• Journal of Korean Society of Environmental Engineers
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• v.30 no.11
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• pp.1067-1074
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• 2008

In this study, the organic carbon normalized-sorption coefficients (Koc) for the binding affinity of phenanthrene (PHE) to 16 different soil humic and fulvic acids of various origins were determined by fluorescence quenching. The humic and fulvic acids used in this study were isolated from 6 different domestic soils including Mt. Hanla soil, IHSS standard soil and peat as well as Aldrich humic acid and characterized by elemental composition, ultraviolet absorption at 254 nm, composition of main structural fragments determined by CPMAS $^{13}$C NMR. The Koc values($\times$10$^4$, L/kg C) for each of HA and FA samples were in the range of 1.48$\sim$8.65 and higher in HA compared to that of FA(3.13$\sim$8.65 vs 1.48$\sim$2.48) in the experimental condition([PHE]/[HS] = 0.02$\sim$0.2(mg/L)/(mg-OC/L), pH 6). The correlation study between the structural descriptors of humic and fulvic acids and log Koc values of phenanthrene, show that the magnitude of Koc values positively correlated with the UV$_{254}$ absorptivity([ABS]$_{254}$) and two $^{13}$C NMR descriptors (C$_{Ar-H,C}$, $\sum$C$_{Ar}$/$\sum$C$_{Alk}$), while negatively correlated with the independent descriptors of the(N+O)/C atomic ratios and $^{13}$C NMR descriptors (I$_{C-O}$/I$_{C-H,C}$). These results confirmed that the binding affinity for the hydrophobic organic compound, phenanthrene are significantly influenced by the polarity and aromaticity of soil humc and fulvic acids.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.11a
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• pp.417-418
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• 2000

휘발성 유기물질(VOC)은 유기용제나 석유화학관련산업에서 배출되어 광화학스모그를 야기시킬 뿐 아니라 지하수와 토양을 오염시킨다. VOC물질중 대부분은 인체에 유해하여 1995년 대기환경보전법에서 VOC를 규제관리대상으로 선정하였다. 이와 같은 VOC를 제어하는 기술로는 흡착방법이 널리 이용되고 있으나 최종적으로 처리하기 위해서는 후처리시설이 필요하다. (중략)

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2001.11a
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• pp.43-44
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• 2001

산업의 발달과 함께 화석연료의 소비가 증가하면서 산성강하물(Acid precipitation)에 대한 관심이 증가하여 왔다. 산성강하물은 주로 화석연료의 연소를 통해 대기로 배출된 질소와 황 산화물들로, 산화ㆍ환원, 산ㆍ염기 중화반응 등 다양한 변환과정을 거쳐 비나 눈과 같은 습성과정이나 가스나 입자상 물질과 같은 건성과정을 통해 다시 토양과 호수 등에 침적되어 이들을 산성화시키는 원인이 된다. 따라서 산성강하물에 대한 이해를 위해서는 강수의 화학조성과 아울러 가스와 입자상으로 존재하는 질소와 황화합물에 대한 관측이 필수적이다. (중략)

• Journal of Wetlands Research
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• v.11 no.1
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• pp.123-130
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• 2009

Hyporheic zone is an area where hydraulic exchanges occur between surface water and ground water. Such transient area is anticipated to facilitate diverse biogeochemical reactions by providing habitats for various microorganism. However, only a few data are available about microbial properties in hyporheic zone, which would be important in better understanding of biogeochemical reactions in whole streams. The study site is Naesung stream, located in the north Kyoung-Sang Province, of which sediment is sandy with little anthropogenic impacts. Soil samples were collected from a transect placed perpendicular to stream flow. The transect includes upland fringe area dominated by Phragmites japonica, bare soil, and soil adjacent to water. In addition, soil samples were also collected from downwelling and upwelling areas in hyporheic zone within the main channel. Soils were collected from 3 depth in each area, and water content, pH, and DOC were measured. Various microbial properties including extracellular enzyme activities ($\beta$-glucosidase, N-acetylglucosaminidase, phosphatase and arylsulfatase), and microbial community structure using T-RFLP were also determined. The results exhibited a positive correlation between water content and DOC, and between extracellular enzyme activities and DOC. Distinctive patterns were observed in soils adjacent to water and hyporheic zone compared with other soils. Overall results of study provided basic information about microbial properties of hyporheic zone, which appeared to be discernable from other locations in the stream corridor.

• Korean Journal of Soil Science and Fertilizer
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• v.36 no.3
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• pp.105-112
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• 2003

Effects of magnesium sulfate ($MgSO_4$) and magnesium hydroxide $[Mg(OH)_2]$, which have different chemical characteristics, on soil pH, electrical conductivity (EC), and exchangeable cation distributions were investigated. Using plastic columns packed with a loam soil, the two Mg-fertilizers were treated at the rate of $300kg\;MgO\;ha^{-1}$ and water was applied on the soil surface four times at every 7 days. Soil samples were taken at 5, 10, 15, and 20 cm depth after 7 days of each water application. Magnesium hydroxide could increase soil pH, but due to the low solubility of $Mg(OH)_2$, the effect on pH was limited on the surface soil. Soil pH was lowered in the $MgSO_4$ treatment and the effect was found through the 20 cm depth. Since the pH decrease in $MgSO_4$ treated soil was due to the salts from $MgSO_4$, after leaching of most salts from the investigated soil depth pH was not significantly different from that of non-treated soil. Soil EC was increased in $MgSO_4$ treatment through the soil depth, but in $Mg(OH)_2$ treatment EC was slightly increased only at the surface layer. Exchangeable Mg was increased in both of the treatments at surface layer after the first water application. In $Mg(OH)_2$ treatment, the increase of exchangeable Mg was found only at 5 cm depth through the experiment, but leaching down of Mg in the $MgSO_4$ treatment was very apparent. High concentration of Mg in the $MgSO_4$ treated soil could effectively replace exchangeable Ca through the investigated soil depth, but the effect of $Mg(OH)_2$ on exchangeable Ca was not significant.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.5
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• pp.733-737
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• 2012

The objectives of this study were to investigate soil chemical properties for forest rehabilitation and suggest design and management in abandoned coal mine areas in Mungyeong, Gyeongsangbuk-do. Total study sites were 10 sites, and soil analysis particular were soil pH, TOC, total-N, C/N ratio, A.v. $P_2O_5$, and CEC. Because most of study sites showed soil pH from 5.0 to 7.0, it seems that soil pH does not affect growth of vegetation. But soil pH in Danbong1 was acidic (pH 4.6), so it is needed to improve with ameliorant such as limestone. Most of study sites is necessary to manage for organic matter and Nitrogen, because there sites showed lower value of TOC and total-N than general forest. The values of A.v. $P_2O_5$ and CEC were good in most of study sites, so it seems that they do not have effect on vegetation growth. All of soil factors has no regression according to elapsed time after rehabilitation. TOC, total-N and A.v. $P_2O_5$ among soil properties have positive relationship between each other. It is necessary to fertilizer for organic matter and Nitroge because of value in TOC, total-N and C/N ratio. The results of this study were analyzed only one time. So, long-term monitoring for soil properties is important for the correct forest rehabilitation and management.

• Korean Journal of Environmental Agriculture
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• v.33 no.1
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• pp.24-29
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• 2014

BACKGROUND: Recently, as the consumption of fresh jujube is increased, fertilizer in jujube cultivation is excessively used to supply nutrient for large fruit produce. This study was conducted to obtain the useful data related to optimum nutrient management technique for fresh jujube cultivation. METHODS AND RESULTS: Nutrient contents of the jujube orchard soils were investigated at 30 different jujube orchards in Boeun, Chungbuk. Soil samples were collected from the different orchards in June, both 2012 and 2013. Soil chemical properties such as pH, organic matter, available phosphate, and exchangeable potassium, calcium, and magnesium were analyzed. Soil available phosphates in optimum level for jujube cultivation were 7% and 13% of total samples in the 2011 and 2012 respectively, and 73% and 57% were higher than optimum level. In Exchangeable K, 37%, 30% were optimum level, 63%, 67% were higher in the year 2011 and 2012 respectively. CONCLUSION: These results showed that nutrient contents of soils were accumulated in jujube orchard of Boeun area. Especially, available phosphate and exchangeable potassium were greatly higher than their optimum level for jujube cultivation respectively.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.6
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• pp.1010-1015
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• 2011

The objectives of this study were to investigate soil chemical characteristics for forest rehabilitation and suggest management in abandoned coal mine areas in Hwasun-gun, South Jeolla Province. Total study sites were 8 sites, and soil analysis particular were soil pH, TOC, total-N, C/N ratio, Avail. $P_2O_5$, and CEC. Average soil pH was 5.8 (4.7~6.4). Average contents of TOC, total-N and C/N ratio were 1.1% (0.2~2.0%), 0.08% (0.02~0.13%) and 15.0 (7.9~31.4), respectively. Average Avail. $P_2O_5$ was $8.3mg\;kg^{-1}$ (2.7~15.0) and Average CEC was $13.7cmol_c\;kg^{-1}$ ($9.9{\sim}18.5cmol_c\;kg^{-1}$). Soil pH was decreased according to elapsed time from forest rehabilitation, while TOC, total N and CEC were increased. Av. $P_2O_5$ did not show any relationship with elapsed time. Soil pH was stable comparing with general forest soil in South Jeolla Province (5.1), while contents of TOC and total N were lower than general forest soil in South Jeolla Province (4.9% and 0.18%, respectively). Therefore, sustainable managements such as fertilization for TOC and total N are necessary for good rooting and growth of vegetation.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.2
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• pp.143-148
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• 2012

Sustainable agriculture requires reliable information on the spatial distribution of the soil chemical properties for effective management of paddy fields. In order to provide adequate soil nutritional information for environmental-friendly agriculture, we investigated the soil chemical properties for 260 paddy soils sampled in Gyeongnam Province from 1999 to 2011 by four years of interval. Soil chemical properties of pH, organic matter, available phosphate and silicate, exchangeable potassium, calcium, and magnesium contents were analyzed. The pH value, organic matter, available phosphate and silicate, and exchangeable calcium and magnesium in paddy soils were significantly elevated in 2011 compared to 1999. The excessive levels of organic matter and available phosphate in paddy soils were detected in 2011. The soil available phosphate was highest in mountain foot-slope (p<0.05) and the soil organic matter was highest in diluvial terrace (p<0.05). It revealed that the soil available phosphate was the responsible factor for the differentiation of soil chemical properties by the topography in paddy soils.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.3
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• pp.321-330
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• 2011

The physical properties of horticultural substrate are important for optimal plant growth. The physical properties should be properly maintained during the crop growing season for producing higher yield. This experiment was carried out to evaluate the physical properties of different mixtures from various raw materials as horticultural substrates. The mixtures at the different ratios of peatmoss, perlite and vermiculite subjected to 10:0:0, 8:2:0, 6:4:0, 4:6:0, 2:8:0, 0:8:2, 0:10:0, 0:6:4, 0:4:6, 0:2:8, 8:0:2, 0:0:10, 6:0:4, 4:0:6, 2:0:8, 2:6:2, 2:4:4, 4:2:4, 4:4:2, 6:2:2 and 2:2:6 were prepared and analyzed according to two methods of the European Standardization (EN) and Rural Development Administration (RDA). The optimum range of physical properties of a specific horticultural substrate can be predicted using physical-property-triangle. This triangle can also be used to convert a physical property from the EN method to that from the RDA method. Results showed that the mixture at a ratio of > 60% peatmoss, in most cases, is in the range of optimum physical condition for plant growth. We conclude that the developed physical-property-triangle can be suitable to suggest the optimum ratios of horticultural substrates used in this study.