• Title/Summary/Keyword: 탄소성 영역

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Study on the Performance and Emission Characteristics of a DI Diesel Engine Operated with LPG / Bio-diesel Blended Fuel (LPG/바이오디젤 혼합연료를 사용하는 직접분사식 디젤엔진의 성능 및 배기특성에 관한 연구)

  • Lee, Seok-Hwan;Oh, Seung-Mook;Choi, Young;Kang, Kern-Yong
    • Journal of the Korean Institute of Gas
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    • v.14 no.1
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    • pp.8-14
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    • 2010
  • In this study, we experimentally investigated a compression ignition engine operated with Bio-diesel blended LPG fuel. In particular, the performance, emissions characteristics (including total hydrocarbon, carbon monoxide, nitrogen oxides, and carbon dioxides emissions), and combustion stability of a CI engine fueled with Bio-diesel blended LPG fuel were examined at 1500 rpm. The percentage of Bio-diesel in the fuel blend ranged from 20-60%. The results showed that stable engine operation was possible for a wide range of engine loads up to 40% Bio-diesel by mass. When the Bio-diesel content was increased, leading to a decrease in the lower heating value of the blended fuel, the cetane value increased, resulting in a advanced start of heat release. Exhaust emission measurements showed that THC and CO emissions were increased when using the blended fuel at low engine speeds due to partial burn from over-mixing. NOx emission was emitted less at lower loads and more at higher loads.

Study of CO2 Absorption in Forest by Airborn LiDAR Data (LiDAR 자료를 이용한 산림 CO2 흡수량 산출 연구)

  • Go, Sin Young;Park, Jung Gi;Cho, Gi Sung
    • Journal of Korean Society for Geospatial Information Science
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    • v.21 no.4
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    • pp.29-35
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    • 2013
  • Generally, Calculation of carbon dioxide absorption in the forest area is calculated using the information of the forest, such as tree height and DBH(Diameter of Breast Height). Tree height and DBH of these are obtained using the remote sensing data such as imagery and information of local forest survey. However, Mixed forest with a high proportion of field survey to lower the accuracy of forest information. In this study, vertical structure of the tree were identified by applying region growing method based on the slope using LiDAR data and height and number of the tree were identified by applying extracting top of the tree algorithm. Through the vertex tree extraction algorithm to identify height of tree and the number of individuals, substitute this for the DBH relation formula which is drawn from data through field surveys. In this, a quantitative calculation of carbon dioxide absorption were able to calculate the basic data. Also, carbon dioxide absorption of three type trees were calculated and average per unit area of carbon dioxide absorption were able to estimate.

Investigation of plasma effect for defect-free nitrogen doping of graphene

  • Lee, Byeong-Ju;Jeong, Gu-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.211.2-211.2
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    • 2016
  • 그래핀은 본연의 우수한 물성으로 인하여 전자소자, 에너지 저장매체, 유연성 전도막 등 다양한 분야로의 응용가능성이 제기되었으나, 실제적인 응용을 위해서는 구조적인 결함을 최소화하며, 특성을 자유로이 제어하거나 향상시키는 공정의 개발이 요구된다. 특히 그래핀을 전자소자로 응용하기 위해서는 전기적 특성을 제어하는 것이 요구된다. 일반적으로 화학적 도핑은 그래핀의 전기적 특성을 제어하는 효율적인 방법으로 알려져 있다. 화학적 도핑은 그래핀을 구성하는 탄소원자를 이종원자로 치환하거나 표면에 흡착시켜 기능화 된 그래핀을 얻는 방법으로, 특정 가스 분위기에서 고온 열처리하거나 활성종들이 존재하는 플라즈마에 노출시키는 방법이 제시되었다. 특히 플라즈마를 이용한 도핑방법은 저온에서 단시간의 처리로 도핑이 가능하고, 플라즈마 변수를 변경하여 도핑정도를 수월하게 제어할 수 있다는 장점을 가지고 있다. 그러나 플라즈마내의 극성을 띄는 다양한 활성종들의 충돌효과로 인하여 구조적인 손상이 발생하여 오히려 특성이 저하될 수 있어 이를 고려한 플라즈마 공정조건의 설정이 필수적이다. 따라서 본 연구에서는 플라즈마에 노출된 그래핀의 Raman 특성을 고찰함으로써 화학적 도핑과 구조적인 결함의 경계를 확립하고 구조결함의 형성을 최소화한 효율적인 도핑조건을 도출하였다. 그래핀은 물리적 박리법을 이용하여 300 nm 두께의 실리콘 산화막이 존재하는 실리콘 웨이퍼 위에 제작하였으며, 평행 평판형 직류 플라즈마 장치를 이용하여 전극의 위치, 인가전력, 처리시간을 변수로 암모니아($NH_3$) 플라즈마를 방전하여 그래핀의 Raman 특성변화를 관찰하였다. 그래핀의 구조적 결함 및 도핑 효과는 라만 스펙트럼의 D, D', 2D밴드의 강도와 G밴드의 위치와 반치폭(Full width at half maximum; FWHM)의 변화를 통해 확인하였다. 그 결과, 인가전력과 처리시간에 따라 결함형성과 질소도핑 영역이 구분 가능함을 확인하였으며, 이를 바탕으로 결함형성을 최소화한 효율적인 도핑조건이 접지전위, 0.45 W의 인가전력, 처리시간 10초이며, 최적조건에서 계산된 도핑레벨은 $1.8{\times}10^{12}cm^{-2}$임을 확인하였다.

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A Study on Electromagnetic Wave Absorbing Sandwich Structures (샌드위치 구조를 갖는 전자기파 흡수체에 관한 연구)

  • Park, Ki-Yeon;Lee, Sang-Eui;Kim, Chun-Gon;Lee, In;Han, Jae-Hung
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.6
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    • pp.64-71
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    • 2004
  • The object of this study is to design the Radar Absorbing Structures (RAS) having sandwich structures in the X-band ($8.2{\sim}12.4GHz$) frequencies. Glass fabric/epoxy composites containing conductive carbon blacks and carbon fabric/epoxy composites were used for the face sheets. Polyurethane(PU) foams containing multi-walled carbon nanotube (MWNT) were used for the core. Their permittivities in the X-band were measured using the transmission line technique. The reflection loss characteristics for multi-layered sandwich structures were calculated using the theory of transmission and reflection in a multi-layered medium. Three kinds of specimens were fabricated and their reflection losses in the X-band were measured using the free space technique. Experimental results were in good agreements with simulated ones in 10dB absorbing bandwidth.

Evaluation and Application of T-Ray Nondestructive Characterization of FRP Composite Materials (FRP 복합재료의 T-Ray 비파괴특성 평가 및 적용)

  • Im, Kwang-Hee;Hsu, David K.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.5
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    • pp.429-436
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    • 2010
  • Recently, (terahertz ray) applications have emerged as one of the most promising new powerful nondestructive evaluation (NDE) techniques. In this study, a new T-ray time-domain spectroscopy system was utilized for detecting and evaluating layup effect and flaw in FRP composite laminates. Extensive experimental measurements in reflection and thru-transmission modes were made to map out the T-ray images. Especially this was demonstrated in thick GFRP laminates containing double saw slots. In carbon composites the penetration of terahertz waves is limited to some degree and the detection of flaws is strongly affected by the angle between the electric field(E-field) vector of the terahertz waves and the intervening fiber directions. The artificial defects investigated by terahertz waves were bonded foreign material, simulated disbond and delamination and mechanical impact damage. The effectiveness and limitations of terahertz radiation for the NDE of composites are discussed.

Electromagnetic Interference Shielding of Carbon Fibers-Reinforced Composites (탄소섬유강화 복합재료의 전자파 차폐특성)

  • 심환보;서민강;박수진
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.860-868
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    • 2000
  • In this work, the electro-magnetic interference (EMI) characteristics of PAN-based carbon fibers-reinforced composites are investigated with difference to manufactural parameters, i.e., fiber grade, fiber orientation angle, and laminating method. As a result, EMI shielding effectiveness (SE) of the composites greatly depends on a fiber orientation in composite angle. Especially, the fiber grade affects SE of composites in case of orientation angle of 0$^{\circ}$. Then the SE become greater as the change of electric character according to the arrangement directions, i.e., electrical anisotropy in the same constituent materials. This is due to the skin effect which is represented in the surface of electro-magnetic wave in high-frequency range. In all cases according to lamination methods, the composites represents SE of 83~98% over. Whereas, in symmetric and unsymmetric laminate structures, the SE decreases slightly as the laminate angles of composites increases. On the contrary. the repeating laminates structure shows the opposite tendency. Especially, 90$^{\circ}$ repeating laminate structure shows the SE more than 90% over the measuring frequency.

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Earth Pressure Distribution with Rigid Retaining Wall Movements (강성토유벽의 움직임에 따른 토압분포)

  • 강병희;채승호
    • Geotechnical Engineering
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    • v.5 no.1
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    • pp.47-60
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    • 1989
  • Lateral earth Pressure distributions due to the ,randy soil backfill behind the rigid vertical walls for three different wall movement modes are obtained by the elasto-plastic finite element analys of soil deformation, and these earth pressures are compared with both Rankine's and Dubrova's active earth pressures. Thereby, the effects of the magnitude and the mode of wall displacement on the earth pressure distribution are investigated. Three different modes of wall movement considered in this study are the rotation about bottom, the rotation about top and the translation. For the case of the wall rotation about top, the earth pressure distribution is shown as a reverse S-curve-shaped distribution due to the arching effect. Consequently, the point of application of the lateral thrust is much higher than one-third of the wall height from the base. And, comparing the other modes of wall movement, the magnitude and the point of appliestion of the lateral thrust for the wall rotation about top are larger and higher, respectively. The wedge-shaped plastic zone in the backfill at active failure is developed only for the mode of wall rotation about bottom. The lateral earth pressure distributions on the walls with inclined backfill of several different slopes are shown for the mode of wall rotation about bottom.

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Analysis of solar power generation efficiency through spatiotemporal analysis of solar radiation on the Korean Peninsula using GK2A (천리안2위성을 활용한 한반도 일사량의 시공간적 분석을 통한 태양광 발전 효율 분석)

  • Hwang, Seunghyun;Baik, Jongjin;Kim, Hyeonjoon;Byun, Jongyun;Cha, Hoyoung;Jun, Changhyun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.457-457
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    • 2022
  • 최근 기후변화로 인한 위기가 인류의 생존을 위협하면서 전 지구적으로 기후변화에 대응하기 위한 탄소 중립 대책을 모색하고 있으며, 지속가능한 신재생에너지에 대해 주목하고 있다. 산업통상자원부는 2034년까지 총 발전량 중 신재생에너지의 비율을 25.8%까지 증가시키는 것을 목표로 신재생에너지의 발전 비율을 증가시키기 위한 다양한 노력을 기울이고 있다. 특히, 신재생에너지 중 가장 많은 비중을 차지하고 있는 태양광 발전은 비교적 광범위한 부지를 필요로 하고 있으며, 환경 및 지형적 영향이 크게 작용하는 만큼 발전 시설 부지 선정 및 운용 계획을 위한 면밀한 분석이 필수적이다. 그러나, 태양광 발전 활용 계획을 수립하기 위해 고려할 수 있는 지상 관측 일사량 및 일조량 데이터는 상당히 제한적이며 관측 밀도가 조밀하지 않다는 한계점이 있다. 본 연구에서는 천리안위성의 후속으로 발사된 천리안2위성의 산출물인 일사량 데이터를 활용하여 한반도 영역에서의 일사량에 대한 시·공간적 분석을 수행하였으며, 이를 기반으로 각 지역적 특성을 파악하고, 토지 피복 유형에 따른 태양광 발전의 효율 정도를 분석·평가하였다. 본 연구의 결과는 계측 지역 및 미계측 지역에서의 시공간적인 태양광 에너지의 효율성에 대한 정보를 제공함에 따라 태양광 발전을 위한 관련 시설물들의 최적 설치 위치 및 규모 등에 대한 설계 기준 마련에 활용될 수 있을 것으로 판단된다.

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A Study on the Field Application of High Strength Joint Buried Pile Retaining Wall Method (고강도 결합 매입말뚝 흙막이 공법의 현장적용성 검토에 관한 연구)

  • Lee, Gwangnam;Kim, Daehyeon
    • The Journal of Engineering Geology
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    • v.32 no.4
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    • pp.671-684
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    • 2022
  • This study verified the stability of a high-strength combined buried pile retaining wall and its applicability in the field. A cast-in-place (C.I.P) retaining wall and the high-strength combined embedded pile retaining wall were compared and analyzed numerically. The numerical analysis assessed the ground behavior and stability (and thus field applicability) of a high-strength combined buried pile retaining wall using data measured in the field. The experimental results showed that the cross-sectional force and displacement of the high-strength bonded pile retaining wall were reduced by 13.6~19.7%, the shear force increased by 0.7~4.7%, and the bending moment increased by 4.5~8.8% relative to the values for the C.I.P retaining wall. Examination of the amount of subsidence in the ground around the excavation showed that the maximum settlement of the C.I.P retaining wall was 46.89 mm and that at the high-strength combined buried pile retaining wall was 39.37 mm. Overall, designing a high-strength combined embedded pile retaining wall by applying the maximum bending moment and shear force calculated using the elastic beam method to the site ground was shown to achieve the safety of all members, as member forces were generated within the elastic region.

Nucleophilic Substitutions at a Carbonyl Carbon Atom (ⅩⅡ). Solvolysis of Methylchloroformate and Its Thioanalogues in $CH_3CN-H_2O$ and $CH_3COCH_3-H_2$ Mixtures (카르보닐탄소원자의 친핵성 치환반응 (제 12 보).아세토니트릴-물 및 아세톤-물 혼합용 매속에서 메틸클로로훠메이트와 그 티오유도체들의 가용매분해반응에 관한 연구)

  • Sangmoo La;Kyeong Shin Koh;Ikchoon Lee
    • Journal of the Korean Chemical Society
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    • v.24 no.1
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    • pp.8-14
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    • 1980
  • Solvolysis rate constants for methylchloroformate, $CH_3O$(CO)Cl, methylthiono-chloroformate, $CH_3O$(CS)Cl, and methylthiolchloroformate, $CH_3S$(CO)Cl, have been determined conductometrically in acetone-water and acetonitrile-water mixtures, and activation parameters, ${\Delta}H^{\neq}$ and ${\Delta}S^{\neq}$, have been derived. Results show that in water-rich regions the order of rate increases as $$CH_3O(CO)Cl while in dipolar aprotic solvent-rich region this order reverses. The plots of log k vs. solvent parameters, Y, $\frac{D-1}{2D+1}$ and log($H_2$) show that the order of rate increase in water-rich region is the results of increase in $S_N1$ character. It is concluded that $CH_3S$(CO)Cl solvolyzes via $S_N1$ mechanism whereas $CH_3O$(CO)Cl reacts via $S_N2$ and $CH_3O$(CS)Cl via intermediate mechanism in water-rich region.

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