• Title/Summary/Keyword: 탄소 함량

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Synthesis of Sn-GIC for Carbon Electrode of Lithium Ion Battery and Its Electrochemical Characteristics (리튬 이온 전지 탄소부극용 Sn-GIC의 합성과 그 전기화학적 특성)

  • Um, Eui-Heum;Lee, Taeck-Young;Lee, Chul-Tae
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.449-453
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    • 2007
  • Synthesis of Sn-GIC (Graphite intercalated compound) and its electrochemical characteristics were investigated to find a method for enhancing the performance of carbon anode of lithium ion battery. The content of Sn intercalated in graphite interlayer increased with increase of concentration of $SnCl_2$ solution and increase of the heat treatment temperature of dried graphite after dipped in $SnCl_2$ solution, respectively. And initial discharge capacity increased upon increase of intercalated Sn content. Sn-GIC with excellent electrochemical performance, which can be synthesized by heat treatment at $900^{\circ}C$ after dipped in 1.0 M $SnCl_2$ solution, showed 356 mAh/g of initial discharge capacity and 13% of capacity decay after 10 cycles.

Effects of Oxygen on Preparation of TiO2 Thin Films by MOCVD (MOCVD법에 의한 TiO2 박막의 제조에 미치는 산소의 영향)

  • Yu, Seong-Uk;Park, Byeong-Ok;Jo, Sang-Hui
    • Korean Journal of Crystallography
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    • v.6 no.2
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    • pp.111-117
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    • 1995
  • TiO2 thin films were prepared on a (100)silicon wafer using a chemical vapor deposition(CVD) method. The deposition experiments were performed using the TTIP in the deposition temperature ransing from 200 content. The deposition rate of TiO2 was increased with the substrate temperature and the oxygen content. The thickness of the deposited thin film and the compositional analysis of this thin films with theoxygen content were measured using Ellipsometry, SEM and ESCA, respectively. The deposited thin film was composed of a bilayer, external TiO2 and internal Ti. Carbon as a residual impurity was found to remain when zero sccm O2 was purged into a reaction chamber and the composition of the deposited thin film was found to change Ti into TiO in a deeper layer. However, when 600sccm O2 was supplied to a reaction chamber, it has been found to reside less carbon content than without O2. Finally, in the condition of 1200sccm O2, no impurity level of carbon was observed and a deeper layer consisted of the Ti composite, even though the deposited surface was composed of TiO2.

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Economic and Environmental Sustainability Assessment of Livestock Manure Gasification for Fuel Gas Production (축분 가스화를 통한 연료가스 생산 공정의 경제적, 환경적 지속가능성 평가)

  • Ji Hong Moon;Kyung Hwan Ryu
    • Applied Chemistry for Engineering
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    • v.34 no.3
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    • pp.291-298
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    • 2023
  • This research evaluates the sustainability of gasifying livestock manure to produce fuel gas from an economic and carbon emission perspective. The entire process, including gasification, fuel gas purification, and pipeline installation to transport the produced fuel gas to the demanding industrial complex, is analyzed for realistic feasibility. The study is conducted using an ASPEN PLUS simulation with experimental data. The results of the economic and CO2 life cycle assessments confirm that the fuel gas produced from livestock manure is competitive with natural gas despite having a lower calorific value. When used as a fuel with a high hydrogen content, the fuel gas emits less CO2 per calorific value, making it more environmentally friendly. A scenario analysis is also performed to determine the expected economics, with price competitiveness being influenced by several factors. Although a significant decrease in natural gas prices could reduce the price competitiveness of the proposed process, it can still be supported by government policies. The cash flow analysis also confirms the economic viability of the process.

Effect of the Particle Size and Unburned Carbon Content on the Separation Efficiency of Fly ash in the Countercurrent Column Flotation (向流컬럼浮選機에서 石炭灰의 크기 및 未燃炭素 含量이 分離特性에 미치는 영향)

  • 이정은;이재근
    • Resources Recycling
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    • v.9 no.6
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    • pp.36-44
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    • 2000
  • Fly ash was composed of the unburned carbon and mineral particles. The former was able to attach on the bubbles, while the latter was not. Therefore, it was possible to separate the unburned carbon and the mineral from fly ash using the froth flotation process. This study was carried out to evaluate the separation efficiency as a function of the ny ash particle properties in the column flotation. Separation efficiency was analyzed for various size fraction of -38 fm,38~125 fm and 1125 W, and for various fly ash samples containing 7, 11, and 20 wt% unburned carbon. For the size fractions of -38 fm containing 7 wt% unburned carbon, separation efficiency was 86ft, whereas separation efficiency was found to be 74% for the size fraction of +125$\mu\textrm{m}$ containing 20 wt% unburned carbon. The results indicated that separation efficiency increased with the decrease in the particle size and the unburned carbon content of the fly ash.

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Analysis of carbon monooxide in blood for teenagers at Cheongju (청주지역 청소년의 혈액 속 일산화탄소 함량 분석)

  • Kim, Chang Suk;Park, Myong Rae;Ryu, Hae-Ill
    • Analytical Science and Technology
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    • v.18 no.4
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    • pp.287-291
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    • 2005
  • The quantitative contents of carbon monooxide in fresh blood for smokers and nonsmokers were measured by uv-visible spectrophotometric methods on the teenagers and adults. As a result, all blood contained some level of carbon monooxide. Typical teenager nonsmokers had a carbon monooxide level between 2.45 and 2.73%, smokers had a between 7.64 and 8.81%. On the other hand, adult nonsmokers contained carbon monooxide to 3.55% in fresh blood and adult smokers had 10.64%. This means that smokers have more carbon monooxide in blood than nonsmokers at the all ages.

Physiological and Biochemical Responses to Ozone Toxicity in Five Species of genus Quercus Seedlings (참나무속 5종의 오존 독성에 대한 생리생화학적 반응)

  • Kim, Du-Hyun;Han, Sim-Hee;Ku, Ja-Jung;Lee, Kab-Yeon;Kim, Pan-Gi
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.10 no.2
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    • pp.47-57
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    • 2008
  • Physiological and biochemical changes of five species of genus Quercus exposed to ozone fumigation were investigated to assess their tolerance against ozone toxicity. At the end of 150 ppb ozone fumigation, chlorophyll contents, photosynthetic characteristics, malondialdehyde(MDA) and antioxidative enzyme activities were measured in the leaves of five Quercus species(Quercus acutissima, Q. aliena, Q. palustris, Q. serrata, and Q. variabilis). Chlorophyll and carotenoid contents, net photosynthesis and carboxylation efficiency decreased after ozone treatment, indicating that $O_3$-exposed plants underwent physiological inhibition. The reduction rate of total chlorophyll contents and carboxylation efficiency were respectively 15% and 34% for Q. aliena and 38% and 62% for Q. variabilis. The amount of MDA increased with the highest increase rate of 140% in Q. acutissima which also showed the highest increase rate(60%) of superoxide dismutase(SOD). Ascorbate peroxidase(APX) activity increased in Q. variabilis, Q. serrata and Q. acutissima by ozone treatment. Based on our results, ozone tolerance of the five Quercus species was ranked as Q. aliena>Q. palustris>Q. serrata>Q. variabilis>Q. acutissima. We concluded that chlorophyll contents, photosynthesis, MDA content and antioxidative enzymes were the important physiological markers for tolerance against ozone stress, which were closely related with one another.

The effects of carbon sources on antitumor and anticomplementary activities of Ganoderan extracted from the mycelium of Ganoderma lucidum IY009 (Ganoderma lucidum IY009 균사체로부터 추출된 ganoderan의 항암 및 항보체 활성에 미치는 탄소원의 영향)

  • Han, Man-Deuk;Lee, June-Woo;Jeong, Hoon;Chung, Sung-Kyun;Lee, Seung-Yong;Yoon, Kyung-Ha
    • The Korean Journal of Mycology
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    • v.23 no.3 s.74
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    • pp.209-225
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    • 1995
  • Ganoderan, antitumor ${\beta}-glucan$ from Ganoderma lucidum was extracted from the mycelium of G.lucidum IY009 which was cultured in various carbon sources. The mycelium was shown to be capable of utilizing various carbon sources, e.g., soluble starch, fructose and glucose, and differs in morphology on carbon sources. In radioisotope assay, about $5.2{\sim}16%$ of glucose was to be incorporated in ganoderan of the mycelium. The monosugars of these ganoderan were mainly consisted of glucose, mannose, galactose. The galactose was not good carbon source for growing the mycelium but the best carbon source for producing the potentialized-ganoderan on the antitumor and anticomplementary activity. The tumor inhibition ratio of ganoderan-GAL, obtained from galactose medium, was 83.6% at the dose of 20 mg/kg/day. This crude polysaccaride was composed of five monosaccharide and the protein contained 16 amino acids. Also, ganoderan-GAL increased the anticomplementary activity than that obtained from any other media. This fact suggests that the structural differences of ganoderan influence the antitumor and anticomplementary activity.

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Characteristics of Coal Methanation in a Hydrogasifier (수소가스화기에서 석탄의 메탄화 반응 특성)

  • Lee, S.H.;Yoon, S.J.;Choi, Y.C.;Kim, J.H.;Lee, J.G .
    • Korean Chemical Engineering Research
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    • v.44 no.6
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    • pp.631-635
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    • 2006
  • To investigate the characteristics of substitute natural gas (SNG) production from direct coal methanation, the continuous lab-scale entrained flow hydrogasifier (I.D. : 0.025 m, Height : 1.0 m) was used in this experiment. The hydrogasification system consisted of high pressure gas handling system, high pressure coal feeder, entrained flow hydrogasifier, and unreacted char separator. The experiment was performed at the various conditions of reaction temperature ($600{\sim}800^{\circ}C$), $H_2$/coal ratio (0.2~0.4), and coal feed rate (0.8~2.5 g/min). Although it was shown that carbon conversion was different trends with coals from the methanation results for 6 sample coals, the carbon conversion increased with increasing reaction temperature. And it increased with increasing H2/coal ratio, whereas the concentration of CH4 decreased. Also. the carbon conversion increased with the carbon content of coal sample and had a maximum value at volatile matter content of 35 wt%.

A Study on Iron-manufacture Method through Analysis of Ironware excavated from Byeokje, Goyang (고양 벽제 제철 유구 출토 철기의 분석을 통한 제철방법 연구)

  • Lim, Ju-Yeon;Kim, Soo-Ki
    • Journal of Conservation Science
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    • v.28 no.4
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    • pp.367-376
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    • 2012
  • The ironware production technology is a measure to fathom the society's level of development in time. To understand iron-manufacure methods in the past, various investigations on the fine structures and additions of ironware remains and Iron ingot have been conducted in a way of natural science. This study metallurgically reclassifies remains excavated in iron-manufacture remains located in Beokje, Goyang, which are thought to be in time of Goryeo Dynasty, and draws an inference from the element analysis on the iron-manufacture and smelting technology. Iron ingot samples with a cast iron structure are divided into those with a white cast iron structure and those with a grey cast iron rich in P. The P content of grey cast iron appeared to be the result of adding a flux agent like lime, iron ingot and carbon steel iron ingot with a cast iron structure excavated in the area is regarded as pig iron which was made without a refining process. In this study it seems that two methods of making ironware were used in the area; one is the method of making ironware by pouring cast iron to the casting, and the other is the method of making carbon steel through the refinement of pig iron. It appears that highly even steel structure of carbon steel and a small amount of MnS inclusion are very similar with that of the modern steel to which Mn is artificially added. Nevertheless, these data alone cannot be used to determine the source of Mn in the carbon steel of the excavated from the iron-manufacture remains, which raises the need for further studies on the source and the possibility of carbon steel via the iron-manufacture process of cast iron.

Effects of Carbon and Nitrogen Sources on the Essential Oil Production and Its Composition in Callus Culture of Mentha piperita L. (탄소와 질소원이 박하정유와 정유성분에 미치는 영향)

  • Oh, Byuong-In;Chae, Young-Am
    • Korean Journal of Medicinal Crop Science
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    • v.1 no.1
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    • pp.58-62
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    • 1993
  • The effects of carbohydrate sources(sucrose, glucose) and ratio of ammonia to nitrate on essential oil production and its com- positions in the callus culture of Mentha piperita L. were studied. An ammonia : nitrate ratio of 1 :2 was more effective for essential oil production regardless of the media used ; Lin-Staba(LS) and modify Murashige-Skoog(MS) medium. Menthol biosynthesis was enhanced when ratio of ammonia to nitrate was 1 :3 in the LS medium while the ratio was 1 :2 in the MS medium. Lower sucrose concentration(20g /1 ) was much better than higher sucrose concentration(30g /1) for both oil and menthol biosynthesis in the LS medium but higher sucrose concentration(30g /1) was more effective for those in the MS medium. When sucrose was replaced with glucose, menthol biosynthesis was sharply decreased or absent regardless of media used.

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