• Title/Summary/Keyword: 퇴화 현상

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화산동굴의 용암석회질화 현상 고찰(제주도 북제주군 협제리 건지굴 중심)

  • 소대화;배두안
    • Proceedings of the Speleological Society Conference
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    • 2004.11a
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    • pp.25-32
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    • 2004
  • 본 논문은 북제주군 협제리 해안가 근처에 소재한 건지굴을 대상으로 화산지역의 용암동굴에서 특이하게 진행되고 있는 용암석회질화 현상에 대하여 동굴내부와 주변 상황에 근거한 분석과 고찰을 통하여 석회질화의 발생 원인을 규명하는데 기여하고자 하였으며, 특히 동굴내부의 생태계와 연관된 분석을 병행 시도하였다. 용암동굴(화산동굴)은 생성이후 퇴화한다. 그러나 용암동굴에서 용암석회질화(lava-calcification) 현상이 발생하면 용암의 기공과 균열부분 또는 용암석간의 틈새에 석회질 성분이 지하수에 녹아 침투하여 고화되면서 구조적 보강효과가 발생하여 견고하게 진행된다. 이러한 현상은 마치 콘크리트 건축구조물에서 구조재료들을 물리적으로 연결하여 결합시키는 시멘트의 역할과 같으며, 따라서 용암동굴의 경우, 동굴이 형성된 이후에 전반적으로 퇴화가 진행된다고 알려진 일반적 경향에 반하여 용암석회질화 현상에 의해 오히려 구조적 보강현상이 이루어지고, 용암석회질화 현상이 진행될수록 용암동굴의 일반적 경향으로 나타나는 동굴퇴화현상 보다는 구조적 견고함의 진행성을 나타내는 특이현상을 갖는다. 이와 같은 진행성 용암석회질화 현상이 북제주군 협제리에 소재한 건지굴에서 진행되고 있음이 국내에서 최초로 확인되었다.

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Maximum likelihood estimation for a mixture distribution (이항-퇴화 혼합분포의 최우추정법)

  • Hwang, Seonyeong;Sohn, Seung Hye;Oh, Changhyuck
    • Journal of the Korean Data and Information Science Society
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    • v.26 no.2
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    • pp.313-322
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    • 2015
  • A mixture distribution of a discrete uniform or degenerated distribution and two binomial distribution is proposed and a method of obtaining the maximum likelihood estimates of the parameters is provided. For the proposed model simulation studies were conducted to see performance of the maximum likelihood estimates and a mixture of a degenerated distribution and two binomial distributions was applied to fit a lecture evaluation data to show a good result.

The Effects of Polymer Degradation on the Drag Reduction in CWM Transport (CWM 관수송의 저항 감소현상에 있어서 고분자첨가제의 퇴화 영향에 관한 연구)

  • 송창환;김종보;김인석;최형진
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.10
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    • pp.1908-1914
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    • 1992
  • A significant drag reduction in the turbulent flow of CWM(coal Water Mixture) adding minute amounts of high molecular weight polymer additives has been obtained and it was compared with pure CWM.However, the rate of drag reduction could come down with flow time, which is caused by polymer degradation, The rate of drag reduction and polymer degradation is affected by polymer type, concentration, molecular weight, and flow velocity. In the present investigation, these important parameters were evaluated for their influences on polymer degradation in order to find out stable conditions for CWM transportation with time. It was necessary to determine the more effective type of polymer additives to guarantee the optimum conditions for CWM transport. Experiments were undertaken with a test section of pipe diameter 9.8mm and pipe length 3500mm(L/D=357) in a closed loop, and polyacrylamide and polyetylene oxide were utilized as polymer additives. The tests were carried out under the conditions of 200, 400, 700ppm of polymer concentrations. CWM concentrations utilized were 5% and 10% with flow velocities of 4.9m/s and 6.1m/s. Experimental data show that polyehylene oxide degraded faster than polyacrylamide in CWM transport, and polyacryamide is considered to be a more effective candidate as additive for long time-CWM transport. Polymer degradation is also found to be more likely at lower polymer concentrations, at higher flow velocities, and higher CWM concentrations.

Analysis of Degradation Products in Madder Dyed Fabrics in Selective Degradation Conditions (퇴화조건에 따른 꼭두서니 염색물의 퇴화물 연구)

  • Ahn, Cheun-Soon;Obendorf, S.-Kay
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.12 s.148
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    • pp.1608-1618
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    • 2005
  • The purpose of this investigation was to investigate the degradation products of the dye component extracted from madder dyed fabrics using the GC-MS analysis and to evaluate the change of color due to degradation treatment. Four different degradation protocols were used in this study,; refrigeration at $7^{\circ}C$ (LT), room temperature (RT), oven treatment at $100^{\circ}C$ (OV), and $H_2O_2/UV(PER)$ method. Degradation times for each thermal system were 6 hour, 24 hour, 48 hour, 1 week, 2 week, 4 week. Alizarin was detected from the control and degraded samples of both alizarin dyed and madder dyed fabrics. Benzoic acid, 2, 4-di-tert-butylphenol, phthalic anhydride were detected as the degradation products for both alizarin dyed and madder dyed fabrics. The result suggest that these products can be used as the fingerprints of GC-MS analysis for the identification of madder dye in archaeological textiles. Both alizarin dyed and madder dyed samples became less red and less yellow after degradation. In the PER degradation system madder dyed sample showed the greatest color difference even after 1 week of degradation treatment. Further research is necessary for investigating the color change in the exhumed textiles, which is caused by the dual action of dye fading and the staining of organic matters in the soil.

Lava-calcification of the volcanic cave in Jeju-do island (제주도 화산동굴의 용암석회질화 -제주도 북제주군 협재리 건지굴 중심-)

  • Soh, Dea-Wha
    • Journal of the Speleological Society of Korea
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    • no.67
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    • pp.1-9
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    • 2005
  • The lava-calcification which was found in Geunjisul located in Jeju-do (Korea) was investigated to analyse the cause of calcification through the internal factor of cave structure and surroundings in company with relevant ecological system. The volcanic cave is degenerated after formation from volcano lava extravasation, however, the cave became more stronger with solidification and petrification by the reinforced structure of calcification as the cement in concrete buildings unprecedentedly if the lava-calcification occurred in the cave. Such a Progressive Phenomena of lava-calcification was verified in progress first in Geonjigul located at Hyubjae-ri, but those would be found in other simiiar case of caves distributed and connected with seaside of shelly sand beach.

A 9-node Degenerated Shell Element for Inelastic Analysis of Reinforced Concrete Structures (철근 콘크리트 구조물의 비탄성 해석을 위한 9절점 퇴화 쉘 요소)

  • 이상진;서정문
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.14 no.4
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    • pp.481-494
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    • 2001
  • An enhanced degenerated shell finite element (FE), which has been developed for inelastic analysis of reinforced concrete structures is described in this paper. Generally, Reissner-Mindlin (RM) assumptions are adopted to develop the degenerated shell FE so that transverse shear deformation effects is considered. However, it is found that there are serious defects such as locking phenomena in RM degenerated shell FE since the stiffness matrix has been overestimated in some situations. As remedies of locking phenomena, reduced integration, incompatible mode and assumed strain method have been used. Especially, the assumed strain method has been successfully used in many FEs. But contrarily, there is a few investigation on the performance of the assumed strains in the inelastic analysis of concrete structures. Therefore, shell formulation is provided in this paper with emphasis on the terms related to the stiffness matrix based on assumed strain method and microscopic concrete material model. Finally, the performance of the present shell element is tested and demonstrated with several numerical examples. From the numerical tests, the present result shows a good agreement with experimental data or other numerical results.

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A Study on the Photo-Degradation Properties of the Spiropyran Using THz-TDS (테라헤르츠 시간 영역 분광법을 이용한 스피로파이란의 광 퇴화 특성 연구)

  • Bang, Jin-Hyuk;Park, Myoung-Hwan;Ryu, Han-Cheol
    • Journal of the Korean Chemical Society
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    • v.60 no.1
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    • pp.28-33
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    • 2016
  • The spiropyran is a typical material having photodegradation properties in the process of photochromism. The spiropyran has been utilized in various applications such as optical switch, optical memories, and biosensor because of its remarkable stability, fast responsive time, stronger color change, and photo-induced controllability. However, the spriropyran is photodegraded by the repetitive optical irradiation. The photodegradation of spiropyran have been investigated by using UV-Visible spectroscopy, nuclear magnetic resonance (NMR), and Raman spectroscopy. Herein, the properties of spiropyran were characterized by using terahertz time-domain spectroscopy (THz-TDS) in the terahertz frequency region. In terahertz region, the measured absorbance of spiropyran was increased due to the photodegradation induced by the repetitive UV irradiation. The absorbance tendency of spiropyran in the terahertz frequency region was compared with that in the visible region, and they were completely opposite to each other.

A Study on the Degradation of Polymer-Coated Stesl in 0.5M NaCl Solution (0.5M NaCl 용액내에서 일어나는 고분자재료로 피복된 강의 퇴화에 관한 연구)

  • Byeon, Su-Il;Jeong, In-Jo;Mun, Seong-Mo;An, Sang-Ho
    • Korean Journal of Materials Research
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    • v.6 no.10
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    • pp.1025-1033
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    • 1996
  • 본 연구에서는 0.5M NaCI 용액내에서 일어나는 고분자재료로 피복된 강의 퇴화현상을 광학현미경 관찰 및 A.C. impedance spectroscopy를 이용하여 연구하였다. 강의 부식은 고분자재료로 피복된 강의 경우 국부부식(localized corrosion)의 형태로 나타난 반면, 피복되지 않은 강의 경우에는 전면부식(uniform corrosion)의 형태로 진행되었다. 고분자재료로 피복된 강의 부식이 국부적으로 진행되는 것은 피복층내에 존재하는 기공이나 크랙과 같은 결함 등에서 부식이 선택적으로 일어나기 때문으로 사료된다. 피복층의 박리(delamination) 현상은 고분자재료로 피복된 강/구리 갈바닉쌍(galvanic couple)의 경우 구리표면 위의 피복층에서만 관찰되었다. 이는 캐소드(cathode)로 작용하는 구리의표면에서 산소의 환원반응에 의해서 형성된 수산화이온(OH-)이 피복층의 박리를 조장하고 있음을 보여준다. 또한, 고분자재료 피복층의 파손 현상은 고분자재료/강의계면에서 석출된 부식생성물에 의해서 크게 조장되고 있음을 알 수 있다.

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A Study on the Nonlinear Analysis of Containment Building in Korea Standard Nuclear Power Plant (한국형 원전 격납건물의 비선형해석에 관한 연구)

  • Lee, Hong-Pyo;Choun, Young-Sun;Lee, Sang-Jin
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.20 no.3
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    • pp.353-364
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    • 2007
  • In this paper, a nonlinear finite element analysis program NUCAS, which has been developed for assessment of ultimate pressure capacity and failure mode for nuclear containment building is described. Degenerated shell element with assumed strain method and low-order solid element with enhanced assumed strain method is adapted to microscopic material and elasto-plastic material model, respectively. Finally, the performance of the developed program is tested and demonstrated with several examples. From the numerical tests, the present results show a good agreement with experimental data or other numerical results.