• Korean Chemical Engineering Research
• /
• v.49 no.4
• /
• pp.480-484
• /
• 2011

In this study, degumming process was carried out for reducing to less than 10 ppm of phosphorus contents and primary properties of crude canola oil including 0.64 mgKOH/g of acid value, 0.09% of water contents, 0.13% of insoluble impurities, and 40 ppm of phosphorus contents. Efficiency of water degumming and enzymatic degumming was compared for the selection of suitable process obtaining feedstock of biodiesel. Degumming method was determined for preparation of raw material of biodiesel, and reaction conditions were also established. The most effective conditions for water degumming were 2% distilled water (w/w oil), $30^{\circ}C$ of reaction temperature, 900 rpm of agitation speed, and 30 min of reaction time, respectively. In case of enzymatic degumming, optimal conditions were found to be 90 ppm of phospholipase A2 (w/w oil), $50^{\circ}C$ of reaction temperature at pH 5, respectively. When comparing water degumming with enzymatic degumming, efficiency of enzymatic degumming was better than water degumming. However, water degumming method was much more suitable for the production of biodiesel feedstock considering reaction time and process feasibility.

• Korean journal of food and cookery science
• /
• v.4 no.1
• /
• pp.27-32
• /
• 1988

The almost similar degumming effect was obtained by using oxalic acid instead of phosphoric acid, which also improves waste-water treatment. At this point, solution of Phosphoric, Acetic, Citric, Oxalic, and Nitric acid were used for degumming of rapeseed and soybean oil. Compared with Phosphoric(PA) and Oxalic acid(OA) were showed a simillar degumming effect in these vegetable oils. In rapeseed oil of 85% PA treating group and 5,10% OA fretting group, residual soap and phosphorus content in neutralized oil, color in bleached oil, and peroxide value and fatty acid content in deodrized oil were showed to simillar result. Soybean oil as well as rapeseed oil were showed to similar result. As a result, we could comfirmed substitutive possibility, which change PA into OA as a degumming agent. In the other hand, waste waters were obtained from 55% PA treating group and 10% OA treating group. Analytical result for this waste waters has showed a wide difference, especially in the BOD and COD. The amount of treating agents and time required in the precipitation seperation and chemical treatment each 3 and 1.7 times, which is PA treating group than OA treating group. We have investigated both the simillar degumming effect by OA solution and an alternative the pollution program means of a chemical treatment process is not possible.

• 한국신재생에너지학회:학술대회논문집
• /
• 2010.11a
• /
• pp.106.2-106.2
• /
• 2010

동식물성 기름과 메탄올의 전이에스테르화 반응에 의해 생산되는 바이오디젤은 환경친화성과 지속가능성이 인정됨에 따라 그 생산량이 급격히 증가하고 있어 대두유, 유채유, 팜유 등의 원료유 부족과 가격 상승, 수급 불안정 등의 문제가 대두되고 있다. 이를 해결하기 위한 방안으로 유리지방산 함량이 높은 저가유지 자원(폐식용유, 폐돈지, 폐우지, soapstock, trapped grease)과 새로운 오일 작물을 이용한 생산 기술 연구가 활발히 진행되고 있다. 본 연구에서는 비활용 해외 열대작물 씨앗에서 착유한 식물성 오일을 정제하여 바이오디젤 원료유를 생산하는 과정에서 발생하는 폐기물(폐유, 폐수)의 경제적 처리 방안으로 유화유 제조 원료(벙커C유, 물)와 유화유 제조 첨가제(무기계, 유기계)로 활용 가능성을 검토하였다. 열대작물 오일의 물성 분석 결과 고형물, 수분, 인지질(phospholipid), 유리지방산(free fatty acid) 함량이 기존 원료유보다 매우 높게 나타났다. 인지질은 바이오디젤 제조 반응후 에스테르와 글리세린의 층분리를 방해하고 유리지방산은 염기촉매와 결합하여 지방산염을 생성해 생산 수율을 감소시킨다. 고형물과 수분 역시 촉매반응에 악영향을 가지나 여과와 감압증발에 의해 쉽게 제거가 가능하다. 유리지방산은 산촉매 에스테르화 반응에 의해 제거가 가능하다. 인지질은 탈검(degumming) 과정을 통해 제거하며 탈검은 수용성 탈검, 산 탈검, 세정 공정으로 구성된다. 착유한 원료유의 고형물을 제거 후 물과 수세하여 수용성 인지질을 수화하여 층 분리해 제거하고 상층의 오일은 추가적인 산 탈검을 수행한다. 그 뒤 세정을 통해 사용된 탈검제인 산과 추가적으로 수화된 인지질을 제거하게 된다. 이러한 3단계의 탈검 과정에서 하층으로 오일과 물이 폐기물로서 배출되며 본 연구에서는 배출 폐기물을 다시 층분리하여 오일층과 물 층으로 구분하여 유화유 제조에 사용되는 벙커C유, 물, 그리고 기존 유기계 및 무기계 유화제의 대체 가능성을 조사하였다. 유화 연료유는 기름과 물을 균일한 분산상으로 혼합한 연료유로 연소시 오일계 성분의 미연분을 감소시켜 연료 효율 제고와 배출가스 성상을 개선하기 위해 개발되어 왔다. 본 발표에서는 다양한 종류의 상용 첨가제 및 바이오디젤 원료유 생산 폐기물을 활용해 유화 연료유를 제조하였으며 각 유화유의 장시간의 상(phase) 안정성을 비교하였다. 바이오 폐기물 중에는 천연 계면활성제(surfactant)인 인지질이 다량 함유되어 있어 기존의 무기계 및 유기계 유화제보다 상 안정성이 우수하게 나타났으며 바이오디젤 원료유 생산 공정의 폐기물인 폐유과 폐수의 활용이 가능한 것으로 나타났다.

• Journal of the Korean Society of Food Science and Nutrition
• /
• v.20 no.3
• /
• pp.220-224
• /
• 1991

Six reagents (water, citric acid, phosphoric acid, oxalic acid, acetic anhydride and maleic anhydride) were evaluated for their effectiveness is degumming rice bran oil. All chemical reagents tested were found to be significantly more effective than water in removing phosphatides from crude rice bran oil. Especially acetic anhydride and phosphoric acid were effective in reducing phosphorous levels (92.5% and 93.3% removeal, respectively). Nonhydratable phospholipids, lysophosphatidyl choline, were removed more effectively by the chemical reagents than by the water degumming. The major phospholipid(PL) components were phophatidyl choline. Oleic, linolieic and palmitic acids were the major fatty acids of PL in rice bran acetone insolubles(AI). The AI recovered by acetic anhydride degumming produced the most stable emulsions. However, the AI obtained from phophoric acid or oxalic acid treatments had very poor emulsifying properties.

• Korean Journal of Food Science and Technology
• /
• v.20 no.6
• /
• pp.868-872
• /
• 1988

The oxidation behaviour of Pinenut(Pinus Koraiensis S & Z) oil during storage were studied. And the oxidative stability of different oil samples by refining stage were also measured. The oil in whole pinenut or mashed pinenut was very stable during the storage at $35^{\circ}C$ for 10 weeks however, the oxidation rate was enhanced when pinenut oil was extracted and isolated from nut cake. On the other hand, crude oil was most stable and the highly purified pinenut oil was least stable, with other samples being intermediate in stability. The changes of fatty acid composition of various pinenut oil samples during storage were also discussed.

• Korean Journal of Food Science and Technology
• /
• v.17 no.2
• /
• pp.128-130
• /
• 1985

Solutions of 4.8 and 12% oxalic and 85% phosphoric acid were used for degumming of crude rice bran oil. 96.6% of total phosphatides was removed by degumming with either 2ml of 85% phosphoric acid or 20ml of 4% oxalic acid when added to 1kg of crude rice bran oil. Yields after degumming with oxalic and phosphoric acids were 63.6% and 61.0%, respectively.

• Korean Journal of Food Science and Technology
• /
• v.29 no.1
• /
• pp.15-20
• /
• 1997

Changes in antioxidative substances-sesamol, sesamin and sesamolin - and mineral contents of sesame oil during refining processes have been studied to investigate the oxidative stability of oils during the storage at $70^{\circ}C$. Fe, Cu, Mg and Zn were nearly removed from the oil by the degumming process. During storage, the changes of total volatile contents in crude and degummed sesame oil were not noticeable but those in alkali-refined and deodorized sesame oil were increased at early period of the storage. The increases of hexanal and pentanal were most noticeable and their concentration was increased markedly in alkali-refined, bleached and deodorized sesame oil at early period of the storage. During refining processes and storage, sesamin was relatively stable but the content of sesamolin was decreased. The content of sesamol was decreased until alkali-refining process but increased during a bleaching process. The content of sesamolin tended to decrease with increasing of sesamol during storage.

• Applied Biological Chemistry
• /
• v.36 no.4
• /
• pp.284-289
• /
• 1993

The effect of oil refining processes-degumming, alkali-refining, bleaching and deodorizing-on oil characteristics and oxidation stability of sesame oil were investigated. The colors(L, a, b) of samples were markedly changed and their peroxide and acid values were decreased, while the other characteristics of samples were not changed during refining stages. The L values of alkali-refined, bleached and deodorized sesame oils were largely decreased and their a values were increased due to browning reaction during the storage at $70^{\circ}C$. The colors of crude and degmmed sesame oils were very stable and their peroxide, free fatty acid and conjugated dienoic acid values were slowly increased. Volatile carbonyl compounds formed by oxidation were increased during the storage at $70^{\circ}C$. The results indicated that refining processes did not affect the sesame oil characteristics but decreased the oxidation stability of sesame oil.

• Korean Journal of Food Science and Technology
• /
• v.13 no.2
• /
• pp.160-164
• /
• 1981

A study was conducted for process conditions for maximum yield of crude soy lecithins and its quality improvement by solvent extraction. Results indicate that maximum yield of the crude lecithins was obtained by hydration with 3% water at degumming temperature $75^{\circ}C$. On the other hand, water level used for hydration was found to affect the recovery yield of the lecithins more profoundly than the degumming temperature. It was also found that extractions with acetone and 2-propanol increased the phosphatidyl choline content from 19.7% to 28.3% and 58%, respectively.

• Korean Journal of Food Science and Technology
• /
• v.47 no.3
• /
• pp.405-408
• /
• 2015

The deacidified oil obtained from the oleaginous fungus, Mortierella sp. (M-12) was bleached, after degumming, using activated clay under a 50-100 mmHg vacuum. The bleaching conditions were partially optimized as follows: activated clay, 1%, bleaching temperature $90^{\circ}C$, and treatment time 20 min. After bleaching, the color of bleached oil as determined by the Lovibond Tintometer, satisfied the specification for edible fats and oils. The bleaching process also decreased the contents of free fatty acids and phosphorus in the deacidified oil. The acid value of the bleached oil also satisfied the specification for edible fats and oils. It was early shown that the normal bleaching process can be used for the bleaching of heavily-colored microbial lipids for human consumption.