• Title/Summary/Keyword: 탄성안정

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Ti-50.4 at% Ni 합금의 형상기억특성에 미치는 냉간가공률의 영향

  • Go, Won-Gi;Kim, Jae-Il;Park, Su-Ho;Kim, So-Jin;Kim, Hyeon;Lee, Gi-Yeong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.106.2-106.2
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    • 2012
  • Ti-Ni합금은 CsCl구조의 B2상, monoclinic 구조의 B19'(M)상과 rhombohedral 구조의 R상(R)이 나타난다고 알려져 있고, 이들 상의 변태에 의해 열탄성 마르텐사이트와 응력유기 마르텐사이트에 의한 형상기억효과와 초탄성 효과를 가지고 있다. 또한 Ti-Ni 합금은 우수한 형상기억특성을 가질 뿐만 아니라 생체적합성, 가공성 및 내식성 등이 뛰어나 공업분야 및 생체분야에서 폭 넓게 활용되고 있다. Ti-Ni합금의 형상기억특성은 냉간가공 후 어닐링 처리의 온도와 시간에 따른 matrix 내 Ni의 농도, 석출물의 밀도와 크기, 전위밀도와 전위주위의 응력장에 의해 영향을 받는다고 알려져 있다. 본 연구에서는 Ti-Ni합금의 형상기억 특성 및 변태온도에 미치는 영향을 조사하기 위해 다양한 냉간가공률의 시료를 제작하여 다양한 온도에서 Annealing 처리를 하여 냉간가공률 및 Annealing 온도가 형상기억특성에 미치는 영향을 조사하였다. Ti-50.4 at.% Ni 합금은 진공 아크 용해로에서 용해 하였으며, 용해된 Ingot는 열간단조 및 열간 압출한 후 냉간 인발과 중간온도에서 어닐링을 반복하면서 직경 0.5mm의 선재로 만들었다. 최종적으로 제작한 선재의 냉간가공률은 9.5%, 18.2%, 34.5%, 45% 이었다. 각 시편은 5X10-5torr의 진공으로 석영관에 진공 봉입하여 각각 673K, 723K, 783K에서 1hr 열처리 하였다. 합금의 형상기억특성과 변태온도는 DSC에 의해 조사되었다. DSC 측정 결과, 냉간가공률이 증가함에 따라 마르텐사이트 변태 온도는 감소하였고, 어닐링 온도가 증가함에 따라 마르텐사이트 변태 온도는 증가하였다. 또한 가공률이 증가하여도 R상 변태온도는 큰 변화가 없었고, Annealing온도가 증가함에 따라 R상 변태온도는 감소하였다. 또한, 형상기억특성은 인장시험기를 이용한 정하중 열싸이클 테스트를 이용하여 평가 하였다. 냉간 가공률이 증가함에 따라 안정한 형상기억특성을 나타내었다.

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Studies on the Preparation of Anion Exchange Membrane through Blending of the Poly(ethylenimine) and the Poly(vinyl alcohol) (폴리비닐알코올과 폴리에틸렌이민과의 혼합을 통한 음이온교환막의 제조 연구)

  • Kim, Sung-Pyo;Kim, Baek-Kyun;Lee, Hak-Min;Rhim, Ji-Won;Jeong, Sung-Il
    • Membrane Journal
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    • v.20 no.4
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    • pp.335-341
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    • 2010
  • This study focuses on the investigation of the anion exchange membrane through blending poly(ethylenimine) (PEI) and poly(vinyl alcohol) (PVA) varying the mixing ratio. To characterize the resulting membranes, the water content, contact angle, FT-IR, thermal gravimetric analysis, ion exchange capacity, ion conductivity and elastic modulus were measured. The PVA / PEI = 90 / 10 membrane showed the ion conductivity, $5.16{\times}10^{-2}S/cm$ and simultaneously the contact angle, $78.3^{\circ}$. According to TGA measurement, the resulting membranes seemed durable at room temperature. Through the modulus test, the mechanical properties increased with increasing PVA content and apparently the membranes looked very robust.

An Experimental Study about appling non-Exposure waterproofing method which combines the Cement Polymer Modified Waterproof Membrane coating and Self adhesive Rubberized Asphalt sheet to the Roof Structure. (무기질계 탄성 도막재와 자착식 고무 아스팔트 시트를 결합한 지붕구조물 비노출 방수공법에 관한 실험적 연구)

  • Moon, You-Seok;Lee, Sun-Gyu;Song, Je-Yeong;Gwak, Gyu-Seong;Oh, Sang-Keun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.613-616
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    • 2008
  • This study is about appling non-exposure waterproofing method which combines the Cement Polymer Modified Waterproof Membrane coating and Selfadhesive Rubberized Asphalt sheet to the Roof Structure, Because there are a lot of problems in previous methods. So We had the performance tests using waterproofing method which combines two materials, and we analyzed the results. This study showed us very important results. We had bond strength test and tensile test under high, normal and low temperature, and the results were successful. And we also tested for coping with crack and movement. We found that tested materials were safe in those conditions. I think that Non-Exposure waterproofing method which combines the Cement Polymer Modified Waterproof Membrane coating and Selfadhesive Rubberized Asphalt sheet is available to concrete structure.

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Preparation and Characterization of the Impregnation to Porous Membranes with PVA/PSSA-MA for Fuel Cell Applications (연료전지 응용을 위한 다공성막에 친수성 고분자의 함침을 통한 고내구성 이온교환막의 제조 및 특성 연구)

  • Lee, Bo-Sung;Jung, Sun-Kyoung;Rhim, Ji-Won
    • Polymer(Korea)
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    • v.35 no.4
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    • pp.296-301
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    • 2011
  • This study focuses on the investigation of the impregnation of poly (vinyl alcohol) (PVA) crosslinked with poly(styrene sulfonic acid-co-maleic acid) (PSSA-MA) to porous polyethylene membrane for the fuel cell application. The membranes were characterized by the measurements of the water content, contact angle, FTIR spectra, thermal gravimetric analysis, ion exchange capacity, proton conductivity, methanol permeability and elastic modulus. The existence of hydrophilic moieties in the impregnated membranes was confirmed by contact angle and FTIR measurements. The impregnated PVA/PSSAMA(90:10) membrane exhibited a higher ion exchange capacity (1.2 meq./g dry membrane) than Nafion membrane (0.91 meq./g dry membrane). Through the elastic modulus measurement, the dimensional stability of the resulting membranes was expected to increase higher than the polyethylene membranes. The methanol crossover and water content decreased even if the PSSA-MA content increased due to the reduction of the free volume.

A Study on the Crack Response and Waterproof Properties of High-Functional Water-Based Acrylic Paints for Exterior Walls (고기능성 외벽용 수성 아크릴계 도료의 균열 대응성 및 방수 특성 평가 연구)

  • Kim, Yong-Ro;Ko, Hyo-Jin;Park, Jin-Sang;Kim, Dong-Bum;Lee, Sang-Wook
    • Journal of the Korea Institute of Building Construction
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    • v.21 no.6
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    • pp.593-604
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    • 2021
  • In this study, a comparative test was conducted on a specially developed elastic waterproof paint and general water-based paint for the purpose of responding to cracks occurring on the outer wall of concrete structures and improving watertightness. Through the comparative experiment, it was confirmed that the watertightness could be improved by securing the crack shielding property, and it was also confirmed that about 10 times more crack responsiveness was secured compared to general water-based paint. In addition, it was confirmed that the adhesion performance of at least 1.3MPa and resistance to a water permeation pressure of 0.1MPa were possible, confirming that stability was secured from a waterproofing perspective.

Static Behavior of Concrete-Filled and Tied Steel Tubular Arch(CFTA) Girder (CFTA거더의 정적 거동연구)

  • Kim, Jong-In;Kim, Doo-kie;Lee, Jang-hyeong;Kim, Jeong-Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.3 s.55
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    • pp.225-231
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    • 2009
  • This study introduces the CFTA girder(Concrete-Filled and Tied Steel Tubular Arch Girder) which is a combined structural system of traditional CFT, arch, and prestress structures. Static load tests and structural behavior analyses were carried out for a 25m long CFTA girder. In the analysis, each load of 58kN, 88kN, 148kN, 207kN,and 298kN was applied incrementally at the positions of 1.0 m distances in both directions from the center of the girder. On each test, strain and displacement were measured. Linear static FEM analyses using Strand7 code were also performed to check the structural stability and to investigate the effects of prestressing(${\pm}$20%) and material property(Young's modulus) on the displacement and strain. The results of this study are summarized as follows: the initial strain & displacement under selfweight and prestressing were influenced with the variation of prestressing, but they were mainly effected only by Young's modulus when additional loads were applied.

Cellular Protective Effect and Liposome Formulation for Enhanced Transdermal Delivery of Persicaria hydropiper L. Extract (여뀌 추출물의 세포 보호 작용과 피부 흡수 증진을 위한 리포좀 제형 연구)

  • Kim, Jung-Eun;Lee, Hye-Jin;Lim, Myoung-Sun;Park, Min-A;Park, Soo-Nam
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.38 no.1
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    • pp.15-31
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    • 2012
  • In our previous studies, the antioxidant, anti-aging, and antibacterial activities of Persicaria hydropipier L. extract, and the moisturizing effect of cream containing P. hydropipier extract were investigated. In this study, the cellular protective effects of P. hydropipier extract and isoquercitrin, main component from P. hydropipier in $^1O_2$-induced photohemolysis of human erythrocytes and ultraviolet B (UVB)-exposed HaCaT cells were investigated. Liposomes such as ethosome and elastic liposome for enhanced transdermal delivery were prepared. Size, loading efficiency, stability, and cumulative permeated amounts of ethosomes and elastic liposomes were evaluated. P. hydropipier extract and isoquercitrin showed more prominent cellular protective effect than (+)-${\alpha}$-tocopherol, known as lipid antioxidant at $5{\mu}g/mL$. P. hydropipier extract didn't show any characteristics of cytotoxicity at $50{\mu}g/mL$. When HaCaT cells were exposed to a single large dose ($400mJ/cm^2$) of UVB, the extract protected the cells against UVB radiation in a concentration dependent manner ($12.5{\sim}50{\mu}g/mL$). Cell viability of HaCaT cells exposed to UVB $400mJ/cm^2$ was increased by treatment with P. hydropipier extract or isoquercitrin from 36 % (cell viability of positve control groups) to 90 % (cell viability of P. hydropipier extract or isoquercitrin- treated groups). The size of 0.04 % P. hydropiper extract loaded ethosomes was 173.0 nm and the loading efficiency was 55.58 %. 0.04 % P. hydropiper extract loaded ethosomes were stable with as monodisperse particles for 1 week. The ethosome exhibited more skin permeability than general liposome and ethanol solution. The optimal ratio of lipid to surfactant ($Tego^{(R)}$ care 450) of 0.1 % P. hydropiper extract loaded elastic liposomes was observed to be 95 : 5. Vesicle size of 0.1 % P. hydropiper extract loaded elastic liposome was 176.5 nm. The deformability index of the elastic liposome was 16.4. The loading efficiency was 68.8 %. The elastic liposome containing P. hydropiper extract showed more skin permeability than liposome without surfactant ($Tego^{(R)}$ care 450).

Case study on the lake-land combined seismic survey for underground LPG storage construction (LPG 지하저장기지 건설을 위한 수륙혼합 탄성파탐사 사례)

  • Cha Seong-Soo;Park Keun-Pil;Lee Ho-Young;Lee Hee-Il;Kim Ho-Young
    • 한국지구물리탐사학회:학술대회논문집
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    • 2002.09a
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    • pp.101-125
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    • 2002
  • A lake seismic survey was carried out to investigate possible geohazards for construction of the underground LPG storage at Namyang Lake. The proposed survey site has a land-lake combined geography and furthermore water depth of the lake is shallow. Therefore, various seismic methods such as marine single channel high resolution seismic reflection survey, sonobuoy refraction survey, land refraction survey and land-lake combined refraction survey were applied. Total survey amounts are 34 line-km of high resolution lake seismic survey, 14 lines of sonobuoy refraction survey, 890 m of land refraction survey and 8 lines of land-lake combined refraction survey. During the reflection survey, there were severe water reverberations from the lake bottom obscured subsurface profiling. These strong multiple events appeared in most of the survey area except the northern and southern area near the embankment where seems to be accumulated mainly mud dominated depositions. The sonobuoy refraction profiles also showed the same Phenomena as those of reflection survey. Meanwhile the results of the land-lake combined refraction survey showed relatively better qualities. However, the land refraction survey did not so due to low velocity soil layer and electrical noise. Summarized results from the lake seismic survey are that acoustic basement with relatively flat pattern appeared 30m below water level and showed three types of bedrock such as fresh, moderately weathered and weathered type. According to the results of the combined refraction survey, a velocity distribution pattern of the lake bottom shows three types of seismic velocity zone such as >4.5 km/s, 4.5-4.0km/s and <4.0km/s. The major fault lineament in the area showed NW-SE trend which was different from the Landsat image interpretation. A drilling was confirmed estimated faults by seismic survey.

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A Feasibility Study of AMT Application to Tidal Flat Sedimentary Layer (갯벌 지역의 하부퇴적층에 대한 AMT 탐사의 적용 가능성 평가)

  • Kwon, Byung-Doo;Lee, Choon-Ki;Park, Gye-Soon;Choi, Su-Young;Yoo, Hee-Young;Choi, Jong-Keun;Eom, Joo-Young
    • Journal of the Korean earth science society
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    • v.28 no.1
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    • pp.64-74
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    • 2007
  • The marine seismic prospecting using a research vessel in the shallow sea near the coastal area has certain limits according to the water depth and survey environment. Also, for the electrical resistivity survey at seashore area, one may need a specially designed high-voltage source to penetrate the very conductive surface layer. Therefore, we have conducted a feasibility study on the application of magnetotelluric method (MT), a passive geophysical method, on investigating of shallow marine environment geology. Our study involves both theoretical modeling and field survey at the tidal flat area which represent the very shallow marine environment. We have applied the audio-frequency magnetotelluric (AMT) method to the intertidal deposits of Gunhung Bay, west coast of Korea, and analysed the field data both qualitatively and quantitatively to investigate the morphology and sedimentary stratigraphy of the tidal flat. The inversion of AMT data well reveals the upper sedimentary layer of Holocene intertidal sediments having a range of 13-20 m thickness and the erosional patterns at the unconformable contact boundary. However, the AMT inversion results tend to overestimate the depth of basement (30-50 m) when compared with the seismic section (27-33 m). Since MT responses are not significantly sensitive to the resistivity of middle layer or the depth of basement, the AMT inversion result for basement may have to be adjusted using the comparison with other geophysical information like seismic section or logging data if possible. But, the AMT method can be an effective alternative choice for investigating the seashore area to get important basic informations such as the depositional environment of the tidal flat, sea-water intrusion and the basement structure near the sea shore.

Geophysical Evidence Indicating the Presence of Gas Hydrates in a Mud Volcano(MV420) in the Canadian Beaufort Sea (캐나다 보퍼트해 진흙화산(MV420) 내 가스하이드레이트 부존을 지시하는 지구물리학적 증거)

  • Yeonjin Choi;Young-Gyun Kim;Seung-Goo Kang;Young Keun Jin;Jong Kuk Hong;Wookeen Chung;Sung-Ryul Shin
    • Geophysics and Geophysical Exploration
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    • v.26 no.1
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    • pp.18-30
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    • 2023
  • Submarine mud volcanos are topographic features that resemble volcanoes, and are formed due to eruptions of fluidized or gasified sediment material. They have gained attention as a source of subsurface heat, sediment, or hydrocarbons supplied to the surface. In the continental slope of the Canadian Beaufort Sea, mud volcano exists at various water depths. The MV420, is an active mud volcano erupting at a water depth of 420 meters, and it has been the subject of extensive study. The Korea Polar Research Institute(KOPRI) collected high-resolution seismic data and heat flow data around the caldera of the mud volcano. By analyzing the multi-channel seismic data, we confirmed the reverse-polarity reflector assumed by a gas hydrate-related bottom simulating reflector(BSR). To further elucidate the relationship between the BSR and gas hydrates, as well as the thermal structure of the mud volcano, a numerical geothermal model was developed based on the steady-state heat equation. Using this model, we estimated the base of the gas hydrate stability zone and found that the BSR depth estimated by multi-channel seismic data and the bottom of the gas hydrate stability zone were in good agreement., This suggests the presence of gas hydrates, and it was determined that the depth of the gas hydrate was likely up to 50 m, depending on the distance from the mud conduit. Thus, this depth estimate slightly differs from previous studies.