• Title/Summary/Keyword: 토양의 화학적 특성

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Investigation of Soil Contamination at Major Roadside in Seoul - I. Manguro in Chungnanggu - (서울시 주요 도로변의 토양오염 조사 - I. 중랑구 망우로 주변 토양 -)

  • Kim, Kwon-Rae;Ryu, Hyung-Ju;Chung, Jong-Bae;Kim, Kye-Hoon
    • Applied Biological Chemistry
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    • v.44 no.2
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    • pp.103-108
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    • 2001
  • The objectives of this study were to investigate the contamination of the soils around the major roadsides in Seoul and to accumulate base-line data. Fifty topsoils ($0{\sim}5$ cm) and 48 subsoils ($20{\sim}50$ cm) were collected from 50 sampling sites near Manguro in Chungnanggu. The samples were air-dried, passed through 2-mm sieves, and analyzed to determine the physicochemical properties and the contents of heavy metals (Cd, Cu, Pb, Zn) and anions (Cl, $NO_3$, $SO_4$). Soil textures of top- and subsoils were mainly loamy sand and sandy loam, respectively. Average $_PH$ of top- and subsoil was approximately 7.5, much higher than that of the forest soils in Seoul. Average heavy metal contents were lower than the levels allowed by the Soil Environment Conservation Act of Korea, whereas much higher than those of the forest soils. Contents of some heavy metals were higher than the maximum allowed levels. Anion concentrations were also much higher than those of the forest soils. A careful management to prevent the aggravation of the present contamination level and the diffusion of contaminants is recommended.

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Soil Chemical Properties of Peach Orchard and Nutrient Content of Peach Leaves In Gyeongbuk Area (경북지역 복숭아 과수원 토양 화학성 및 복숭아 엽의 양분함량 조사)

  • Seo, Young-Jin;Kim, Jong-Su;Kim, Jae-Kyu;Cho, Jae-Uk;Kwon, Tae-Young;Lee, Jae-Seog
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.3
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    • pp.175-184
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    • 2002
  • Soil chemical parameters of peach orchards and the concentration of nutrients in peach leaves were investigated. Results of soil analysis showed that pH value and content of exchangeable calcium was quite low, required to adjust soil acidity in many investigated soils. Nitrogen and phosphorous contents in leaves were founded to be excessive comparing to RDA's optimal levels(N $29.3{\sim}35.9g\;kg^{-1}$, P $1.7{\sim}2.2g\;kg^{-1}$), while calcium contents were lower than optimal levels($11.2{\sim}21.0g\;kg^{-1}$) in many sites and Potassium content was higher in peach cultivars than nectarine cultivars. Correlation analysis revealed that organic matter contents in subsoils and exchangeable calcium content in soils(top and subsoil) were increased with cultivation year, but available phosphate contents in subsoils were decreased. Organic matter and exchangeable magnesium contents in top soils were positively correlated with potassium and magnesium contents in leaves, whereas were negatively correlated with calcium contents in leaves, impling antagonistic absorption of calcium against potassium and magnesium. The findings indicated that most of soils ought to managed to adjust soil acidity and application amount of nitrogen, phosphorous fertilizer and compost should be controlled properly.

Effects of Amendments on Heavy Metal Uptake by Leafy, Root, Fruit Vegetables in Alkali Upland Soil (염기성 밭 토양에서 안정화제에 의한 엽채류, 근채류, 과채류 작물들의 중금속 전이 특성)

  • Kim, Min-Suk;Min, Hyun-Gi;Lee, Sang-Hwan;Kim, Jeong-Gyu
    • Ecology and Resilient Infrastructure
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    • v.7 no.1
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    • pp.63-71
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    • 2020
  • Various types of amendments have been studied for heavy metal stabilization in soil. However, researches on the effect of amendments on alkali soil and their effects on the plants at various edible parts are insufficient. The aim of this study was to evaluate the stabilization efficiency of heavy metals and their transfer into edible parts of food crops. Abandoned mine area was selected and 3 types of amendments (lime stone, LS; steel slag, SS; acid mine drainage sludge, AMDS) was applied with 3% (w/w). in field. After 6 month aging, Chinese cabbage (leafy), bok choy (leafy), garlic (root) and red pepper (fruit) were transplanted and cultivated. For chemical assessment, total concentration and bioavailability using Mehlich-3 solution were determined. For biological assessment, fresh weight and heavy metal uptakes were analyzed. It was revealed that AMDS reduced bioavailability most effectively, resulting in the decrease in heavy metal concentration in edible parts of all crops. When explaining the heavy metal uptake of plants, the bioavailability was more appropriate than the total contents of soil heavy metals. Therefore, bioavailability-based further research and management practices should be carried out continuously for the sustainable environment management, safe crop production, and human health risk reduction.

Processing Quality of Potato (Solanum tuberosum L.) Tubers as Influenced by Soil and Climatic Conditions (감자의 가공품질에 영향을 미치는 토양 및 기상조건)

  • Jeong, Jin-Cheol;Yun, Yeong-Ho;Chang, Dong-Chil;Park, Chun-Soo;Kim, Sung-Yeol
    • Korean Journal of Environmental Agriculture
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    • v.22 no.4
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    • pp.261-265
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    • 2003
  • In order to examine the difference in processing quality of potato tubers among localities, chemical properties of soils were analyzed and climatic conditions were investigated. Potatoes (Solanum tuberosum L.) were grown at seven localities of Korea during two years from 1994 to 1995. Soil samples and tubers were obtained from 2 to 3 commercial farms per locality with 10 days interval from 70 days before harvesting. As the result of that, higher correlation in processing quality was found with organic material content among soil conditions. On the climatic conditions, minimum temperature and sunshine hours during the period from 30 to 11 days before harvesting exhibited highly significant negative correlations with all quality parameters except reducing sugar content. Additionally, regression equations based on the observed level of these factors showed the relatively high coefficients of determination for dry matter content and chip color. To produce higher quality potatoes for processing, therefore, climatic conditions such as minimum temperature and sunshine hour and soil condition such as organic matter content have to be considered before the selection of areas or fields.

Characterization of the Water Soluble Organic Fraction Extracted from a Sewage Sludge Amended Soil (Sewage Sludge를 시용(施用)한 토양(土壤)에서 추출(抽出)한 수용성유기물(水溶性有機物)의 화학구조적(化學構造的) 특성(特性))

  • Lim, Hyungsik;Volk, V.V.;Baham, J.
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.1
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    • pp.38-49
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    • 1985
  • The water soluble organic fractions (WSOF) from an agricultural soil (W), a soil treated with sludge for 6 years ($WS_6$), a sludge-soil mixture incubated for one week ($WS_1$), and sewage sludge (SS) were extracted, purified, and characterized by elemental analysis, functional group determinations, infrared, UV-visible, and proton nuclear magnetic resonance spectrosocpy. The SS was characterized by higher organic H, N, and P contents, a higher H/C ratio, and a lower C/N ratio than W. Total acidity carboxyl and phenolic hydroxyl group contents were generally highest in SS, intermediate in $WS_6$ and $WS_1$, and lowest in W. Overall aromatic character and aromatic carboxyl group contents were highest in W, and lowest in SS. Aliphatic proton, aliphatic carboxyl, and phenolic hydroxyl group contents were highest in SS, and lowest in W. Protein decomposition products were the pronounced components in SS, and decreased in concentration as the sludge component in the mixtures decreased. The $^1H$-NMR spectra suggested that the SS-protons were bound to a wider range of functional groups than W-protons. Structural complexities around the aromatic protons followed the following order: SS>$WS_1$>$WS_6$>W.

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Geochemical Investigation of Fluoride Migration in the Soil Affected by an Accidental Hydrofluoric Acid Leakage (불산 누출사고 지역 토양수의 지구화학적 특성을 통한 불소 거동 및 확산 잠재성 연구)

  • Kwon, Eunhye;Lee, Hyun A;Kim, Doyoung;Lee, Junseok;Lee, Sanghoon;Yoon, Hye-On
    • Journal of Soil and Groundwater Environment
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    • v.20 no.3
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    • pp.65-73
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    • 2015
  • The hydrofluoric acid (HF) leakage accident occurred on September 2012 in Gumi, Korea affected the surrounding soils and plants. In this study, we investigated fluoride migration in Gumi area through geochemical properties of soil-liquid phase (pore water F and water-soluble F). The concentrations of porewater F and water-soluble F were obtained from N.D (Not detected) to 9.79 mg/L and from 0.001 to 21.4 mg/L, respectively. F in pore water seemed to be affected by artificial and natural origin, and PHREEQC results implied that fluorite is F control factor. F concentrations of soil and soil-liquid phase did not exceed concern level of regulatory criteria and showed similar trends compared by previous studies. Therefore, F contents remained in the soil and soil-liquid phase were considered to be not affected by HF leakage accident.

Occurrence of Meloidogyne hapla in Peony Fields (작약 재배지에서 당근뿌리혹선충 발생양상)

  • 박소득;김기재;김정혜;유오종;류정기
    • Korean journal of applied entomology
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    • v.37 no.2
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    • pp.123-125
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    • 1998
  • In peony fields located in Uisong and Yeongcheon distribution of Meloidogyne hapla was examined. Of 131 fields examined, M. hapla was isolated from 102 fields. In 57.8% of the infested fields, M. hapla density was higher 31 larvae1300 ml soil, the larval density isolated from upland fields were higher than those from paddy fields. Sandy loam soil harbored higher number of larvae than clay soil. Physio-chemical properties of soil might affect nematode population: High larval density was detected from those fields with low contents of OM, K+ and low pH. Fields infested with high larval densities required more lime than those with low or non infested fields.

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Mineral Nutrition of Field-Grown Rice Plant -II Recovery of fertilizer nitrogen, phosphorus, and potassium in relation to climatic zone and physical or chemical characteristics of soil profile (포장재배(圃場栽培) 수도(水稻)의 무기영양(無機營養) -II 삼요소(三要素) 이용율(利用率)과 기상권(氣象圈) 및 토양단면(土壤斷面)의 물리(物理)·화학적(化學的) 성질(性質)과의 관계(關係))

  • Park, Hoon;Shin, Chun Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.6 no.1
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    • pp.17-26
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    • 1973
  • A survey on nutrient recovery by rice plant was carried out countrywide in 1967 and 1968. The relationships between percent recovery of fertilizer nutrient and climatic zone or deposition mode, drainage grade, and texture of paddy soil profile, or chemical characteristics of surface soil were as follows. 1. The percent recovery of fertilizer nitrogen was highest in south and least in north, and that of potassium was highest in south and least in middle climatic zone. 2. Since the percent recovery of Phosphorus variates yearly with climatic zone, mode of deposition drainage grade or soil texture, it seemed to depend greatly on soil-weather interaction. 3. Nitrogen recovery was highest in alluvial colluvial (AC) and it was followed by alluvial (A), fluvomarine (FM) and old alluvial in decreasing order while potassium recovery was OA>AC>A>FM. 4. The greater the drainage was, the higher the nitrogen recovery. The recovery of potassium and phosphorus tended to show high in moderately well drain, and low in poorly and well drain. 5. Nitrogen recovery was highest in fine silty and gradually decreased with coarseness. That of potassium or phosphorus was greater in those below fine loamy than in those above coarse silty. 6. Nitrogen recovery was high in Jisan, Geugrag, and Sindab series, and low in Hwadong, Gyuam, Yongji and Hwabong series. 7. Nitrogen recovery showed significant positive correlation with the content of organic matter (OM), Ca, CEC of surface soil and only in the year of high phosphorus recovery it had significant negative correlation with soil phosphorus. Phosphorus recovery had significant posititive correlation with CEC, Mg or Ca. 8. Potassium recovery showed negative correlation with K/(Ca+Mg), P, OM or K while positive correlation with Ca, Mg, CEC but significant only with K/(Ca+Mg) in the year of low potassium recovery. In the year of high K recovery it showed positive correlation with P, OM, K/(Ca+Mg) or K while negative with CEC, Mg or Ca but significant only with P, OM or CEC. Soil potassium has significant positive correlation with soil OM and P only in the year of low potassium recovery. 9. The percent recovery of N, P or K showed negative correlation coefficient with pH without significant. 10. There was significant positive correlation between OM and P, K or K/(Ca+Mg), P and K or K/(Ca+Mg), K and K/(Ca+Mg), Mg or CEC, Ca and K/(Ca+Mg), Mg, CEC or pH, Mg and CEC while significant negative correlation between Mg and OM, P or K/(Ca+Mg), P and CEC, Ca and K/(Ca+Mg). 11. From the percent rcovery of fertilizer and soil chemical characteristics it was known that soil organic matter increase nitrogen uptake, that K uptake has closer relation to K/(Ca+Mg) than K, that Mg affects P ugtake, and that the annual difference of P and K recovery was partly explainable.

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Study on Construction of Soil Structure in Creation of Man-made Tidal Flat (인공 간석지 창출에 있어서 토양조성에 관한 연구)

  • Lee, Jeoung-Gyu;Suh, Hea-Dong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.8 no.2
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    • pp.85-92
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    • 2000
  • The purpose of this study was to identify the controlling factors to construct tidal flat ecosystems having similar characteristics as natural ones. We transplanted the soil in a constructed tidal flat to a natural one and vice versa. Parameters monitored after these transplantations were silt content, organic matter, bacterial population and oxidation-reduction potential. Moreover, the relationship among silt content, organic matter and bacterial population was investigated by laboratory column experiment. The silt content, organic matter, bacterial population and vortical profile of oxidation-reduction potential in the soil transplanted from the constructed tidal flat to the natural one changed to similar values to those In the natural one. On the contrary, all the parameters for the soil transplanted from the natural tidal flat to the constructed one changed to similar values as those in the constructed one. The silt contents in these two transplanted soils were in proportion to the organic carbon contents and bacterial population. Similarly, the bacterial population in laboratory column experiment increased with the increase in silt and organic matter contents. It seemed to be important to select a place to enhance accumulative of silt and/or to maintain the silt content by hydrodynamic control of seawater in order to construct a tidal flat having similar characteristics as natural one.

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Chemical and Spectroscopic Characterization of Soil Humic and Fulvic Acids and Sorption Coefficient of Phenanthrene: A Correlation Study (토양 휴믹물질의 화학적.분광학적 특성에 따른 페난트린 흡착상수와의 상관성 규명에 대한 연구)

  • Lee, Doo-Hee;Lee, Seung-Sik;Shin, Hyun-Sang
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.11
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    • pp.1067-1074
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    • 2008
  • In this study, the organic carbon normalized-sorption coefficients (Koc) for the binding affinity of phenanthrene (PHE) to 16 different soil humic and fulvic acids of various origins were determined by fluorescence quenching. The humic and fulvic acids used in this study were isolated from 6 different domestic soils including Mt. Hanla soil, IHSS standard soil and peat as well as Aldrich humic acid and characterized by elemental composition, ultraviolet absorption at 254 nm, composition of main structural fragments determined by CPMAS $^{13}$C NMR. The Koc values($\times$10$^4$, L/kg C) for each of HA and FA samples were in the range of 1.48$\sim$8.65 and higher in HA compared to that of FA(3.13$\sim$8.65 vs 1.48$\sim$2.48) in the experimental condition([PHE]/[HS] = 0.02$\sim$0.2(mg/L)/(mg-OC/L), pH 6). The correlation study between the structural descriptors of humic and fulvic acids and log Koc values of phenanthrene, show that the magnitude of Koc values positively correlated with the UV$_{254}$ absorptivity([ABS]$_{254}$) and two $^{13}$C NMR descriptors (C$_{Ar-H,C}$, $\sum$C$_{Ar}$/$\sum$C$_{Alk}$), while negatively correlated with the independent descriptors of the(N+O)/C atomic ratios and $^{13}$C NMR descriptors (I$_{C-O}$/I$_{C-H,C}$). These results confirmed that the binding affinity for the hydrophobic organic compound, phenanthrene are significantly influenced by the polarity and aromaticity of soil humc and fulvic acids.