• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2001.09a
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• pp.180-183
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• 2001

오염물 이동에 영향을 미치는 지연계수는 용질과 시료의 흡착특성을 나타낸다. 흡착특성을 표현하는 데에는 Freundlich등온식, Langmuir등온식 또는 선형등온식등을 사용할 수 있는 데, 본 연구에서는 상관계수를 이용하여 각등온식의 적용성을 평가하고 용질이동 수치해 석을 하여 농도가 10ppm 이하로 낮을 경우의 용질이동정도를 상호 비교하였다. 아연, 크롬, 납에 대한 등온식의 상관계수에 따른 적용성 평가결과 Freundlich 등온식이 보편적으로 적용 가능한 것으로 나타났고, 수치해석 결과 농도가 10ppm 이하일 경우는 용질이동성이 동일하게 나타났다.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.09a
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• pp.248-251
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• 2004

일반적으로 유기오염 물질의 경우 sequestration 또는 aging 현상에 의해 탈착저항성을 띠게 되는 것으로 알려져 있다. 그러나 중금속의 경우 흡/탈착반응은 탈착저항성이 없는 가역적 반응이라는 보고가 있는 반면 홉/탈착 반응은 비가역적이며 탈착저항성이 존재한다는 보고도 있다. 본 연구에서는 해양 연안 퇴적물에 대한 납의 흡/탈착 실험을 통하여 탈착 저항성을 화인하고 연속추출 실험을 수행함으로써 탈착 저항성 부분의 크기를 규명하고자 하였다. 그리고 각기 다른 pH(4, 6)에서 흡착 실험을 수행함으로써 pH에 따른 흡착친화도를 규명하였다. 그 결과 퇴적물에 대한 납의 흡착량은 높은 pH(6)에서 더 많았고, 각 pH 범위에서 납은 탈착저항성을 가지는 것으로 나타났으며, 연속추출결과 Organic Material bound부분에 66% 정도가 흡착되어 있음을 알 수 있었다.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1996.11a
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• pp.97-101
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• 1996

산림부산물인 수피에 의한 카드뮴 이온의 선택적 흡착 현상을 이용하여 인공폐수로부터 카드뮴이온의 제거를 시도하였다. 카드뮴 이온 선택성이 우수한 소나무와 상수리 나무의 수피를 이용한 효율적인 연속식 대량 수처리 시스템의 개발을 위한 기초 실험으로 카드뮴 이온흡착 등온선을 조사하였고, batch stirred reactor, airlift reactor, packed bed column 등 여러 접촉시스템에서의 카드뮴 이온의 제거 효율을 검토하였다. 카드뮴 흡착등온선은 두 수피 모두 Langmuir 형식으로 나타났으며 소나무 수피의 최대흡착용량은 약 7 mg/g, 상수리나무 수피의 경우에는 약 8 mg/g 정도로 나타났다. Batch stirred reactor를 이용한 시스템에서 초기농도 13 ppm의 카드뮴용액 100 $m\ell$ 을 수피 10 g 과 접촉시킨 결과 30분 이내에 95% 이상 제거되는 효율성을 보여주었다. Airlift reactor를 이용한 시스템에서는 수피 30 g 을 포기농도 10 ppm 카드뮴 용액 1 liter와 접촉시킨 결과 15분 이내에 93 % 이상 제거되었으며 4 cycle 반복 운전에서도 거의 같은 성능을 유지하였고 그 이상의 cycle에서는 점점 성능이 떨어짐을 보여주었다. Packed bed column을 이용한 시스템에서는 20 g의 수피를 충전시켰을 경우 초기농도 20 ppm에서 effluent 2.5 liter 까지는 95% 정도의 제거효율을 보여주었다.

• Korean Journal of Soil Science and Fertilizer
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• v.19 no.2
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• pp.115-121
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• 1986

This experiment was conducted to examined the effects of the physico-chemical and mineral-logical properties of paddy soil on the desorption of $Cs^{137}$ from radionuclide, $Cs^{137}$ absorbed soils. 1. Adsorption of $Cs^{137}$ by paddy soil was very much and exchangeable fraction of $Cs^{137}$ extracted by ammonium acetate was very high compared to the water soluble fraction. Exchangeable fraction of $Cs^{137}$ in paddy soil decreased with the increase of potassium application and increased proportionally with the increase of $Cs^{137}$ treatment. 2. The distribution of several forms of $Cs^{137}$ in soils depend on the soil type. Average-distribution rates of water soluble, exchangeable and non-exchangeable fractions of $Cs^{137}$ in soils were 5.9%, 17.1% and 77.0%, respectively. 3. The desorption of $Cs^{137}$ from adsorbed soils decreased with increase of pH and exchangeable cations of the soils, but it increased as organic matter and clay content increase in soil. 4. Non-exchangeable adsorption of $Cs^{137}$ was high in the soils of which both Illite and Vermiculite were dominant.

• Korean Journal of Agricultural and Forest Meteorology
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• v.2 no.4
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• pp.190-197
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• 2000

Anions such as C $l^{[-10]}$ , N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$, P $O_4$$^{3-}$, and organic anions, that do not become a part of the clay mineral crystal lattice, are of considerable interest in soils which are a potential sink caused by acid rain. In this paper, elution of native sulfate and breakthrough curves (BTC) were obtained from miscible displacement of non-specifically or specifically adsorbed anions through non-saturated or saturated Bt soil of Chungwon series. The shape and position of the BTC's could be affected by adsoprtion and ion exchange onto the soil particle surfaces. Measured BTC's for oxalic acid under unsaturated and saturated conditions showed that less pore volumes were required to displace the native S $O_4$$^{2-}$S from the soil column, and that maximum detection limit of oxalic acid reached earlier than under unsaturated. The retarded BTC's to the righthand side could be attributed by different adsorption behavior of each anion, although BTC's may be influenced by the smaller order of velocity change. The alternate breakthrough and elution curves show the rapid approach to the maximum detection limit of C/Co = 1, compared to progressive tailing of elution curve to reach to C/Co = 0. The probable explanation for asymmetric elution patterns for both anion is that the anion was selectively adsorbed on the positively charged soil surface from the solution passing in the soil column. On the other hand, the variations of pH in effluent showed that pH was increased to 7 in the first 6 pore volume and then gradually decreased to pH 4.

• Journal of Soil and Groundwater Environment
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• v.6 no.2
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• pp.3-13
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• 2001

It has been known that nonlinear characteristics of sorption affect the transport behavior of water soluble pollutants in soils. However detailed experimental studies have not been performed to verify the effect of non-linearity of adsorption isotherm on transport of chemicals in porous media. In this research, the distortion of breakthrough curves of a cationic surfactant (cetylpyridinium chloride, CPC) in a engineered stainless steel column packed with glass beads were investigated. Glass beads with about 110 $\mu\textrm{m}$diameter coated with a thin n-decane film were used as the media providing the sorption surface for CPC. The CPC adsorption isotherm on the surface of n-decane from aqueous solution was a typical Langmuir type. The breakthrough curve of CPC using step Input showed a late breakthrough on the front side and early breakthrough on the back side accordance to the shape of the isotherm. The retardation factor of CPC was found to be a strong function of the input concentration, which also a manifestation of the non-linearity of the isotherm. The retardation factors for the CPC with step input agreed with those of pulse input that the maximum concentrations are controlled to be the same as the step input concentrations. This results support the validity of the unproven field practices of using hydrogeotracers with non-linear adsorption isotherms to determine the hydrogeological parameters, e.g., NAPL saturation, air-water or NAPL-water interfacial areas.

• Journal of the Korean Society of Groundwater Environment
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• v.4 no.2
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• pp.78-84
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• 1997

Batch and column tests were performed to investigate the sorption capacity of bottom soils of Kimpo metropolitan waste landfill. Sorption capacity and sorption isotherm from the batch test for inorganic and heavy metal substances and retardation capacity of heavy metals from the column test are obtained. It was recognized from the tests that the samples match well with Freundlich isotherm and marine clay has good sorption capacity for potassium and heavy metals such as lead and cadmium. The soil samples with different geologic origins did not show significant differences in the sorption capacity of tested components.

• Korean Journal of Environmental Agriculture
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• v.21 no.4
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• pp.286-290
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• 2002

This work has been conducted to investigate the behavior of pesticides in ginseng(Panax ginseng C. A. Meyer) cultivation environment, with a fungicide procymidone as a model pesticide. Procymidone adsorption on ginseng cultivating soil was studied and persistency of procymidone in soil was monitored in indoor incubation experiments at 25$^{\circ}C$ and 10$^{\circ}C$. The soil adsorption coefficients($K_{oc}$) of procymidone were in the range of 513$\sim$743 suggesting the mobility of procymidone in soil is relatively low. Procymidone showed higher persistency in soil under indoor incubation condition than outdoor field condition. The half lives estimated from the first order reaction kinetics were 248 days and 330 days at 25$^{\circ}C$ and 10$^{\circ}C$, respectively.

• Korean Journal of Soil Science and Fertilizer
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• v.21 no.4
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• pp.380-385
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• 1988

The urease adsorption on zeolite and the various properties of adsorbed urease were investigated to find out the influence of zeolite on activity and properies of urease. Free urease in solution was adsorbed on zeolite untill the max. adsorption, and the amount of max. adsorption was 11.3mg urease/100mg zeolite at pH 7.0. It is apparent that free urease was adsorbed on the outer surface of zeolite by cation exchange reaction, and more than 70% of urease adsorption was adsorbed within 30 min. The activity of adsorbed urease was decreased by 89.6%, whereas Km value was increased to 34.4mM, which is higher than that of free urease. The optimum pH of adsorbed urease was widened 6.5 to 7.0, compared to that of free urease 7.0. The resistance of urease to protease became weaker by adsorption, however substrate specificity and thermal stability were not affected.

• Korean Journal of Environmental Agriculture
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• v.20 no.3
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• pp.162-168
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• 2001

This study was conducted to evaluate the degradation, adsorption and desorption and leaching of acetamiprid in soils. The half-life of acetamiprid in field condition was $1.7{\sim}3.3$ days in Bokhyun soil and, in case of laboratory condition, 15.5 days. Adsorption of acetamiprid was equilibrated in 12 hours incubation. In adsorption experiment using modified soils, such as oxidized soil, oxidized soil added humic acid, fulvic acid, kaolinite or montmorillinite, adsorption rate of acetamiprid was the highest in the oxidized soil added fulvic acid. The desorption rate was the lowest in the oxidized soil added fulvic acid. The adsorption and desorption results should be suggested that acetamiprid could be strongly adsorbed with soil humic materials, especially fulvic acid. When the mobility of acetamiprid in soil was calculated according to GUS (Groundwater Ubiquity Score) equation, it was prove to non-leacher, and it was confirmed in the leaching experiment with soil column. Most of acetamiprid was remained in the upper 30 cm of the soil column after eluting with water and it was not even detected in leachate.