury, and fluoride. This study identifies the distribution of these contaminants using GIS modeling to analyze the spatial probability of soil contamination originating from geology. The modeling found that cadmium, copper, lead, nickel, and mercury often exceed the regulated standard by <1%. Concentrations of arsenic and zinc greatly exceeded the standard in the vicinity of mines and industrial complexes: mining and industry seemed to have substantial effects on the concentrations of these metals. Although fluoride was sampled at the lowest number of points, its frequency of exceeding the standard was the highest. No obvious source of artificial contamination has been identified, and fluoride's distribution characteristics showed continuity over a wide area, suggesting a strong correlation between geological characteristics and fluoride concentration. The highest frequencies of fluoride exceeding the standard were in Jurassic granite (40.00%) and Precambrian banded gneiss (34.12%). As these rocks contributed to the formation of soil through their weathering, high fluoride concentrations can be expected in soil in areas where these rocks are distributed.

• Tunnel and Underground Space
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• v.33 no.1
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• pp.29-41
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• 2023

The brittleness of rocks plays an important role in determining the fragmentation and failure behavior of rock. However, there is still no standard method to evaluate the brittleness of rock, and previous studies have suggested the several definitions for estimation of brittleness of rock. Even in the process of mechanical rock excavation and drilling, the brittleness of rock is considered as an important property for evaluating the excavation efficiency of mechanical excavators or boreability of rock. The previous studies have been carried out to investigate the correlation between different brittleness of rock and cutting efficiency and boreability of rock. This study introduced a method for calculating the brittleness of rock from punch penetration test, and analyzed the correlation between the brittleness of rock calculated by the uniaxial compressive and Brazilian tensile strengths and that from punch penetration test. From the results of correlation analysis, the relationship between various brittleness was confirmed, and it was found that PSI and BI₃ showed a good correlation with the strength-based brittleness index. In addition, the results indicated that B₃ and B₄ are suitable to represent the brittleness of rock in the field of mechanical rock excavation.