• Journal of the Korean Recycled Construction Resources Institute
• /
• v.5 no.3
• /
• pp.239-246
• /
• 2017

RC(Reinforced Concrete) structures can keep their performance during intended service life through initial service life and extension of the life through repairs. In the deterministic repairing method, cost and the related $CO_2$ emission increase with step-shaped escalation, however continuous results can be obtained through probabilistic repairing technique, and this is capable of reducing $CO_2$ emission through $CO_2$ absorption. In the work, repairing timing and $CO_2$ emission/absorption are evaluated based on the different methods like deterministic and probabilistic manner. The probabilistic technique considering $CO_2$ absorption with carbonation progress is evaluated to be very effective to reduction of $CO_2$ emission through extension of initial and additional service life due to repairs. When the variations of the service life from initial construction and repair material can be determined, the proposed technique can contribute to reduction of cost and $CO_2$ with decreasing repairing number.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.2 no.2
• /
• pp.135-143
• /
• 2004

An experimental study on the sorption of U(VI) onto a Korean granite was performed as a function of the geochemical parameters such as contact time, pH, ionic strength, and carbonate concentration using a batch procedure. The distribution coefficient,$K_d$, was about 1-200 mL/g depending on the experimental conditions. The sorption of U(VI) onto granite particles was greatly dependent upon the contact time, pH, and carbonate concentration, but insignificantly dependent on the ionic strength. It was noticed that the sorption of U(VI) onto granite particles was highly correlated with the uranium speciation in the solution, which was dependent on the pH and carbonate concentrations. It was deduced from the kinetic sorption experiment that a two-step first-order kinetic behavior could dominate the kinetic sorption of U(VI) onto granite particles. In the alkaline range of a pH above 7, U(VI) sorption was greatly decreased and this might be due to the formation of anionic U(VI)-carbonate aqueous complexes as predicted by the speciation calculations.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.18 no.7
• /
• pp.714-719
• /
• 2017

The controlled synthesis of inorganic materials with a specific size and morphology is an important factor in the development of new materials in many fields, such as nanoparticles, medicine, electronics, semiconductors, pharmaceutical sand cosmetics. Solution crystallization is one of the most widely used separation processes in the chemical and pharmaceutical industries. Calcium carbonate has attracted a great deal of attention in industry because of its numerous applications. The mean crystal size, crystal size distribution and morphology are important factors in the continuous crystallization process. In this study, the continuous crystallization of calcium carbonate by the calcium chloride process was investigated. The mean crystal size and crystal size distribution data were obtained by a particle size analyzer. The morphological imaging of the crystalswasper formed by SEM. Under steady state operation, the mean crystal size change was small, but increasing the input concentration and mixing rate increased the crystal size. In this operation, some aragonite was found, but the main crystal phase was calcite.

• Journal of the Korean Geotechnical Society
• /
• v.27 no.5
• /
• pp.75-84
• /
• 2011

There are some kinds of microorganisms within soils which can precipitate some minerals such as calcite under suitable conditions. Such precipitated calcites within pores of soil may reduce permeability and also cement soil particles. In this study, whether such microorganisms can fill pores within soil and increase the strength is investigated. Basillus pasteurii was repeatedly injected into weakly cemented sand with 3% cement ratio up to 10 times for 20 days. Then, cemented sand injected with microorganisms was tested for an unconfined compressive strength and evaluated for filling voids between soil particles. The unconfined compressive strength of one time injected specimen showed a 5% increase compared to untreated specimen. However, for more than two times the strength of injected specimens gradually decreased up to 50% of the untreated specimen by microorganisms. As the number of microorganism injection increased, the amount of calcite precipitation slightly increased within voids. However, over-precipitated calcites may result in strength decrease of slightly cemented soils.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.1 no.3
• /
• pp.173-180
• /
• 2013

This paper is to investigate an effect of waste cooking oil(WCO) on the engineering properties and durability of high volume admixture concrete. Fly ash with 30% and blast furnace slag with 60% were incorporated in OPC to fabricate high volume admixture concrete with 0.5 of W/B. Emulsified refining cooking oil(ERCO) was made by mixing WCO and emulsifying agent to improve fluidity. ERCO was replaced by cement from 0.25 to 1.0%. As results, the increase of ERCO resulted in decrease of slump and air contents. For compressive strength, the use of ERCO led to decrease the compressive strength at 28 days, while it had similar strength or much higher strength than plain concrete at 180 days. Resistance to carbonation and chloride penetration was improved with the increase of ERCO contents due to decreased pore distribution by saponification between ERCO and concrete, while freeze-thaw resistance was degraded due to air loss.

• Journal of Adhesion and Interface
• /
• v.14 no.4
• /
• pp.175-182
• /
• 2013

In this work, we aim to investigate the specific gravity, thermal, and mechanical property changes of solid-state extruded polypropylene (PP)/calcium carbonate composites before and after orientation. For this work, we prepared $PP/CaCO_3$ composites having two different sizes (OM-1 and OM-10). On increasing the filler content, the specific gravity of the composites increases. The specific gravity of the oriented specimen containing filler in PP matrix is found to be much smaller than that of pre-specimen due to the formation of more microvoids. The presence of microvoids in case of oriented composite specimen significantly affected the tensile and flexural properties of the composites. It was observed that the effect of orientation on both flexural strength and modulus is much stronger than the effect of filler contents, regardless of the filler particle size.

• Applied Chemistry for Engineering
• /
• v.31 no.3
• /
• pp.258-266
• /
• 2020

The chemical fixation of CO₂ into cyclic carbonates is considered to be one of the most promising way to alleviate global warming and produce fine chemicals. In this work, the catalytic applicability of metal-organic frameworks (MOFs) as porous crystalline materials for the synthesis of five-membered cyclic carbonate from CO₂ and epoxides was reviewed. In addition, we have briefly classified the materials based on their different structural features and compositions. The studies revealed that MOFs exhibited good catalytic performance towards cyclic carbonate synthesis because of the synergistic effect between the acid sites of MOFs and nucleophile. Moreover, the effect of structure of designed MOFs and mechanism for the cycloaddition of CO₂ were suggested.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.27 no.6
• /
• pp.303-308
• /
• 2017

The $FeCl_3$ waste solution used to etch various metals contains valuable metal such as nickel. In this study, we recovered as high purity nickel carbonate crystalline powders from nickel-containing etching waste solution after regeneration of iron chloride. Firstly we eliminated about of the iron impurities under the condition of pH 4 using 5 % NaOH aqueous solution and then removed the remaining impurities such as Ca, Mn and Zn etc. by using solvent extractant D2EHPA (Di-(2-ethylhexyl) phosphoric acid). Thereafter, nickel carbonate powder having a purity of 99.9 % or more was obtained through reaction with sodium carbonate in a nickel chloride solution.

• Journal of the Korean Chemical Society
• /
• v.27 no.3
• /
• pp.178-182
• /
• 1983

The conductances of sodium, potassium, ammonium, tetramethylammonium, and tetraethylammonium iodides, picrates(Pic) of sodium and potassium, and tetrabutylammonium tetraphenyl-boride have been measured in ethylene carbonate-acetone mixtures at $25{\circ}C$. The limiting equivalent conductances of the electolytes were computed by Fuoss-Kraus equation and the order was $(C_4H_9)_4NB(ph)_4 at any composition of the mixtures. The dissociation constants of the salts showed that the mixtures are good ionizing solvents for the salts. The order of limiting ionic equivalent conductance, $Na^+, is consistent with exactly the reverse order found for solvation number. Effective solvated radii calibrated by the Nightingale method showed that picrate ion seems to be unsolvated and that iodide ion seems to be solvated to some extent in the mixtures.

• Applied Chemistry for Engineering
• /
• v.19 no.2
• /
• pp.209-213
• /
• 2008

The fixed bed gasification reactor with 1 m hight and 10.2 cm diameter was utilized for the hydrogen production from biomass wastes. Lauan sawdust was used for non-catalytic and catalytic gasification reaction as a sample in the fixed bed reactor. The fixed bed temperature and catalyst are the major variables affecting the process operation. Thus, the effect of fixed bed temperature and the catalysts on gas composition were studied at the temperature range from $400^{\circ}C$ to $700^{\circ}C$. The yield of hydrogen was increased at higher temperature in the fixed bed reaction. Fractions of hydrogen, carbon monoxide and methane gas in the product gas increased when sodium carbonate ($Na_2CO_3$) and potassium carbonate ($K_2CO_3$) catalysts were used. Furthermore, sodium carbonate catalyst was more effective to obtain higher hydrogen yield compared to potassium carbonate catalyst.