• The Journal of Engineering Geology
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• v.23 no.4
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• pp.363-373
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• 2013

This study investigates the dispersion and behavior of Au and heavy metals in the water system (soil, AMD and stream sediment) at the abandoned Bonjeong gold mine, based on XRD, aqua regia, sequential extraction, and physico-chemical analyses. The XRD analyses targeted quartz and kaolinite in the mine waste soil and quartz and goethite in stream sediment. The physico-chemical analyses of AMD with increasing distance from water system showed that pH increased from 3.00 to 3.19 and Eh decreased from 450 to 396 mV. The Au content in AMD ranged from 0.68 to 0.97 mg/L upstream, but was not detected downstream. The Au content of stream sediment was 13.76 to 22.85 mg/kg. Sequential extraction from stream sediment revealed 10.84% exchangeable (STEP I), 11.09% carbonates (STEP II), 25.53% Fe-Mn oxides (STEP III), 26.62% organic matter (STEP IV), and 24.61% residual (STEP V).

• Applied Chemistry for Engineering
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• v.23 no.6
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• pp.618-623
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• 2012

The significance of soil environment has been gradually increased because of petroleum leak accidents. Comparing with wastewater clean treatments and air pollutant controls, the soil purification requires a long-term process and it is very expensive. In this study, we analyzed the physicochemical properties of total petroleum hydrocarbon (TPH) contaminated in soil. This could be applied to deciding the source of petroleum when a soil contamination accident occurs.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.11a
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• pp.51-54
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• 2000

수은의 순환현상은 원소성 수은의 지화학적 분포특성으로 대표된다 (Kim et al., 1997). 강한 휘발성과 화학적인 안정성은 광역적으로 수은이 균질한 분포특성을 유지하여 지구규모의 대기순환에 종속되는 원인으로 이해된다. 수은의 순환과 관련된 근래의 연구들은 다음과 같이 다양한 환경권계면간에서 진행되는 교환현상들에 주로 초점을 맞추어 왔다. 대기환경과 수림식생과의 교환현상에 대한 연구 (Lindbereg et al., 1995, 1998), 대기환경과 토양생태계의 교환 (Carpi and Lindberg, 1998; Kim et al., 1995; Kim and Kim, 1999, 1998. Xiao et al., 1991), 수환경과 대기환경계의 교환(Poissant and Casimir, 1998)등 상대적으로 오염원의 강한 영향을 받는 환경권역을 중심으로 한 교환현상에 대한 정량적인 평가자료는 아직까지 드물게 보고되고 있다. (중략)

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.3
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• pp.444-450
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• 2012

The physical and chemical properties of soil in the Mangyeong and Dongjin river basin had been investigated in order to establish the most optimum soil improvement plan on the reclaimed land. The total soil area by reclamation in Saemangeum basin is 113,971 ha. The classification by the distribution of soil series and soil texture is as following. 13 soil series including Chonnam, Buyong and Chonbuk series are period-unknown areas. Regarding the soil texture, they are fine silty ~ clayey very fine. From 1920s to 1960s, Mangyeong, Gwanghwal and Chonbuk series had coarse silty textured soil. After the 1970s, Mangyeong, Gwanghwal, Munpo, Yeompo, Poseung, Gapo and Hasa series have more sandy soil ~ moderately coarse loamy textured soil. Regarding the chemical properties, the concentrations of EC, Exch. $K^+$, $Mg^{2+}$, $Na^+$ and pH are high regardless of the time of reclamation. On the other hand, organic matter (OM) of top soil were 3.3~16.1 g $kg^{-1}$. The organic matter contents were very low though the soil had been farmed for a long time. Furthermore, the deep soil had almost no organic matter with 5.6~1.1 g $kg^{-1}$. The reason is believed that there had not been any movement of OM and clay because pressure or induced pans had been formed by large agricultural machineries and poor vertical drain. Regarding the forming of illuvial horizon (B layer) which tells the development extent of soil, only in the Hwapo reclaimed area where rice had been cultivated for past 90 years, Fe and Mn from top soil are deposited at underground 20~30 cm with 7~8 cm thickness by the movement of clay. It is believed that it had been possible because the earthiness is silty clay loam soil with relatively high content of clay. The soils are soil with concern of damage from sea water, soil on flimsy ground and sandy soil. Therefore, soil improvement for stable crop production can be expected; if the water table would be lowered by subsurface drainage, the water permeability would be enhanced by gypsum and organic matter, and the sandy soil would be replaced by red soil with high content of clay.

• Korean Journal of Poultry Science
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• v.33 no.1
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• pp.65-80
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• 2006

Ash amendment to manure holds potential as a method to neutralize manure for reducing odor and reduce phosphorus (P) solubility in runoff from fields where manure has been applied. This review focuses on the literature published about ash characteristics and their environmental uses. There is no uniform physico-chemical definition of the selected ashes (coal fly ash-CFA, wood ash-WA, and rice hull ash-RHA) used in various studies. These ashes vary greatly in their acidity (pH<6.0) or alkalinity (pH>12.5) based on the conditions at which they were farmed and the composition of the ash source. CFA amendment to manure reduced manure-P solubility and application of CFA amended manure to agricultural soils is a method to improve water quality WA may prove to be a valuable manure odor control amendment since WA contains a high level of carbon. A major biomass source is rice hull (husk) which provides an ash source (RHA). The .ice hull and RHA are sources of silica, compromising about 20% and 60%, respectively. So far research has been directed at the use of CFA, WA and RHA as soil amendments, but there is potential use of these materials as manure additives to sequester P and reduce odors.

• Journal of the Korean earth science society
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• v.26 no.8
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• pp.800-808
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• 2005

Elemental mobility during the weathering of granite in the Gwangju Hyangdeung area was investigated using ICP-MS analysis. It appeared that Al, Fe, Ti, K were lost from the profile, whereas Si, Ca, Na Mg, P and Mn were immobile during chemical weathering. In less weathered soil, large enrichment of K and Ti were found relative to Al, whereas other elements such as Si, Ca, Na, Mg and P are deplete. Fe content is constant throughout the weathered profiles. Amounts of Rb, Sr, Y, Cs, Pb, Th and U increased toward the surface. Nb, and Co have accumulated in the deepest parts of the weathered soil profile. These results agree with similar published studies. In addition, the analytical data shows that Ba and Ga increased, while Cu, Zn, Cr and Ni were relatively constant in this area. REE tend to increase in most samples, while LREEs, relative to Al, were enriched in the lower and upper saprolite. HREEs were enriched in the lower and upper saprolite.

• Journal of Soil and Groundwater Environment
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• v.8 no.1
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• pp.57-67
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• 2003

Nitrate contamination by human activities is a serious problem to water-supply in agricultural area. Shallow groundwater is the main source of water-supply, but it is very sensitive to contamination. Study area for nitrate contamination is a region of Iljuk, Kyunggi where is an agricultural area having many livestock facilities in various scales. As a result, the points having availability of incoming of external contaminant are 77%, and the ones over the Drinking Water Limit (DWL) are 32～42%. For a nitrogen isotope analysis, all the points having availability of incoming of external contaminant have $\delta$$^{15}$ N-NO$_3$ values over 5$\textperthousand$, and the points of 59% are strongly affected by nitrogen originated from animal wastes. The major source of nitrate in this area is intensive livestock facilities. Even though a livestock facility had enclosed, it affects groundwater quality for a long time. The chemical property of contaminant source is various according to animal species in surface water, but not in groundwater since some solutes are removed by reactions during an inflow to subsurface.

• Journal of the Korean Institute of Landscape Architecture
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• v.43 no.3
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• pp.77-91
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• 2015

This study aims to suggest adequate soil management through the analysis of physicochemical properties of soil in the planting grounds of Incheon International Airport, which was constructed on a massive land reclamation site. Study areas were 5 sites at the international business complex, the passenger terminal, the airport support complex, the free trade zone, and the access road. Soil profile analysis showed that 9 plots out of the 27 plots were hardpan and heterospere within 80cm from the soil surface. The earth laid on the ground was categorized as gravel based soil(4 plots), dredged soil from the sea bottom and mixed reclamation materials(2 plots), clay with poor permeability(3 plots) and waste construction material(1 plot). Average soil hardness was $11.5kg/cm^2$ and soil textures were sandy soil, sandy loam and loamy sand. Average soil pH was 6.7 and average organic matter content was 0.7%. Electrical conductivity was 0.0dS/m and exchangeable cation concentrations were $Ca^{2+}$ 3.4cmol/kg, $Mg^{2+}$ 1.5cmol/kg, $K^+$ 0.3cmol/kg and $Na^+$ 1.0cmol/kg. Average cation exchange capacity was 11.0cmol/kg. Although average figures in Solum mostly meet the landscape design criteria, properties of each soil layer showed various values sometimes over the limit. Base saturations were $Ca^{2+}$ 29.9%, $Mg^{2+}$ 13.3% and $K^+$ 3.7% for lower soil, $Ca^{2+}$ 33.3%, $Mg^{2+}$ 17.0% and $K^+$ 2.7% for mid-soil and $Ca^{2+}$ 32.6%, $Mg^{2+}$ 12.2% and $K^+$ 1.9% for upper soil. Exchangeable sodium percentages were 16.4% for lower soil, 7.5% for mid-soil and 4.7% upper soil. Sodium adsorption rates were 0.8 for lower soil, 0.3 for mid-soil and 0.2 for upper soil. Factors affecting to the vegetation growth were heterogeneity and poorness of solum, disturbance of dredged soils, high soil hardness including hardpan in the subsurface soil layer and shallow effective soil depth, high soil acidity, imbalance of base contents, low organic matter content and low available phosphate levels in the soil.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2003.05b
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• pp.223-224
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• 2003

포장도로에서 발생되는 미세먼지는 주로 자동차의 운행에 의한 직접 배출되는 입자와 도로 표면에서 비산되는 토양입자 그리고 타이어나 브레이크 패드의 마모에 의한 고무 및 석면 둥 다양한 배출원에 의해 발생되는데, 도로 주변의 배출원에 의해 많은 영향을 받을 것으로 판단된다. (최금찬등, 1996) 특히 인천에는 많은 비산먼지 배출원이 산재하여 있어, 이 들 배출원들의 영향이 여타 대도시보다 클 것으로 판단된다. 따라서, 본 연구에서는 인구와 교통량이 많고 공업활동이 활발한 인천지역의 주요 포장도로(H-ADT: High Average Daily Traffic, 5,000대/일 이상인 도로)에서 채취한 silt를 주거지역, 공업지역, 상업지역, 기타지역별로 채취하여 화학적 성분분석을 통해 지역별 특성을 조사하여, 각 지역 별 포장도로에서의 silt의 기원이 무엇인지를 추정하는 기초자료를 구축하고자하였다. (중략)

• Journal of the Korean Society of Groundwater Environment
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• v.4 no.1
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• pp.41-53
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• 1997

Geochemical data of soil and water samples were presented in order to assess the environmental impart for drinking water sites. Microscopic observation of rock samples and physical and chemical analysis of soil and water samples were undertaken. The geology of study areas are classified into three groups such as granitic rocks, meta-sedimentary rocks and sedimentary rocks. Enrichment of heavy metals derived from those rocks is not found in this study areas. Soils were analyzed for Cu, Pb, Zn, Cd and Cr using AAS extracted by HNO$_3$+HClO$_4$ and 0.1 N HCl. Heavy metal concentrations in soils are within the range of those in uncontaminated soils. In comparison of metal contents extracted by 0.1 N HCl and HNO$_3$+HC1O$_4$, less than 10% of the heavy metals are present in the exchangeable fraction. In particular, an pollution index has been proposed to assess the degree of soil contamination. Pollution index in soils are between 0.03 and 0.47 therefore, soils are not polluted with heavy metals. Deep groundwaters within granitic rocks have been evolved into Na$\^$＋/-HCO$_3$$\^$-/ type, whereas other deep groundwaters evolved into Ca$\^$2＋/-HCO$_3$$\^$-/ type. The predominance of Na$\^$＋/ over Ca$\^$2＋/ in deep groundwaters within granitic rocks is a result of dissolution of plagioclase, but for sedimentary and meta-sedimentary rocks, dissolution of calcite is a dominant factor for their hydrogeochemistry. The pH, conductivity and contents of the most dissolved ions in the water increase with depth. Shallow groundwaters, however, are highly susceptible to pollution owing to agricultural activities, considering the fact that high contents of nitrate, chloride and potassium, and high K/Na ratio are observed in some shallow groundwaters. In a thermodynamic approach, most natural water samples are plotted within the stability fields of kaolinite and smectite. Therefore, microcline and other feldspars will alter to form clay minerals, such as kaolinite and smectite. From the modelling for water-rock interactions based on mass balance equation, models accord well with behavior of the ions and results of thermodynamic studies are derived.