• Title/Summary/Keyword: 탄소입자

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Seasonal Variations of Particle Fluxes in the Bransfield Strait, Antarctica (남극 브랜스필드 해협에서 입자 플럭스 계절변화)

  • Kim, Dong-Seon;Kim, Dong-Yup;Kim, Young-June;Kang, Young-Chul
    • Ocean and Polar Research
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    • v.24 no.2
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    • pp.153-166
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    • 2002
  • Particle fluxes were measured by using time-series sediment traps in the Bransfield Strait from December 27th, 1999 to December 26th, 2000. Total mass fluxes showed distinct seasonal variations with high fluxes in the austral summer and low fluxes in the austral winter at a 678m water depth in the eastern Bransfield Strait, while they were high only in January and fairly low in other months at a 960m water depth in the central Bransfield Strait. The reason that total mass fluxes occurred only in January at a 960m water depth in the central Bransfield Strait seems to be the strong current in the surface waters, which leads to a substantial amount of terrestrial materials and locally produced organic matter being advected away from the mooring site. Total mass fluxes were very high from January to October at a 1678m water depth in the eastern Bransfield Strait, while they were high only in January and February at a 1860m water depth in the central Bransfield Strait. The fact that total mass fluxes were higher at the deep water in the both sites than at the intermediate water depth may reflect that a substantial amount of terrestrial and organic materials are laterally transported by strong tidal current from the shallow environments to the deep basins.

고 분산성 자성 나노유체의 열전도도 및 점성

  • Seo, Yong-Jae;Lee, Hyo-Suk;Jo, Guk;Gil, Dae-Seop;Jeong, Gyeong-U;Ju, Myeong-Eun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.4.2-4.2
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    • 2010
  • 최근 열전달율을 획기적으로 향상시킬 수 있는 고 열전도성 나노유체가 주목을 받고 있다. 고 열전도성 나노유체는 액상보다 열전도도가 수백~수만 배 높은 고상의 금속 또는 비금속 나노입자를 물이나 오일 등에 미량 균일하게 분산시킴으로써 기존의 유체가 가지지 못한 높은 열전도율과 분산안정성을 갖는 기능성유체를 말한다. 고 열전도성 나노유체는 기존 냉각시스템에서 냉각유체만 교체할 경우에도 열전달 효율을 20% 이상 향상시킬 수 있는 저비용 고효율작동 유체이다. 이 나노유체는 발전설비, 공조설비, 에너지 산업, 석유화학, 화학공업, 제철산업, 가정용 냉난방설비, 자동차 등 산업 전 분야의 열교환시스템에 활용이 가능하다. 따라서 고 열전도성 나노유체는 종래 열효율의 한계를 돌파할 수 있는 에너지 이용 효율 향상 기술의 패러다임을 바꿀 혁신적인 신소재로 여겨지고 있다. 그러나 현재까지 개발된 나노유체는 초기 열전도 특성은 우수하나 장기간 분산안정성이 확보되지 않아 시간이 경과함에 따라 열전도도가 점점 감소하는 경향을 보인다. 또한 탄소나노튜브를 분산한 나노유체의 경우와 같이 유체의 점도가 크게 증가하여 실제 산업에 적용 시 커다란 동력손실을 초래할 수 있으며 열교환시스템에 파울링이 발생할 소지가 크다. 이러한 문제점을 해결하기 위해서는 나노유체에서 열전달이 일어나는 메커니즘이 규명되어야 하지만 아직 명확한 이론이나 가설이 정립되어 있지 않다. 이 논문에서는 나노유체가 높은 열전도율을 보이는 현상을 설명할 수 있는 몇 가지 이론을 살펴 보고 지금까지 개발된 안정성이 아주 높은 나노유체의 열전도 특성을 비교 분석하여 획기적인 열전도성 나노유체 개발 가능성을 살펴보고자 한다. 이를 위해 나노입자의 조성, 유체 내 농도 및 자기장 등이 나노유체의 열전도율에 미치는 영향을 연구하였다.

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The Effect of Cleaning the Intake System of LPG Vehicles on Engine and Emissions (LPG차량 흡기계통 Cleaning이 엔진 및 배출가스에 미치는 영향)

  • Hong, Sung-In;Lee, Seung-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.3
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    • pp.1229-1235
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    • 2014
  • At the LPG vehicle air intake system, most of dust particles in the air cleaner are removed. However very small particles are not removed and accumulated. The accumulation of carbon in air intake system is going to affect the idle speed control and sensor signal. It also causes engine chattering and transmission troubles of automatic transmission. This is study about cleaning up intake system using cleaning chemical. We can clean up the intake system by spraying cleaning liquid onto intake device when the engine is idling after intake hose is removed from warmed up vehicle. We can obtain the following experimental results by cleaning up ISC, surge tank, intake manifold, intake valves and combustion chamber. According to this results, the stroll valve works correctly and power rate of engine is up to the standard, it is smoothy to control the idling speed when a vehicle pulls up. After cleaning up CO grow down about 0.15%, HC does about 20~100 ppm.

Water Lubrication Characteristics and Effect of Nano Particles based on the Substrate (기판 종류에 따른 물 윤활 특성 및 나노 입자의 영향)

  • Kim, Hye-Gyun;Kim, Tae-Hyung;Kim, Jongkuk;Jang, Young-Jun;Kang, Yong-Jin;Kim, Dae-Eun
    • Tribology and Lubricants
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    • v.33 no.6
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    • pp.245-250
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    • 2017
  • In this work, we examine pure water and water with nanoparticles to investigate water lubrication characteristics and the effect of nanoparticles as lubricant additives for different substrates. We test carbon-based coatings and metals such as high-speed steel and stainless steel in pure deionized (DI) water and DI water with nanoparticles. We investigate water lubrication characteristics and the effect of nanoparticles based on the friction coefficient and wear rate for different substrates. The investigation reveals that nanoparticles enhance the friction and wear properties of high-speed steel and stainless steel. The friction coefficient and wear rate of both high-speed steel and stainless steel decreases in DI water with nanoparticles compared with the results in pure DI water. The presence of nanoparticles in water show good lubricating effect at the contact area for both high-speed steel and stainless steel. However, for carbon-based coatings, nanoparticles do not improve friction and wear properties. Rather, the friction coefficient and wear rate increases with an increase in the concentration of nanoparticles in case of water lubrication. Because carbon-based coatings already have good tribological properties in a water environment, nanoparticles in water do not contribute toward improving the friction and wear properties of carbon-based coatings.

은 도핑 효과를 이용한 그래핀 투명 전도성 필름의 전기적 특성 향상

  • Jeong, Sang-Hui;Lee, Su-Il;Kim, Yu-Seok;Song, U-Seok;Kim, Seong-Hwan;Cha, Myeong-Jun;Park, Sang-Eun;Min, Gyeong-Im;Park, Jong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.566-566
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    • 2012
  • 그래핀(Graphene)은 모든 탄소 동소체의 기본구성 요소로 2 차원 결정구조를 가지며, 양자홀 효과(quantum Hall effect), 뛰어난 열 전도도, 고 탄성, 광학적 투과성 등과 같은 탁월한 물리적 성질을 보이는 물질이다. 이러한 그래핀의 우수한 특성은 전계 효과 트랜지스터(field effect transistor), 화학/바이오 센서, 투명 전극(transparent electrode) 등의 다양한 전자소자를 개발하는 응용 가능하다. 그 중, 그래핀 투명전극의 제조는 가장 응용가능성이 높은 분야이다. 현재 투명전극 물질로는 인듐-주석 산화물(indium tin oxide; ITO)가 널리 이용되고 있으나, 인듐의 고갈로 인한 공급부족 문제 및 고 생산비용, 휘어지지 않는 취성 등의 단점을 지니고 있다. 따라서, 우수한 광학적 투과성과 전기전도성을 지닌 그래핀이 ITO의 대체 물질로서 각광받고 있다.[1-5] 본 연구에서는 그래핀의 투명전도필름의 응용을 위해 면저항을 낮추기 위한 방법으로 화학적 도핑(doping)을 이용하였다. 그래핀은 구리(copper; Cu) 호일을 촉매로 사용하여 열 화학증착법(Thermal Chemical Vapor Deposition)을 이용하여 합성하였다. 합성된 그래핀은 PMMA(Poly(methyl methacrylate)) 전사법을 이용하여 산화실리콘(SiO2) 기판에 전사 후, 염화은(AgCl)과 클로로벤젠(C6H5Cl)으로 만든 콜로이드(colloid) 용액에 디핑(dipping)하여 그래핀에 은 입자를 도핑 하였다. 그 결과, 은 입자 도핑 농도에 따라 면저항이 감소하는 양상을 보였다. 제작된 그래핀 투명전도성 필름의 투과도는 자외선-가시광선-근적외선 분광법(UV-Vis-NIR spectroscopy)를 이용하여 측정하였고, 라만 분광법(Raman spectroscopy)을 통해 그래핀 필름의 질적 우수성과 성장 균일도를 조사하였다.

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A Study on the Desulfurization and Demineralization by Chemical Treatment of Petroleum Cokes (Petroleum Cokes의 화학적 처리에 의한 황성분 및 회분제거에 관한 연구)

  • Han, Woong;Lee, Si-Hyun;Park, Chu-Sik;Yang, Hyun-Soo
    • Applied Chemistry for Engineering
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    • v.7 no.6
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    • pp.1115-1124
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    • 1996
  • An MCL(Molten Caustic Leaching) treatment is a chemical refinery process which is used for the desulfurization and demineralization by alkali treatment. The MCL treatment removes ash by converting mineral like Si, Fe, V, Ni etc. in petroleum cokes into soluble salts. The MCL has an advantage minimizing carbon loss in comparison to other desulfurization process. Reaction variables for the desulfurization and demineralization in the study were leaching temperature, leaching time, ratio of caustic to cokes, acid concentration and time for washing, and particle size. At the optimum condition, above 99% of desulfurization and about 90% of demineralization was obtained. FT-IR and SEM analysis showed that the structure and surface of the particle was closely related with the degree of sulfur and ash removal, and leaching temperature as well.

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Smoke Characteristics of a Small Scale Pool Eire (작은 풀화재에서의 연기 특성)

  • Lee Eui-Ju;Ahn Chan-Sol;Shin Hyun-Joon;Oh Kwang-Chul;Lee Uen-Do
    • Fire Science and Engineering
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    • v.19 no.3 s.59
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    • pp.58-63
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    • 2005
  • Experimental measurements of flames and the product properties were performed for small kerosene pool fires. which is widely used as a fire source of laboratory scale experiments with scaling modeling. The flame length and flickering frequency were investigated for the flame structures, and compared with the theory. Three measurement methods were introduced to clarify the smoke characteristics, i.e. various gas concentrations, smoke density and thermophoretic sampling with transmission electron microscopy (TEM). The yield of carbon dioxide and the consumption of oxygen were proportional to the heat release rate of pool fires, but there is no trend on carbon monoxide emission. Smoke density of turbulent flames was exponentially increased with the heat release rate. The morphology of the soot particle was investigated to address the degree of soot maturing. The results show that the similar smoke morphology between an inverse jet flame and a pool fire exists despite of different combustion controlling mechanisms.

Experimental of Absorption Performance Enhancement for Binary Nanofluids($NH_3/H_2O$ + Nano Particles) (이성분 나노유체($NH_3/H_2O$+나노입자)의 흡수성능 촉진실험)

  • Lee, Jin-Ki;Jung, Chung-Woo;Koo, June-Mo;Kang, Yong-Tae
    • Proceedings of the SAREK Conference
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    • 2008.06a
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    • pp.124-129
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    • 2008
  • The objectives of this paper are to examine the effect of nano-particles on the pool type absorption heat transfer enhancement and to find the optimal conditions to design a highly effective compact absorber for $NH_3/H_2O$ absorption system. The effect of $Al_2O_3$ and CNT particles on the absorption performance is studied experimentally. The experimental ranges of the key parameters are 20% of $NH_3$ concentration, $0{\sim}0.08%$ (volume fraction) of CNT particles, and $0{\sim}0.06%$ (volume fraction) of $Al_2O_3$ nano-particles. For the $NH_3/H_2O$ nanofluids, the heat transfer rate and absorption rate with 0.02 vol% $Al_2O_3$ nano-particles were found to be 28.9% and 17.8% higher than those without nano-particles, respectively. It is recommended that the concentration of 0.02 vol% of $Al_2O_3$ nano-particles be the best candidate for $NH_3/H_2O$ absorption performance enhancement.

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The variation of aerosol optical depth over the polar stations of Korea (남북극 과학기지에서의 에어로졸 광학 깊이 변동성)

  • Koo, Ja-Ho;Choi, Taejin;Cho, Yeseul;Lee, Hana;Kim, Jaemin;Ahn, Dha Hyun;Kim, Jhoon;Lee, Yun Gon
    • Particle and aerosol research
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    • v.13 no.4
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    • pp.141-150
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    • 2017
  • Using the NASA's Modern-Era Retrospective Analysis for Research and Applications, version 2 (MERRA-2) reanalysis for aerosol optical depth (AOD) and satellite-observed carbon monoxide (CO) data, we examined the basic pattern of AOD variations over the three polar stations of Korea: Jangbogo and King Sejong stations in the Antarctica, and Dasan station in the Arctic area. AOD values at King Sejong and Dasan station show the maximum peaks in spring, which looks associated with the high amount of atmospheric CO emitted from the natural burning and the biomass burning. Jangbogo station shows the much less AOD compared to other two stations, and seems not strongly affected by the transport of airborne particles generated from mid-latitude regions. All three polar stations show the AOD increasing trend in general, indicating that the polar background air quality becomes polluted.

Spatial Analysis of Major Atmospheric Aerosol Species Using Earth Observing Satellite Data (지구관측 위성자료를 이용한 주요 대기 에어러솔 성분의 공간분포 분석)

  • Lee, Kwon-Ho
    • Journal of the Korean Association of Geographic Information Studies
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    • v.14 no.2
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    • pp.109-127
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    • 2011
  • Atmospheric aerosols, small particles in the atmosphere, are one of the important parameters in climate change and human health. Additionally, accurate estimates of aerosol species are increasingly important in environmental impact assessment studies. Recent advances in global satellite remote sensing provide powerful tool for air quality monitoring. This study explores the potential usage of satellite derived data such as atmospheric aerosols for air quality monitoring as well as climate change study. The objectives of this study is to understand the general features of the global distribution of type dependent aerosols. A detailed spatio-temporal variability of the each different satellite dataset shows the variation of the global zonal average and specific geographical regions where the strong emission sources are located. Especially, significantly large aerosol amounts are observed in Asia and Africa because of the desert dust storm, anthropogenic and biomass burning emissions.