• Title/Summary/Keyword: 탄산화 속도

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An Experimental Study on Engineering Properties of Self-healing Mortar according to PCC(Powder Compacted Capsule) Size and Mixing Ratio (PCC(Powder Compacted Capsule) 크기 및 혼입율에 따른 자기치유 모르타르의 공학적 특성에 관한 실험적 연구)

  • Jae-In, Lee;Chae-Young, Kim;Se-Jin, Choi
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.514-522
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    • 2022
  • In this study, as part of a study to improve the self-healing performance of concrete structures by applying self-healing capsules made of cementitious materials to cement composite materials, the engineering characteristics of mortars according to PCC(Powder Compacted Capsule) size and mixing ratio were compared and analyzed. For this, fluidity, compressive strength, reload test, carbonation, ultrasonic velocity, and water permeability characteristics were measured according to PCC size and mixing ratio of mortar. As a result of the measurement, the fluidity and compressive strength increased as the mixing ratio of PCC increased, and in the case of the load reload test, the healing ratio increased as the mixing ratio of PCC increased in the 03PC formulation. In the case of water permeability test, it was found that when PCC was used, the reduction ratio of water flow was up to 35 % higher than that of Plain, and when PCC with a size of 0.3 to 0.6 mm was mixed with 15 %, it was found to be effective in improving the crack healing ratio of the mortar.

Comparative Modeling of Low Temperature Char-CO2 Gasification Reaction of Drayton Coal by Carbon Dioxide Concentration (이산화탄소 농도에 따른 드레이톤 탄의 저온 차-이산화탄소 가스화반응 모델링 비교)

  • Park, Ji Yun;Lee, Do Kyun;Hwang, Soon Cheol;Kim, Sang Kyum;Lee, Sang Heon;Yoon, Soo Kyung;Yoo, Ji Ho;Lee, Si Hyun;Rhee, Young Woo
    • Clean Technology
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    • v.19 no.3
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    • pp.306-312
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    • 2013
  • We investigated the effects of the concentration of carbon dioxide on the char-$CO_2$ gasification reaction under isothermal conditions of $850^{\circ}C$ using the Drayton coal. Potassium carbonate was used to improve the low-temperature gasification reactivity. The enhancement of carbon dioxide concentration increased the gasification rate of char, while gasification rate reached a saturated value at the concentration of 70%. The best $CO_2$ concentration for gasification is determined to be 70%. We compared the shrinking core model (SCM), volumetric reaction model (VRM) and modified volumetric reaction model (MVRM) of the gas-solid reaction models. The correlation coefficient values, by linear regression, of SCM are higher than that of VRM at low concentration. While the correlation coefficients values of VRM are higher than that of SCM at high concentration. The correlation coefficient values of MVRM are the highest than other models at all concentration.

A Study on the Synthesis of Calcium Lactate Using Precipitated Calcium Carbonate (침강성 탄산칼슘을 이용한 젖산칼슘 합성에 관한 연구)

  • Park, Joo-Won;Cho, Kye-Hong;Park, Jin-Koo;Ahn, Ji-Whan;Han, Choon
    • Applied Chemistry for Engineering
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    • v.19 no.2
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    • pp.173-178
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    • 2008
  • Calcium lactate was prepared by reacting lactic acid with precipitated calcium carbonate (PCC) which was prepared by carbonation process (calcite) and solution process (aragonite). Effects of PCC morphology (calcite and aragonite) on calcium lactate by the solution process were investigated experimentally. Despite the slow forming rate at the initial stage, the final yield of calcium lactate appeared higher when calcite was used. Therefore, the maximum yield of calcium lactate using aragonite was 85.0% and that using calcite was 88.7%, respectively. For both cases, the optimum temperature for the preparation appeared at around $60^{\circ}C$. Furthermore, the increase in lactic acid concentration over 2.0 mol% increased slurry viscosity and deteriorated mass transfer, which resulted in low yield of calcium lactate for both cases. SEM analyses showed that the prepared calcium lactate appeared as plate-like crystal form, irrespective of PCC morphologies, reaction temperatures, and concentrations of lactic acid.

Characteristic of Precipitated Metal Carbonate for Carbon Dioxide Conversion Using Various Concentrations of Simulated Seawater Solution (해수 농축수 내 금속 이온 농도에 따른 이산화탄소 전환 생성물의 특성연구)

  • Choi, Eunji;Kang, Dongwoo;Yoo, Yunsung;Park, Jinwon;Huh, Il-sang
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.539-546
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    • 2019
  • Global warming has mentioned as one of the international problems and these researches have conducted. Carbon Capture, Utilization and Storage (CCUS) technology has improved due to increasing importance of reducing emission of carbon dioxide. Among of various CCUS technologies, mineral carbonation can converted $CO_2$ into high-cost materials with low energy. Existing researches has been used ions extracted solid wastes for mineral carbonation but the procedure is complicated. However, the procedure using seawater is simple because it contained high concentration of metal cation. This research is a basic study using seawater-based wastewater for mineral carbonation. 3 M Monoethanolamine (MEA) was used as $CO_2$ absorbent. Making various concentrations of seawater solution, simulated seawater powder was used. Precipitated metal carbonate salts were produced by mixing seawater solutions and $rich-CO_2$ absorbent solution. They were analyzed by X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), and Thermogravimetric Analysis (TGA) and studied characteristic of producing precipitated metal carbonate and possibility of reusing absorbent.

Effect of Alkanolamine Additives on CO2 Absorption Rate and Salt Formation of K2CO3 Aqueous Solution (알카놀아민 첨가제가 K2CO3 수용액의 이산화탄소 흡수속도와 염 석출에 미치는 영향)

  • Moon, Cheol-Ho;Jung, Taesung;Cho, Chang Sin;Kim, Jong-Nam;Rhee, Young Woo
    • Clean Technology
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    • v.20 no.2
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    • pp.146-153
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    • 2014
  • In this study, the effect of alkanolamine additives, 2-amino-2-methyl-1-propanol (AMP) and 2-amino-2-methyl-1,3-propanediol (AMPD) on $CO_2$ absorption rate of $K_2CO_3$ solution and the formation of $KHCO_3$ crystals was investigated. The normalized $CO_2$ flux and the equilibrium $CO_2$ partial pressure were measured for 5 wt% additives and 30 wt% $K_2CO_3$ mixtures using a wetted-wall column unit at $40^{\circ}C$ and $60^{\circ}C$. Both additives showed the increased $CO_2$ absorption rate and lowered the equilibrium $CO_2$ partial pressure acting as promoters. Besides, AMPD which has two hydroxyl groups enhanced the formation of $KHCO_3$ solid product separated from the $CO_2$-rich solution from the results of batch cooling crystallization experiments.

CO2 Fixation by Magnesium Hydroxide from Ferro-Nickel Slag (페로니켈 슬래그로 부터 제조된 Mg(OH)2를 이용한 CO2 고정화)

  • Song, Hao-Yang;Seo, Jong-Beom;Kang, Seong-Kuy;Kim, In-Deuk;Choi, Bong-Wook;Oh, Kwang-Joong
    • Clean Technology
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    • v.20 no.1
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    • pp.42-50
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    • 2014
  • In this study, the $Mg(OH)_2$ slurry was made form ferro-nickel slag and then used for $CO_2$ sequestration. The experiments were in the order as leaching step, precipitation, carbonation experiments. According to the leaching results, the optimal leaching conditions were $H_2SO_4$ concentration of 1 M and the temperature of 333 K. In the $Mg(OH)_2$ manufacturing step, NaOH was added to increase the pH upto 8, the first precipitation was confirmed as $Fe_2O_3$. After removal the first precipitation, the pH was upto 11, the $Mg(OH)_2$ was generated by XRD analysis. The $Mg(OH)_2$ slurry was used for $CO_2$ sequestration. The pseudo-second-order carbonation model was used to apply for $CO_2$ sequestration. The $CO_2$ sequestration rate was increased by the $CO_2$ partial pressure and temperature. However, $CO_2$ sequestration rate was decreased when temperature upto 323 K. After $CO_2$ sequestrated by $Mg(OH)_2$, the $CO_2$ can be sequestrated stable as $MgCO_3$. This study also presented optimal sequestration condition was the pH upto 8.38, the maximum $MgCO_3$ can be generated. This study can be used as the basic material for $CO_2$ sequestration by ferro-nickel slag at pilot scale in the future.

Combustion Characteristics of Spruce Wood by Pressure Impregnation with Waterglass and Carbon Dioxide (물유리와 이산화탄소로 가압함침한 가문비 나무의 연소특성)

  • Park, Hyung-Ju;Lee, Se-Myeoung
    • Fire Science and Engineering
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    • v.26 no.4
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    • pp.18-23
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    • 2012
  • After produce the extracted wood to silicic acid gel, sodium carbonate and silicon dioxide with application of the making method for carbon dioxide, ignition time, ignition temperature, mass loss rate and critical heat flux are measured according to external radiation source (20, 25, 35 and 50 $kW/m^2$). From the results, pressure impregnation wood to use with water glass and carbon dioxide has fire retardant performance at heat flux (less than 20 $kW/m^2$) of Pre-Flashover fires. If we find out the excellent maxing ratio through continuously study, it might be decided to be able to be utilized as fire-retardant wood.

Solid state reaction between Titanjum dixide and Barium Carbonate (이산화 티타늄 ($TiO_2$) 과 탄산 바륨 ($BaCO_3$) 간의 고체상태 반응)

  • Lee, Sang-Beom;Son, Byeong-Chan
    • The Journal of Natural Sciences
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    • v.1
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    • pp.33-45
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    • 1987
  • $BaCO_3$ 와 다양한 입자크기의 $TiO_2$ 의 고체상태 반응을 산소 ( 혹은 공기 ) 와 이산화탄소 중에서 열중량 분석법 (TG) 과 시차 열분석법 (DTA) 를 이용하여 반응속도론 및 반응기구를 조사하였다. 중간생성물과 최종생성물의 확인은 X-ray 회절 분석법 (XRD) 을 이용하였다. $TiO_2$ 의 반응성은 입자의 크기가 $0.15\mum$이하일 때 현저히 증가하였다. 반응초기에 $BaTiO_3$ 는 반응물의 접촉표면에서 생기기 시작하며 반응의 진행과정은 Jander 에 따라 확산조절과정이 된다. 반응과정에서 BaO-$TiO_2$ 의 상평형도에 기술된 화합물들이 중간물질로써 나타난다. 공기중에서는 상당한 양의 $Ba_2$$TiO_4$ 가 생성되지만 $CO_2$ 의 분위기에서는 약 $1100^{\circ}C$까지 억제된다. 이 온도는 열역학적 계산치인 $1060\pm$ $50^{\circ}C$와 잘 일치하고 있다. 확산과정의 활성화 에너지 값은 공기중에서는 56.4Kcal/mol 이었으며 이산화탄소의 경우에서는 79.6Kacl/mol 이었다.

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A Study on Poisoning of the Reforming Catalysts on the Position of Anode in the Direct Internal Reforming Molten Carbonate Fuel Cell (직접 내부개질형 용융탄산염 연료전지의 음극판 위치에 따른 개질 촉매 피독에 관한 연구)

  • Wee, Jung Ho;Chun, Hai Soo
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.652-659
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    • 1999
  • The trend of poisoning of reforming catalyst along with the position of anodic catalyst bed was studied. Keeping the conditions that steam to carbon ratio was 2.5, operating voltage was 0.75 V, current density was $140mA/cm^2$, the unit cell was operated during 24 hrs at a steady state. And then the cell was stopped, the catalysts packed in the position of inlet, middle and outlet were sampled individually and then the amount of carbon, Li and K poisoned were analysed. After 100 hrs operated, the catalysts at the same positions were analysed at the same manner. The result of this experiment was as followings. After 24 hrs operated, the poisoning amounts of Li and K in the catalyst were 0.27 wt% at inlet, 0.23 wt% at middle and the highest value 1.59 wt% at outlet. After 100 hrs, the amount of poisoning is the highest in the catalyst packed at the inlet of unit cell. The performance simulation of unit cell explained these trends of poisoning catalysts. The simulation told that the catalyst in the region of the inlet of unit cell treated the 90% of initial methane flow rate and the highest electrochemical reaction happened in this region. So the catalysts of this region were the most poisoned with carbon, Li and K and also the rate of poisoning is faster than that of the catalyst at other regions. The temperature at the region of outlet of unit cell was $30^{\circ}C$ higher than that of other regions, so more Li, and K vaporized than at other regions and little reforming reaction at this region made the catalysts poisoning rate low.

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오일샌드 저류층 지질특성화를 위한 기초연구 소개

  • Choe, Jae-Yong;Kim, Dae-Seok;Gwon, Lee-Gyun;Jeong, Gong-Su
    • 한국지구과학회:학술대회논문집
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    • 2010.04a
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    • pp.106-106
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    • 2010
  • 오일샌드는 비투멘(bitumen), 물, 점토, 모래의 혼합체로 이루어진 비재래형 탄화수소 자원으로 세계적인 고유가 시대에 큰 관심을 받고 있는 석유자원 중 하나이다. 오일샌드는 대부분이 캐나다 앨버타주에 분포하고 있으며 주요 저류층으로는 아스바스카(Athabasca), 콜드레이크(Cold Lake) 지역의 멕머레이층(McMurray Formation), 클리어워터층(Clearwater Formation), 그랜드래피드층(Grand Rapid Formation)과 피스리버(Peace River) 지역의 블루스카이층(Bluesky Formation), 게팅층(Gathing Formation)이 있다. 오일샌드 저류층은 고생대 탄산염 기반암 위에 하성-에스츄어리에 이르는 다양한 퇴적환경에서 형성되어 매우 복잡한 지질특성이 나타난다. 오일샌드 저류층의 효율적인 개발을 위해서는 저류층의 복잡한 지질학적 특성의 이해가 반드시 필요하다. 본 연구에서 캐나다 오일샌드 시추코어 분석 DB, 물리검층 자료, 현장 및 현생 시추코어를 통하여 오일샌드 저류층의 지질특성화 정보의 도출을 시도하였다. 우선 캐나다 앨버타 전역에 분포하는 시추공의 기본 정보(표고, 위경도, 층서별 최상부 심도, 생산광구명, 광구개발업체)를 제공하는 AccuMap DB 프로그램을 이용하여 광역적인 오일샌드 저류층의 분포 특성을 이해하고자 주요층서에 대한 고지형도 및 층후도를 생산광구별로 도면화하여 분석하였다. 또한 캐나다 ENCANA사와 국제공동연구의 일환으로 확보된 크리스티나 레이크(Christina Lake)광구의 현장 시추코어를 이용하여 코어의 상세기재, 비파괴 물성측정, 입도/비투멘 함유량 분석과 같은 다양한 실내 시추코어분석 실험을 수행 중이다. 비파괴 물성측정은 현장 시추코어의 물리적/화학적 특성을 파악하고자 MSCL(Multi sensor core logger)과 XRF 코어 스캐너(X-ray fluorescence core scaner)를 통해 이루어지며, 분석결과로 시추코어의 감마밀도(gamma density), P파 속도(P-wave velocity), 전기비저항(resistivity), 대자율(magnetic susceptibility) 및 색지수의 물성과 정량적 화학조성을 측정한다. 현장 시추코어의 일부는 유기용매를 이용하여 퇴적물 내의 비투멘을 완전히 추출하고 퇴적물 입도와 저류층 비투멘 함유량 측정에 이용되었다. 현장 시료 분석 결과들은 물리검층 자료와 대비를 통하여 저류층의 지질특성을 규명하는 연구에 이용될 예정이다. 마지막으로 오일샌드의 현생 유사 퇴적환경으로 알려진 서해 경기만 조간대에서 시추코어 퇴적물을 획득하여 상세 기재하였으며, 이를 통해 오일샌드 저류층의 퇴적 모델을 제시하고자 퇴적층서 연구를 진행 중이다. 향후 오일샌드 관련 시추코어의 분석 결과들이 종합되면 기존 보다 비투멘 회수효율을 향상시킬 수 있는 정밀한 오일샌드 저류층 지질모델을 수립할 수 있을 것으로 기대된다.

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