• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.05a
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• pp.292-296
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• 2003

Autoclaving처리를 하지 않은 키토산과 autoclaving처리한 키토산과의 중금속 흡착실험을 해 본 결과 다음과 같은 결과를 도출 할 수 있었다. 1) 먼저 중금속간의 흡착능을 고찰하기 위하여 Langmuir와 Freundlich 흉착등온식에 적용시켜 본 결과 Freundlich 흡착등온식 보다는 Langmuir 흡착등온식이 보다 적합한 것으로 나타났다. 2) 시간에 따라서 autoclaving 처리한 키토산의 중금속 제거 가능성과 그 효율을 검토하기 위하여 각 중금속간의 Langmuir 흡착등온식을 이용하여 $q_{max}$를 나타냈다. 15 min > 60 min > 0 min 순으로 모든 중금속 제거 실험에서 15 min 동안 autoclaving 처리한 키토산의 중금속 흡착량이 가장 높은 것으로 나왔다. 그러므로 기존의 키토산 보다는 15 min동안 autoclaving 처리한 키토산이 중금속 제거에 더 좋은 흡착제로써 역할을 할 수 있을 것으로 판단된다. 3) 키토산을 이용한 중금속 제거에서는 $Pb^{2+}$ > $Cd^{2+}$ > $Cu^{2+}$ > $Cr^{3+}$순서로 제거가 되었다. 여러 연구자들의 실험 결과를 종합해 볼 때 Pb$^{2+}$가 중금속 중에 제거가 잘 된다는 연구 결과가 많이 발표 되었으며, $Cd^{2+}$, $Cu^{2+}$, $Cr^{3+}$의 경우에는 흡착제의 종류에 따라서 제거되는 순서가 다르다는 연구 결과들이 보고 되고 있다. 그러나 어떠한 이유로 중금속의 제거에 차이가 있는지에 대해서는 명확한 결론이 내려져 있지 않는 실정이다. 이러한 중금속간의 경쟁적인 관계에 대해 더 많은 세밀한 연구가 이루어져야 할 것 같다.는 0.52mg/$\ell$~0.99mg/$\ell$~의 범위이었다. 신천에 금호강물을 혼합한 이후에도 부유물질, 생화학적산소요구량, 암모니아태 질소, 총인 등의 농도가 개선되지 않았다. 즉 금호강물의 혼합은 신천수질환경사업소에서 배출되는 방류수에 함유되어 있을 2차 오염물질의 희석이라는 이점외의 수질개선효과는 확인되지 않았다.l years and a new type of transfer crane has been developed. Design concepts and control methods of a new crane will be introduced in this paper.and momentum balance was applied to the fluid field of bundle. while the movement of′ individual material was taken into account. The constitutive model relating the surface force and the deformation of bundle was introduced by considering a representative prodedure that stands for the bundle movement. Then a fundamental equations system could be simplified considering a steady state of the process. On the basis of the simplified model, the simulation was performed and the results could be confirmed by the experiments under various conditions.뢰, 결속 등 다차원의 개념에 대한 심도 깊은 연구와 최근 제기되고 있는 이론

• Korean Journal of Organic Agriculture
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• v.19 no.1
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• pp.121-134
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• 2011

For this study, Smilex powder, a pesticide, was sprayed on the Altari radish, and then underground water, Chitosan solution (${\times}$500), and wood vinegar solution (${\times}$1000) were evenly sprayed on the Altari radish respectively. Samples of Altari radishs for residual pesticide analysis were taken two hours, 1 day, 7 days, and 15 days after treatments, and the detectable concentration and degradability of procymidone, the pesticide residue, were measured. The results obtained are as follows: 1. When detectable concentration of procymidone within the altari radish was measured, treatment plots sprayed with underground water, Chitosan solution (${\times}$500), and wood vinegar solution (${\times}$1000) were found to show lower detectable concentration than the non-treatment plot which was sprayed with pesticide only. Especially, the treatment plots sprayed with Chitosan solution (${\times}$500), and with wood vinegar solution (${\times}$1,000) showed lower values than the average. 2. When the degradability of procymidone within the Altari radish was measured, the plot treated with Chitosan solution (${\times}$500) and the plot treated with wood vinegar solution (${\times}$1,000) were found to have relatively higher degradability of procymidone. There were not much differences among testing materials in the degradability of residual pesticides. However, the plot treated with Chitosan solution (${\times}$500) showed higher degradability. In terms of average degradability with time, degradability increased sharply 7 days after the foliar application of testing materials. 3. When the daily far-sighted view survey was conducted in order to find out growth disorder and damage on the Altari radish plants by the treatment of un-derground water, Chitosan solution (${\times}$500), and wood vinegar solution (${\times}$1,000), no symptomatic physiological disorders was observed on all the plants tested during the whole growing season at the tested concentration level.

• Horticultural Science & Technology
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• v.17 no.4
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• pp.481-484
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• 1999

This experiment was conducted to examine the effects of chitosan and sucrose on the vase life of cut rose (Rosa hybrida L. cv. Cardinal). Addition of 5 mg/L chitosan and 3% sucrose to the holding solution prolonged the vase life for 3 days as compared to the control, and improved quality of cut rose in flower diameter and fresh weight. Development of bent-neck was delayed by supply of 2 mg/L or 5 mg/L chitosan and 3% sucrose about 2 or 3 days. When 3% sucrose was added to the holding solution, the rate of water absorption more slowly decreased compared to the other treatments.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2012.03a
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• pp.59-59
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• 2012

의류용 섬유제품은 고유의 기능인 보온성을 비롯하여, 태나 착용감, 또는 패션에 부응하는 다양한 성능이 요구되고 있다. 섬유 직물의 보온기능은 경량 보온과 축열 보온 그리고 발열 등이 중요한 기능으로 인식되고 있으며 특히 적극적인 보온성이 요구된다. 본 연구에서는 그 개선책으로서 패션소재표면에 상전이물질을 코팅하여 보온성을 조사했다. 상전 이물질 (PCM,Phase change materials) 입자를 DSC분석기로 측정하여 열거동을 관찰하였고, 실크직물과 실크혼방 직물에 PCM과 키토산을 농도별로 처리하여 보온성 테스트와 SEM을 측정하였다. 실크직물과 실크혼방 직물에 PCM과 키토산 처리하여 직물의 보온성을 측정해 본 결과, 실크직물 9.1% 실크혼방 직물은 29.9%로 실크혼방 직물이 실크직물보다 우수한 보온성을 보였다. SEM 관찰에서도 실크직물과 실크혼방 직물의 표면에 PCM입자의 침투정도도 확연한 차이를 보였다. 이를 미루어 볼 때 실크직물보다 실크혼방 직물에 PCM과 키토산을 처리하였을 경우 우수한 보온성을 보인다고 생각된다.

• Korean Journal of Food Science and Technology
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• v.35 no.3
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• pp.410-416
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• 2003

Effects of calcium and chitosan treatments on storage and quality of pork were investigated. Porks were coated with 1% each of 30 and 120 kDa chitosans in 3% gelatin solution. Self-life and antioxidation increased significantly in all samples. In contrast with non-treated group, pH of the chitosan-treated group was very stable. Moisture content and water activity (Aw) were similar among all samples. Water-holding capacity decreased slightly, whereas cooking loss increased, during storage in all samples. Value of redness increased in chitosan-coated pork. Tenderness of pork injected with calcium was the highest among all samples. These results showed that preservation and quality of pork were improved by the treatment of calcium and 30 kDa of chitosan.

• Proceedings of the Korean Society for Bio-Environment Control Conference
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• 2001.04b
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• pp.65-66
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• 2001

제주도의 감자재배면적은 전국의 30.6%를 차지하고 있으며 본도 제2의 소득작물로 자리잡고 있는데 최근 국내외적으로 친환경농산물에 대한 관심이 고조됨에 따라 안전농산물에 대한 수요가 늘면서 유기농업자제를 이용한 고품질 안전 농산물을 생산하려는 시도가 늘어가고 있다. 이런 관점에서, 키토산을 \circled1토양처리 (1kg/a), \circled2키토산침지 (0.2%/30분), \circled3토양처 리＋생육기처리 100배 (2회), \circled4토양처리＋생육기처리 200배 (2회), \circled5생육기처리 100배 (2회), \circled6생육기처리＋200배 (2회), \circled7무처리로 구분하여 시험하였다. 발아율은 대조구에 비해서 종서침지, 토양관주＋생육기 200배처리, 생육기 200배처리한 것이 다소 높은 편이었고, 경장 경수 및 복지수는 시일이 경과할수록 많은 편이고 그 중에서 종서침지가 가장 양호한 편이었다. 그리고 10a당 총수량, 상서수량 및 설서수량(30g이하인 괴경)은 역시 종서침지, 토양관주＋생육기 200배 (2회)처리 및 토양관주＋생육기 100배처리 순서로 상서수량이 많은 편이었다. 처리별 상서수량은 종서침지한 것이 71%, 29%로 가장 많았고 토양관주＋생육기 100배처리한 것이 대조구보다 많은 경향이었다(Table 1).

• Journal of the Korean Society of Clothing and Textiles
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• v.33 no.12
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• pp.1873-1882
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• 2009

Hospital patient clothing material was treated with a mixture of chitosan in order to enhance functionality, such as the durability and dimensional stability of the cotton fabric used. Chitosan is a natural polymer with excellent biocompatibility, however there is a deteriorating adherence efficiency. The addition of a nanosilver colloidal solution in accordance with a prescribed ratio can further increase the performance of chitosan. Changes in the structural characteristics and physical properties of the chitosan/nanosilver treated fabric were observed in a comparison with fabric treated only with chitosan. The add-on ratio increased when the mixing ratio of nanosilver colloidal solution was higher; however, the crystalline structure of the treated fabric remains similar. In the case of CH3/NS1 treated fabric (where the mixing ratio of chitosan and nanosilver solution was 3:1) the K/S value, whiteness index, wet tensile strength, and wrinkle recovery angle were superior. The dimension stability, pilling resistance, and abrasion resistance of the fabric treated with a mixed solution increased in comparison to the fabric treated only with chitosan. The chitosan/nanosilver treated cotton fabric used for patient clothing material has excellent physical properties.

• Food Science and Industry
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• v.53 no.1
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• pp.69-83
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• 2020

For the development of the chitosan industry in Korea, the catch of red snow crabs caught on the east coast is rapidly decreasing. Therefore, it is urgent to develop raw materials that can replace the red snow crab as the top priority to solve the supply and demand problems, as well as wastewater treatment costs account for a large proportion of the cost of chitosan. In order to solve the problems, continuous research on biological extraction methods such as enzymatic extraction and microbial fermentation will increase production efficiency and lower unit cost as well as chemical extraction methods. Further efficient manufacturing method can be established. Establishing of novel techniques is indispensable for production of high-purity chitosan and the ability to regulate and separate the molecular weight, as well as joint research with industry, academia and research institute for the research and development of high-functional chitosan derivatives.

• Proceedings of the KAIS Fall Conference
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• 2011.05b
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• pp.937-940
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• 2011

물/유기용매의 혼합용액에 키토산을 분산시키고 이 현탁액에 글리시딜 트리알킬 암모늄염, 글리시딜 아릴염 등의 에테르 시약을 상온에서 현탁상태로 반응시켜 4급화 키토산을 제조하는 새로은 방법을 개발하였다. 이 방법으로 합성한 결과 수득율이 90%이상이었으며 후처리과정이 필요없었다. 4급화 키토산의 균에 대한 최소저지농도(MIC)를 조사한 결과 E. coli O157:H7 균주의 MIC는 0.007%-0.01%(70-100ppm)로 추정되었고 V. vulnificus 균주의 MIC는 0.005%(50ppm)정도이고 V.vulnificus 균주의 MIC는 0.007%(70ppm)이었다. 작물에 대한 항균성을 알아보기 위하여 4N-키토산의 항균 활성만이 검정되었는데, 4N-키토산은 고추 역병균인 P. capsici에 대하여 가장 높은 항균 활성을 보여 4,000 ppm에서부터 키토산 무첨가 대조구에 비하여 항균활성을 보였으며 P. capsici보다는 약하지만 잿빛곰팡이병균 B. cinerea에 대하여도 약간의 항균 활성을 보이고 있어, 16,000 ppm에서는 항균서이 뚜렷이 나타났으나 고추 탄저병균인 C. gloeosporioides에 대해서는 16,000 ppm 이라는 높은 농도에서도 항균 활성을 전혀 보이고 있지 않았다.

• Korean Journal of Food Science and Technology
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• v.32 no.1
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• pp.218-224
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• 2000

The antimicrobial activities of chitosan oligosaccharide(chitohexaose) and two types of chitosans M.W.(10,000 and M.W. 100,000) were examined against Escherichia coli O157 : H7(ATCC 43894), Staphylococcus aureus(ATCC 144458) and Candida albicans(KFRI 432). Chitosan with molecular weight of 10,000 showed the strongest antimicrobial activities to E. coil O157 : H7 and S. aureus, whereas chitohexaose acted most strongly against C. albicans. The most effective concentration of chitosan was measured to be 0.1 mg/mL for E. coil O157 : H7 and S. aureus, and that of chitohexaose to be 1 mg/mL for C. albicans. Antimicrobial activities of chitosans and chitohexaose were maintained for 60 min after their treatment. They were found to induce leakage of intracellular proteins and nucleic acids from treated microorganisms. The efflux determined by assaying the ${\beta}-galactosidase$ leaked from the lactose-induced E. coli O157 : H7 cells was observed to reach the highest level within 60 min after treatment with the antimicrobial agents and chitosan with 10,000 molecular weight gave the highest ${\beta}-galactosidase$ activity. Therefore, it is supposed that the antimicrobial activity of chitosan with its unique polycationic nature might be caused by its binding to anionic component(s) of the cell envelope and thereby inhibiting the membrane metabolism and/or leaking intracellular materials.