• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.04a
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• pp.389-392
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• 2005

Visual MODFLOW를 이용하여 서울지하철 7호선 706공구에 계획된 터널 굴착에 따른 지하수 유동계의 변화를 모사하였다. 경계조건은 모델 영역 내 하천(굴포천)의 경우 일정수두경계, 터널 굴착 구간의 경우 $0.39{\sim}0.58m^2/day$의 전도계수를 갖는 배수경계(Drain), 터널 개착구간은 Inactive cell이 존재하는 일정수두경계 조건으로 설정하였다. 모델 보정은 현장시험을 통해 구해진 수리상수는 일정하게 유지하고 함양률을 변화시키면서 실시하였으며, 정류모사를 반복 수행하여 최적의 함양률(150 mm/yr)을 결정하였다. 모사 결과 터널 구간으로의 지하수 유입량은 굴착 및 개착 완료 시 $623m^3/day$, 터널 완공 후 정류상태의 경우 $584m^3/day$인 것으로 나타났다. Zone Budget을 이용한 유출입량 분석 결과 정류 상태 시 터널 내로 유입되는 지하수의 69%는 터널 인근 하천수의 유입에 기인하며, 나머지 31%는 주변 지역에서 함양된 지하수에 의한 것으로 나타났다.

• Geotechnical Engineering
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• v.9 no.2
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• pp.65-69
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• 1993

강우에 의해 발생되는 토양(soil)에서의 Recharge를 구하기 위해 두가지 모델 즉, ((i) Simple Mass Balance Model (ii) Numerical Model : UNSAT 1)을 사용했는데, 이 두 모델들은 불포화상태의 흙(unsaturated zone : above groundwater table)에서 그의 가정과 개념에 약간 차이가 있다. Unsaturated Zone에서의이 두 모델의 적용에 있어서 몇가지 중요한 사항이 지적되고 있는데, 균질의 불포화 영역(unsaturated zone)의 토양에서 Mass Balance Model을 사용함으로써 얻은 Recharge는 UNSAT 1(numerical model)을 통해 얻은 결과와 비교할 때 서로 상이한 결과를 보였다. 또한, Recharge의 계산에 있어서 지하수위의 변화에 따른 영향을 알아보기 위해 Sensitivity Analysis를 수행하였다. 즉, 고정수위(fixed groundwater table)로 가정했을 때 발생되는 오차를 한개의 수리학적 계수(hydraulic parameter)의 함수로 보고 계산을 했으며 이 결과를 그림으로 나타내어 보았다. 이 연구의 결과는 Model Simulation에 있어서 수리학적 경계조건을 결정하는데 큰 도움이 될 것이며, 또한 이 연구에서는 Unsaturated-Saturated Flow Model이나 Drainage Model을 함께 병행시켜 Simulation을 수행하는데 촛점을 두고 있다.

• Korean Journal of Soil Science and Fertilizer
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• v.35 no.1
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• pp.12-26
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• 2002

The phylogenetic relationships for 33 strains belonging to the genera Azorhizobium, Bradyrhizobium, Mesorhizobium, Rhizobium and Sinorhizobium were conducted by the sequence analyses of the ITS regions. The sequence homologies of these strains showed the high variations(28.0 - 94.9%). According to the phylogenetic analysis of ITS regions. 37 ITS clones from 33 strains of 32 species were classified into four groups. Group I included all strains of the genus Sinorhizobium as core members and R. giardinii as a peripheral member. The genus Rhizobium strains were clustered into group II which was very heterogeneous and the tree toplogy of this group were very unstable. Among the members of group II. the taxonomic position of R. radiobacter and R. rubi was not clearly identified on the basis of ITS I regions. R. undicola and R. vitis were remotely related with other Rhizobium strains including R. leguminosarum, R. galegae, R. gallicum, R. mongolense, R. tropici, R. hainanense, R. rhizogense and R. huautlense of group II were supposed to be loosely related to R. leguminosarum. While the stains of the genera Bradyrhizobium constituted group III with Azorhizobium caulindans, the strains of the genus Mesorhizobium formed group IV on the relatively high sequence homology level.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.6
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• pp.1203-1210
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• 2012

As the area of upland crops increase, it is become more important for farmers to understand status of soil water at their own fields due to key role of proper irrigation. In order to estimate daily water balance and soil water content with simple weather data and irrigation records, we have developed the model for estimating water balance and soil water content, called AFKAE0.5, and verified its simulated results comparing with daily change of soil water content observed by soil profile moisture sensors. AFKAE0.5 has two hypothesis before establishing its system. The first is the soil in the model has 300 mm in depth with soil texture. And the second is to simplify water movement between the subjected soil and beneath soil dividing 3 categories which is defined by soil water potential. AFKAE0.5 characterized with determining the amount of upward and downward water between the subjected soil and beneath soil. As a result of simulation of AFKAE0.5 at Gongju region with red pepper cultivation in 2005, the water balance with input minus output is recorded as - 88 mm. the amount of input water as precipitation, irrigation, and upward water is annually 1,043, 0, and 207 mm, on the other, output as evapotranspiration, run-off, and percolation is 831, 309, and 161 mm, respectively.

• Journal of Soil and Groundwater Environment
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• v.12 no.2
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• pp.27-36
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• 2007

A recent study showed that MTBE can be degraded by Fenton's Reagent (FR). The treatment of MTBE with FR, however, has a definite limitation of extremely low pH requirement (optimum pH $3{\sim}4$) that makes the process impracticable under neutral pH condition on which the ferrous ion precipitate forming salt with hydroxyl anion, which result in the diminishment of the Fenton reaction and incompatible with biological treatment. Consequently, this process using only FR is not suitable for in-situ remediation of MTBE. In order to overcome this limitation, modified Fenton process using NTA, oxalate, and acetate as chelating reagents was introduced into this study. Modified Fenton reaction, available at near neutral pH, has been researched for the purpose of obtaining high performance of oxidation efficiency with stabilized ferrous or ferric ion by chelating agent. In the MTBE degradation experiment with modified Fenton reaction, it was observed that this reaction was influenced by some factors such as concentrations of ferric ion, hydrogen peroxide, and each chelating agent and pH. Six potential chelators including oxalate, succinate, acetate, citrate, NTA, and EDTA were tested to identify an appropriate chelator. Among them, oxalate, acetate, and NTA were selected based on their remediation efficiency and biodegradability of each chelator. Using NTA, the best result was obtained, showing more than 99.9% of MTBE degradation after 30 min at pH 7; the initial concentration of hydrogen peroxide, NTA, and ferric ion were 1470 mM, 6 mM, and 2 mM, respectively. Under the same experimental condition, the removal of MTBE using oxalate and acetate were 91.3% and 75.8%, respectively. Optimum concentration of iron ion were 3 mM using oxalate which showed the greatest removal efficiency. In case of acetate, $[MTBE]_0$ decreased gradually when concentration of iron ion increased above 5 mM. In this research, it was showed that modified Fenton reaction is proper for in-situ remediation of MTBE with great efficiency and the application of chelatimg agents, such as NTA, was able to make the ferric ion stable even at near neutral pH. In consequence, the outcomes of this study clearly showed that the modified Fenton process successfully coped with the limitation of the low pH requirement. Furthermore, the introduction of low molecular weight organic acids makes the process more available since these compounds have distinguishable biodegradability and it may be able to use natural iron mineral as catalyst for in situ remediation, so as to produce hydroxyl radical without the additional injection of ferric ion.

• Journal of Korean Society of Environmental Engineers
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• v.31 no.5
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• pp.352-357
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• 2009

Due to rapid consumption of hydrogen peroxide, large amount of hydrogen peroxide is required when Fenton reaction is applied to the contaminated soil. In this study, acetate was employed as a ligand of $Fe^{2+}$ to enhance the efficiency of removal of phenanthrene by securing the stability of hydrogen peroxide. 0.5 ${\sim}$ 3 times of acetate (2${\sim}$12mM) was added to compare with molar concentration of $Fe^{2+}$. Low initial concentration of hydrogen peroxide was 0.7% to eliminate side effect of removal efficiency. The results showed that hydrogen peroxide lifetime was lasted up to 72 hours, or more than 50 times of normal lifetime. Phenanthrene removal efficiency was improved up to 70% due to stabilized hydrogen peroxide. Ferrous ion was oxidized to ferric ion and oxidation-reduction was repeated during the reaction. Finally ferric ion was reduced to ferrous by $HO_2$. It was confirmed that, due to the influence of hydrogen peroxide, pH was acid region and it remained at the range of 4 ${\sim}$ 5 when 8 mM or more of acetate was added. Acetate which was used as the ligand of Fe was also decomposed by Fenton reaction. The decomposition time of acetate was slower than phenanthrene. Therefore, it was able to come to the conclusion that phenanthrene was superior to acetate at the competition for decomposition. Through the results of this study, it was able to identify the possibilities to improve the efficiency of Fenton reaction in the contaminated soil and its economic feasibility, and to move to more realistic technique through research expanded to neutral pH region.

• Journal of Korea Water Resources Association
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• v.32 no.6
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• pp.751-762
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• 1999

In this study, a 1-D laboratory experiment was conducted to investigate the characteristics of transient unsaturated solute transport by using two kinds of soils of which properties were known by test. Especially the TDR method which is proposed in this study was used to measure water content and solute concentration. As results, in the transient flow, the wetting front moves down rapidly, and the distribution of solute concentration near the wetting front showed the similar type of the water content distribution(semi-bell type). A numerical model HYDRUS was used to compare with the experimental results. Numerical results for the water movement are similar to experimental result. However, numerical results of the distribution of solute concentration are more scattered than experimental results. It means that measured dispersivity, numerical dispersion, adsorption coefficient, and soil sample size etc. should be considered in order to determine the dispersivity used in the numerical model. The present measuring method was proved to be superior to other formula and to be an available method to apply to solute transport test. The measuring error of the developed method is estimated smaller than 10% while water content is larger than 0.15.

• Journal of Korean Home Economics Education Association
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• v.16 no.3
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• pp.131-146
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• 2004

The Purpose of this study is to suggest strategies for environmental education through the Practical Arts(TechnologyㆍHome economics) Subject in a viewpoint of the clothing & textiles resources to resolve problems in the clothing life area. For this, this study was carried out through review of literature which is related with the consumption, the environmental problems, the environmental policies, and regulations of the government and new environmental technologies, of clothing & textiles industries and environmental education. The major findings of the study were as follows; 1) The environmental education system model in a viewpoint of the Clothing & Textiles resources was developed. This model system is consisted with interactions on school, government, industry, home and non-government organizations. Thus, the fact that Practical Arts(TechnologyㆍHome economics) Subject were the most effective subject to teaching the environmental education viewpoint of the Clothing & Textiles resources was confirmed. 2) The standards were analysed out to analyse the contents in the clothing area of the Practical Arts(TechnologyㆍHome economics) Subject. It were consist of 4 factors and 12 elements under the factors: Awareness of clothing & textile resources(clothing consumption, production of clothing & textile and environmental problems). Planning and buying of clothing(planning, buying), Management of clothing(understand of textile. human body & environment, laundering and Environmental pollution, arrangement & conservation) Recycling & exhaust of clothing(contribution, redesign, recycling, exhaust) 3) Analysing the current Practical Arts (TechnologyㆍHome economics) subject from the Environmental education in the clothing section, the environmental education related with clothing were taught the most in the middle school course, and environmental contents were concentrated in the recycling factors. but not so much on other factors. 4) After analysing the Practical Arts (TechnologyㆍHome economics) subject, the strategies were suggested for reinforcing the environmental education in the clothing of the Practical Arts(TechnologyㆍHome economics) subject.

• Proceedings of the KSRS Conference
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• 2006.03a
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• pp.214-217
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• 2006

전 지구영역에 대해 1km 의 해상도로 제공되는 새로운 개념으로 완성된 지표 변수데이터 베이스인 Ecoclimap-1이 소개 된 바 있다. 이것은 기상과 기후의 모델에서 토양과 식물과 대기 사이의 이동 모식을 설명하기 위해 고안 되었으며, 이러한 Ecoclimap-1은 토지피복지도와 기후기도를 중첩하여 얻어진 Ecosystem 지도를 기본 주제도로 사용한다. 하지만 중첩한 결과 같은 class 에 포함되더라도 내부 class 에서의 식생의 시간 변동성은 여전히 높게 나타난다. 이와 달리 Ecoclimap-2는 새로운 방법으로, SPOT/VEGETATION S10 NDVI 자료를 이용하여 토지피복을 보다 동질의 하위 집단으로 분류 한다. 본 연구 에서는 이러한 Ecoclimap-2의 일환으로 동북 아시아 영역의 생태기후지도를 제공하고자 한다. 이러한 Ecosystem map 은 앞으로의 기후 모델 연구에 있어 중요한 base map 으로 사용 되어질 것으로 보이며 또한 생태계모델, 기상 모델의 중요한 input 자료로서 쓰여 질 것으로 사료 된다.

• Journal of Korea Soil Environment Society
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• v.2 no.2
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• pp.81-94
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• 1997

In many solute transport studies, either flux or resident concentration has been used. Choice of the concentration mode was dependent on the monitoring device in solute displacement experiments. It has been accepted that no priority exists in the selection of concentration mode in the study of solute transport. It would be questionable, however, to accept the equivalency in the solute transport parameters between flux and resident concentrations in structured soils exhibiting preferential movement of solute. In this study, we investigate how they differ in the monitored breakthrough curves (BTCs) and transport parameters for a given boundary and flow condition by performing solute displacement experiments on a number of undisturbed soil columns. Both flux and resident concentrations have been simultaneously obtained by monitoring the effluent and resistance of the horizontally-positioned TDR probes. Two different solute transport models namely, convection-dispersion equation (CDE) and convective lognormal transfer function (CLT) models, were fitted to the observed breakthrough data in order to quantify the difference between two concentration modes. The study reveals that soil columns having relatively high flux densities exhibited great differences in the degree of peak concentration and travel time of peak between flux and resident concentrations. The peak concentration in flux mode was several times higher than that in resident one. Accordingly, the estimated parameters of flux mode differed greatly from those of resident mode and the difference was more pronounced in CDE than CLT model. Especially in CDE model, the parameters of flux mode were much higher than those of resident mode. This was mainly due to the bypassing of solute through soil macropores and failure of the equilibrium CDE model to adequate description of solute transport in studied soils. In the domain of the relationship between the ratio of hydrodynamic dispersion to molecular diffusion and the peclet number, both concentrations fall on a zone of predominant mechanical dispersion. However, it appears that more molecular diffusion contributes to the solute spreading in the matrix region than the macropore region due to the nonliearity present in the pore water velocity and dispersion coefficient relationship.