Kim, Kwon-Rae;Ryu, Hyung-Ju;Chung, Jong-Bae;Kim, Kye-Hoon
Applied Biological Chemistry
/
v.44
no.2
/
pp.103-108
/
2001
The objectives of this study were to investigate the contamination of the soils around the major roadsides in Seoul and to accumulate base-line data. Fifty topsoils ($0{\sim}5$ cm) and 48 subsoils ($20{\sim}50$ cm) were collected from 50 sampling sites near Manguro in Chungnanggu. The samples were air-dried, passed through 2-mm sieves, and analyzed to determine the physicochemical properties and the contents of heavy metals (Cd, Cu, Pb, Zn) and anions (Cl, $NO_3$, $SO_4$). Soil textures of top- and subsoils were mainly loamy sand and sandy loam, respectively. Average $_PH$ of top- and subsoil was approximately 7.5, much higher than that of the forest soils in Seoul. Average heavy metal contents were lower than the levels allowed by the Soil Environment Conservation Act of Korea, whereas much higher than those of the forest soils. Contents of some heavy metals were higher than the maximum allowed levels. Anion concentrations were also much higher than those of the forest soils. A careful management to prevent the aggravation of the present contamination level and the diffusion of contaminants is recommended.
Laser induced breakdown spectroscopy(LIBS) is an simple analysis method for directly quantifying many kinds of soil micro-elements on site using a small size of laser without pre-treatment at any property of materials(solid, liquid and gas). The purpose of this study were to find an optimum condition of the LIBS measurement including wavelengths for quantifying soil elements, to relate spectral properties to the concentration of soil elements using LIBS as a simultaneous un-breakdown quantitative analysis technology, which can be applied for the safety assessment of agricultural products and precision agriculture, and to compare the results with a standardized chemical analysis method. Soil samples classified as fine-silty, mixed, thermic Typic Hapludalf(Memphis series) from grassland and uplands in Tennessee, USA were collected, crushed, and prepared for further analysis or LIBS measurement. The samples were measured using LIBS ranged from 200 to 600 nm(0.03 nm interval) with a Nd:YAG laser at 532 nm, with a beam energy of 25 mJ per pulse, a pulse width of 5 ns, and a repetition rate of 10 Hz. The optimum wavelength(${\lambda}nm$) of LIBS for estimating soil and plant elements were 308.2 nm for Al, 428.3 nm for Ca, 247.8 nm for T-C, 438.3 nm for Fe, 766.5 nm for K, 85.2 nm for Mg, 330.2 nm for Na, 213.6 nm for P, 180.7 nm for S, 288.2 nm for Si, and 351.9 nm for Ti, respectively. Coefficients of determination($r^2$) of calibration curve using standard reference soil samples for each element from LIBS measurement were ranged from 0.863 to 0.977. In comparison with ICP-AES(Inductively coupled plasma atomic emission spectroscopy) measurement, measurement error in terms of relative standard error were calculated. Silicon dioxide(SiO2) concentration estimated from two methods showed good agreement with -3.5% of relative standard error. The relative standard errors for the other elements were high. It implies that the prediction accuracy is low which might be caused by matrix effect such as particle size and constituent of soils. It is necessary to enhance the measurement and prediction accuracy of LIBS by improving pretreatment process, standard reference soil samples, and measurement method for a reliable quantification method.
Due to relatively high permittivity of water in soils, we placed the soil condenser into soils to measure the soil moisture content. The soil condenser was made with two insulated iron sticks. The capacitance of the soil condenser was determined by the pulse period from RC type oscillation circuit and the highest voltage output accepting 10MHz pulse. After zero point adjustment, the measured relative capacitance percentage (RCS) to the standard condenser obtained by the oscillation circuit almost linearly correlated with the end depth of the sensor submerged in water. The RC type oscillation was disturbed by many sensor installed in a close distance in one place, presumably resulting in that the sensor sticks played as a interfering antennas generating or accepting electron waves from them. The temperature dependance of the output from the sensors could be corrected through experimentally determined revision function. Although lineal correlation was found between soil moisture and RCS, users should derive their own correlation function for every sensor to measure soil moisture, because the outputs were influenced by the installation depth and layout in the soil. The voltage type sensor responded inversely with soil moisture content and so was not suitable to the accurate measurement of soil moisture, but allows high economic benefit in various application such as simplified measurement of soil moisture and irrigation line control because of its low component count. The voltage type moisture sensor could be reinforced by relay controlling circuit to open and to close the solenoid valves respectively at optimal limits of the least and the most soil moisture according to user's adjustment.
The total acreage of 4,894ha of upland soils in Yeongyang area, the main crop cultivated were red-pepper. They were distributed mainly on local valleys and alluvial fans(54.9%), about 61.2% had 7~15% slopes, and about 73.2% had fine loamy family in soil texture. the soils were classified into Ochrepts(73.7%). Udalfs(16.9%), Fluvents(6.2%) and Psamments(3.2%) etc. The upland soils with 100~250m in altitude and "moderately well drained" had higher contents in inorganic nutrients. The red-pepper Produced in the high altitude(>400m) were lower in quality and yields, while the content of sugar and yields of pepper produced in fine loamy textured soils were higher than other soil textures. The yields of red-pepper produced in the "moderately well drained" soils which had better water supply capacity were higher than "well drained" soils.
Kim, Ki-Ho;Park, Jae-Soo;Kim, Hae-Keum;Choi, Sang-Il
Korean Journal of Soil Science and Fertilizer
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v.45
no.2
/
pp.287-292
/
2012
This study was to build the database by collecting the results of legal leak test and self-test conducted by the owners of soil contamination facilities at soil-related specialized agency to grip objective status on soil contamination facilities and evaluate classification results. The results of the study showed that the unsuitable rate of business unit is 53.6%, the business with leak that could cause actual pollution is 25.7%, the unsuitable rate of the voluntary self-test is 57.3%, that of the compulsory inspection is 17.2% depending on the test motivation, that of the direct-test is 58.9%, and that of the indirect-test is 22.5% depending on the test methods. There was a significant difference between the test motivation conducted and the test methods applied. From the results of the unsuitable reasons obtained we could assume that about 20% of the whole target tanks became potential sources with natural defects occurred when such tanks were made, and 2.2% of the whole tankers examined that persisting period was caused by progressing corrosion below the minimum thickness.
Park, Chol-Soo;Jung, Yeong-Sang;Joo, Jin-Ho;Lee, Gye-Jun
Korean Journal of Soil Science and Fertilizer
/
v.38
no.3
/
pp.127-133
/
2005
The measurement technique using laser distometer to estimate soil erosion on sloped upland was assessed for its possibility for application. This technique was practiced in lysimeter installed in Chuncheon and Pyeongchang in 2001. The lysimeter installed at Chuncheon has 12% slope, 10 m slope length, 2 m width, and soil texture was sandy loam, while the lysimeter installed at Pyeongchang showed 23% slope, 15 m slope length, 5 m width, and sandy loam soil. Change of surface soil height was monitored using laser distance meter before and after rainy season on same spots. The Investigated periods in Chuncheon and Pyeongchang were from 22 June to 22 September and from July to October, respectively. Precipitation in Chuncheon and Pyeongchang in this period was 892.2 and 931.9 mm, respectively. Rainfall over 60% of annual precipitation was concentrated on July and August in Chuncheon and September and October in Pyeongchang, respectively. By monitoring the change of surface soil height using laser distance meter before and after rainy season, eroded soil surface in up-down fallow field in Chuncheon was 0.874 cm, while eroded soil surface in slant furrow field in Pyeongchang was 1.127 cm, which correspond to 79.5 and $98.0MT\;ha^{-1}$. Soil erosion increased as furrow length increased. Amounts of estimated soil loss using laser distance meter was 0.98-1.18 times higher compared to the estimated values through Iysimeter experiment, which implies possibility for application to monitor soil loss particularly in up-down and slant furrowed field. However, in the lysimeter with contoured tillage, amount of estimated soil loss using laser distance meter was approximately a half compared to that from lysimeter experiment, which implies inadequacy of distance meter application in contour- tillage field. The great soil loss difference between distance meter and lysimeter might be caused by disruption of some of the contoured furrows in lysimeter. The measurement technique using distometer in this study could be useful to estimate soil loss especially in up-down and slant-tillage fields.
The soil geochemical exploration was carried out targeting around Tri Le area far from about 30 km with northwestern direction from Que Phong within Nghe An province. The interval of sampling are horizontal 200 m interval with 23 line and longitudinal 300 m with 10 line, resulting in 228 soil samples. Based on the result of the soil geochemical exploration, the detailed pitting survey was carried out targeting the grid point with high TREO content, resulting in 75 soil samples within 7 pits. The geology of survey area are consisted of Ban Chieng biotite granite complex and granitic gneiss intruding Ban Khang formation comprising of quartz schist and marble. Main mineralization in the study area have the characteristics of occurrence with tin, ruby and REE-bearing monazite and xenotime to be thought as occurring at the alteration zone of granite complex. In order to elucidate the source rock of monazite and xenotime confirmed from heavy sand, soil geochemical exploration was carried out. As a analysis result with ICP-MS on the soil samples from the soil geochemical exploration, total REE oxide content of background amount to about 2 times of crustal abundance, enriching the heavy rare earth(about 2 times) and light rare earth(about 1.5 times). As a analysis result with ICP-MS on the soil samples from the soil detailed pit survey, we only identified outcrop considering as economic weathered granite body at the grid point 1-10 pit among 7 pits. As a synthetic consideration on the soil geochemical exploration and detailed pit survey, we tentatively designated Tri Le area as no promising target for REE. In 2014, we have the plan to carry out the soil geochemical exploration targeting the extended economic REE ore body in Quy Chau as project area from 2011 to 2012.
Journal of Korean Society of Environmental Engineers
/
v.37
no.1
/
pp.69-72
/
2015
This study investigated the effects of oil dose and soil texture on the analysis results for total petroleum hydrocarbon (TPH) in artificially oil-contaminated soils. The same amount of diesel was mixed with soils having different soil texture, and soil TPH concentrations were then analyzed for comparison. Presence of clay in the soil showed lower soil TPH analysis results than that of sand only. As the clay content was increased in the soil, the lower soil TPH concentration was obtained by incompleteness of solvent extraction. As the organic matter content in soil was increased from 5.2% to 10% (weight basis), a higher concentration of TPH was obtained by TPH analysis. However, at a higher organic content in the soil, 18%, resulted in a lower TPH concentration than those of 5.2% and 10%. Gasoline dose to the soil resulted in a significantly low TPH concentration due to the volatilization of gasoline while soil mixing and analysis. This study results would provide fundamental information either to the expectation of TPH concentration in artificially oil-contaminated soil or to estimation of oil release in the real oil-contaminated site.
To grasp the physico-chemical properties on the management groups of upland soil, the data obtained from the detailed soil survey which conducted from 1964 to 1979 by Agricultural sciences Institute, were analyzed and classified. The clay content in A horizon soil was low in sandy textured and well adapted types and high in heavy clayey type, and that in B horizon was lowest in volcanic ash type and highest in heavy clayey type. High organic matter content was found in the volcanic ash and plateau type. The correlations among soil physico-chemical properties were significant. Especially canon exchange capacity of B horizon soil was highly correlated with the content of available water, clay, silt and organic matter positively.
These studies were aimed to find out the representative values of physico-chemical properties in Korean soils and to serve the basic informations to improve the soil properties for increasing the soil productivity. By the results of detailed soil survey, 14 physico-chemical properties (soil texture, moisture characteristics, organic matter content etc) were collected from 315 series of soils except Cheju soils, computerized the simple mean and the distributed area by weighted mean values with grouping of land use, drainage class and soil type. The results were as follows; 1. Simple mean values within the efficient soil depth in whole country soils were clay 20.0%, organic matter 2.03% and CEC 10.3me/100g. But weighted mean values with land area belonged to the same soil series were clay 18.0%, OM 1.85% and CEC 8.6me/100g. 2. Mean values of paddy soils weighted by area were clay 19.7%, OM 2.0% and CEC 9.1me/100g but those of upland soils were 17.9%, 1.8% and 8.1me/100g and forest soils were 16.7%, 1.8% and 8.6me/100g respectively. 3. Weighted mean values of moderately well soils with covered area were clay 18.9%, organic matter 1.7%, CEC 8.4me/100g but those of imperfectly drained soils were 21.3%, 2.2% and 9.5me/100g, and those of poorly drained soils were 15.1%, 1.8% and 9.9me/100g respectivcly. 4. Simple mean and area weighted mean values of clay content, pH, organic matter contents, cation exchange capacity and base saturation were calculated by the types of paddy and upland.
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