• Korean Journal of Food Science and Technology
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• v.21 no.4
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• pp.461-467
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• 1989

The effect of $CO_2$ concentration on the post-harvest physiology and quality of Shiitake mushroom (Lentinus edodes) were investigated during CA storage. The respiratory rates of the mushroom stored in CA conditions were abruptly increased in proportion to $CO_2$ concentration after 40 days, and then declined, while that of the mushroom in air was continuously decreased throughout storage period. Large amounts of ethanol and acetaldehyde were produced from the 20 days CA stored mushrooms. The least changes in 5'-GMP content and electrophoresis pattern of protein in the mushroom were observed at $CO_2$ concentration of 2% during storage. Based on the changes in quality factors of the mushroom during storage, it could be concluded that $CO_2$ concentration of 2% with fixed $O_2$ concentration of 2% was more effective in extension of the freshness than any other $CO_2$ level in this experiment.

• Food Science and Preservation
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• v.9 no.2
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• pp.144-147
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• 2002

This study was conducted to investigate the effect of sub-ingredients of kimchi on the formation of carbon dioxide and vessel pressure. The pH, titratable acidity, formation of carbon dioxide and vessel pressure of kimchi prepared with different sub-ingredients were determined during storage at 10$^{\circ}C$. In the kimhi without GA, the pH decrease and acidity increase was slow during storage, but those of the kimchis without Gl, RP and SA were began to higher from 3th day after storage showed maximum values and was maintained 9th day after storage. The main sub-ingredient for formation of carbon dioxide was garlic and the gas formation was low in the kimchi without garlic. Vessel pressure in kimchi of the latter term of storage generally showed sub-atmospheric pressure and the more formation of carbon dioxide showed the more degree of sub-atmosphere.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.1053-1056
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• 2008

Permeability coefficient of concrete is a substantial key parameter for understanding the durability performance of concrete and its micro-structural densification. Many researches to deal with the issue have been accomplished, however, it is very rare to deal with the theoretical study on permeability coefficient in connection with carbonation of concrete and the effect of volumetric fraction of cement paste or aggregate on the permeability coefficient. The majority of these researches have not dealt with this issue combined with carbonation of concrete, although carbonation can significantly impact on the permeability coefficient of concrete. The purpose of this study is to establish a fundamental approach to compute the permeability coefficient of (non)carbonated concrete. When simulating micro-structural characteristics as a starting point for deriving a model for the permeability coefficient by the numerical simulation program for cementitious materials, HYMOSTRUC, a more realistic formulation can be achieved. For several compositions of cement pastes, the permeability coefficient is calculated with the analytical formulation, followed by a microstructure-based model. Emphasis is on the micro-structural changes and its effective change of the permeability coefficient of carbonated concrete. The results of micro-structural water permeability coefficient model will be compared with results achieved from permeability experiments.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.501-504
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• 2008

A concrete carbonation model has been constructed that takes account of the diffusion of carbon dioxide through a coating and reaction with calcium hydroxide, and this model has been validated by an accelerated carbonation experiment. (1) By using values for the coatings calculated on the basis of a diffusion.permeation theory as input data for the analysis of diffusion.reaction carbonation in an unsteady state, the effect of the coatings in reducing carbonation can be represented with high accuracy. (2) Through a sensitivity analysis of the diffusion.reaction carbonation model and the experimental results, we found that the diffusion coefficient of calcium hydroxide shows a high interrelationship at 1e-12($m^2/s$). The reaction rate constant for carbonation shows a high interrelationship at 5e-5($m^3/mol/s$).

• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.6
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• pp.123-129
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• 2018

Recently, there has been a growing interest in the study of treatment of $CO_2$ generated by industrial activities and resource recycling of industrial byproducts. The aim of this study is to investigate the applicability of industrial byproducts that can be used as concrete mixed materials by carbonation curing. For this purpose, the physical and chemical changes of the pastes with research cement(RC), blast furnace slag powder (GGBFS) and circulating fluidized bed combustion ashes (CFBC) were evaluated by carbonation curing. XRD and SEM analyzes were performed to investigate micro-structural changes. As a result, it was confirmed that calcium carbonate, which is a reaction product produced by carbonation curing, filled the space inside the paste and formed a dense micro-structure. Also, as the $CO_2$ curing time increased, it was confirmed that calcium carbonate crystals were grown together to form a dense micro-structure.

• Resources Recycling
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• v.26 no.1
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• pp.37-42
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• 2017

It has been reported that aqueous indirect carbonation process of calcium silicate mineral could be one of the most promising methods for $CO_2$ sequestration. The process consists of two main steps, extraction of Ca from calcium silicate and carbonation of the extracted solution by $CO_2$. Many types of acids such as HCl and $HNO_3$ can be used in the extraction step of the process. In the case of using aqueous acetic acid solution as the extraction solvent, acetic acid can be reproduced at the carbonation step of the extracted solution by $CO_2$ and recycled to extraction step for reuse it. Industrial by-products such as iron and steel slags are potential raw materials of the indirect carbonation process due to their high contents of calcium silicate. In this study, in order to examine the extraction efficiency of domestic electric arc furnace steel slag by aqueous acetic acid solution, extraction experiments of the slag were performed by using the aqueous acetic acid solutions of varying extraction conditions ; acetic acid concentrations, extraction temperatures and times.

• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.5
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• pp.119-127
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• 2010

This paper provides a new approach for durability prediction of reinforced concrete structures exposed to carbonation. In this method, the prediction can be updated successively by a Bayes' theorem when additional data are available. The stochastic properties of model parameters are explicitly taken into account in the model. To simplify the procedure of the model, the probability of the durability limit is determined based on the samples obtained from the Latin Hypercube Sampling(LHS) technique. The new method may be very useful in design of important concrete structures and help to predict the remaining service life of existing concrete structures which have been monitored. For using the new method, in which the prior distribution is developed to represent the uncertainties of the carbonation velocity using data of concrete structures(3700 specimens) in Korea and the likelihood function is used to monitor in-situ data. The posterior distribution is obtained by combining a prior distribution and a likelihood function. Efficiency of the LHS technique for simulation was confirmed through a comparison between the LHS and the Monte Calro Simulation(MCS) technique.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.24 no.3
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• pp.389-399
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• 2019

The calcium carbonate saturation state in the Ulleung Basin of East Sea was calculated using bottle data set of pH, dissolved inorganic carbon and total alkalinity obtained from the year 1999, 2014, 2017, and 2018 cruise. In the 2010s calcium carbonate saturation state was significantly lowered at all depth compared to the 1999 reference state. Accordingly calcite saturation horizon and aragonite saturation horizon shoaled to 500 m and 200 m, respectively. A key chemical species for the calcium carbonate saturation state, carbonate ion showed distinctive profile between upper and deep waters: it is moderately high (${\sim}175{\mu}mol\;kg^{-1}$) in upper waters and very low (< ${\sim}50{\mu}mol\;kg^{-1}$) in the deep waters. However the decreasing trend of carbonate ion concentration was pronounced in the upper water than deep waters, suggesting atmospheric $CO_2$ penetration is largely confined to the upper waters in the 2000s.

• Journal of the Korean Recycled Construction Resources Institute
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• v.6 no.4
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• pp.259-266
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• 2018

In the work, the carbonation behavior and strength characteristics in cold-joint concrete are evaluated for OPC(Ordinary Portland Cement) and GGBFS(Ground Granulated Blast Furnace Slag)concrete considering three levels of curing age (28, 91 and 365 days). The compressive strength in GGBFS concrete is level of 86% of OPC concrete at the 91 days of curing period, but is level of 107% at 365 curing days due to hydration reaction. Carbonation velocities in both OPC and GGBFS concrete significantly decease after 91 curing days. The effect of cold joint on carbonation is evaluated to be small in GGBFS concrete. The increasing ratios of carbonation velocity in cold joint are 1.06 and 1.33 for 28-day and 365-day curing condition, respectively. However they decreases to 1.08 and 1.04 for GGBFS concrete for the same curing conditions.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.5
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• pp.222-228
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• 2019

In this study, we carried out the experiment to prepare lithium carbonate powder through gas-liquid reactions with a lithium-containing solution and $CO_2$ gas using lithium hydroxide, lithium chloride, and lithium sulfate. Thermodynamically, the carbonation reaction of a lithium-containing solution showed that aqueous reaction of lithium hydroxide occurs spontaneously, but aqueous reactions of lithium chloride and lithium sulfate does not occur spontaneously. In the case of lithium hydroxide solution, the recovery rate of lithium carbonate was 69.8 % at room temperature ($25^{\circ}C$), and increased to 89.4 % at $60^{\circ}C$. In the case of lithium chloride and lithium sulfate solution, lithium carbonate could be prepared using sodium hydroxide as an additive, but the recovery rates were 19.2 % and 16.7 %, respectively.