• Title/Summary/Keyword: 탄소입자

Search Result 646, Processing Time 0.035 seconds

탄소나노튜브 나노유체의 파울링 현상에 따른 열적 특성에 대한 연구

  • Mun, Ji-Eun;Kim, Yeong-Hun;Kim, Nam-Jin
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2016.02a
    • /
    • pp.383.1-383.1
    • /
    • 2016
  • 열전달 시스템에서 임계 열유속 발생 시 시스템의 물리적 손상을 야기하기 때문에 비등 열전달에서 임계 열유속은 열전달 시스템의 한계 또는 안전성을 나타낸다. 따라서 열전달 시스템의 안정성을 위해서는 임계 열유속 향상이 필수적이다. 최근에는 나노유체를 열전달 시스템에 적용할 경우 임계 열유속이 증가한다고 보고되었다. 하지만 나노유체는 원전 및 각종 열전달 시스템에 적용 시 나노입자가 열전달 표면에 침착되는 파울링 현상을 발생시킬 수 있으며, 이 때문에 시스템의 열효율이 크게 감소할 수 있다. 따라서 본 연구에서는 열전달 시스템에 나노유체를 적용했을 때, 나노유체의 침착현상이 시스템에 미치는 영향을 분석하였다. 그 결과 유속과 코팅시간이 증가할수록 산화처리된 다중벽 탄소나노튜브 나노유체의 임계 열유속이 크게 증가하고 있음을 확인할 수 있다. 하지만 나노입자 침착정도와 유속이 증가할수록 비등 열전달 표면과 유체의 포화온도의 차이인 과열도가 상당히 크게 증가함을 알 수 있었으며, 열전달 계수는 순수 물의 0 m/s의 비등 열전달 계수와 비교하면 감소하는 것을 확인하였다.

  • PDF

Elasto-Plasticity of Granular Micro-Structures (미소구조에서의 탄소성모델)

  • Park Jae-gyun
    • Journal of the Computational Structural Engineering Institute of Korea
    • /
    • v.18 no.4 s.70
    • /
    • pp.453-458
    • /
    • 2005
  • This study deals with elasto-plasticity of granular micro-structures which recovers continuum elasto-plasticity in its counterpart. The theory is based on doublet mechanics that assumes particles of finite size and connecting linear springs, and it makes extensions to plasticity. The result shows that the micro model has one to one relationship with the continuum model in the simplest case. Micro-strain and micro-stress of two dimensional plane stress problem were calculated, which shows the behavior of the specimen and verifies the effectiveness of this model.

A study on the formation region, droplet size and stability of O/W microemulsion (O/W형 microemulsion의 생성영역과 입자크기 및 안정성에 관한 연구)

  • Jo, Ju-Yeong;Han, Chang-Gyu;Jo, Chun-Gu
    • Journal of the Society of Cosmetic Scientists of Korea
    • /
    • v.21 no.2
    • /
    • pp.22-48
    • /
    • 1995
  • This study was investigated to search for the effects of the structure of each component in four-component O/W microemulsion system on its formation region, droplet size and stablilty. The results was that the more number of OH site, the shorter carbon chain length of polyol, the larger formation region of microemulsion was showed. The small microemulsion droplet was obtained on condition that the polatry of oil was large and carbon chain length of hydrophobic group of surfactant was long. In using satrated hydrocarbon (such as liquid paraffin, squalane) as dispersed phase, the stability of microemulsion was better than aromatic oil phase.

  • PDF

Preparation of Monosized Titanium Dioxide Powder from TEOT (TEOT로부터 TiO₂단분산 분말 합성에 관한 연구)

  • 안영필;최석홍
    • Journal of the Korean Ceramic Society
    • /
    • v.25 no.5
    • /
    • pp.50-50
    • /
    • 1988
  • The controlled Ti(CO2H5)4 hydrolysis reactions for the synthesis of Spherical Monodispersed Titania powders are described. Increasing the concentration of TEOT and the molar ratio of water to TEOT in alcohol solution decrease the reaction time and the particle size. The reaction time is delalyed by increasing the chain length and the number of carbon branches of alcohol as a solvent. The prepared powders with an average diameter of 0.8μ and the spherical monodispersed transfer to Rutile phase at 550℃.

Soil Carbon and Microbial Activity Influenced by Pasture and Rice Paddy Management (목초재배지 및 벼논 관리 변화에 따른 토양 탄소 및 미생물 활성도)

  • Yoo, Ga-Young;Kim, Hyun-Jin;Kim, Ye-Sol;Jung, Min-Hung
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.45 no.3
    • /
    • pp.435-443
    • /
    • 2012
  • This study investigated soil carbon storage and microbial activities influenced by different management practices in rice paddies and pastures. Soils under a single-crop farming of rice (CON) and rice-Italian ryegrass rotation farming (IRG) were compared in Jangheung, Jeollanam-do, Seocheon and Cheonan, Chungcheongnam-do. Soils from pastures were analyzed to investigate the effect of duration period (P1, P2, P3) in Namwon, Jeollabuk-do and Seosan, Chungcheongnam-do. In rice paddy, total and particulate carbon (PC) concentrations in the IRG soils were significantly higher than those in the CON soils both in Jangheung and Seocheon where the IRG has been established for three years, whereas carbon concentrations were not significantly different in Cheonan where IRG planting history is only one year. In rice paddy soils, PC was suggested as an early indicator to monitor changes in soil carbon storage followed by adopting different management practices. In pasture, total and PC concentrations increased with duration period especially in the 0-5 cm soils. Contrary to the rice paddy soils, the magnitude of change in PC concentration is not as great as that in total carbon concentration, implying that there is a need to develop a new early indicator other than PC using different fractionation scheme. The soil carbon storage in pasture also increased with years since establishment and the increasing rate was significantly greater in the early stage (0-5 yrs) than the later one (> 5 yrs). Microbial activities measured from fluorescein diacetate (FDA) hydrolysis analysis were significantly lower in the IRG soils than CON soils, whereas no difference was observed in the pastures of different ages. This shows that FDA activity is not a sensitive indicator to differentiate soil qualities influenced by management practices if it is used by itself.

Selection of the Best Oxygen Carrier Particle for Syngas Fueled Chemical-Looping Combustor (합성가스 연소 매체순환식 가스연소기 적용을 위한 최적 산소공여입자 선정)

  • Ryu, Ho-Jung;Kim, Ji-Woong;Jo, Wan-Kuen;Park, Moon-Hee
    • Korean Chemical Engineering Research
    • /
    • v.45 no.5
    • /
    • pp.506-514
    • /
    • 2007
  • To select the best oxygen carrier particle for syngas fueled chemical-looping combustor, the reduction reactivity and carbon deposition characteristics were determined in a thermogravimetric analyzer. Four kinds of oxygen carrier particles (NiO/bentonite, $NiO/LaAl_{11}O_{18}$, $Co_xO_y/CoAl_2O_4$, $NiO/NiAl_2O_4$) were tested with the simulated syngas (30% $H_2$, 10% $CO_2$, 60% CO) as a reduction gas. With each of these particles, the maximum conversion and oxygen transfer capacity increase with increasing the reduction temperature At the given experimental range, the optimum operating temperature to maximize oxygen transfer rate is found to be $900^{\circ}C$ and carbon deposition on the particles could avoid at the temperature above $800^{\circ}C$. Among four kinds of oxygen carrier particles, the NiO-based particles exhibits better reactivity than the CoO-based particle. Moreover, the NiO/bentonite particle produces the best reactivity based on the oxygen transfer rate and the degree of carbon deposition. The measured oxygen transfer rate increases as the metal oxide content in NiO/bentonite particle is increased thereby higher metal oxide contents could provide stable operation of chemical-looping combustor.

Study on the Effect of Physical Properties of Fuels on the Anode Reaction in a DCFC System (연료의 물리적 특성과 직접탄소연료전지의 연료극 반응성에 관한 연구)

  • Ko, Tae-Wook;Ahn, Seong-Yool;Choi, Gyung-Min;Kim, Duck-Jool
    • Journal of Energy Engineering
    • /
    • v.20 no.4
    • /
    • pp.309-317
    • /
    • 2011
  • The effect of physical properties of coal fuels and carbon particle on performance of DCFC (Direct Carbon Fuel Cell) was investigated. Shenhua and Adaro were selected as coal fuel and carbon particle was used for comparing with coal. The Ultimate, proximate, SEM, XRD, and BET analysis of samples were conducted. The component of char was more important than that of raw coal because the operating temperature of reactor is higher than devolatilization region of coal. The surface area and volume of pores affected significantly the performance of the system than content of fixed carbon or char rates. The performance of DCFC with carbon particle was in proportional to working temperature.

Single Particle Analysis of Aerosols collected at Seoul, CheongJu, and ChunCheon, Using Low-Z Electron Probe X-ray Microanalysis (Low-Z Electron Probe X-ray Microanalysis를 이용한 서울, 청주, 춘천의 입자상 물질 분석)

  • ;;;;R. Van Grieken
    • Proceedings of the Korea Air Pollution Research Association Conference
    • /
    • 2001.11a
    • /
    • pp.307-308
    • /
    • 2001
  • 본 연구는 서울, 청주, 춘천 세 개 도시 대기에서의 입자상 물질에 대한 분석을 Electron Probe X-ray Microanalysis(EPMA)를 이용한 단일 입자 분석법으로 행하였다. 단일 입자 분석법은 개개 입자의 형상과 크기 그리고 화학 조성에 대한 정보를 동시에 제공하기 때문에 개개 입자의 생성, 이동, 반응 그리고 환경에의 영향에 대한 자세한 정보를 얻을 수 있다. 또한 최근에 개발된 ultrathin window를 장착한 EPMA 분석법(Low-Z EPMA)은 종래의 통상적인 EPMA 방법으로는 분석하기 어려웠던 탄소, 질소, 산소 등의 원소를 정량적으로 분석할 수 있다. 따라서 도시 대기의 중요 구성 입자상 물질인 황산염, 질산염, 암모늄염, 유기 입자 등도 포함하여 도시 대기 입자 분석에 유용하게 활용된다. (중략)

  • PDF