• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.362-365
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• 2002

토양의 물리/화학적 특성에 따른 토양의 유기오염물 흡착능 변화를 규명하기 위하여, 토양 내 clay 함량 및 유기물 함량변화, 수용액 내 TCE 농도변화에 따른 TCE 의 토양내 흡착량 변화를 측정하였다. 수용액의 pH와 실내온도는 일정하게 유지시켰으며 clay는 표면적이 다른 Ca-montmorillonite, Na-montmorillonite, kaolin을 이용하였고, 유기물질로는 활성탄을 사용하였다. 일정한 토양성분과 실제토양에 대해 수용액 내 TCE의 농도를 변화시켜 농도변화에 따른 흡착량 변화를 측정하였다. 실험결과 유기물과 점토함량의 증가에 따라 흡착량은 모두 증가하였으나 활성탄에 의한 TCE 흡착량이 점토에 비해 매우 높았으므로 유기물에 의한 TCE 흡착영향이 점토에 의한 흡착 영향보다 큰 것으로 나타났다. TCE 농도변화에 따른 흡착결과는 실제토양과 모사토양에서 모두 농도가 증가함에 따라 흡착 증가율이 증가하다가 감소하는 Langmuir isotherm 형태를 보여 주었다.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.09a
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• pp.338-341
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• 2003

유기염소계 농약 중 대표적인 살충제 $\delta$-BHC(hexachlorocyclohexane)와 1, 2-DCB (1, 2-dichlorobenzene)에 대한 논, 밭 토양 및 풍화 토에 흡착 배치실험을 통하여 토양 특성과 유기오염물간의 흡착 관계를 규명하였다. 13개의 토양시료에 대하여 pH, CEC, 유기물 함량, 비표면적, 입도분석, 원소조성분석을 통하여 토양의 물리ㆍ화학적 특징이 토양 흡착에 미치는 영향을 규명하고자 하였다. 유기염소계 농약의 흡착량을 Freundlich isotherm으로 나타내어 흡착분배계수(K$_{d}$)를 산출하였다. $\delta$-BHC는 유기물 함량이 높은 soil-4$_{d}$에서 가장 높은 $K_{d}$ 값을 보였으며, 1,2-DCB의 경우 CEC, 비표면적이 가장 낮은 soil-5에서 낮은 $K_{d}$ 값을 보여 토양 내 유기물 함량과 비표면적이 유기오염물 흡착량에 중요한 요소로 작용함을 알 수 있었다.

• Journal of Korea Soil Environment Society
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• v.1 no.1
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• pp.81-88
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• 1996

To study the Cd adsorption in the presence of competing ions in soil-solution interphase, three soil samples from the Bt horizon were taken and analyzed for their physical and chemical properties. Adsorption of ethylene glycol monoethyl ether(EGME) and N, were determined to establish the specific surface area of the soils. We attempted to establish a qeneralizing competitive sorption isotherms for soils of entirely different composition of the solid phase, resulting in the routine use as a guidelines for the fate of reactive solute in soil profiles. Many physicochemical factors including competitive adsorption bettween solutes will affect the general adsorption phenomena as shown in a single not only on the soil:solution ratio used, but also on the surface areas of its respective soil samples. This phenomenon was attributed to competition Cd for sorption sites with Mg by different soil constituents. These adsorption isotherms are able to use as examples to demonstrate that this phenomenon can complicate the development of a standardized batch adsorption procedure as well as interpreting fate and adsorption of toxic inorganic compounds.

• Magazine of the Korean Society of Agricultural Engineers
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• v.37 no.2
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• pp.41-52
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• 1995

혼합상태에서 유기화합물들이 토양에 흡착하는 성질에 관해서 5개의 유기화합물(페놀,2,4-디크로로페놀, 2,4,6-트리크로로페놀, 부루신, 따이오유리아)과 2종류의 토양을 이용하여 연구하였다. 일반적으로 따이오유리아를 제외하고는 한가지 물질이 혼합상태에 있는 다른물질이에 의 흡착력이에 제약을 받아서 단독으로 있을때 보다 흡착율이 낮았다. 따이오유리아는 단독인 경우보다 혼합상태일 때 더 많은 흡착을 보였는데 이는 혼합상태에서 오히려 흡착이 증가할수도 있음을 나타낸다. 혼합이 흡착에 비치는 영향은 페놀의 혼합상태와 단독상태에서의 흡착상태를 여러가지 형태로 비교하여 검토하였는데 산성이고 유기물질이 많은 토양보다 혼합으로 인한 흡착의 억제 효과가 뚜렷하였다.

• Journal of the Korean GEO-environmental Society
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• v.2 no.1
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• pp.103-114
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• 2001

Sorption studies were conducted to determine if slow sorption fraction is observed in recent1y deposited organic matter by studying wetland soils explicitly. Sorption characteristics of hydrophobic organic compounds (chlorobenzene and phenanthrene) in recently deposited freshwater marsh soils were determined using a batch sorption procedure. Relative indicators of organic matter age were assessed using several techniques including the ratio of elemental oxygen to carbon in the organic matter. Slow sorption characteristics for both surface marsh soil (top 0-2 cm, <5 years old) and deeper marsh soil (below 10-cm, >20 years old) were compared against relatively older PPI (Petro Processors, Inc. Superfund site) and BM (Bayou Manchac) soils to investigate whether soil age can cause differences in sorption of organic compounds in wetland soils. Increases in sorption non-linearity of slow sorption model parameters (increase in KF and decrease in N) explain the existence of slow sorption fraction. The results of slow sorption model indicates the presence of a sizable slow sorption fraction; 25.4 - 26.3% (chlorobenzene) and 1.4 - 1.9% (phenanthrene) of the sorbed mass in wetland soils and 40.0 - 55.93% (chlorobenzene) and 2.9 - 3.19% (phenanthrene) of the sorbed mass in PPI and BM soils, respectively. The slow sorption fraction increased in the order of surface < deeper < PPI < BM soil indicating that size of the slow sorption fraction increases with soil organic matter age.

• Korean Journal of Environmental Agriculture
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• v.9 no.2
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• pp.105-111
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• 1990

The soil adsorption coefficient of butachlor was measured mainly following the guidelines of U. S. EPA and OECD. The soil adsorption coefficient, Koc, of butachlor agreed well with the values in the literature. It was observed that soil adsorption differed about 5% with an increase or decrease by $15^{\circ}C$, implying that temperature does affect soil adsorption. The estimated value of the soil adsorption coefficient using water solubility and molecular structure deviated by factors of 2 and 20, respectively. The soil adsorption coefficient, Koc, of butachlor was 543 so this value means that butachlor is tightly bound to organic matter in soil and is considered immobile. A novel trial estimating the soil adsorption coefficient by molecular structure might be utilized to design efficient and/or non-polluting agrochemicals by organic chemists.

• Korean Journal of Soil Science and Fertilizer
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• v.37 no.6
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• pp.371-377
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• 2004

Sulfate adsorption in forest soils is a process of sulfur dynamics playing an important role in plant uptake, cation movement, acid neutralization capacity and so on. The relationship between sulfate adsorption and some physicochemical properties of four forest soils was investigated. Extractable sulfate contents and sulfate adsorption capacity (SAC) in the forest soils varied much among study sites. Extractable sulfate contents were more in sub-surface soils with lower organic matter and greater Al and Fe oxides than in surface soils. The average contents of $Al_d$ and $Fe_d$ in the sub-surface soils were 8.49 and $12.45g\;kg^{-1}$, respectively. Soil pH, cation exchange capacity and clay content were positively correlated with the extractable sulfate contents and SAC. Organic carbon content, however, was negatively correlated with the extractable sulfate contents, implying the competitive adsorption of sulfate with soil organic matter. Considerably significant correlation was found between inorganic + amorphous Al and Fe oxides and the sulfate adsorption, but crystalline Al and other fractions of Fe oxide showed no correlation. Relatively close relationship between the adsorbed sulfates and soil pH, cation exchange capacity, or amorphous Al oxides indicates that the accelerated soil acidification may substantially reduce the potential for sulfate adsorption contributing to sulfur flux in forest ecosystems.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2006.04a
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• pp.162-165
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• 2006

유해성 유기물질로 오염된 토양의 복원을 위한 토양세척공정에서 계면활성제를 선택적으로 재이용하기 위해 활성탄을 이용한 흡착 칼럼의 성능을 평가하였다. 계면활성제로는 Triton X-100을 소수성 유해 유기물질로는 다환방향족 탄화수소의 하나인 phenanthrene를 사용하여 그 성능을 평가하였다. 계면활성제의 흡착은 phenartthrene에 비해 빠른 흡착 특성을 보였으며 phenanthrene은 계면활성제의 포화흡착상태에서도 지속적으로 흡착이 이루어졌다. 이는 계면활성제의 흡착이 종료된 이후에도 유해성 유기물질의 지속적인 흡착을 기대할 수 있어 계면활성제의 지속적인 재이용과 활성탄 사용시간의 증대를 가져올 수 있음을 의미한다. 이와 같은 활성탄 칼럼에서의 유해성 유기물질의 우수한 선택적 흡착 결과는 기본적으로 소수성 정도의 차이와 size exclusion에 의한 기작뿐만 아니라 활성탄에 흡착된 계면활성제에 의한 다환방향족 탄화수소의 추가적인 흡착이 일어나 전체적인 성능이 향상되는 것에 기인한다.

• Korean Journal of Soil Science and Fertilizer
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• v.29 no.2
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• pp.86-91
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• 1996

Water vapor adsorption isotherms were measured for samples of the A horizons of five typical Korean soils. The experimental data were fitted to the BET and Aranovich adsorption equations. The adsorption isotherms studied followed the BET equation for the relative water vapor pressures in 0.03-0.33 range and the Aranovich equation in 0.03-0.6 range. The calculated surface areas were higher for Aranovich than for BET and opposite relations were found for adsorption energies. For the description of the water adsorption on soils, the use of the Aranovich theory is recommended.

• Korean Journal of Soil Science and Fertilizer
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• v.8 no.1
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• pp.1-17
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• 1975

Laboratory experiments on the phosphorus adsorption by soil were conducted to evaluate the parameters for determination of phosphorus adsorption capacity of soil, which serve as a basis for establishing the amount of phosphorus required to improve newly reclaimed soil and volcanic ash soil. The calculated Langmuir adsorption maxima varied from 6.2-32.9, 74.7-90.4 and 720-915mg p/100g soil for cultivated soils, non-cultivated soils, and volcanic ash soils respectively. The phosphorus absorption coefficient ranged from 116-179, 161-259 and 1,098-1,205mg p/100g soil for cultivated soils, non-cultivated soils, and volcanic ash soils respectively. The ratio of the phosphorus absorption coefficient to Langmuir adsorption maximum was low in soils of high phosphorus adsorption capacity (1.3-1.5) and high in soils of low phosphorus adsorption capacity (2.2-18.7). Changes in the amount of phosphurus adsorption induced by liming and preaddition of phosphorus were hadly detected by the phosphorus absorption coefficient, which is measured using a test solution with a relatively high phosphorus concentration. The Langmuir adsorption maximum was a more sensitive index of the phosphorus adsorption capacity. The Langmuir adsorption maxima of the non-cultivated soils, which were treated with an amount of calcium hydroxide equivalent to the exchangeable Al and incubated ($25-30^{\circ}C$) for 40 days at field capacity, were lower than the original soils. The change in the adorption maximum on incubation following the liming of soils was insignificant for other soils. The secondary adsorption maximum of soils, which received phosphorus equivalent to the Langmuir adsorption maximum of the limed soils incubated ($25-30^{\circ}C$) for 50 days at held capacity, was 74.5, 5.6 and 23.8% of the primary adsorption maximum for volcanic ash soils, non-cultivated soils, and cultivated soils respectively. The amount of phosphorus adsorbed by soils increased quadratically with the concentration of phosphorus solution added to the soils. The amount of phosphorus adsorbed by 5-g soil samples from 100ml of 100- and 1,000mg p/l solution for the mineral soils and volcanic ash soils respectively was found to be close to the Langmuir adsorption maximum. The amount of the phosphorus adsorbed at these concentrations is defined as a saturation adsorption maximum and proposed as a new parameter for the phosphorus adsorption capacity of the soil. The evaluation of the phosphorus adsorption capacity by the saturation adsorption maximum is regarded as a more practical method in that it obviates the need for the various concentrations used for the determination of the Langmuir adsorption maximum.