• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.2
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• pp.151-157
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• 2019

Concrete bridge constructed in metropolitan cities has different superstructure members like slabs and girders, and their carbonation depths vary with different design strengths and local environmental conditions. In this paper, 54 concrete cores were obtained from prestressed concrete girders and the related tests were performed for compressive strength and carbonation depth measurement. Referred to the specified compressive strength of 24MPa for slab and 35MPa for I-type girder, the strengths from cores were evaluated to 82% and 73% of design grade, respectively. For carbonation depth, the slab member showed 30.6mm of average with 32.9% of COV(Coefficient of Variation) and I-type girder showed 16.7~17.0mm with 22.8~33.6 of COV. The I-type girder has much lower carbonation depth and COV compared to slab member, however it has higher COV than column structures.

• Journal of the Korea Concrete Institute
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• v.24 no.3
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• pp.315-322
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• 2012

Alkali-activated slag (AAS) is the most obvious alternative materials that can replace OPC. But, AAS industrial usage as a structural material should be evaluated for its durability. Carbonation resistance is one of the most important factors in durability evaluation. Test results for 18 slag-based mortars activated by sodium silicate and 6 OPC mortars were obtained in this study to verify the carbonation property. Main variables considered in the study were flow, compressive strength before and after carbonation, and carbonation depth. Mineralogical and micro-structural analysis of OPC and AAS specimens prior to and after carbonation was conducted using XRD, TGA, FTIR FE-SEM. Test results showed that CHS was major hydration products of AAS and, unlike OPC, no other hydration products were found. After carbonation, CSH of hydration product in AAS turned into an amorphous silica gel, and alumina compounds was not detected. From the analysis of the results, it was estimated that the micro-structures of CSH in AAS easily collapsed during carbonation. Also, the results showed that this collapse of chemical chain of CSH lowered the compressive strength of concrete after carbonation. By increasing the dosage of activators, carbonation resistance and compressive strength were effectively improved.

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.301-302
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• 2009

Uncertainties in carbonation process of concrete structures are treated by probability-based durability analysis for carbonation using Monte Carlo simulation technique. The results requires the minimum cover thickness of 53mm for 10% of corrosion probability under 4mm/$year^{0.5}$ of carbonation coefficient. The more researches on statistical properties of design variables may give reliable durability analysis/design methods for carbonation of concrete structures.

• Journal of the Korea Concrete Institute
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• v.19 no.5
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• pp.613-621
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• 2007

Due to the increasing significance of durability, much researches on carbonation, one of the major deterioration phenomena are carried out. However, conventional researches based on fully hardened concrete are focused on prediction of carbonation depth and they sometimes cause errors. In contrast with steel members, behaviors in early-aged concrete such as porosity and hydrates (calcium hydroxide) are very important and may be changed under carbonation process. Because transportation of deteriorating factors is mainly dependent on porosity and saturation, it is desirable to consider these changes in behaviors in early-aged concrete under carbonation for reasonable analysis of durability in long term exposure or combined deterioration. As for porosity, unless the decrease in $CO_2$ diffusion due to change in porosity is considered, the results from the prediction is overestimated. The carbonation depth and characteristics of pore water are mainly determined by amount of calcium hydroxide, and bound chloride content in carbonated concrete is also affected. So Analysis based on test for hydration and porosity is recently carried out for evaluation of carbonation characteristics. In this study, changes in porosity and hydrate $(Ca(OH)_2)$ under carbonation process are performed through the tests. Mercury Intrusion Porosimetry (MIP) for changed porosity, Thermogravimetric Analysis (TGA) for amount of $(Ca(OH)_2)$ are carried out respectively and analysis technique for porosity and hydrates under carbonation is developed utilizing modeling for behavior in early-aged concrete such as multi component hydration heat model (MCHHM) and micro pore structure formation model (MPSFM). The results from developed technique is in reasonable agreement with experimental data, respectively and they are evaluated to be used for analysis of chloride behavior in carbonated concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 2009.05a
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• pp.259-260
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• 2009

Many concrete structures have suffered from carbonation or chloride ion diffusion induced reinforcement corrosion, and a number of studies have been done on these topics. Many studies were mostly confined to the single deterioration of carbonation or chloride ion, although the environment actually presents a combined condition. This paper tried to develop the approach to compute re-diffusion of de-sorbed chloride due to carbonation of concrete. This is a key for successful combined deterioration model of carbonation and chloride. It is thought that this paper can contribute to express mathematically chloride enrichment and re-diffusion of chloride at front of carbonation.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.4
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• pp.349-354
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• 2023

This study wa s conducted a s pa rt of ma ximizing the use of ca rbon dioxide by a pplying CCU(Ca rbon Ca pture, Utiliza tion) a mong technologies for reducing CO₂ in the cement industry. In a carbon dioxide curing environment, changes in carbonation depth and changes in basic physical properties by age due to the mixing of carbonation reaction accelerators were usually targeted at Portland cement paste. In addition, in order to check the fixed amount of CO₂ in the concrete field, a thermal analysis method was applied to evaluate CaCO₃ decarbonization at high temperatures. As a result of the evaluation, it was confirmed that the carbonation depth in the cured body significantly increased due to the incorporation of CRA in the carbonation depth diffusion performance. In addition, it was confirmed that the weight reduction rate increased by 23.8 % and 40.77 %, respectively, compared to Plain, in the order of curing conditions for constant temperature and humidity and curing conditions for carbonation chambers, so it was confirmed that the amount of excellent CaCO₃ produced by the addition of CRA increased as the concentration of CO₂ increased.

• Resources Recycling
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• v.29 no.4
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• pp.58-66
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• 2020

Carbonation (step I) and cryo-crystallization (crystallization at low temperature) (step II) were performed to synthesize Na compounds from sodium concentrated solution. In the step 1, the solubility and pH of carbon dioxide (95 wt.%) affecting carbonation could be changed by the variation of reaction temperature. The step II was performed at 2 ℃ after carbonation. The injection of carbon dioxide was carried out twice for the stable production and the saturated solubility of carbonate ions in solution. Firstly, we tried to inject CO₂ for controlling the solubility of CO₂ by changing the reaction temperature from 35 ℃ to 10 ℃, and the second injection was aimed at 10 ℃ for inducing nucleation of Na compound through carbonation after NaCl solution addition. In the cryo-crystallization step, the crystal growth of Na compounds could be induced by slowing the carbonation rate through reaction temperature change from 10 ℃ to 2 ℃. In this study, the effect on NaOH concentration was examined and the purity of Na compound was increased when 2M NaOH was used. In addition, the synthesized Na compounds were mostly rod-shaped and consisted of sodium carbonate or sodium carbonate with monohydrate.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.4
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• pp.220-227
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• 2021

PCT (Power Cable Tunnel) and UT (Utility Tunnel), which are non-transport underground infrastructures, are mostly RC (Reinforced Concrete) structures, and their durability decreases due to the deterioration caused by carbonation over time. In particular, since the rate of carbonation varies by use and region, a predictive model based on actual carbonation data is required for individual maintenance. In this study, a carbonation prediction model was developed for non-transport underground infrastructures, such as PCT and UT. A carbonation prediction model was developed using multiple regression analysis and deep neural network techniques based on the actual data obtained from a safety inspection. The structures, region, measurement location, construction method, measurement member, and concrete strength were selected as independent variables to determine the dependent variable carbonation rate coefficient in multiple regression analysis. The adjusted coefficient of determination (Ra2) of the multiple regression model was found to be 0.67. The coefficient of determination (R2) of the model for predicting the carbonation of non-transport underground infrastructures using a deep neural network was 0.82, which was superior to the comparative prediction model. These results are expected to help determine the optimal timing for repair on carbonation and preventive maintenance methodology for PCT and UT.

• Journal of the Korea Concrete Institute
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• v.22 no.2
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• pp.209-217
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• 2010

Recently, some mathematical models for the prediction on progress of carbonation of concrete were reported. These models take account for $CO_2$ diffusion and chemical reaction between $Ca(OH)_2$ and $CO_2$. Based on the assumption that $CO_2$ diffuses in the carbonation zone and reacts with $Ca(OH)_2$ at the outer face of carbonation zone and non-carbonation zone. In this study, a mathematical model to predict the progress of carbonation of concrete has been established based on the reducing concentration of $Ca(OH)_2$ in the carbonation progress zone, where $Ca(OH)_2$ reacts with $CO_2$ and $Ca(OH)_2$ and $CaCO_3$ coexist. Also, the prediction model of carbonation progress rate of concrete using the air permeability coefficient regarding to $CO_2$ diffusion is developed. As a result of this study, an expression, the model equation is obtained for the prediction of carbonation based on the time and interaction velocity between $CO_2$ and Ca(OH)$_2$ dependent air permeability coefficient. The prediction by the model satisfied the experimental data of the accelerated carbonation for painted concrete. Consequently, the model can predict the rate of carbonation and the potential service life of concrete structure exposed to atmosphere.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.6
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• pp.45-52
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• 2019

Steel corrosion due to carbonation in RC (Reinforced Concrete) structures easily occurs in urban cities with high CO₂ concentration. RC structures are always subjected to external loading with various boundary conditions. The induced stress level causes changes in diffusion of harmful ion like CO₂. In this work, a quantification of carbonation progress with stress level is carried out and carbonation prediction is derived through the relations. Determining the design parameters like cover depth, CO₂ diffusion coefficient, carbonatable materials, and exterior CO₂ concentration as random variables, service lifes under carbonation with design parameter's variation are obtained through MCS(Monte Carlo Simulation). Additionally the service life with different stress level is derived and the results are compared with those from deterministic method. Cover depth and cement hydrates are evaluated to be very effective to resist carbonation, and the proposed method which can consider the effect of stress on service life can be applied to maintenance priority determination.