• Applied Chemistry for Engineering
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• v.33 no.6
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• pp.630-635
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• 2022

Copper(II) oxide (CuO), electroless plated on a nitrogen-containing carbon sponge prepared by a melamine sponge thermal treatment, was developed as a nitric oxide (NO) gas sensor that operates without a wafer. The CuO content on the surface of the carbon sponge increased as the plating time increased, but the content of nitrogen known to induce NO gas adsorption decreased. The untreated carbon sponge showed a maximum resistance change (5.0%) at 18 min. On the other hand, the CuO plated sample (CuO30s-CS) showed a maximum resistance change of 18.3% in 8 min. It is considered that the improvement of the NO gas sensing capability was caused by the increase in hole carriers of the carbon sponge and improved movement of electrons due to CuO. However, the NO gas detection resistance of the CuO electroless plated carbon sponge for 60 s decreased to 1.9%. It is considered that the surface of the carbon sponge was completely plated with CuO, resulting in a decrease in the NO gas adsorption capacity and resistance change. Thus, CuO-plated carbon sponge can be used as an effective NO gas sensor because it has fast and excellent resistance change properties, but CuO should not be completely plated on the surface of the carbon sponge.

• Composites Research
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• v.35 no.6
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• pp.394-401
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• 2022

Two polymer precursors, polyvinylidene chloride-resin (PVDC-resin) and polyvinylidene fluoride (PVDF), are assembled into the microporous carbon by pyrolysis. Microporous carbon is advantageous as an electrode for supercapacitors that store electric charges through ion adsorption/desorption. The pyrolysis also turns the various heteroatoms of two precursors into functional groups, contributing to the additional charge storage. The analysis of the porous structure and function group during carbonization are important to develop the carbon for energy storage. Here, we analyzed the functional groups of two polymer-derived carbons through X-ray photoelectron spectroscopy. The electrochemical properties of the functional groups were explored in various pH electrolytes. The specific capacitance of two carbons in the acidic electrolyte (1 M H₂SO₄) was improved compared to that in the neutral electrolyte (0.5 M Na₂SO₄) due to the faradaic charge/discharge reaction of the quinone functional group. In particular, the carbon electrode derived from PVDC-resin exhibits a lower capacity than the carbon from PVDF due to the small micropores. In the alkaline electrolyte (6 M KOH), the highest specific capacitance and rate capability were obtained among the three electrolytes for both electrodes based on the facile adsorption of the constituent electrolyte ions (K⁺, OH^-).

• Korean Chemical Engineering Research
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• v.61 no.4
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• pp.576-583
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• 2023

This study aimed to investigate the impact of enhancing the electrode conductivity and mitigating the production of hydrogen peroxide - a by-product arising from lactate oxidation - on the performance of lactate electrodes. The electrical conductivity of the electrode was improved by modifying the surface of carbon paper with single-walled carbon nanotubes. Catalase was introduced to effectively eliminate the hydrogen peroxide produced during the lactate oxidation reaction. The carbon paper electrode, with simultaneous immobilization of both lactate oxidase and catalase, yielded a current 1.7 times greater than the electrode where only lactate oxidase was immobilized. The electrode in which lactate oxidase and catalase were co-immobilized on the surface of carbon paper modified with single-walled carbon nanotubes, produced a current of 171 µA, which was more than twice as much current as the carbon paper with only lactate oxidase immobilized. The optimized electrode showed a linear response up to lactate concentration of 20 mM, confirming that it can be used as a sensor electrode.

• Journal of Advanced Technology Convergence
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• v.2 no.4
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• pp.13-19
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• 2023

Following the signing of the Paris Agreement on Climate Change (UNFCCC, 2015), the world is expanding greenhouse gas reduction activities through comprehensive participation that includes not only developed countries but also developing countries. Major countries around the world are placing high expectations on the effectiveness of total carbon emissions regulation through the carbon emissions market. However, in order to obtain carbon credits, third-party verification is required based on quantitative carbon reduction data. Accordingly, in this paper, we developed an AIoT high-efficiency street light for carbon emissions and conducted a performance analysis study to measure the luminous efficiency of the lighting fixture. To obtain carbon emissions rights, we used high-efficiency LED PKG, developed our own high-voltage PFC, and developed high-efficiency lighting fixtures capable of communication. For communication, the 2.4GHz LoRa method was adopted between the lighting fixture and the gateway. Lens design was conducted through simulation of Korea Expressway Corporation's standard streetlight types A, B, and C. The performance of the streetlight was verified as being more efficient than other existing products through the measurement of luminous efficiency by an accredited rating agency, and it is expected that carbon emissions rights will be obtained by reducing electrical energy through this.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2012.05a
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• pp.463-464
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• 2012

• 한국전기화학회:학술대회논문집
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• 2005.07a
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• pp.71-74
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• 2005

• Proceedings of the Korean Vacuum Society Conference
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• 2002.02a
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• pp.146-146
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• 2002

• Proceedings of the Korean Vacuum Society Conference
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• 2001.07a
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• pp.43-43
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• 2001

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.04a
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• pp.71-72
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• 2006

• Proceedings of the Membrane Society of Korea Conference
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• 2004.11a
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• pp.169-171
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• 2004